均质纤维素膜的制备及其正渗透性能研究

张兵涛1、张林2、黄和()1、侯立安2,3

中国工程科学 ›› 2014, Vol. 16 ›› Issue (7) : 57-61.

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PDF(2443 KB)
中国工程科学 ›› 2014, Vol. 16 ›› Issue (7) : 57-61.

均质纤维素膜的制备及其正渗透性能研究

  • 张兵涛1、张林2、黄和()1、侯立安2,3

作者信息 +

Preparation and performance of homogeneous cellulose forward osmosis membrane

  • Zhang Bingtao1,Zhang Lin2,Huang He1,Hou Li'an2,3

Author information +
History +

摘要

以纤维素(cellulose)为膜材料,离子液体1-乙基-3 甲基咪唑醋酸盐(EMIMAc)为溶剂,水为非溶剂,无纺布作为支撑层,通过相转化法制备了纤维素均质膜。采用红外、X-射线衍射和扫描电子显微镜表征了膜的结构及形貌,考察了该膜的正渗透性能。结果表明:纤维素溶解再生过程中没有发生化学变化,但晶型发生了转变;当原料液为0.6 mol/L 的氯化钠水溶液,汲取液为特制的营养液时,所制备的正渗透膜的水通量为3.534 L/(m2· h),截盐率达到99 %以上。

Abstract

The nonporous homogeneous cellulose membrane for forward osmosis was prepared via phase inversion method using ionic liquid 1-ethyl-3-methyl-imidazolium acetate (EMIMAc) as solvent, water as nonsolvent on a non-woven fabric substrate. The characterizations of Fourier transform infrared (FTIR) and X-ray diffraction (XRD) spectroscopies showed that no obvious change occurred in the chemical structure of cellulose after membrane formation, but the crystallinity had a certain degree of decline. The cross-section and the surface morphologies of the cellulose forward osmosis membrane were analyzed by scanning electron microscopy (SEM). The membrane performance were investigated by measuring water flux and rejection of simulated seawater. The water flux of the cellulose forward osmosis membrane, which the cellulose concentration is 8 %(wt) in casting solution, was 3.534 L/m2.h and the rejection for NaCl was more than 99 %, using 0.6 mol/L NaCl solution as the feed solution and lab-made nutrient solution as the draw solution.

关键词

正渗透 / 离子液体 / 纤维素膜 / 相转化 / 膜制备

Keywords

forward osmosis / ionic liquid / cellulose membrane / phase inversion / membrane preparation

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导出引用
张兵涛,张林,黄和,侯立安. 均质纤维素膜的制备及其正渗透性能研究. 中国工程科学. 2014, 16(7): 57-61

参考文献

基金
国家自然科学基金重点资助项目(51238006);广东顺德科技计划资助项目(2013CXTD08)
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