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仿生与生物启发膜 1

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Biomineralization-inspired copper-cystine nanoleaves capable of laccase-like catalysis for the colorimetric

Miao Guan, Mengfan Wang, Wei Qi, Rongxin Su, Zhimin He

《化学科学与工程前沿（英文）》 2021年第15卷第2期页码 310-318 doi: 10.1007/s11705-020-1940-y

摘要： Recently, many efforts have been dedicated to creating enzyme-mimicking catalysts to replace natural enzymes in practical fields. Inspired by the pathological biomineralization behaviour of L-cystine, in this study, we constructed a laccase-like catalyst through the co-assembly of L-cystine with Cu ions. Structural analysis revealed that the formed catalytic Cu-cystine nanoleaves (Cu-Cys NLs) possess a Cu(I)-Cu(II) electron transfer system similar to that in natural laccase. Reaction kinetic studies demonstrated that the catalyst follows the typical Michaelis-Menten model. Compared with natural laccase, the Cu-Cys NLs exhibit superior stability during long-term incubation under extreme pH, high-temperature or high-salt conditions. Remarkably, the Cu-Cys NLs could be easily recovered and still maintained 76% of their activity after 8 cycles. Finally, this laccase mimic was employed to develop a colorimetric method for epinephrine detection, which achieved a wider linear range (9–455 μmol·L ) and lower limit of detection (2.7 μmol·L ). The Cu-Cys NLs also displayed excellent specificity and sensitivity towards epinephrine in a test based on urine samples.

关键词： biomineralization laccase L-cystine colorimetric detection enzyme mimic

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Cystine-assisted accumulation of gold nanoparticles on ZnO to construct a sensitive surface-enhanced Raman spectroscopy substrate

《化学科学与工程前沿（英文）》 2023年第17卷第1期页码 15-23 doi: 10.1007/s11705-022-2177-8

摘要： Recently, various semiconductor/metal composites have been developed to fabricate surface-enhanced Raman spectroscopy substrates. However, low metal loading on semiconductors is still a challenge. In this study, cystine was introduced to increase the accumulation of gold nanoparticles on zinc oxide, owing to the biomineralization property of cystine. Morphological analysis revealed that the obtained ZnO/Au/cystine composite not only had a higher metal loading but also formed a porous structure, which is beneficial for Raman performance. Compared with ZnO/Au, the ZnO/Au/cystine substrate displayed a 40-fold enhancement in the Raman signal and a lower limit of detection (10^–11 mol·L⁻¹) in the detection of rhodamine 6G. Moreover, the substrate has favorable homogeneity and stability. Finally, ZnO/Au/cystine displayed excellent performance toward crystal violet and methylene blue in a test based on river water samples. This study provided a promising method to fabricate sensitive semiconductor/noble metal-based surface-enhanced Raman spectroscopy substrates for Raman detection.

关键词： biomineralization cystine semiconductor/metal composite SERS detection Raman detection

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仿生与生物启发膜的研究进展

彭冬冬,贺明睿,杨昊,张蓓,高博鑫,范琳,丁鹤,南延虎,潘福生,苏延磊,吴洪,姜忠义

《中国工程科学》 2014年第16卷第12期页码 102-112

摘要：

仿生与生物启发的思想和策略在众多基础与工程科学领域取得了重要进展。研究者们通过借鉴和模仿自然界中生物材料多样的组成、精巧的结构、温和的形成过程以及强大的功能，设计制备了多种高性能膜材料，并将其应用于水处理、气体分离、有机小分子液体混合物分离等领域，显示出良好的应用前景。仿生和生物启发膜主要是以细胞膜、荷叶和贻贝等为仿生原型，以生物矿化、生物黏合和自组装等为工具，以绿色、高效、节能为目标，在资源、能源高效利用和可持续发展等方面会发挥越来越大的作用，并逐步发展成为膜和膜过程领域的重要分支。本文将对仿生和生物启发膜的研究进展进行简要总结，重点介绍抗污染膜、杂化膜和复合膜的制备与应用。

关键词：仿生与生物启发膜膜和膜过程表面偏析仿生矿化仿生黏合