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ASSESSMENT OF HEAVY METALS IN HYDROCHAR PRODUCED BY HYDROTHERMAL CARBONIZATION OF DAIRY MANURE

《农业科学与工程前沿（英文）》 2023年第10卷第3期页码 437-447 doi: 10.15302/J-FASE-2023507

摘要：

● Content of heavy metals in hydrochar varies considerably, from 50% to 100%.

关键词： heavy metals dairy manure hydrochar hydrothermal carbonization waste management

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Co-pyrolysis of sludge and kaolin/zeolite in a rotary kiln: Analysis of stabilizing heavy metals

《环境科学与工程前沿（英文）》 2022年第16卷第7期 doi: 10.1007/s11783-021-1488-1

摘要：

• Adding kaolin/zeolite promotes the formation of stable heavy metals.

关键词： Co-pyrolysis Sewage sludge Heavy metals Rotary kiln Immobilization mechanism

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Predicting non-carcinogenic hazard quotients of heavy metals in pepper (

Marzieh Mokarram, Hamid Reza Pourghasemi, Huichun Zhang

《环境科学与工程前沿（英文）》 2020年第14卷第6期 doi: 10.1007/s11783-020-1331-0

摘要： Abstract • There was significant absorption of heavy metals by the pepper in contaminated soils. • The target hazard quotient (THQ) indices followed the order of Pb>Zn>>Cd » Ni. • Relationships exist between contaminated plants and electromagnetic wave. • PCA and random search can select the main spectra and predict THQ for each element. Given the tendency of heavy metals to accumulate in soil and plants, the purpose of this study was to determine the contamination levels of Cd, Ni, Pb, and Zn on peppers (leaves and fruit) grown in contaminated soils in industrial centers. For this purpose, we measured the uptake of the four heavy metals by peppers grown in the heavy metal contaminated soils throughout the four growth stages: two-leaf, growth, flowering, and fruiting, and calculated various vegetation indices to evaluate the heavy metal contamination potentials. Electromagnetic waves were also applied for analyzing the responses of the target plants to various heavy metals. Based on the relevant spectral bands identified by principal component analysis (PCA) and random search methods, a regression method was then employed to determine the most optimal spectral bands for estimating the target hazard quotient (THQ). The THQ was found to be the highest in the plants contaminated by Pb (THQ= 62) and Zn (THQ= 5.07). The results of PCA and random search indicated that the spectra at the bands of b570, b650, and b760 for Pb, b400 and b1030 for Ni, b400 and b880 for Cd, and b560, b910, and b1050 for Zn were the most optimal spectra for assessing THQ. Therefore, in future studies, instead of examining the amount of heavy metals in plants by chemical analysis in the laboratory, the responses of the plants to the electromagnetic waves in the identified bands can be readily investigated in the field based on the established correlations.

关键词： Heavy metals Plants Target Hazard Quotient (THQ) Principal Component Analysis (PCA) Random search Electromagnetic wave

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Effect of lime on speciation of heavy metals during composting of water hyacinth

Jiwan SINGH,Ajay S. KALAMDHAD

《环境科学与工程前沿（英文）》 2016年第10卷第1期页码 93-102 doi: 10.1007/s11783-014-0704-7

摘要： Composting is attractive and inexpensive method for treatment and biomass disposal of water hyacinth. However, the major disadvantage of water hyacinth composting is the high content of heavy metals in the final compost. Addition of lime sludge significantly reduced most bioavailable fractions (exchangeable and carbonate) of heavy metals. Studies were carried on composting of water hyacinth ( ) with cattle manure and sawdust (6:3:1 ratio) and effects of addition of lime (1%, 2% and 3%) on heavy metal speciation were evaluated during 30 days of composting period. The Tessier sequential extraction method was employed to investigate the changes in speciation of heavy metals such as Zinc (Zn), Copper (Cu), Manganese (Mn), Iron (Fe), Lead (Pb), Nickel (Ni), Cadmium (Cd) and Chromium (Cr) during water hyacinth composting. Effects of physicochemical parameters such as temperature, pH and organic matter on speciation of heavy metals were also studied during the process. Results showed that, the total metal content was increased during the composting process. The higher reduction in bioavailability factor (BF) of Cu, Fe, Ni, Cd and Cr was observed in lime 2 treatment about 62.1%, 64.4%, 71.9%, 62.1% and 58.9% respectively; however higher reduction in BF of Zn and Pb was observed in lime 1 treatment during the composting process. Reducible and oxidizable fractions of Ni, Pb and Cd were not observed during the process. Addition of lime was very effective for reduction of bioavailability of heavy metals during composting of water hyacinth with cattle manure and sawdust.

关键词： composting lime heavy metals bioavailability factor speciation

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Human health ambient water quality criteria for 13 heavy metals and health risk assessment in Taihu Lake

《环境科学与工程前沿（英文）》 2022年第16卷第4期 doi: 10.1007/s11783-021-1475-6

摘要：

• The concentrations of 13 heavy metals in Taihu Lake were analyzed.

关键词： Heavy metals Human health ambient water quality criteria Taihu Lake Health risk assessment Contribution rate

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Re-evaluation of several heavy metals removal by natural limestones

Ali SDIRI,Samir BOUAZIZ

《化学科学与工程前沿（英文）》 2014年第8卷第4期页码 418-432 doi: 10.1007/s11705-014-1455-5

摘要： Different treatment technologies have been efficiently applied to remove heavy metals from wastewater. Efforts have been made to find out the most economic water treatment technology by using low cost and easily accessible natural materials. On the other hand, heavy metals are the most threatening groundwater contaminants because of their toxicity and harmful effects on human and biota. This review discusses the use of natural geological materials for heavy metal removal in aqueous systems. Special attention has been devoted to natural limestone through a systematic inventory of relevant published reports. The removal of toxic metals may include different mechanisms (e.g., physisorption, chemisorptions, precipitation, etc.), depending on the physico-chemical properties of the material and the removed metal. Sorption of toxic metals (e.g., Pb, Cu, Cd, Zn, Cr, Hg, etc.) onto natural limestone involved precipitation of metal carbonate as a predominant removal process, but often subordinated by adsorption and ion exchange, depending on the physico-chemical properties of the studied limestone.

关键词： limestone heavy metals sorption wastewater passive treatment technology

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An overview of carbon nanotubes role in heavy metals removal from wastewater

Leila Ouni, Ali Ramazani, Saeid Taghavi Fardood

《化学科学与工程前沿（英文）》 2019年第13卷第2期页码 274-295 doi: 10.1007/s11705-018-1765-0

摘要： The scarcity of water, mainly in arid and semi-arid areas of the world is exerting exceptional pressure on sources and necessitates offering satisfactory water for human and different uses. Water recycle/reuse has confirmed to be successful and promising in reliable water delivery. For that reason, attention is being paid to the effective treatment of alternative resources of water (other than fresh water) which includes seawater, storm water, wastewater (e.g., dealt with sewage water), and industrial wastewater. Carbon nanotubes (CNTs) are called the technology of 21st century. Nowadays CNTs have been widely used for adsorption of heavy metals from water/wastewater due to their unique physical and chemical properties. This paper reviews some recent progress (from 2013 to 2018) in the application of CNTs for the adsorption of heavy metals in order to remove toxic pollutants from contaminated water. CNTs are expected to be a promising adsorbent in the future because of its high adsorption potential in comparison to many traditional adsorbents.

关键词： carbon nanotubes heavy metals removal water treatment

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Joint effects of Penta-BDE and heavy metals on

Baohua TANG, Lingyan ZHU, Qixing ZHOU

《环境科学与工程前沿（英文）》 2011年第5卷第1期页码 99-110 doi: 10.1007/s11783-010-0260-8

摘要： The joint toxicity of Penta-BDE (Pe-BDE) and heavy metals including cadmium and copper on ( ) was evaluated on the basis of determining the 48 h survival, antioxidative enzyme responses, and lipid peroxidation. The response was classified as additive, greater than additive, or less than additive by comparing the measured “toxic units, TU” with one. Based on the survival of , less-than-additive interactions were found in most of mixtures treatments. This may be attributed to the different toxicity mechanism between Pe-BDE and metals. Cu and Cd played a greater role in toxicity than what Pe-BDE did. As for the superoxide dismutase (SOD) and catalase (CAT) activity, most response was less than additive. For the glutathione -transferases (GST) activity, most of the greater-than-additive responses were found in the Cu plus Pe-BDE treatments, but the additive responses occurred in Cd plus Pe-BDE treatments and binary metal treatments. For lipid peroxide levels, which were measured as malondialdehyde (MDA) levels, less-than-additive response occurred in the 50% Cd plus 50% Cu and ternary mixture treatments. Results suggested that Pe-BDE, Cd, and Cu could induce different patterns of antioxidant enzyme responses, such as antioxidant/prooxidant responses, depending on their capability to produce reactive oxygen species and antioxidant enzymes to detoxify them.

关键词： polybrominated diphenyl ethers (PBDEs) heavy metal mixture toxicity toxic units (TUs) antioxidant enzyme lipid peroxidation

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A 50-year sedimentary record of heavy metals and their chemical speciations in the Shuangtaizi River

Baolin LIU, Ke HU, Zhenglong JIANG, Fengge QU, Xin SU

《环境科学与工程前沿（英文）》 2011年第5卷第3期页码 435-444 doi: 10.1007/s11783-011-0352-0

摘要： Two parallel sediment cores collected from tidal flat located in the Shuangtaizi River estuary were analyzed for heavy metal concentrations and chemical speciations. Based on the Cs activity profile, mean sedimentation rate at the sampling site during the past 50 years was estimated to be 1.3 cm·a . Correlation analyses show that almost all the metals are associated with each other, suggesting that these metals might be derived from same sources and/or affected by same geochemical processes. Influence of total organic carbon (TOC) content on the concentrations of Cr, Ni, Cu and Cd is evident. Silt and clay contents, instead of sand content, play an important role in the distribution of these metals. The dominant binding phases for most of the metals (except for Cd) are the residual. The relative decrease of the residual fraction of Cd and Pb in the upper 66 cm of the core is striking. The distribution of chemical fraction confirms that the residual fractions of these metals have a natural origin, while only the non-residual fractions of Cd and Pb increased upward the core due to pollution in the past five decades. Pollution assessment on these heavy metals based on Index of Geoaccumulation ( ) also demonstrates that most of the metals are unpolluted. The weak pollution as observed in the sediments is perhaps related to a local plant, the Kitag, which may have played a significant role in the biodegradation of these metals and the metal distribution in the estuary.

关键词： Shuangtaizi River estuary sediment core heavy metals pollution

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Reduced texaphyrin: A ratiometric optical sensor for heavy metals in aqueous solution

Harrison D. Root, Gregory Thiabaud, Jonathan L. Sessler

《化学科学与工程前沿（英文）》 2020年第14卷第1期页码 19-27 doi: 10.1007/s11705-019-1888-y

摘要： We report here a water-soluble metal cation sensor system based on the as-prepared or reduced form of an expanded porphyrin, texaphyrin. Upon metal complexation, a change in the redox state of the ligand occurs that is accompanied by a color change from red to green. Although long employed for synthesis in organic media, we have now found that this complexation-driven redox behavior may be used to achieve the naked eye detectable colorimetric sensing of several number of less-common metal ions in aqueous media. Exposure to In(III), Hg(II), Cd(II), Mn(II), Bi(III), Co(II), and Pb(II) cations leads to a colorimetric response within 10 min. This process is selective for Hg(II) under conditions of competitive analysis. Furthermore, among the subset of response-producing cations, In(III) proved unique in giving rise to a ratiometric change in the ligand-based fluorescence features, including an overall increase in intensity. The cation selectivity observed in aqueous media stands in contrast to what is seen in organic solvents, where a wide range of texaphyrin metal complexes may be prepared. The formation of metal cation complexes under the present aqueous conditions was confirmed by reversed phase high-performance liquid chromatography, ultra-violet-visible absorption and fluorescence spectroscopies, and high-resolution mass spectrometry.

关键词： texaphyrin fluorescent sensor ion-sensing indium mercury

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Efficient removal of heavy metals from electroplating wastewater using polymer ligands

Md. Lutfor RAHMAN,Shaheen M. SARKAR,Mashitah Mohd YUSOFF

《环境科学与工程前沿（英文）》 2016年第10卷第2期页码 352-361 doi: 10.1007/s11783-015-0783-0

摘要： Poly(hydroxamic acid)-poly(amidoxime) chelating ligands were synthesized from poly(methyl acrylate-co-acrylonitrile) grafted acacia cellulose for removing toxic metal ions from industrial wastewaters. These ligands showed higher adsorption capacity to copper (2.80 mmol?g ) at pH 6. In addition, sorption capacities to other metal ions such as iron, zinc, chromium, and nickel were also found high at pH 6. The metal ions sorption rate (t ) was very fast. The rate of adsorption of copper, iron, zinc, chromium, nickel, cobalt, cadmium and lead were 4, 5, 7, 5, 5, 8, 9 and 11 min, respectively. Therefore, these ligands have an advantage to the metal ions removal using the column technique. We have successfully investigated the known concentration of metal ions using various parameters, which is essential for designing a fixed bed column with ligands. The wastewater from electroplating plants used in this study, having chromium, zinc, nickel, copper and iron, etc. For chromium wastewater, ICP analysis showed that the Cr removal was 99.8% and other metal ions such as Cu, Ni, Fe, Zn, Cd, Pb, Co and Mn removal were 94.7%, 99.2%, 99.9%, 99.9%, 99.5%, 99.9%, 95.6% and 97.6%, respectively. In case of cyanide wastewater, the metal removal, especially Ni and Zn removal were 96.5 and 95.2% at higher initial concentration. For acid/alkali wastewater, metal ions removing for Cd, Cr and Fe were 99.2%, 99.5% and 99.9%, respectively. Overall, these ligands are useful for metal removal by column method from industrial wastewater especially plating wastewater.

关键词： heavy metals adsorption wastewater chelating ligands plating industry

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Distribution and potential ecological risk of heavy metals in the typical eco-units of Haihe River Basin

Jingling LIU,Tao YANG,Qiuying CHEN,Feng LIU,Binbin WANG

《环境科学与工程前沿（英文）》 2016年第10卷第1期页码 103-113 doi: 10.1007/s11783-014-0686-5

摘要： The distribution and characteristics of seven heavy metals in sediments located in the typical ecological units (eco-units) (e.g., rivers, lakes, and estuaries) of Haihe River Basin were analyzed. The Hakanson potential ecological risk index was used for ecological risk assessment. The results indicated that the concentration scales of As, Hg, Cr, Cd, Pb, Cu, and Zn in the eco-units were 2.08 to 24.80 mg·g , 0.01 to 1135.50 mg·g , 28.70 to 152.73 mg·g , 0.03 to 195765.83 mg·g , 8.65 to 157.82 mg·g , 6.47 to 178.61 mg·g , and 21.09 to 1076.25 mg·g , respectively. The maximum concentrations of Hg, Cd, and Zn showed higher levels than other water bodies around the world. Hg and Cd have high concentrations in Zhangweinanhe River (1135.50 and 195765.83 mg·g , respectively) and Haihe Estuary (790.50 and 548.47 mg·g , respectively). According to the ecological factor, Cd and Hg showed very strong ecological risks. The seven heavy metals, namely, Cd, Hg, As, Cr, Pb, Cu, and Zn, exhibited ecological risk levels in descending order. Based on the potential ecological risk index, Luanhe River and Baiyangdian Lake had moderate ecological risks, whereas every site in Zhangweinanhe River and Haihe Estuary had substantial risk levels. The risk order of the typical eco-units are as follows: Zhangweinan River (2278345.68)>Estuary (161914.74)>Luanhe River (191.54)>Baiyangdian Lake (120.95). These results provided a scientific basis for water environment improvement and risk management of the Haihe River Basin.

关键词： Haihe River Basin ecological risk eco-units heavy metals

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Current status and developing trends of the contents of heavy metals in sewage sludges in China

Jun YANG,Mei LEI,Tongbin CHEN,Ding GAO,Guodi ZHENG,Guanghui GUO,Duujong LEE

《环境科学与工程前沿（英文）》 2014年第8卷第5期页码 719-728 doi: 10.1007/s11783-013-0600-6

摘要： It is essential to determine the heavy metal concentrations in sewage sludge to select appropriate disposal methods. We conducted a national survey of heavy metal concentrations of sewage sludge samples from 107 municipal sewage treatment plants located in 48 cities covering the 31 provinces and autonomous regions, as well as Hong Kong, Macao and Taiwan by Xinjiang Production and Construction Corps in 2006, and identified the temporal trends of heavy metal contents in sewage sludge by comparison with surveys conducted in 1994–2001. In 2006, the average concentrations of As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn in sewage sludge were 20.2, 1.97, 93.1, 218.8, 2.13, 48.7, 72.3, and 1058 mg·kg , respectively. Because of the decreased discharge of heavy metals into industrial wastewater in China and the increasingly stringent regulations governing the content of industrial wastes entering sewers, the average concentrations of Cd, Cr, Cu, Hg, Ni, Pb, and Zn have decreased by 32.3%, 49.7%, 54.9%, 25.0%, 37.2%, 44.8%, and 27.0%, respectively, during the past 12 years. The concentrations of Cd, Cr, Cu, Ni, and Zn in the samples exceeded the heavy metal limits of the Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant in China (GB 18918-2002) by 6.5%, 3.7%, 6.5%, 6.5%, and 11.2%, respectively. From these results, 85 of the 107 municipal sludges analyzed would be considered suitable for land application.

关键词： sewage sludge heavy metals temporal variation national survey environmental policies

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Leaching characteristics of heavy metals during cement stabilization of fly ash from municipal solid

LIANG Shunwen, JIANG Jianguo, ZHANG Yan, XU Xin

《环境科学与工程前沿（英文）》 2008年第2卷第3期页码 358-363 doi: 10.1007/s11783-008-0060-6

摘要： The leaching characteristics of heavy metals in products of cement stabilization of fly ash from a municipal solid waste incinerator were investigated in this paper. The stabilization of heavy metals such as Cd, Pb, Cu, and Zn in fly ash from such incinerators was examined through the national standard method in China based on the following factors: additive quantity of cement and NaS, curing time, and pH of leaching liquor. The results showed that as more additives were used, less heavy metals were leached except for Pb, which is sensitive to pH of the leachate, and the worse effect was observed for Cd. The mass ratio of cement to fly ash = 10% is the most appropriate parameter according to the national standard method. When the hydration of cement was basically finished, stabilization of heavy metals did not vary after curing for 1 d. The mixtures of cement and fly ash had excellent adaptability to environmental pH. The pH of leachate was maintained at 7 when pH of leaching liquor varied from 3 to 11.

关键词： heavy national standard environmental leachate liquor

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Occurrence and health risk assessment of trace heavy metals via groundwater in Shizhuyuan Polymetallic

Bingbing XU,Qiujin XU,Cunzhen LIANG,Li LI,Lijia JIANG

《环境科学与工程前沿（英文）》 2015年第9卷第3期页码 482-493 doi: 10.1007/s11783-014-0675-8

摘要： The Shizhuyuan Polymetallic Mine in Chen-zhou City is an important multi-metal deposit in China. After a dam accident in 1985, there are still a number of mining plants, smelters and tailing ponds in this area. These had the potential to pollute the surrounding groundwater. In this study, groundwater samples were collected from 20 residents’ wells in this area during both dry and wet seasons. In particular, this study focused on the exposure and the health risk assessment of trace heavy metal in groundwater. Multiple statistical analysis and fuzzy comprehensive method were employed to reveal the distribution characteristics of heavy metal and to assess the groundwater quality. Results indicated that Cr, Fe, Ni, Cu, Zn, As, Cd, Ba, Hg and Pb were widespread with low exposure levels. There were 19 wells with low level exposure and one well with a moderate level exposure in the dry season. All of the wells were in low level exposure during the wet season. As and Mn exhibited potential non-carcinogenic concern, because their maximum hazard quotient (HQ) was higher than 1.0. This may cause adverse health effect on adults in dry season or on children in both seasons. Only As, showed that the maximum carcinogenic risk was more than 10 , suggesting a high cancer risk for children in both dry and wet seasons. Therefore, analysis and reduction the concentrations of As and Mn in groundwater are needed in order to protect the health of residents and especially children in the area.

关键词： groundwater heavy metal health risk assessment mine area

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标题作者时间类型操作

ASSESSMENT OF HEAVY METALS IN HYDROCHAR PRODUCED BY HYDROTHERMAL CARBONIZATION OF DAIRY MANURE

期刊论文

Co-pyrolysis of sludge and kaolin/zeolite in a rotary kiln: Analysis of stabilizing heavy metals

期刊论文

Predicting non-carcinogenic hazard quotients of heavy metals in pepper (

Marzieh Mokarram, Hamid Reza Pourghasemi, Huichun Zhang

期刊论文

Effect of lime on speciation of heavy metals during composting of water hyacinth

Jiwan SINGH,Ajay S. KALAMDHAD

期刊论文

Human health ambient water quality criteria for 13 heavy metals and health risk assessment in Taihu Lake

期刊论文

Re-evaluation of several heavy metals removal by natural limestones

Ali SDIRI,Samir BOUAZIZ

期刊论文

An overview of carbon nanotubes role in heavy metals removal from wastewater

Leila Ouni, Ali Ramazani, Saeid Taghavi Fardood

期刊论文

Joint effects of Penta-BDE and heavy metals on

Baohua TANG, Lingyan ZHU, Qixing ZHOU

期刊论文

A 50-year sedimentary record of heavy metals and their chemical speciations in the Shuangtaizi River

Baolin LIU, Ke HU, Zhenglong JIANG, Fengge QU, Xin SU

期刊论文

Reduced texaphyrin: A ratiometric optical sensor for heavy metals in aqueous solution

Harrison D. Root, Gregory Thiabaud, Jonathan L. Sessler

期刊论文

Efficient removal of heavy metals from electroplating wastewater using polymer ligands

Md. Lutfor RAHMAN,Shaheen M. SARKAR,Mashitah Mohd YUSOFF

期刊论文

Distribution and potential ecological risk of heavy metals in the typical eco-units of Haihe River Basin

Jingling LIU,Tao YANG,Qiuying CHEN,Feng LIU,Binbin WANG

期刊论文

Current status and developing trends of the contents of heavy metals in sewage sludges in China

Jun YANG,Mei LEI,Tongbin CHEN,Ding GAO,Guodi ZHENG,Guanghui GUO,Duujong LEE

期刊论文

Leaching characteristics of heavy metals during cement stabilization of fly ash from municipal solid

LIANG Shunwen, JIANG Jianguo, ZHANG Yan, XU Xin

期刊论文

Occurrence and health risk assessment of trace heavy metals via groundwater in Shizhuyuan Polymetallic

Bingbing XU,Qiujin XU,Cunzhen LIANG,Li LI,Lijia JIANG

期刊论文

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