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Effect of current density on groundwater arsenite removal performance using air cathode electrocoagulation

《环境科学与工程前沿（英文）》 2021年第15卷第6期 doi: 10.1007/s11783-021-1399-1

摘要：

• With the same charge, current density had little effect on As(III) removal in ACEC.

关键词： Electrocoagulation Air cathode Arsenic Current density Energy consumption

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Synthesis of aluminum nanoparticles as additive to enhance ignition and combustion of high energy density

Xiu-Tian-Feng E, Lei Zhang, Fang Wang, Xiangwen Zhang, Ji-Jun Zou

《化学科学与工程前沿（英文）》 2018年第12卷第3期页码 358-366 doi: 10.1007/s11705-018-1702-2

摘要：

High energy density fuels are critical for hypersonic aerospace propulsion but suffer from difficulties of ignition delay and incomplete combustion. This research reports aluminum nanoparticles (Al NPs) assisted ignition and combustion of high energy density JP-10 fuel. Al NPs with a size of 16 nm were fabricated through a mild and simple method by decomposing AlH₃·Et₂O with the addition of a surfactant ligand. The uniform size distribution, nanoscaled size and surface ligand make Al NPs stably suspend in JP-10, with 80% NPs being dispersed in the liquid fuel after six months. A shock tube test shows that the presence of 1 wt-% Al NPs can significantly shorten ignition delay time at temperature of 1500 to 1750 K, promote the combustion, and enhance energy release of JP-10. This work demonstrates the potential of Al NPs as ignition and combustion additive for high energy density fuel in hypersonic applications.

关键词： aluminum nanoparticles combustion ignition shock tube test high energy density fuel

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Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

《化学科学与工程前沿（英文）》 2023年第17卷第8期页码 1010-1027 doi: 10.1007/s11705-023-2307-y

摘要： Powering the future, while maintaining strong socioeconomic growth and a cleaner environment, is going to be one of the biggest challenges faced by mankind nowadays. Thus, there is a transition from the use of fossil fuels to renewable energy sources. Cellulose, the main component of paper, represents a unique type of bio-based building blocks featuring exciting properties: low-cost, hierarchical fibrous structures, hydrophilicity, biocompatible, mechanical flexibility, and renewability, which make it perfect for use in paper-based sustainable energy storage devices. This review focuses on lithium-ion battery application of celluloses with cellulose at different scales, i.e., cellulose microfibers, and nanocellulose, and highlights the new trends in the field. Recent advances and approaches to construct high mass loading paper electrodes toward high energy density batteries are evaluated and the limitations of paper-based cathodes are discussed. This will stimulate the use of natural resources and thereby the development of renewable electric energy systems based on sustainable technologies with low environmental impacts and carbon footprints.

关键词： cellulose paper electrodes Li-ion batteries high energy density

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Tripotassium citrate monohydrate derived carbon nanosheets as a competent assistant to manganese dioxide with remarkable performance in the supercapacitor

《化学科学与工程前沿（英文）》 2022年第16卷第3期页码 420-432 doi: 10.1007/s11705-021-2065-7

摘要： Production cost, capacitance, and electrode materials safety are the key factors to be concerned about for supercapacitors. In this work, a type of carbon nanosheets was produced through the carbonization of tripotassium citrate monohydrate and nitric acidification. Subsequently, a well-designed manganese dioxide/carbon nanosheets composite was synthesized through hydrothermal treating. The carbon nanosheets served as the substrate for growing the manganese dioxide, regulating its distribution, and preventing it from inhomogeneous dimensions and severe agglomeration. Many manganese dioxide nanosheets grew vertically on the numerous functional groups generated on the surface of the carbon nanosheets during acidification. The synergistic combination of carbon nanosheets and manganese dioxide tailors the electrochemical performance of the composite, which benefits from the excellent conductivity and stability of carbon nanosheets. The carbon nanosheets derived from tripotassium citrate monohydrate are conducive to the remarkable performance of manganese dioxide/carbon nanosheets electrode. Finally, an asymmetric supercapacitor with active carbon as the cathode and manganese dioxide/carbon nanosheets as the anode was assembled, achieving an outstanding energy density of 54.68 Wh·kg^–1 and remarkable power density of 6399.2 W·kg^–1 superior to conventional lead-acid batteries. After 10000 charge-discharge cycles, the device retained 75.3% of the initial capacitance, showing good cycle stability. Two assembled asymmetric supercapacitors in series charged for 3 min could power a yellow light emitting diode with an operating voltage of 2 V for 2 min. This study may provide valuable insights for applying carbon materials and manganese dioxide in the energy storage field.

关键词： carbon nanosheets manganese dioxide asymmetric supercapacitors energy density power density

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高能量密度爆炸与化学爆炸的物理特征及爆炸次生洪水波效应探讨

周丰峻

《中国工程科学》 2000年第2卷第12期页码 45-51

摘要：

文章根据高能量密度爆炸的辐射流体动力学计算与TNT装药爆炸计算的结果，对二类爆炸波系的形成发展，爆炸近区、远区的物理特征和爆炸作用物理模拟问题进行了研究，得出了对防护工程比较重要的几点结论。同时对于同两类爆炸引起的次生洪水波灾害进行了探讨，阐明了系统开展洪水波防护研究的重要意义。

关键词：高能量密度爆炸化学焊炸冲击波洪水波

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Assessment of wind energy potential in Gaza Strip

Juma Yousuf ALAYDI

《能源前沿（英文）》 2011年第5卷第3期页码 297-304 doi: 10.1007/s11708-010-0134-6

摘要： The analysis of collected wind data at two sites in the Gaza Strip, namely, Gaza City and Gaza International Airport in Rafah city, is presented. The two sites are candidates for remote area wind energy applications. The purpose of this paper is to present the results of the assessment of wind energy potential in the Gaza Strip in order to evaluate the wind regimes for installing wind energy conversion systems for power generation. The data on wind speed, direction and frequency distribution are used to analyze wind energy characteristics and availability at some stations in the Gaza Strip. The vertical extrapolation was based on the power-law expression, and the wind energy and potential have been estimated at the wind turbine hub height of approximately 50 m. Furthermore, the values of the Weibull parameters and are determined from summary statistics of wind resource. Consequently, the wind power is estimated by adoption of the Weibull distribution expression. Based on the results of this paper, sites are recommended for wind energy exploitation in the Gaza Strip.

关键词： wind data wind resource assessment wind power density wind energy the Weibull distribution and Weibull parameters

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Metal-based direct hydrogen generation as unconventional high density energy

Shuo XU, Jing LIU

《能源前沿（英文）》 2019年第13卷第1期页码 27-53 doi: 10.1007/s11708-018-0603-x

摘要： Metals are unconventional hydrogen production materials which are of high energy densities. This paper comprehensively reviewed and digested the latest researches of the metal-based direct hydrogen generation and the unconventional energy utilization ways thus enabled. According to the metal activities, the reaction conditions of metals were generalized into three categories. The first ones refer to those which would violently react with water at ambient temperature. The second ones start to react with water after certain pretreatments. The third ones can only react with steam under somewhat harsh conditions. To interpret the metal-water reaction mechanisms at the molecular scale, the molecule dynamics simulation and computational quantum chemistry were introduced as representative theoretical analytical tools. Besides, the state-of-the-art of the metal-water reaction was presented with several ordinary metals as illustration examples, including the material treatment technologies and the evaluations of hydrogen evolution performances. Moreover, the energy capacities of various metals were summarized, and the application potentials of the metal-based direct hydrogen production approach were explored. Furthermore, the challenges lying behind this unconventional hydrogen generation method and energy strategy were raised, which outlined promising directions worth of further endeavors. Overall, active metals like Na and K are appropriate for rapid hydrogen production occasions. Of these metals discussed, Al, Mg and their alloys offer the most promising hydrogen generation route for clean and efficient propulsion and real-time power source. In the long run, there exists plenty of space for developing future energy technology along this direction.

关键词： metal hydrogen generation hydrolysis metal water reaction clean energy

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Evaluation of the wind energy potential of two south west sites in Nigeria

Olaleye M. AMOO

《能源前沿（英文）》 2012年第6卷第3期页码 237-246 doi: 10.1007/s11708-012-0201-2

摘要： Wind resource assessment is a crucial first step in gauging the potential of a site to produce energy from wind turbines. In this paper, the wind energy potential of Abeokuta (07°03'N, 03°19'E) and Ijebu-Ode (06°47'N, 03°58'E), two south west sites in Nigeria were examined. Twenty years (1990–2010) of monthly mean wind data from a 10 m height were subjected to two-parameter Weibull analysis and other statistical analyses. The results show that the average annual mean wind speed variation for Abeokuta ranges from 2.2 to 5.0 m/s. For Ijebu-Ode, it ranges from 2.0 to 5.0 m/s. The wind power density variation based on the Weibull analysis ranges from 4.26 to 24.51 W/m for Abeokuta and from 8.54 to 76.46 W/m for Ijebu-Ode. Ijebu-Ode was found to be the better of the two sites in terms of annual variation of mean wind speed.

关键词： wind potential wind speed wind power density wind gust turbulence intensity Nigeria

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Investigation on available wind energy at Tungku beach

M. G. YAZDANI, M. A. SALAM

《能源前沿（英文）》 2012年第6卷第3期页码 275-279 doi: 10.1007/s11708-012-0194-x

摘要： In this paper, wind velocities and directions (sea and land) are recorded in different days and times. The data collected were compared with the weather data from the Brunei Darussalam Meteorological Service (BDMS) and the findings of other researchers and were found to be in good agreement. The potential of wind energy is predicted from the available data collected. The average generated power (forenoon and afternoon) is found to be 25 (mean) and 18 W (median), 101 (mean) and 73 W (median), 912 (mean) and 660 W (median), 10137 (mean) and 7331 W (median) for a rotor with a diameter of 2.5, 5, 15 and 50 m, respectively. The power density for wind farming is found to be 0.26 (mean) and 0.19 (median), 0.31 (mean) and 0.22 (median) for the rotor whose diameter is 2.5 and 50 m, respectively, while the average values are found to be 0.28 (mean) and 0.2 (median) for the rotor whose diameter is 5 and 15 m.

关键词： wind velocity temperature tower height power density Raleigh distribution electrical power

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A model for creep life prediction of thin tube using strain energy density as a function of stress triaxiality

Tahir MAHMOOD, Sangarapillai KANAPATHIPILLAI, Mahiuddin CHOWDHURY

《机械工程前沿（英文）》 2013年第8卷第2期页码 181-186 doi: 10.1007/s11465-013-0257-7

摘要：

This paper demonstrates the application of a new multiaxial creep damage model developed by authors using stress traixiality to predict the failure time of a component made of 0.5%Cr-0.5%Mo-0.25%V low alloy steel. The model employs strain energy density and assumes that the uniaxial strain energy density of a component can be easily calculated and can be converted to multi-axial strain energy density by multiplying it to a function of stress trixiality which is a ratio of mean stress to equivalent stress. For comparison, an elastic-creep and elastic-plastic-creep finite element analysis (FEA) is performed to get multi-axial strain energy density of the component which is compared with the calculated strain energy density for both cases. The verification and application of the model are demonstrated by applying it to thin tube for which the experimental data are available. The predicted failure times by the model are compared with the experimental results. The results show that the proposed model is capable of predicting failure times of the component made of the above-mentioned material with an accuracy of 4.0%.

关键词： elastic-creep elastic-plastic-creep stress triaxiality life prediction pressure vessels finite element analysis (FEA)

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carbon derived from one-step self-activation of zinc gluconate for symmetric supercapacitors with high energydensity

《化学科学与工程前沿（英文）》 2023年第17卷第4期页码 387-394 doi: 10.1007/s11705-022-2250-3

摘要： Porous carbons with high specific area surfaces are promising electrode materials for supercapacitors. However, their production usually involves complex, time-consuming, and corrosive processes. Hence, a straightforward and effective strategy is presented for producing highly porous carbons via a self-activation procedure utilizing zinc gluconate as the precursor. The volatile nature of zinc at high temperatures gives the carbons a large specific surface area and an abundance of mesopores, which avoids the use of additional activators and templates. Consequently, the obtained porous carbon electrode delivers a satisfactory specific capacitance and outstanding cycling durability of 90.9% after 50000 cycles at 10 A∙g^–1. The symmetric supercapacitors assembled by the optimal electrodes exhibit an acceptable rate capability and a distinguished cycling stability in both aqueous and ionic liquid electrolytes. Accordingly, capacitance retention rates of 77.8% and 85.7% are achieved after 50000 cycles in aqueous alkaline electrolyte and 10000 cycles in ionic liquid electrolyte. Moreover, the symmetric supercapacitors deliver high energy/power densities of 49.8 W∙h∙kg^–1/2477.8 W∙kg^–1 in the Et₄NBF₄ electrolyte, outperforming the majority of previously reported porous carbon-based symmetric supercapacitors in ionic liquid electrolytes.

关键词： self-activation zinc organic salts abundant mesopores symmetric supercapacitor liquid electrolyte

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Review on design, preparation and performance characterization of gelled fuels for advanced propulsion

《化学科学与工程前沿（英文）》 2022年第16卷第6期页码 819-837 doi: 10.1007/s11705-021-2122-2

摘要： With the increasing demand for high-performance and safe fuels in aerospace propulsion systems, gelled fuels have attracted increasing attention. Because of their unique structure, gelled fuels exhibit the advantages of both solid and liquid fuels, such as high energy density, controllable thrust and storage safety. This review provides an overview on design, preparation and performance characterization of gelled fuels. The composition, preparation process and gelation mechanism of gelled high-energy-density fuels are described. Considering these aspects, the rheology and flow behavior of gelled fuels is summarized in terms of the shear thinning property, dynamic viscoelasticity and thixotropy. Moreover, the progress of atomization of gelled fuels is reviewed with a focus on the effect of atomizing nozzles. In addition, the experiments and theoretical models of single droplet combustion and combustor combustion are described. Finally, research directions for the development and application of gelled fuels are suggested.

关键词： gelled fuels high-energy-density fuels rheological properties atomization combustion

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Characterization and comparison of organic functional groups effects on electrolyte performance for vanadium redox flow battery

《化学科学与工程前沿（英文）》 2023年第17卷第9期页码 1221-1230 doi: 10.1007/s11705-023-2298-8

摘要： The vanadium redox flow battery with a safe and capacity-controllable large-scale energy storage system offers a new method for the sustainability. In this case, acetic acid, methane sulfonic acid, sulfonic acid, amino methane sulfonic acid, and taurine are used to overcome the low electrolyte energy density and stability limitations, as well as to investigate the effects of various organic functional groups on the vanadium redox flow battery. When compared to the pristine electrolyte (0.22 Ah, 5.0 Wh·L^–1, 85.0%), the results show that taurine has the advantage of maintaining vanadium ion concentrations, discharge capacity (1.43 Ah), energy density (33.9 Wh·L^–1), and energy efficiency (90.5%) even after several cycles. The acetic acid electrolyte is more conducive to the low-temperature stability of the V(II) electrolyte (177 h at −25 °C) than pristine (82 h at −2 °C). The –SO₃H group, specifically the coaction of the –NH₂ and –SO₃H groups, improves electrolyte stability. The –NH₂ and –COOH additive groups improved conductivity and electrochemical activity.

关键词： vanadium redox flow battery functional groups organic additives energy density stability

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Industrial bio-based plant aggregates as hygric and insulating construction materials for energy efficient

Yunhong Jiang, Mike Lawrence, Meng Zhang, Jiandong Cui

《化学科学与工程前沿（英文）》 2022年第16卷第10期页码 1532-1532 doi: 10.1007/s11705-020-1960-7

摘要： In this paper, the bulk density, microstructure, porosity and pore size distribution of the selected aggregates, including hemp shiv, flax shiv, rape shiv and wheat straw, are fully studied due to these properties are highly related to their excellent characteristics and more or less linked to the properties of the final product. The scanning electron microscope results showed all the selected aggregates have a highly porous and complex hierarchical structure, whereas the arrangement of pores and the thickness of cell wall are significantly different among these aggregates. All the selected aggregates had a low bulk density ranging from 30 to 130 kg∙m and a high porosity between 75.81% and 88.74%. The thermal conductivity of the selected bio-aggregates ranged from 0.04 to 0.06 W∙m ∙K . The thermal conductivity of the selected aggregates was not only depending on the bulk density of the sample but also depending on the raw material. Hemp shiv, rape shiv and flax shiv were excellent hygric regulators with moisture buffer value ( ) ranging from 2.07 to 2.36 g∙m ∙%RH , whereas, wheat straw had a lower MBV value ranging from 1.76 to 1.97 g∙m ∙%RH . The results showed that particle size does not affect the value. The value increases linearly with bulk density.

关键词： bio-based aggregates density porosity thermal conductivity hygric properties

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Three-dimensional composite Li metal anode by simple mechanical modification for high-energy batteries

《能源前沿（英文）》 2023年第17卷第5期页码 569-584 doi: 10.1007/s11708-023-0875-7

摘要： Lithium (Li) metal is believed to be the “Holy Grail” among all anode materials for next-generation Li-based batteries due to its high theoretical specific capacity (3860 mAh/g) and lowest redox potential (−3.04 V). Disappointingly, uncontrolled dendrite formation and “hostless” deposition impede its further development. It is well accepted that the construction of three-dimensional (3D) composite Li metal anode could tackle the above problems to some extent by reducing local current density and maintaining electrode volume during cycling. However, most strategies to build 3D composite Li metal anode require either electrodeposition or melt-infusion process. In spite of their effectiveness, these procedures bring multiple complex processing steps, high temperature, and harsh experimental conditions which cannot meet the actual production demand in consideration of cost and safety. Under this condition, a novel method to construct 3D composite anode via simple mechanical modification has been recently proposed which does not involve harsh conditions, fussy procedures, or fancy equipment. In this mini review, a systematic and in-depth investigation of this mechanical deformation technique to build 3D composite Li metal anode is provided. First, by summarizing a number of recent studies, different mechanical modification approaches are classified clearly according to their specific procedures. Then, the effect of each individual mechanical modification approach and its working mechanisms is reviewed. Afterwards, the merits and limits of different approaches are compared. Finally, a general summary and perspective on construction strategies for next-generation 3D composite Li anode are presented.

关键词： lithium (Li)-ion battery (LIB) Li metal battery three-dimensional (3D) composite Li metal anode mechanical modification reducing local current density

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标题作者时间类型操作

Effect of current density on groundwater arsenite removal performance using air cathode electrocoagulation

期刊论文

Synthesis of aluminum nanoparticles as additive to enhance ignition and combustion of high energy density

Xiu-Tian-Feng E, Lei Zhang, Fang Wang, Xiangwen Zhang, Ji-Jun Zou

期刊论文

Review on cellulose paper-based electrodes for sustainable batteries with high energy densities

期刊论文

Tripotassium citrate monohydrate derived carbon nanosheets as a competent assistant to manganese dioxide with remarkable performance in the supercapacitor

期刊论文

高能量密度爆炸与化学爆炸的物理特征及爆炸次生洪水波效应探讨

周丰峻

期刊论文

Assessment of wind energy potential in Gaza Strip

Juma Yousuf ALAYDI

期刊论文

Metal-based direct hydrogen generation as unconventional high density energy

Shuo XU, Jing LIU

期刊论文

Evaluation of the wind energy potential of two south west sites in Nigeria

Olaleye M. AMOO