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《中国工程科学》 >> 2013年 第15卷 第3期

辽河流域水环境沉积物质量风险评估

中国环境科学研究院国家环境保护河口与海岸带环境重点实验室,北京 100012

资助项目 :国家水体污染控制与治理科技重大专项(2009ZX07528-002) 收稿日期: 2012-12-13 发布日期: 2013-03-15 14:18:30.000

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摘要

采集辽河流域浑河、太子河干流及大伙房水库共56个站点的表层沉积物样品,根据相平衡分配法的修正模型建立辽河流域沉积物重金属质量基准(Cu、Pb、Zn、Cd的SQC(基于CCC)分别为75.26 μg/g、25.72 μg/g、255.96 μg/g、2.52 μg/g),依据重金属急、慢性生物毒性风险确定辽河流域沉积物重金属质量三级标准,并创建沉积物质量风险评估方法——沉积物污染指数法(SPI),对辽河流域水环境进行沉积物质量风险评估,评估结果显示:浑河干流中下游、太子河中上游及大伙房水库库中、库尾处的沉积物质量状况为中风险,此沉积物重金属污染状况使长期生活在其中的底栖生物受到轻微重金属慢性毒性影响,其中浑河中游红透山铜矿处和细河上游沈阳工业区的沉积物质量风险极高。

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参考文献

[ 1 ] 黄延林. 沉积物中重金属释放动力学及试验研究[J]. 环境科学 学报,1995,15(4):440-446. 链接1

[ 2 ] Adams W J,Kimerle R A,Barnett J W. Sediment quality and aquatic life assessment[J]. Environmental Science Technology, 1992,26(10):1865-1875. 链接1

[ 3 ] 陈静生,王飞跃. 关于水体沉积物质量基准问题[J]. 环境化学, 1992,11(3):60-70. 链接1

[ 4 ] Vanderkooij L A,Vandement D,Vanleeuwen C J,et al. Deriving quality criteria for water and sediment from the results of aquatic toxicity tests and product standards:application of the equilibrium partitioning method[J]. Water Research,1991, 25(6):697-705. 链接1

[ 5 ] Webster J,Ridgway I. The application of the equilibrium partitioning approach for establishing sediment quality criteria at two UK sea disposal and outfall sites[J]. Marine Pollution Bulletin, 1994,28(11):653-661. 链接1

[ 6 ] 陈云增,杨 浩,张振克,等. 水体沉积物环境质量基准建立方 法研究进展[J].地球科学进展,2006 ,21(1):53-61. 链接1

[ 7 ] Rauret G F,Lopez-Sanchez J,Sahuquillo A,et al. Improvement of the BCR three step sequential extraction procedure prior to the certification of new sediment and soil reference materials [J]. Journal of Environmental Monitoring,1999,1(1):57-61. 链接1

[ 8 ] Davidson C M,Thomas R P,McVey S E,et al. Evaluation of a sequential extraction procedure for the speciation of heavy metals in sediments[J]. Analytical Chimical Acta,1994,291(3): 277-286. 链接1

[ 9 ] Quevauviller P,Rauret G,López-Sánchez J F,et al. Certification of trace metal extractable contents in a sediment reference material(CRM 601)following a three-step sequential extraction procedure[J]. Science of the Total Environment,1997,205(2- 3):223-234. 链接1

[10] Umoren I,Udoh A,Udousoro I,et al. Concentration and chemical speciation for the determination of Cu,Zn,Ni,Pb and Cd from refuse dump soils using the optimized BCR sequential extraction procedure[J]. The Environmentalist,2007,27(2): 241-252. 链接1

[11] United States Environmental Protection Agency. Briefing report to the EPA Science Advisory Board on the equilibrium partitioning approach togenerating sediment quality criteria[R]. Washington D. C.:EPA2440252892002,1989. 链接1

[12] National Oceanic and Atmospheric Administration. The utility of AVS/EqP in hazardous waste site evaluations[R]. Washington D. C.:NOSORCA 87,Seattle,1995.

[13] 孟 伟,张 远,郑丙辉. 水环境质量基准、标准与流域水污 染物总量控制策略[J]. 环境科学研究,2006,19(3):1-6. 链接1

[14] United States Environmental Protection Agency. Office of Water of Science and Technology,Draft implementation framework for the use of equilibrium partitioning sediment quality guideline[R]. Washington D. C.:2000,4217.

[15] Burton G A,Jr. Sediment sampling and analysis plan- West Branch G rand Calumet River 1993 sediment toxicity test data summaries [R]. USA:United States Environmental Protection Agency,1993.

[16] Chapman P M,Wang F,Adams W J,et al. Appropriate applications of sediment quality values for metals and metalloids[J]. Environmental Science and Technology,1999,33(22):3937- 3941. 链接1

[17] Hansen D J,Berry W J,Mahony J D,et al. Predicting the toxicity of metal contaminated field sediments using interstitial concentrations of metals and acid-volatile sulfide normalizations[J]. Environmental Toxicology and Chemistry,1996,15(12): 2080-2094. 链接1

[18] United States Environmental Protection Agency. National recommended water quality criteria correction[R]. Washington D. C.:United States Environmental Protection Agency,1999.

[19] United States Environmental Protection Agency. National recommended water quality criteria[R]. EPA 822-R-02-047,2002.

[20] 夏 青,陈艳卿,刘宪兵. 水质基准与水质标准[M]. 北京:中 国标准出版社,2004.

[21] 方 涛,徐小清. 应用平衡分配法建立长江水系沉积物金属 相对质量基准[J]. 长江流域资源与环境,2007,16(4):525-531. 链接1

[22] 邓保乐,祝凌燕,刘 慢,等. 太湖和辽河沉积物重金属质量 基准及生态风险评估[J]. 环境科学研究,2011,24(1):33-42. 链接1

[23] Chapman P M,Allard P J,Vigers G A. Development of sediment quality values for Hong Kong special administrative region:A possible model for other jurisdictions[J]. Marine Pollution Bulletin,1997,38(3):161-169. 链接1

[24] 霍文毅,陈静生. 我国部分河流重金属水-固分配系数及在河 流质量基准研究中的应用[J]. 环境科学,1997,4:10-13. 链接1

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