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期刊论文 15

会议视频 1

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2024 3

2023 4

2021 8

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MXene纳米片 1

保暖性能 1

光热转换 1

抗菌性能 1

武器系统；基于过程的建模（PBM）；作战场景；交互分析；元模型；Petri网 1

皮革涂层 1

矢量孤子；类噪声脉冲；MXene；光纤激光器 1

绿色化工 1

苯乙烯替代物 1

香草醛 1

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MXene supported PtCo bimetallic catalyst for hydrogen evolution in acidic conditions

《能源前沿（英文）》 2024年 第18卷 第3期   页码 369-377 doi: 10.1007/s11708-024-0925-9

摘要： Using the electrochemical technology to split water molecules to produce hydrogen is the key to obtain green hydrogen for solving the energy crisis. The large-scale application of hydrogen evolution reaction (HER) in water dissociation requires a highly active catalyst. In this paper, the highly dispersed PtCo bimetallic nanoparticles loading on MXene (PtCo/MXene) were prepared by using a step-to-step reduction strategy. The mentioned PtCo/MXene catalyst exhibits a high current density of −100 mA/cm2 in an acidic medium with just a 152 mV overpotential. In addition, the PtCo/MXene catalyst also displays a superior stability. Computational analysis and experimental testing demonstrate that the electronic interaction between Pt and Co can effectively modify the electronic structure of the active site, thereby enhancing the inherent catalytic performance of the material. More importantly, MXene two-dimensional nanosheets can expose more active sites because of their large specific surface area. Furthermore, MXene substrate with excellent electrical conductivity and harmonious interfaces between PtCo and MXene enhance charge transfer efficiency and lower the reaction activation energy.

关键词： MXene     PtCo bimetallic     hydrogen evolution reaction (HER)    

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Recent progress in the design and fabrication of MXene-based membranes

Kai Qu, Kang Huang, Zhi Xu

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 820-836 doi: 10.1007/s11705-020-1997-7

摘要： Two-dimensional membranes have attracted significant attention due to their superior characteristics, and their ability to boost both flux and selectivity have led to their reputation as potential next-generation separation membranes. Among them, emerging MXene-based membranes play significant roles in the competitive membrane-separation field. In this mini-review, we systematically discuss the assembly and separation mechanisms of these membranes. Moreover, we highlight strategies based on the crosslinking of MXene nanosheets and the construction of additional nanochannels that further enhance the permeabilities and anti-swelling properties of MXene-based membranes and meet the requirements of practical applications, such as gas-molecule sieving, ion sieving, and other small-molecule sieving. MXene nanosheets can also be used as additives that introduce specific functionalities into hybrid membranes. In addition, extended applications that use MXenes as scaffolds are also discussed.

关键词： MXene     2D materials     membranes     separation    

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Electroconductive RGO-MXene membranes with wettability-regulated channels: improved water permeability

《环境科学与工程前沿（英文）》 2023年 第17卷 第1期 doi: 10.1007/s11783-023-1601-8

摘要：

● Electroconductive RGO-MXene membranes were fabricated.

关键词： Reduced graphene oxide     MXene     Membrane     Water permeance     Dye rejection     Electro-assistance    

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Regularly channeled MXene membranes for ionic and molecular separation

Jingchong Liu, Nü Wang

《化学科学与工程前沿（英文）》 2021年 第15卷 第3期   页码 591-594 doi: 10.1007/s11705-020-1966-1

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Toughening of vinyl ester resins by two-dimensional MXene nanosheets

《化学科学与工程前沿（英文）》   页码 1651-1658 doi: 10.1007/s11705-022-2208-5

摘要： Two-dimensional nanosheets are highly effective tougheners for vinyl ester resins. The toughening effect is related to the high specific surface area and unique two-dimensional planar structure of the nanosheets. In this study, a coupling agent γ-(2,3-epoxypropoxy) propytrimethoxysilane (Kh-560) was used to modify MXene nanosheets (M-MXene) for use in toughening vinyl ester resin. The mechanical properties, including the tensile strength, flexural strength, Young’s modulus and elongation, of neat vinyl ester resin and vinyl ester resin modified with MXene and M-MXene were investigated. The results showed that modification significantly improved the mechanical properties of the vinyl ester resin. The tensile and flexural strengths of the MXene-nanosheet-modified vinyl ester resin were 27.20% and 25.32% higher, respectively, than those of the neat vinyl ester resin. The coupling agent improved the interfacial compatibility between the MXene nanosheets and vinyl ester resin, which resulted in the tensile and flexural strengths of the M-MXene-nanosheet-modified vinyl ester resin being 52.57% and 54.60% higher, respectively, than those of the neat vinyl ester resin for a loading quantity of nanosheets of only 0.04 wt %, which is economically viable. The main mechanisms by which the nanosheets toughen the resin are crack deflection and crack pinning.

关键词： MXene nanosheets     2D material     vinyl ester resin     modification     coupling agent    

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Dual cross-linked MXene/cellulose nanofiber/nickel alginate film with improved mechanical properties

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1460-1469 doi: 10.1007/s11705-023-2335-7

摘要： Electromagnetic interference pollution has raised urgent demand for the development of electromagnetic interference shielding materials. Transition metal carbides (MXenes) with excellent conductivity have shown great potential in electromagnetic interference (EMI) shielding materials, while the poor mechanical strength, flexibility, and structural stability greatly limit their further applications. Here, cellulose nanofibers and sodium alginate are incorporated with MXene nanosheets as flexible matrices to construct strong and flexible mussel-like layered MXene/Cellulose nanofiber/Sodium Alginate composite films, and nickel ions are further introduced to induce metal coordination crosslinking of alginate units. Benefited from the dual-crosslinked network structure of hydrogen bonding and metal coordination, the tensile strength, Young’s modulus, and toughness of the MXene/cellulose nanofiber/nickel alginate composite film are significantly increased. After subsequent reduction by ascorbic acid, excess nickel ions are reduced to nickel nanoparticles and uniformly dispersed within the highly conductive composite film, which further improved its hysteresis loss effect toward the incident electromagnetic waves. Consequently, the MXene/cellulose nanofiber/nickel alginate-Ni composite film presents a considerably enhanced electromagnetic interference shielding effectiveness (47.17 dB) at a very low thickness of 29 μm. This study proposes a feasible dual-crosslinking and subsequent reduction strategy to synergistically enhance the mechanical properties and electromagnetic interference shielding performance of MXene-based composite materials.

关键词： Ti3C2Tx MXene     double crosslinking     mechanical properties     EMI shielding performance    

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Cobalt-nanoparticle catalysts derived from zeolitic imidazolate framework@MXene composites for efficient

Jie Chen;Mingyuan Jian;Deqiong Xie;Kecan Dou;Deli Chen;Weidong Zhu;Fumin Zhang

《化学科学与工程前沿（英文）》 2024年 第18卷 第1期   页码 9-9 doi: 10.1007/s11705-023-2378-9

摘要： In this study, we synthesize a catalyst comprising cobalt nanoparticles supported on MXene by pyrolyzing a composite in a N2 environment. Specifically, the composite comprises a bimetallic Zn/Co zeolitic imidazole framework grown in situ on the outer surface of MXene. The catalytic efficiency of the catalyst is tested for the self-coupling of 4-methoxybenzylamine to produce value-added imine, where atmospheric oxygen (1 atm) is used as the oxidant. Based on the results, the catalyst displayed impressive catalytic activity, achieving 95.4% yield of the desired imine at 383 K for 8 h. Furthermore, the catalyst showed recyclability and tolerance toward benzylamine substrates with various functional groups. The outstanding performance of the catalyst is primarily attributed to the synergetic catalytic effect between the cobalt nanoparticles and MXene support, while also benefiting from the three-dimensional porous structure. Additionally, a preliminary investigation of potential reaction mechanisms is conducted.

关键词： MXene     sacrificial template     oxidative self-coupling     Co nanoparticles     imine    

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具有理想保暖性和抗菌性的生物基水性聚（香草醛-丙烯酸丁酯）/MXene纳米复合皮革涂层 Article

马建中, 马莉, 张雷, 张文博, 范倩倩, 韩布兴

《工程（英文）》 2024年 第36卷 第5期   页码 248-261 doi: 10.1016/j.eng.2023.06.005

摘要： 进一步将具有优异光热转换性能和抗菌性能的MXene纳米片，通过超声分散的方式引入P(MV-BA)细乳液中，制得P(MV-BA)/MXene纳米复合细乳液。最后，将P(MV-BA)/MXene纳米复合细乳液喷涂在皮革表面，当其在皮革表面逐渐固化时，MXene在超声空化效应和其两亲性的共同作用下，逐渐向皮革涂层表面迁移，从而可与光和细菌充分接触，发挥最大光热转换性能和抗菌效果当MXene用量为1.4% 时，P(MV-BA)/MXene 纳米复合细乳液涂饰革样在冬季太阳光的照射下，表面温度升高了约15 ℃；涂饰革样在模拟日光下处理 30 min后，对大肠杆菌和金黄色葡萄球菌的抗菌率接近此外，MXene 纳米片的引入还提高了皮革涂层的透气性、透水汽性和热稳定性。本研究为开发具有优异保暖性和抗菌性的新型、绿色、水性生物基纳米复合皮革涂层提供了新思路。

关键词： MXene纳米片     香草醛     苯乙烯替代物     皮革涂层     光热转换     保暖性能     抗菌性能    

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Nickel(II) ion-intercalated MXene membranes for enhanced H2/CO2 separation

Yiyi Fan, Jinyong Li, Saidi Wang, Xiuxia Meng, Yun Jin, Naitao Yang, Bo Meng, Jiaquan Li, Shaomin Liu

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 882-891 doi: 10.1007/s11705-020-1990-1

摘要： Hydrogen fuel has been embraced as a potential long-term solution to the growing demand for clean energy. A membrane-assisted separation is promising in producing high-purity H . Molecular sieving membranes (MSMs) are endowed with high gas selectivity and permeability because their well-defined micropores can facilitate molecular exclusion, diffusion, and adsorption. In this work, MXene nanosheets intercalated with Ni were assembled to form an MSM supported on Al O hollow fiber via a vacuum-assisted filtration and drying process. The prepared membranes showed excellent H /CO mixture separation performance at room temperature. Separation factor reached 615 with a hydrogen permeance of 8.35 × 10 mol·m ·s ·Pa . Compared with the original Ti C T /Al O hollow fiber membranes, the permeation of hydrogen through the Ni -Ti C T /Al O membrane was considerably increased, stemming from the strong interaction between the negatively charged MXene nanosheets and Ni . The interlayer spacing of MSMs was tuned by Ni . During 200-hour testing, the resultant membrane maintained an excellent gas separation without any substantial performance decline. Our results indicate that the Ni tailored Ti C T /Al O hollow fiber membranes can inspire promising industrial applications.

关键词： MXene     H2/CO2 separation     nickel ions     hollow fiber    

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在光纤激光器中利用Ti3C2 MXene材料产生矢量孤子和类噪声脉冲 Research

王帅1,李雷1,宋宇峰2,唐定远3,沈德元1,赵鹭明1,4

《信息与电子工程前沿（英文）》 2021年 第22卷 第3期   页码 287-436 doi: 10.1631/FITEE.2000033

摘要： 本文利用Ti3C2 MXene材料作为可饱和吸收体，搭建了铥钬共掺光纤激光器，观察到矢量孤子和类噪声脉冲的形成。其中，可饱和吸收体是通过将Ti3C2溶液滴在侧面抛光的D形光纤上自然挥发后制备而成。据我们所知，这是首次利用Ti3C2 MXene材料作为可饱和吸收体从光纤激光器中获得矢量孤子。

关键词： 矢量孤子；类噪声脉冲；MXene；光纤激光器    

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Engineering the electronic and geometric structure of VO/BN@TiO heterostructure for efficient aerobic oxidative desulfurization

《化学科学与工程前沿（英文）》 2023年 第17卷 第3期   页码 276-287 doi: 10.1007/s11705-022-2242-3

摘要： Particle size governs the electronic and geometric structure of metal nanoparticles (NPs), shaping their catalytic performances in heterogeneous catalysis. However, precisely controlling the size of active metal NPs and thereafter their catalytic activities remain an affordable challenge in ultra-deep oxidative desulfurization (ODS) field. Herein, a series of highly-efficient VOx/boron nitride nanosheets (BNNS)@TiO2 heterostructures, therein, cetyltrimethylammonium bromide cationic surfactants serving as intercalation agent, BNNS and MXene as precursors, with various VOx NP sizes were designed and controllably constructed by a facile intercalation confinement strategy. The properties and structures of the prepared catalysts were systematically characterized by different technical methods, and their catalytic activities were investigated for aerobic ODS of dibenzothiophene (DBT). The results show that the size of VOx NPs and V5+/V4+ play decisive roles in the catalytic aerobic ODS of VOx/BNNS@TiO2 catalysts and that VOx/BNNS@TiO2-2 exhibits the highest ODS activity with 93.7% DBT conversion within 60 min under the reaction temperature of 130 °C and oxygen flow rate of 200 mL·min–1, which is due to its optimal VOx dispersion, excellent reducibility and abundant active species. Therefore, the finding here may contribute to the fundamental understanding of structure-activity in ultra-deep ODS and inspire the advancement of highly-efficient catalyst.

关键词： oxidative desulfurization     boron nitride     vanadium     MXene     intercalation confinement    

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Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1440-1449 doi: 10.1007/s11705-023-2333-9

摘要： The composite electrode of CoNiSx and Ti3C2Tx MXene was successfully prepared using a one-step hydrothermal method under the in-situ doping of the cobalt element. The effects of in-situ doping of the cobalt element on the micromorphology and electrochemical performance of the electrodes were investigated. After in-situ doping of the cobalt element, NiS with a needle-like structure was converted into a CoNiSx with petal-like structure. The petal-like CoNiSx with a rough surface was very dense and evenly wrapped on the surface and interlamination of Ti3C2Tx, which helped increase the specific surface area and pore volume of the electrode. Under the identical test conditions, CoNiSx@Ti3C2Tx had a higher specific capacitance and capacitance retention than NiS@Ti3C2Tx. This result indicated that the in-situ doping of the cobalt element promoted the electrochemical performance of the electrode. The energy density of the CoNiSx@Ti3C2Tx/nickel foam (NF)//activated carbon (AC)/NF asymmetric supercapacitor device was 59.20 Wh·kg–1 at a power density of 826.73 W·kg–1, which was much higher than that of NiS@Ti3C2Tx/NF//AC/NF. Three CoNiSx@Ti3C2Tx/NF//AC/NF in series were able to illuminate the light emitting diode lamp for about 10 min, which was higher than the 5 min of three NiS@Ti3C2Tx/NF//AC/NF in series under the same condition. The CoNiSx@Ti3C2Tx/NF//AC/NF with high energy density had better application potential in energy storage than the NiS@Ti3C2Tx/NF//AC/NF.

关键词： MXene     supercapacitor     cobalt doping     structure characterization     electrochemical performance    

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The prior rules of designing Ti

Yingying Jian, Danyao Qu, Lihao Guo, Yujin Zhu, Chen Su, Huanran Feng, Guangjian Zhang, Jia Zhang, Weiwei Wu, Ming-Shui Yao

《化学科学与工程前沿（英文）》 2021年 第15卷 第3期   页码 505-517 doi: 10.1007/s11705-020-2013-y

摘要： Working temperature, sensitivity, and selectivity are some of the characteristics of the applied gas sensors. How to design and fabricate an ideal gas sensor working at room temperature is still challenging and attracting lots of interest. Two-dimensional (2D) materials with ultra-thin structure have been demonstrated as a family of ideal candidates to achieve this goal. Among them, Ti C T MXene, a kind of layered sheet synthesized by selectively etching MAX phases materials, shows remarkable potential to be the sensitive materials solely or in a composite. However, their designing rules are still lacking critical thinking from the viewpoint of the intrinsic property of Ti C T MXene based materials. In this article, two critical features, i.e., the thickness of the sensitive materials, and the scope of the analytes, are elaborated towards Ti C T MXene based gas sensors after characterizing the performance of sensing reducing gases (NH and CO) and oxidizing gas (NO ). First, the thinner the Ti C T MXene sensitive layer, the better the sensitivity. Second, the Ti C T MXene based gas sensor is not suitable for strong and moderate oxidation gas due to its ease of oxidation. These two rules are demonstrated, and could be considered with priority both in the future researches and practical applications.

关键词： MXene based sensor     prior     reducing gases     oxidizing gases    

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Synthesis of Chl@Ti

Wenxin Xu, Xin Zhao, Jiali Tang, Chao Zhang, Yu Gao, Shin-ichi Sasaki, Hitoshi Tamiaki, Aijun Li, Xiao-Feng Wang

《化学科学与工程前沿（英文）》 2021年 第15卷 第3期   页码 709-716 doi: 10.1007/s11705-020-1984-z

摘要： Two-dimensional (2D) titanium carbide MXene Ti C has attracted significant research interest in energy storage applications. In this study, we prepared Chl@Ti C composites by simply mixing a chlorophyll derivative (e.g., zinc methyl 3-devinyl-3-hydroxymethyl- pyropheophorbide (Chl)) and Ti C in tetrahydrofuran, where the Chl molecules were aggregated among the multi-layered Ti C MXene or on its surface, increasing the interlayer space of Ti C . The as-prepared Chl@Ti C was employed as the anode material in the lithium-ion battery (LIB) with lithium metal as the cathode. The resulting LIB exhibited a higher reversible capacity and longer cycle performance than those of LIB based on pure Ti C , and its specific discharge capacity continuously increased along with the increasing number of cycles, which can be attributed to the gradual activation of Chl@Ti C accompanied by the electrochemical reactions. The discharge capacity of 1 wt-% Chl@Ti C was recorded to be 325 mA·h·g at the current density of 50 mA·g with a Coulombic efficiency of 56% and a reversible discharge capacity of 173 mA·h·g at the current density of 500 mA·g after 800 cycles. This work provides a novel strategy for improving the energy storage performance of 2D MXene materials by expanding the layer distance with organic dye aggregates.

关键词： zinc chlorin aggregate     Ti3C2 MXene     anode material     lithium storage    

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标题 作者 时间 类型 操作

MXene supported PtCo bimetallic catalyst for hydrogen evolution in acidic conditions

期刊论文

Recent progress in the design and fabrication of MXene-based membranes

Kai Qu, Kang Huang, Zhi Xu

期刊论文

Electroconductive RGO-MXene membranes with wettability-regulated channels: improved water permeability

期刊论文

Regularly channeled MXene membranes for ionic and molecular separation

Jingchong Liu, Nü Wang

期刊论文

Toughening of vinyl ester resins by two-dimensional MXene nanosheets

期刊论文

Dual cross-linked MXene/cellulose nanofiber/nickel alginate film with improved mechanical properties

期刊论文

Cobalt-nanoparticle catalysts derived from zeolitic imidazolate framework@MXene composites for efficient

Jie Chen;Mingyuan Jian;Deqiong Xie;Kecan Dou;Deli Chen;Weidong Zhu;Fumin Zhang

期刊论文

具有理想保暖性和抗菌性的生物基水性聚（香草醛-丙烯酸丁酯）/MXene纳米复合皮革涂层

马建中, 马莉, 张雷, 张文博, 范倩倩, 韩布兴

期刊论文

Nickel(II) ion-intercalated MXene membranes for enhanced H2/CO2 separation

Yiyi Fan, Jinyong Li, Saidi Wang, Xiuxia Meng, Yun Jin, Naitao Yang, Bo Meng, Jiaquan Li, Shaomin Liu

期刊论文

在光纤激光器中利用Ti3C2 MXene材料产生矢量孤子和类噪声脉冲

王帅1,李雷1,宋宇峰2,唐定远3,沈德元1,赵鹭明1,4

期刊论文

Engineering the electronic and geometric structure of VO/BN@TiO heterostructure for efficient aerobic oxidative desulfurization

期刊论文

Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

期刊论文

王海辉：用于分离的二维MXene膜（2019年5月25日）

2021年04月22日

会议视频

The prior rules of designing Ti

Yingying Jian, Danyao Qu, Lihao Guo, Yujin Zhu, Chen Su, Huanran Feng, Guangjian Zhang, Jia Zhang, Weiwei Wu, Ming-Shui Yao

期刊论文

Synthesis of Chl@Ti

Wenxin Xu, Xin Zhao, Jiali Tang, Chao Zhang, Yu Gao, Shin-ichi Sasaki, Hitoshi Tamiaki, Aijun Li, Xiao-Feng Wang

期刊论文