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Effect of fineness of ash on pozzolanic properties and acid resistance of sugarcane bagasse ash replaced

Shan E ALI; Rizwan AZAM; Muhammad Rizwan RIAZ; Mohamed ZAWAM

《结构与土木工程前沿（英文）》 2022年 第16卷 第10期   页码 1287-1300 doi: 10.1007/s11709-022-0872-7

摘要： This paper addresses the potential use of Sugar Cane Bagasse Ash (SCBA) as a pozzolanic material for partial cement replacement in concrete mixtures. Cement mortars containing SCBA having five different particle size distributions at a replacement rate of 20% by weight were used to study the chemical and physical pozzolanic properties of SCBA. The durability of SCBA replaced mortars was also evaluated. SCBA with 0% retained on sieve No. 325 was used to replace 20% by weight of cement and create mortar specimens that were subjected to sulfuric acid attack of varying concentrations (1%−3% by weight of water). The tested samples were observed to check visual distortion, mass loss, and compressive strength loss at 1, 7, 14, 28, and 56 d of acidic exposure, and the results were compared to those for the control sample, that was lime water cured, at the same ages. The SCBA sets were found to meet the requirements for pozzolan class N specified by ASTM C 618. Mortars containing SCBA with 0% or 15% retention produced better compressive strength than the control mortars after 28 d. Additionally, X-ray fluorescence and X-ray diffraction analysis showed that the SCBA had favorable chemical properties for a pozzolanic material. Furthermore, SCBA replaced samples at all ages showed improved resistance against acidic attack relative to that of the control mortars. Maximum deterioration was seen for 3% concentrated solution. This study’s findings demonstrated that SCBA with an appropriate fineness could be used as a pozzolanic material, consistently with ASTM C 618.

关键词： durability     cement replacement     sugarcane bagasse ash     fineness of ash     pozzolanic properties     mortar acid resistance    

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Fresh and hardened properties of high-performance fiber-reinforced concrete containing fly ash and ricehusk ash: Influence of fiber type and content

Nguyen-Trong HO; Viet Quoc DANG; Minh-Hieu NGUYEN; Chao-Lung HWANG; Trong-Phuoc HUYNH

《结构与土木工程前沿（英文）》 2022年 第16卷 第12期   页码 1621-1632 doi: 10.1007/s11709-022-0884-3

摘要： Although fibers are used only infrequently as an additive in concrete in the construction industry, fiber-enhanced concrete is known to provide a wide range of advantages over conventional concrete. The main objective of this study was to investigate the influences of fiber type and content on the mechanical properties and durability of high-performance fiber-reinforced concrete (HPFRC) designed using a novel densified mixture design algorithm with fly ash and rice husk ash. Three types of fiber, including polypropylene (PP) fiber, steel fiber (SF), and hybrid fiber (HF), were considered. Based on the results, the inclusion of fibers decreased HPFRC flowability, regardless of fiber type. Although the compressive strength of HPFRC with 1.6% PP fiber content was 11.2% below that of the reference HPFRC specimen at 91 d of curing age, the 91-d compressive strengths of both SF and HF-enhanced HPFRC specimens were significantly better than that of the reference HPFRC specimen. Furthermore, the HPFRC specimens incorporating SF and HF both exhibited better splitting tensile and flexural strengths as well as less drying shrinkage than the HPFRC specimens incorporating PP fiber. However, the fiber-enhanced specimens, especially those with added SF, registered less surface electrical resistivity and greater vulnerability to chloride ion penetration than the reference HPFRC specimen.

关键词： high-performance fiber-reinforced concrete     fly ash     rice husk ash     durability     mechanical strength    

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Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass

《环境科学与工程前沿（英文）》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1728-7

摘要：

● A higher sulfur content reduced the curing rate of Cr in glass.

关键词： Dechlorinated fly ash     SO3     Heavy metal     Chemical speciation     Glass solidification    

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Direct synthesis of carbon nanotubes on fly ash particles to produce carbon nanotubes/fly ash composites

Fangxian LI, Cheng ZHOU, Pengfei YANG, Beihan WANG, Jie HU, Jiangxiong WEI, Qijun YU

《结构与土木工程前沿（英文）》 2019年 第13卷 第6期   页码 1405-1414 doi: 10.1007/s11709-019-0564-0

摘要： Fly ash was used as catalytic support for carbon nanotubes (CNTs) growth by chemical vapor deposition (CVD) due to having ideal compositions (SiO , Al O , and Fe O ). In this paper, CNTs were synthesized on Ni catalyst/fly ash substrate using CVD method. The influence of parameters (e.g., reaction temperature and gas flow rate) on the carbon yield and structure of the resulting CNTs was on the carbon yield and structure of the resulting CNTs was investigated by thermo-gravimetric analyses, Scanning electron microscopy, and Raman spectroscopy analysis. The results indicated that the growth temperature controlling had a significant effect on the diameter of CNTs. And the proper acetylene and hydrogen flow rate would decrease in defect density and increase in yield of as-grown CNTs on fly ash. Finally, the amorphous carbon on the surface of as-grown CNTs were removed by heating in air. Experimental results showed that the hydrophobic of the annealed CNTs was weak due to introducing functional groups to the surface of CNTs.

关键词： carbon nanotubes     fly ash     chemical vapor deposition     parameters     purification    

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Effect of circulating ash from CFB boilers on NO and N

Xiangsong HOU, Shi YANG, Junfu LU, Hai ZHANG, Guangxi YUE

《能源前沿（英文）》 2009年 第3卷 第2期   页码 241-246 doi: 10.1007/s11708-009-0006-0

摘要： NO and N O emissions from circulating fluidized bed (CFB) boilers are determined by their formation and destruction rates in the furnace. The effect of circulating ash from a CFB boiler on NO and N O emissions were investigated in a laboratory-scale fluidized bed reactor. The results show that the residue char in circulating ash and the CO generated from the char play an important role in NO reduction and N O formation; however, active components of circulating ash such as CaO, Fe O accelerate the decomposition of N O. Experiment was also conducted on a 75 t/h CFB boiler fueled with the mixture of anthracite and biomass. The lower residue carbon content of circulating ash in this experiment is lower; therefore, the reacting rate of NO deoxidize is limited. This result verified the conclusion of laboratory research.

关键词： CFB boiler     circulating ash     NO reduction     N2O thermal decomposition     biomass    

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Accelerated engineering properties of high and low volume fly ash concretes reinforced with glued steel

Vallarasu Manoharan SOUNTHARARAJAN, Dr. Anandan SIVAKUMAR

《结构与土木工程前沿（英文）》 2013年 第7卷 第4期   页码 429-445 doi: 10.1007/s11709-013-0226-6

摘要： The present study focuses on the improvement of pozzolanic reaction of fly ash particles with the cement hydration products. Low and high volume fly ash concrete mixtures were studied systematically with the addition of accelerating admixtures and accelerated curing of the concrete specimens in a steam chamber for 18 h at 75°C. Also, the reinforcing effects of glued steel fibers addition on the compressive and flexural performance of fly ash concrete were investigated. The test results indicated that the addition of accelerator improved the rate of hardening and the inclusion of steel fibers provided higher flexural performance. Also, it can be noted that the high volume fly ash (50%) addition in concrete showed a reduction in strength; however, the addition of accelerator has compensated the deceleration in strength gain. The proper selection of concrete ingredients, addition of accelerator and initial steam curing for 18 h showed better improvement on the engineering properties in fly ash concrete. A maximum increase (41.7%) in compressive strength of fly ash concrete around 52.90 MPa was noticed for 25% fly ash substitution and 1.5% steel fibers addition. Dynamic elastic modulus was also calculated in loaded concrete specimen using ultrasonic pulse velocity test and showed a good agreement with the experimental value.

关键词： fly ash     pozzolanic index     steam curing     superplasticizer     accelerator     steel fibres     elastic modulus    

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Effects of seeding nucleation agent on geopolymerization process of fly-ash geopolymer

Lapyote PRASITTISOPIN, Issara SEREEWATTHANAWUT

《结构与土木工程前沿（英文）》 2018年 第12卷 第1期   页码 16-25 doi: 10.1007/s11709-016-0373-7

摘要： Geopolymer, an inorganic aluminosilicate material activated by alkaline medium solution, can perform as an inorganic adhesive. The geopolymer technology has a viability to substitute traditional concrete made of portland cement (PC) because replacing PC with fly ash leads to reduced carbon dioxide emissions from cement productions and reduced materials cost. Although fly ash geopolymer stimulates sustainability, it is slow geopolymerization reaction poses a challenge for construction technology in term of practicality. The development of increasing geopolymerization reaction rate of the geopolymer is needed. ?The purpose of this study is to evaluate seeding nucleation agents (NA) of fly ash geopolymer that can accelerate polymerization reactions such that the geopolymer can be widely used in the construction industry. Results from the present study indicate that the use of NA (i.e., Ca(OH) ) can be potentially used to increase geopolymerization reaction rate and improve performance characteristics of the fly ash geopolymer product.

关键词： fly ash     geopolymer     nucleation agent     portland cement replacement    

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Service life prediction of fly ash concrete using an artificial neural network

《结构与土木工程前沿（英文）》 2021年 第15卷 第3期   页码 793-805 doi: 10.1007/s11709-021-0717-9

摘要： Carbonation is one of the most aggressive phenomena affecting reinforced concrete structures and causing their degradation over time. Once reinforcement is altered by carbonation, the structure will no longer fulfill service requirements. For this purpose, the present work estimates the lifetime of fly ash concrete by developing a carbonation depth prediction model that uses an artificial neural network technique. A collection of 300 data points was made from experimental results available in the published literature. Backpropagation training of a three-layer perceptron was selected for the calculation of weights and biases of the network to reach the desired performance. Six parameters affecting carbonation were used as input neurons: binder content, fly ash substitution rate, water/binder ratio, CO2 concentration, relative humidity, and concrete age. Moreover, experimental validation carried out for the developed model shows that the artificial neural network has strong potential as a feasible tool to accurately predict the carbonation depth of fly ash concrete. Finally, a mathematical formula is proposed that can be used to successfully estimate the service life of fly ash concrete.

关键词： concrete     fly ash     carbonation     neural networks     experimental validation     service life    

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Fault simulation of boiler heating surface ash deposition in a power plant system

Weiwei ZHANG, Huisheng ZHANG, Ming SU

《能源前沿（英文）》 2011年 第5卷 第4期   页码 435-443 doi: 10.1007/s11708-011-0162-x

摘要： The simulation model of a power generation system was developed based on EASY5 simulation platform. The performances of the power plant under the conditions of the furnace slagging and ash deposition of the heating surfaces in the boiler were simulated. The results show that the simulation model can reasonably reflect the characteristics of the power plant when each component is under fault conditions. Through fault simulation, the change of the performance parameters can be obtained, which can be used in fault diagnosis system as the diagnosis criterion for expert system.

关键词： boiler     slagging     ash deposition     fault simulation    

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Effect of fly ash replacement level on the fracture behavior of concrete

Mahdi AREZOUMANDI, Jeffery S. VOLZ

《结构与土木工程前沿（英文）》 2013年 第7卷 第4期   页码 411-418 doi: 10.1007/s11709-013-0228-4

摘要： The production of portland cement–the key ingredient in concrete–generates a significant amount of carbon dioxide. However, due to its incredible versatility, availability, and relatively low cost, concrete is the most consumed manmade material on the planet. One method of reducing concrete’s contribution to greenhouse gas emissions is the use of fly ash to replace a significant amount of the cement. ?This study presents the results of an experimental investigation that evaluates effect of fly ash replacement level on the fracture energy of concrete. This study includes four mixes with 0%, 30%, 50%, and 70% fly ash as a cement replacement. This experimental program consisted of 32 fracture beams to study the fracture behavior of concrete. The experimental fracture energies were compared with the fracture energy provisions of different design codes and also different analytical equations. Furthermore, statistical data analyses (parametric and non-parametric) were performed to evaluate whether or not there is any statistically significant difference between the experimental fracture energies of different mixes. Results of these statistical tests show that the mix with higher level of fly ash replacement level has higher fracture energy.

关键词： concrete     fracture energy     fly ash    

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Experimental studies of ash film fractions based on measurement of cenospheres geometry in pulverized

Siqi LIU, Yanqing NIU, Liping WEN, Yang LIANG, Bokang YAN, Denghui WANG, Shi’en HUI

《能源前沿（英文）》 2021年 第15卷 第1期   页码 91-98 doi: 10.1007/s11708-020-0806-9

摘要： In pulverized coal particle combustion, part of the ash forms the ash film and exerts an inhibitory influence on combustion by impeding the diffusion of oxygen to the encapsulated char core, while part of the ash diffuses toward the char core. Despite the considerable ash effects on combustion, the fraction of ash film still remains unclear. However, the research of the properties of cenospheres can be an appropriate choice for the fraction determination, being aware that the formation of cenospheres is based on the model of coal particles with the visco-plastic ash film and a solid core. The fraction of ash film is the ratio of the measuring mass of ash film and the total ash in coal particle. In this paper, the Huangling bituminous coal with different sizes was burnt in a drop-tube furnace at 1273, 1473, and 1673 K with air as oxidizer. A scanning electron microscope (SEM) and cross-section analysis have been used to study the geometry of the collected cenospheres and the effects of combustion parameters on the fraction of ash film. The results show that the ash film fraction increases with increasing temperature and carbon conversion ratio but decreases with larger sizes of coal particles. The high fraction of ash film provides a reasonable explanation for the extinction event at the late burnout stage. The varied values of ash film fractions under different conditions during the dynamic combustion process are necessary for further development of kinetic models.

关键词： ash film fraction     cenospheres     coal combustion     fly ash    

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The investigation of fly ash based asphalt binders using atomic force microscope

Rajan SAHA, Kyle MALLOY, Emil BAUTISTA, Konstantin SOBOLEV

《结构与土木工程前沿（英文）》 2017年 第11卷 第4期   页码 380-387 doi: 10.1007/s11709-017-0437-3

摘要： Atomic Force Microscope (AFM) is a relatively new technique for investigation of construction materials. In this study AFM was used to investigate the interaction of asphalt binder with fly ash. Fly ash is a coal combustion byproduct of electric power utilities having pozzolanic properties and commonly used in Portland cement concrete. In this study, an investigation was made by using different types of fly ash with two types of asphalt binders such as PG 58-28 and PG 64-28. Asphalt microstructure is divided into four subgroups such as Saturates, Aromatics, Resins and Asphaltenes (SARA). These four phases can be distinguished by the atomic force microscope. The interaction of these phases affected by introducing fly-ash was investigated and correlation with rheological properties was observed.

关键词： AFM     fly ash     bee     rheology     asphalt    

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Porous silica synthesis out of coal fly ash with no residue generation and complete silicon separation

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1712-2

摘要：

● Both amorphous and crystalline silicon are completely separated from coal fly ash.

关键词： Coal fly ash     Alkali fusion     Micro-/meso-porous Si     Zeolite MCM-48     Crystalline transformation    

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Experiments on the effect of the pressure on the mineral transformation of coal ash under the different

Nijie JING, Qinhui WANG, Zhongyang LUO, Tao JIE, Xiaomin LI, Kefa CEN

《化学科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 394-399 doi: 10.1007/s11705-010-0505-x

摘要： This paper investigated the effect of the pressures, reaction atmospheres and coal ash species on the ash fusibility with high-pressure thermogravimetric analysis (PTGA) apparatus and X-ray diffraction (XRD) analysis. Each specimen analyzed by XRD was observed for the mineral conversion and formation of new minerals with the pressures under different atmospheres. These results indicate that the pressure restrains the transformation and decomposition of minerals. Many low-temperature minerals are still present under the elevated pressure. The different reaction atmospheres have different effects on the formation of coal ash minerals. Under the N atmosphere, the present microcline may decrease the melting temperature of coal ash. And later, it transforms into sanidine at high pressure; thus, the melting temperature of coal ash may increase. Under the CO atmosphere, the minerals such as microcline, lomonitite, geothite and illite are still present with the increase in pressure; this may reduce the melting temperature. While under the H O atmosphere, there are magnetite and anorthoclase, which may produce the low-temperature eutectics decreasing the melting temperature. The coal ash abundance in basic oxides or higher SiO , Fe O , K O and Na O has lower melting temperature. While the ash sample with more SiO and Al O and less Fe O and basic oxides may lead to higher melting temperature.

关键词： ash fusibility     XRD analysis     PTGA     low-temperature eutectic    

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Mercury emission and adsorption characteristics of fly ash in PC and CFB boilers

Li JIA, Baoguo FAN, Xianrong ZHENG, Xiaolei QIAO, Yuxing YAO, Rui ZHAO, Jinrong GUO, Yan JIN

《能源前沿（英文）》 2021年 第15卷 第1期   页码 112-123 doi: 10.1007/s11708-020-0682-3

摘要： The mercury emission was obtained by measuring the mercury contents in flue gas and solid samples in pulverized coal (PC) and circulating fluidized bed (CFB) utility boilers. The relationship was obtained between the mercury emission and adsorption characteristics of fly ash. The parameters included unburned carbon content, particle size, and pore structure of fly ash. The results showed that the majority of mercury released to the atmosphere with the flue gas in PC boiler, while the mercury was enriched in fly ash and captured by the precipitator in CFB boiler. The coal factor was proposed to characterize the impact of coal property on mercury emissions in this paper. As the coal factor increased, the mercury emission to the atmosphere decreased. It was also found that the mercury content of fly ash in the CFB boiler was ten times higher than that in the PC boiler. As the unburned carbon content increased, the mercury adsorbed increased. The capacity of adsorbing mercury by fly ash was directly related to the particle size. The particle size corresponding to the highest content of mercury, which was about 560 ng/g, appeared in the range from 77.5 to 106 µm. The content of mesoporous (4–6 nm) of the fly ash in the particle size of 77.5–106 µm was the highest, which was beneficial to adsorbing the mercury. The specific surface area played a more significant role than specific pore volume in the mercury adsorption process.

关键词： mercury     combustion modes     coal property     fly ash     particle size    

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标题 作者 时间 类型 操作

Effect of fineness of ash on pozzolanic properties and acid resistance of sugarcane bagasse ash replaced

Shan E ALI; Rizwan AZAM; Muhammad Rizwan RIAZ; Mohamed ZAWAM

期刊论文

Fresh and hardened properties of high-performance fiber-reinforced concrete containing fly ash and ricehusk ash: Influence of fiber type and content

Nguyen-Trong HO; Viet Quoc DANG; Minh-Hieu NGUYEN; Chao-Lung HWANG; Trong-Phuoc HUYNH

期刊论文

Effects of sulfur on variations in the chemical speciation of heavy metals from fly ash glass

期刊论文

Direct synthesis of carbon nanotubes on fly ash particles to produce carbon nanotubes/fly ash composites

Fangxian LI, Cheng ZHOU, Pengfei YANG, Beihan WANG, Jie HU, Jiangxiong WEI, Qijun YU

期刊论文

Effect of circulating ash from CFB boilers on NO and N

Xiangsong HOU, Shi YANG, Junfu LU, Hai ZHANG, Guangxi YUE

期刊论文

Accelerated engineering properties of high and low volume fly ash concretes reinforced with glued steel

Vallarasu Manoharan SOUNTHARARAJAN, Dr. Anandan SIVAKUMAR

期刊论文

Effects of seeding nucleation agent on geopolymerization process of fly-ash geopolymer

Lapyote PRASITTISOPIN, Issara SEREEWATTHANAWUT

期刊论文

Service life prediction of fly ash concrete using an artificial neural network

期刊论文

Fault simulation of boiler heating surface ash deposition in a power plant system

Weiwei ZHANG, Huisheng ZHANG, Ming SU

期刊论文

Effect of fly ash replacement level on the fracture behavior of concrete

Mahdi AREZOUMANDI, Jeffery S. VOLZ

期刊论文

Experimental studies of ash film fractions based on measurement of cenospheres geometry in pulverized

Siqi LIU, Yanqing NIU, Liping WEN, Yang LIANG, Bokang YAN, Denghui WANG, Shi’en HUI

期刊论文

The investigation of fly ash based asphalt binders using atomic force microscope

Rajan SAHA, Kyle MALLOY, Emil BAUTISTA, Konstantin SOBOLEV

期刊论文

Porous silica synthesis out of coal fly ash with no residue generation and complete silicon separation

期刊论文

Experiments on the effect of the pressure on the mineral transformation of coal ash under the different

Nijie JING, Qinhui WANG, Zhongyang LUO, Tao JIE, Xiaomin LI, Kefa CEN

期刊论文

Mercury emission and adsorption characteristics of fly ash in PC and CFB boilers

Li JIA, Baoguo FAN, Xianrong ZHENG, Xiaolei QIAO, Yuxing YAO, Rui ZHAO, Jinrong GUO, Yan JIN

期刊论文