There are complicatedly interdependent and interactional relationships in Energy-Economy- Environment-Ecology (4E) compounded system, and the coordinated development of 4E system is the final goal of sustainable social development. In this paper, on the basis of game theory and collaborative analysis of the development of 4E system, and according to the people-oriented principle, we construct a distinct evaluation index system of 4E development by Analytic Hierarchy Process (AHP), and work out the coupling coordination degree of 4E system by coordination coefficient method. Through empirical study, the coordinating evaluation model and the corresponding calculating method can quantitatively express the status of coordination development of 4E system, which provides the decision-making basis to coordinated 4E development.