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Decoding and quantitative detection of antibiotics by a luminescent mixed-lanthanide-organic framework

《环境科学与工程前沿（英文）》 2022年第16卷第12期 doi: 10.1007/s11783-022-1589-5

摘要：

● A series of mixed-LOFs and portable LOF-fibers were synthesized.

关键词： Antibiotics Sensor Luminescence Lanthanide-organic frameworks

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Acute toxicity assessment of drinking water source with luminescent bacteria: Impact of environmental

Xuewen Yi, Zhanqi Gao, Lanhua Liu, Qian Zhu, Guanjiu Hu, Xiaohong Zhou

《环境科学与工程前沿（英文）》 2020年第14卷第6期 doi: 10.1007/s11783-020-1288-z

摘要： Abstract • Acute toxicity assessment was conducted in Luoma lake watershed, East China. • Impacts of environmental factors on the toxicity testing was fully evaluated. • Dissolve oxygen had a weak positive correlation with luminescence inhibition rate. Protecting the quality of lake watersheds by preventing and reducing their contamination is an effective approach to ensure the sustainability of the drinking water supply. In this study, acute toxicity assessment was conducted on the basis of acute bioluminescence inhibition assay using the marine bacterium Vibrio fischeri as the test organism and Luoma Lake drinking water source in East China as the research target. The suitable ranges of environmental factors, including pH value, organic matter, turbidity, hardness, and dissolved oxygen of water samples were evaluated for the toxicity testing of bioluminescent bacteria. The physicochemical characteristics of water samples at the selected 43 sites of Luoma Lake watershed were measured. Results showed that the variations in pH value (7.31–8.41), hardness (5–20 °d) and dissolved oxygen (4.44–11.03 mg/L) of Luoma Lake and its main inflow and outflow rivers had negligible impacts on the acute toxicity testing of V. fischeri. The luminescence inhibition rates ranged from -11.21% to 10.80% at the 43 sites. Pearson’s correlation analysis in the experiment revealed that temperature, pH value, hardness, and turbidity had no correlation with luminescence inhibition rate, whereas dissolved oxygen showed a weak statistically positive correlation with a Pearson correlation coefficient of 0.455 (p<0.05).

关键词： Bioluminescent bacteria Acute toxicity Pearson correlation analysis Drinking water source Vibrio fischeri

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Photoluminescent properties of Sb

Fushan WEN, Lingling SUN, Jinhyeok KIM

《化学科学与工程前沿（英文）》 2011年第5卷第4期页码 429-434 doi: 10.1007/s11705-011-1138-4

摘要： Sb -doped YBO crystals were prepared through a low-temperature hydrothermal method and a high-temperature solid-state technique, respectively. The effects of preparation methods on the morphologies and luminescent properties of YBO phosphors were investigated. The YBO crystals from the hydrothermal system look like flowers, whereas those from the solid-state process look like some agglomerates of little spheres. The Sb -doped YBO powders prepared via both methods showed the blue emission with the peak at around 452 nm, which corresponds to the P → S transition of Sb ions. However, the emission intensity of the Sb -doped YBO from the hydrothermal system is about 3.5 times as much as that from the solid-state process. The (Sb ,Eu ) co-doped YBO crystals were also prepared through the two methods. The results showed that the emission intensity of Sb ions in (Sb , Eu ) co-doped YBO synthesized by the hydrothermal method is stronger than that by the solid-state process.

关键词： hydrothermal solid-state luminescent borate

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Self-assembled bright luminescent hierarchical materials from a tripodal benzoate antenna and heptadentate

Aramballi J. Savyasachi, David F. Caffrey, Kevin Byrne, Gerard Tobin, Bruno D'Agostino, Wolfgang Schmitt, Thorfinnur Gunnlaugsson

《化学科学与工程前沿（英文）》 2019年第13卷第1期页码 171-184 doi: 10.1007/s11705-018-1762-3

摘要：

The europium heptadentate coordinatively unsaturated (Eu(III)) and the terbium (Tb(III)) 1,4,7,10-tetraazacyclododecane (cyclen) complexes 1 and 2 were used in conjunction with ligand 3 (1,3,5-benzene-trisethynylbenzoate) to form the supramolecular self-assembly structures 4 and 5; this being investigated in both the solid and the solution state. The resulting self-assemblies gave rise to metal centered emission (both in the solid and solution) upon excitation of 3, confirming its role as a sensitizing antenna. Drop-cased examples of ligand 3, and the solid forms of 4 and 5, formed from both organic and mixture of organic-aqueous solutions, were analyzed using Scanning Electron Microscopy, which showed significant changes in morphology; the ligand giving rise to one dimensional structures, while both 4 and 5 formed amorphous materials that were highly dense solid networks containing nanoporous features. The surface area (216 and 119 m²·g⁻¹ for 4 and 5 respectively) and the ability of these porous materials to capture and store gases such as N₂ investigated at 77 K. The self-assembly formation was also investigated in diluted solution by monitoring the various photophysical properties of 3–5. This demonstrated that the most stable structures were that consisting of a single antennae 3 and three complexes of 1 or 2 (e.g., 4 and 5) in solution. By monitoring the excited state lifetimes of the Eu(III) and Tb(III) ions in H₂O and D₂O respectively, we showed that their hydration states (the q-value) changed from ~2 to 0, upon formation of the assemblies, indicating that the three benzoates of 3 coordinated directly to the each of the three lanthanide centers. Finally we demonstrate that this hierarchically porous materials can be used for the sensing of organic solvents as the emission is highly depended on the solvent environment; the lanthanide emission being quenched in the presence of acetonitrile and THF, but greatly enhanced in the presence of methanol.

关键词： self-assembly supramolecular chemistry lanthanides Eu(III) and Tb(III) complexes luminescence metallostars

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Near-field radiative thermoelectric energy converters: a review

Eric TERVO, Elham BAGHERISERESHKI, Zhuomin ZHANG

《能源前沿（英文）》 2018年第12卷第1期页码 5-21 doi: 10.1007/s11708-017-0517-z

摘要： Radiative thermoelectric energy converters, which include thermophotovoltaic cells, thermoradiative cells, electroluminescent refrigerators, and negative electroluminescent refrigerators, are semiconductor p-n devices that either generate electricity or extract heat from a cold body while exchanging thermal radiation with their surroundings. If this exchange occurs at micro or nanoscale distances, power densities can be greatly enhanced and near-field radiation effects may improve performance. This review covers the fundamentals of near-field thermal radiation, photon entropy, and nonequilibrium effects in semiconductor diodes that underpin device operation. The development and state of the art of these near-field converters are discussed in detail, and remaining challenges and opportunities for progress are identified.

关键词： energy conversion systems luminescent refrigeration near-field radiation thermophotovoltaic thermoradiative cell