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固体氧化物燃料电池 8

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Phase transition regulation and caloric effect

《能源前沿（英文）》页码 463-477 doi: 10.1007/s11708-023-0860-1

摘要： Solid state refrigeration based on caloric effect is regarded as a potential candidate for replacing vapor-compression refrigeration. Numerous methods have been proposed to optimize the refrigeration properties of caloric materials, of which single field tuning as a relatively simple way has been systemically studied. However, single field tuning with few tunable parameters usually obtains an excellent performance in one specific aspect at the cost of worsening the performance in other aspects, like attaining a large caloric effect with narrowing the transition temperature range and introducing hysteresis. Because of the shortcomings of the caloric effect driven by a single field, multifield tuning on multicaloric materials that have a coupling between different ferro-orders came into view. This review mainly focuses on recent studies that apply this method to improve the cooling performance of materials, consisting of enlarging caloric effects, reducing hysteresis losses, adjusting transition temperatures, and widening transition temperature spans, which indicate that further progress can be made in the application of this method. Furthermore, research on the sign of lattice and spin contributions to the magnetocaloric effect found new phonon evolution mechanisms, calling for more attention on multicaloric effects. Other progress including improving cyclability of FeRh alloys by introducing second phases and realizing a large reversible barocaloric effect by hybridizing carbon chains and inorganic groups is described in brief.

关键词： phase transition regulation caloric effect solid state refrigeration

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New refrigeration system using CO vapor-solid as refrigerant

HUANG Dongping, DING Guoliang, QUACK Hans

《能源前沿（英文）》 2008年第2卷第4期页码 494-498 doi: 10.1007/s11708-008-0070-x

摘要： A refrigerant must be in the vapor-liquid phase in a vapor-compression refrigeration system, therefore, CO cannot be used as a refrigerant for temperatures lower than -56°C because solid CO will form under the triple point temperature of -56°C. A refrigeration system with CO vapor-solid particles as refrigerant is put forward, by which a temperature lower than the triple point is achieved. An adjustable nozzle, a sublimator, a high-pressure regulating valve and a low-pressure regulating valve are used to replace the conventional evaporator. Theoretical cycle analysis of the refrigeration system shows that its COP can be 50% higher than that of the conventional one.

关键词： refrigerant adjustable temperature vapor-compression refrigeration sublimator

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Biological pretreatment of corn stover by solid state fermentation of

Jian ZHANG, Xin REN, Wenqun CHEN, Jie BAO

《化学科学与工程前沿（英文）》 2012年第6卷第2期页码 146-151 doi: 10.1007/s11705-012-1220-6

摘要： Biological pretreatment is a promising way to overcome the biorecalcitrance of cleaving the supermolecular structure of lignocellulose by lignin degrading enzymes from microorganisms. Solid state fermentation of corn stover with the white-rot fungus was carried out and the efficiency of this pretreatment was evaluated. The enzymatic hydrolysis yield reached a maximum when the corn stover was biologically pretreated for nine days, and the hydrolysis yield decreased sharply if the solid state fermentation was carried out for more than nine days. A possible explanation for this sharp decrease is that not only the lignin degrading enzymes (LiP and MnP) were secreted, but also other metabolites, which were toxic or fatal to the hydrolysis enzymes resulting in the lower hydrolysis yield were generated during the prolonged period of biopretreatment. These results are useful to help determine the optimal timing and to understand the lignin structure and degradation mechanism in biological pretreatment processes.

关键词： biological pretreatment Phanerochaete chrysosporium solid state fermentation biorecalcitrance hydrolysis yield

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Solubility of CO in solid-state PET measured by pressure-decay method

CHEN Miaocan, ZHAO Ling, LIU Tao, WU Jiangwei, YUAN Weikang

《化学科学与工程前沿（英文）》 2008年第2卷第2期页码 214-219 doi: 10.1007/s11705-008-0040-1

摘要： The solubility of CO in solid-state PET was measured using a pressure-decay method. In order to calculate the solubility of CO in the amorphous region of PET, the crystallinity of solid state PET dissolved in CO at different pressures and temperatures was measured by differential scanning calorimetry (DSC). The solubility increases with increasing pressure and it follows a linear relationship and obeys Henry’s law when the pressure is below 8 MPa. The effect of temperature on solubility is weak and the solubilities at different temperatures are almost the same under low pressures. At higher pressure, the solubility decreases with an increase in temperature. The solubility of CO in the amorphous region of PET at 373.15 K, 398.15 K and 423.15 K was correlated with the Sanchez-Lacombe equation of state with a maximal correlation error of 6.69%.

关键词： Sanchez-Lacombe equation solid-state PET different relationship calorimetry

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Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

《能源前沿（英文）》页码 320-323 doi: 10.1007/s11708-023-0889-1

摘要： Promoting hydrogen industry with high-capacity Mg-based solid-state hydrogen storage materials and systems

关键词： materials systems

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Highly effective extraction of oil from soybean by pretreatment of solid-state fermentation with fungi

Xiaojuan NIU, Shuyi QIU, Yuangen WU, Jie YUAN, Yingying XU

《化学科学与工程前沿（英文）》 2011年第5卷第1期页码 122-125 doi: 10.1007/s11705-010-0533-6

摘要： The solid-state prefermentation by (CICC 2377) and (CICC 40536) was employed to increase the oil extraction yield from soybean. The influence of incubation time on oil yield was investigated. The maximum oil yield extracted from the substrate prefermented by for 96 h was 23%, which increased by 47.4% compared with control (15.6%). In the same fermentation conditions, the maximum oil yield extracted from substrate prefermented by was 21.6%, which increased by 38.5% compared with control (15.6%). The quality of soybean oil was not changed obviously by the pretreatment of fermentation with fungi.

关键词： soybean Aspergillus niger Aspergillus flavus solid-state fermentation extraction of oil

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Series transformer based diode-bridge-type solid state fault current limiter

Amir HEIDARY,Hamid RADMANESH,Seyed Hamid FATHI,G. B. GHAREHPETIAN

《信息与电子工程前沿（英文）》 2015年第16卷第9期页码 769-784 doi: 10.1631/FITEE.1400428

摘要： We propose a novel series transformer based diode-bridge-type solid state fault current limiter (SSFCL). To control the fault current, a series RLC branch is connected to the secondary side of an isolation series transformer. Based on this RLC branch, two current limiting modes are created. In the first mode, R and C are bypassed via a paralleled power electronic switch (insulated-gate bipolar transistor, IGBT) and L remains connected to the secondary side of the transformer as a DC reactor. In the second mode, the series reactor impedance is not enough to limit the fault current. In this case, the fault current can be controlled by selecting a proper on-off duration of the parallel IGBT, across the series damping resistor ( ) and capacitor, which inserts high impedance into the line to limit the fault current. Then, by controlling the magnitude of the DC reactor current, the fault current is reduced and the voltage of the point of common coupling (PCC) is kept at an acceptable level. In addition, in the new SSFCL, the series RC branch, connected in parallel with the IGBT, serves as a snubber circuit for decreasing the transient recovery voltage (TRV) of the IGBT during on-off states. Therefore, the power quality indices can be improved. The measurement results of a built prototype are presented to support the simulation and theoretical studies. The proposed SSFCL can limit the fault current without any delay and successfully smooth the fault current waveform.

关键词： Solid state fault current limiter (SSFCL) Power quality Voltage sag Point of common coupling (PCC) Isolation transformer

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Study on microbial protein and the mechanism of solid-state fermentation with periodical dynamic changes

FU Xiaoguo, CHEN Hongzhang, LI Hongqiang, MA Runyu

《化学科学与工程前沿（英文）》 2007年第1卷第2期页码 113-117 doi: 10.1007/s11705-007-0021-9

摘要： The effect of different extraction and purification conditions on the microbial protein obtained from solid-state fermentation (SSF) and the effect of periodical dynamic changes of air on protein have been studied. The mechanism of solid-state fermentation with periodical dynamic changes of air is also discussed. Compared with static solid-state fermentation, periodical dynamic changes of air afford a higher protein mass; from 1 g of the fermentation microbe, 5.3 mg of the intracellular protein (an increase of 34.63%) and 9.09 mg of the extracellular protein (an increase of 17.8%) were obtained on the sixth day of fermentation. The filter paper activity and carboxymethyl cellulose activity (FPA and CMCase) of the extracellular protein are 1.739 μmol/s and 109.592 μmol/s, respectively, which represent increases of 60.1% and 21.2% over the corresponding values for static solid-state fermentation. The FPA and CMCase of the intracellular protein are 0.245 μmol/s and 6.392 μmol/s, respectively, which represent decreases of 22.2% and 38.7% over the corresponding values for static solid-state fermentation. The enzyme activity of the microbial extracellular protein in solid-state fermentation with periodical dynamic changes of air on the fifth day is nearly equal to that on the sixth day without periodical dynamic changes of air, so the period of fermentation can be shortened. The sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) experiments suggest that pulsating air pressure stimulation leads to a decrease in the amount of protein component with molecule mass of about 80400Da, and an increase in the amount of protein component with molecule mass of about 28520Da.

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Solid-state NMR for metal-containing zeolites: From active sites to reaction mechanism

Xingling Zhao, Jun Xu, Feng Deng

《化学科学与工程前沿（英文）》 2020年第14卷第2期页码 159-187 doi: 10.1007/s11705-019-1885-1

摘要： Metal-containing zeolite catalysts have found a wide range of applications in heterogeneous catalysis. To understand the nature of metal active sites and the reaction mechanism over such catalysts is of great importance for the establishment of structure-activity relationship. The advanced solid-state NMR (SSNMR) spectroscopy is robust in the study of zeolites and zeolite-catalyzed reactions. In this review, we summarize recent developments and applications of SSNMR for exploring the structure and property of active sites in metal-containing zeolites. Moreover, detailed information on host-guest interactions in the relevant zeolite catalysis obtained by SSNMR is also discussed. Finally, we highlight the mechanistic understanding of catalytic reactions on metal-containing zeolites based on the observation of key surface species and active intermediates.

关键词： metal-containing zeolites solid-state NMR active site host-guest interaction reaction mechanism

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A fully solid-state cold thermal energy storage device for car seats using shape-memory alloys

《能源前沿（英文）》页码 504-515 doi: 10.1007/s11708-022-0855-3

摘要： Thermal energy storage has been a pivotal technology to fill the gap between energy demands and energy supplies. As a solid-solid phase change material, shape-memory alloys (SMAs) have the inherent advantages of leakage free, no encapsulation, negligible volume variation, as well as superior energy storage properties such as high thermal conductivity (compared with ice and paraffin) and volumetric energy density, making them excellent thermal energy storage materials. Considering these characteristics, the design of the shape-memory alloy based the cold thermal energy storage system for precooling car seat application is introduced in this paper based on the proposed shape-memory alloy-based cold thermal energy storage cycle. The simulation results show that the minimum temperature of the metal boss under the seat reaches 26.2 °C at 9.85 s, which is reduced by 9.8 °C, and the energy storage efficiency of the device is 66%. The influence of initial temperature, elastocaloric materials, and the shape-memory alloy geometry scheme on the performance of car seat cold thermal energy storage devices is also discussed. Since SMAs are both solid-state refrigerants and thermal energy storage materials, hopefully the proposed concept can promote the development of more promising shape-memory alloy-based cold and hot thermal energy storage devices.

关键词： shape-memory alloy (SMA) elastocaloric effect (eCE) cooled seat cold thermal energy storage

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State-of-the-art applications of machine learning in the life cycle of solid waste management

《环境科学与工程前沿（英文）》 2023年第17卷第4期 doi: 10.1007/s11783-023-1644-x

摘要：

● State-of-the-art applications of machine learning (ML) in solid waste (SW) is presented.

关键词： Machine learning (ML) Solid waste (SW) Bibliometrics SW management Energy utilization Life cycle

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Covalent triazine framework with efficient photocatalytic activity in aqueous and solid media

Cyrine Ayed, Wei Huang, Kai A. I. Zhang

《化学科学与工程前沿（英文）》 2020年第14卷第3期页码 397-404 doi: 10.1007/s11705-019-1884-2

摘要： Covalent triazine frameworks (CTFs) have been recently employed for visible light-driven photocatalysis due to their unique optical and electronic properties. However, the usually highly hydrophobic nature of CTFs, which originates from their overall aromatic backbone, leads to limitations of CTFs for applications in aqueous media. In this study, we aim to extend the range of the application media of CTFs and design hybrid material of a CTF and mesoporous silica (SBA-15) for efficient photocatalysis in aqueous medium. A thiophene-containing CTF was directly synthesized in mesopores of SBA-15. Due to the high surface area and the added hydrophilic properties by silica, the hybrid material demonstrated excellent adsorption of organic molecules in water. This leads not only to high photocatalytic performance of the hybrid material for the degradation of organic dyes in water, but also for efficient photocatalysis in solvent-free and solid state. Furthermore, the reusability, stability and easy recovery of the hybrid material offers promising metal-free heterogeneous photocatalyst for broader applications in different reaction media.

关键词： photocatalysis covalent triazine framework aqueous medium SBA-15 solid state

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Solid-state transformer-based new traction drive system and control

Jianghua FENG, Jing SHANG, Zhixue ZHANG, Huadong LIU, Zihao HUANG

《机械工程前沿（英文）》 2018年第13卷第3期页码 411-426 doi: 10.1007/s11465-018-0467-0

摘要：

A new type of traction drive system consisting of solid-state traction transformer (SSTT), inverter unit, auxiliary inverter, traction motor and other key components is built in order to suit the demand of developing the next-generation electric traction system which will be efficient and lightweight, with high power density. For the purpose of reducing system volume and weight and improving efficiency and grid-side power quality, an efficient SSTT optimized topology combining high-voltage cascaded rectifiers with high-power high-frequency LLC resonant converter is proposed. On this basis, an integrated control strategy built upon synchronous rotating reference frame is presented to achieve unified control over fundamental active, reactive and harmonic components. The carrier-interleaving phase shift modulation strategy is proposed to improve the harmonic performance of cascaded rectifiers. In view of the secondary pulsating existing in a single-phase system, the mathematical model of secondary power transfer is built, and the mechanism of pulsating voltage resulting in beat frequency of LLC resonant converter is revealed, so as to design optimum matching of system parameters. Simulation and experimental results have verified that the traction system and control scheme mentioned in this paper are reasonable and superior and that they meet the future application requirements for rail transit.

关键词： solid-state traction transformer high-voltage cascaded rectifier LLC resonant converter synchronous rotating reference frame carrier-interleaving phase shift control secondary pulsating voltage beat frequency

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高亮度固体激光器技术发展研究

唐晓军,王钢,刘娇,耿林,姜东升

《中国工程科学》 2020年第22卷第3期页码 49-55 doi: 10.15302/J-SSCAE-2020.03.008

摘要：

激光推进、激光传能等重大科研方向对高亮度固体激光器技术提出了重大需求，使得相关研究持续成为国际关注焦点。本文阐述了高亮度固体激光器技术的宏观需求，梳理国内外的技术研究现状并总结发展趋势，凝练技术进一步发展所面临的问题；据此完成高亮度固体激光器的关键技术分析，并结合国情提出未来发展建议。板条激光器和光纤激光器由于具有突出优点成为研究热点，在单台激光器输出功率不断提升的同时，可配合光束合成方法来实现高亮度激光输出。研究表明，应着重推动新型激光材料、高端半导体激光泵浦源、高精度封装工艺、自适应光束控制、光束合成关键器件等方面的技术攻关，尽快形成核心技术体系；科学布局以表层增益板条激光器技术为代表的、具有良好发展潜力的固体激光器技术研究课题，加强共用基础技术研究与积淀，为未来固体激光器输出亮度、转换效率、功率质量比的持续提升奠定坚实基础。

关键词：固体激光器高亮度技术路线关键技术

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Nickel nanopore arrays as promising current collectors for constructing solid-state supercapacitors with

Huaping Zhao, Long Liu, Yaoguo Fang, Ranjith Vellacheri, Yong Lei

《化学科学与工程前沿（英文）》 2018年第12卷第3期页码 339-345 doi: 10.1007/s11705-018-1699-6

摘要：

In this work, nickel nanopore arrays with a highly-oriented nanoporous structure inherited from porous alumina membranes were used as nanostructured current collectors for constructing ultrahigh rate solid-state supercapacitors. A thin layer of poly(3,4-ethylenedioxythiophene) (PEDOT) as electroactive materials was conformally coated onto nickel nanopores to form heterostructured electrodes. The as-prepared electrodes have a large specific surface area to ensure a high capacity, and the highly-oriented nanoporous structure of nickel nanopores reduces the ion transport resistance, allowing the ions in the solid-state electrolytes to quickly access the PEDOT surface during the fast charge-discharge process. As a result, the assembled solid-state supercapacitor in a symmetric configuration exhibits an ideal capacitive behavior and a superior rate capability even at an ultrahigh scan rate of 50 V·s⁻¹.

关键词： supercapacitor ultrahigh rate metallic nanopore arrays current collectors PEDOT