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基于MTO生产策略的供应链联盟集成决策模型研究

梁樑,王志强,王国华,田俊峰,汤卫君

《中国工程科学》 2005年第7卷第5期页码 57-62

摘要：

根据供应链运作的特点提出了供应链绩效综合评价的四个标准，以此为基础建立了MTO生产策略下供应链联盟集成决策指派求解模型。

关键词： MTO 供应链绩效集成决策联盟博弈

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Effect of temperature in the conversion of methanol to olefins (MTO) using an extruded SAPO-34 catalyst

Ignacio Jorge Castellanos-Beltran, Gnouyaro Palla Assima, Jean-Michel Lavoie

《化学科学与工程前沿（英文）》 2018年第12卷第2期页码 226-238 doi: 10.1007/s11705-018-1709-8

摘要： The methanol-to-olefin (MTO) reaction was investigated in a bench-scale, fixed-bed reactor using an extruded catalyst composed of a commercial SAPO-34 (65 weight percentage, wt-%) embedded in an amorphous SiO matrix (35 wt-%). The texture properties, acidity and crystal structure of the pure SAPO-34 and its extruded form (E-SAPO-34) were analyzed and results indicated that the extrusion step did not affect the properties of the catalyst. Subsequently, E-SAPO-34 was tested in a temperature range between 300 and 500 °C, using an aqueous methanol mixture (80 wt-% water content) fed at a weight hour space velocity (WHSV) of 1.21 h . At 300 °C, a low conversion was observed combined with catalyst deactivation, which was ascribed to oligomerization and condensation reactions. The coke analysis showed the presence of diamandoid hydrocarbons, which are known to be inactive molecules in the MTO process. At higher temperatures, a quasi-steady state was reached during a 6 h reaction where the optimal temperature was identified at 450 °C, which incidentally led to the lowest coke deposition combined with the highest H/C ratio. Above 450 °C, surges of ethylene and methane were associated to a combination of H-transfer and protolytic cracking reactions. Finally, the present work underscored the convenience of the extrusion technique for testing catalysts at simulated scale-up conditions.

关键词： MTO SAPO-34 temperature extrusion coke light alkanes

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Effect of SiO

Qian WANG, Lei WANG, Hui WANG, Zengxi LI, Xiangping ZHANG, Suojiang ZHANG, Kebin ZHOU

《化学科学与工程前沿（英文）》 2011年第5卷第1期页码 79-88 doi: 10.1007/s11705-010-0550-5

摘要： A series of SAPO-34 molecular sieves with different SiO /Al O ratios have been synthesized for the methanol-to-olefin (MTO) reaction. Their physico-chemical properties are characterized by various techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FT-IR) and N adsorption-desorption. The results are compared with those of the commercial HZSM-5, which show that the crystallinity and particle diameter of SAPO-34 as well as HZSM-5 increase with SiO /Al O ratio. The variation of BET surface area of SAPO-34 is different from that of HZSM-5 and the sample with SiO /Al O ratio of 0.4 exhibits the highest BET surface area. FT-IR spectra indicate that HZSM-5 has both Br?nsted and Lewis acid sites and Br?nsted acid sites are stronger, whereas SAPO-34 samples are dominated only by Lewis acid sites. When the SiO /Al O ratio increases, propylene and butylenes become the predominant product of the MTO reaction over HZSM-5. In contrast, the main products of this reaction catalyzed by SAPO-34 are ethylene and propylene. According to the product distribution, the reaction mechanism over HZSM-5 catalysts is proposed.

关键词： HZSM-5 SAPO-34 methanol-to-olefin (MTO) SiO₂/Al₂O₃ ratio

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Organosilane surfactant-assisted synthesis of mesoporous SSZ-39 zeolite with enhanced catalytic performance in the methanol-to-olefins reaction

Hao Xu, Chi Lei, Qinming Wu, Qiuyan Zhu, Xiangju Meng, Daniel Dai, Stefan Maurer, Andrei-Nicolae Parvulescu, Ulrich Müller, Fengshou Xiao

《化学科学与工程前沿（英文）》 2020年第14卷第2期页码 267-274 doi: 10.1007/s11705-019-1845-9

摘要： SSZ-39 zeolite with AEI framework structure is a good catalyst candidate for the methanol-to-olefins (MTO) reaction. However, the diffusion limitation and coke formation often results in fast deactivation of the SSZ-39 zeolite catalyst. One solution for this challenge is to introduce mesoporosity in the SSZ-39 zeolite. Herein, we report the synthesis of mesoporous SSZ-39 zeolite using an organosilane surfactant, , -dimethyl- -(3-(trimethoxysilyl)propyl)octan-1-aminium chloride, as a mesopore template and , -dimethyl- -2,6-dimethylpiperidinium as a micropore template. The obtained zeolites were characterized by X-ray diffraction, N sorption, scanning electron microscopy, temperature programmed desorption of ammonia, and magic angle spinning nuclear magnetic resonance of Al. The results show that the mesoporous SSZ-39 zeolite has high crystallinity, meso/microporosity, high surface area, cuboid morphology, and abundant acidic sites. More importantly, this mesoporous SSZ-39 zeolite exhibits enhanced catalyst lifetime in the MTO reaction due to the presence of mesoporosity for fast mass transfer, compared with a conventional SSZ-39 zeolite without mesoporosity.

关键词： SSZ-39 zeolite mesopores organosilane surfactant MTO reaction soft template mass transfer