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Effect of extrusion temperature on the physical properties of high-silicon aluminum alloy

YANG Fuliang, GAN Weiping, CHEN Zhaoke

《机械工程前沿(英文)》 2007年 第2卷 第1期   页码 120-124 doi: 10.1007/s11465-007-0021-y

摘要: Light-weight high-silicon aluminum alloys are used for electronic packaging in the aviation and space-flight industry. Al-30Si and Al-40Si are fabricated with air-atomization and vacuum-canning hot-extrusion process. The density, thermal conductivity, hermeticity and thermal expansion coefficients of the material are measured, and the relationship between extrusion temperature and properties is obtained. Experimental results show that the density of high-silicon aluminum alloys prepared with this method is as high as 99.64% of the theory density, and increases with elevating extrusion temperature. At the same time, thermal conductivity varies between 104-140 W/(m " K); with the extrusion temperature, thermal expansion coefficient also increases but within 13?10 (at 100?C) and hermeticity of the material is high to 10 order of magnitude.

关键词: coefficient     hermeticity     temperature     relationship     air-atomization    

Bicontinuous porous membranes with micro-nano composite structure using a facile atomization-assisted

《化学科学与工程前沿(英文)》 2022年 第16卷 第8期   页码 1268-1280 doi: 10.1007/s11705-022-2143-5

摘要: The micro-nano composite structure can endow separation membranes with special surface properties, but it often has the problems of inefficient preparation process and poor structural stability. In this work, a novel atomization-assisted nonsolvent induced phase separation method, which is also highly efficient and very simple, has been developed. By using this method, a bicontinuous porous microfiltration membrane with robust micro-nano composite structure was obtained via commercially available polymers of polyacrylonitrile and polyvinylpyrrolidone. The formation mechanism of the micro-nano composite structure was proposed. The microphase separation of polyacrylonitrile and polyvinylpyrrolidone components during the atomization pretreatment process and the hydrogen bonding between polyacrylonitrile and polyvinylpyrrolidone molecules should have resulted in the nano-protrusions on the membrane skeleton. The membrane exhibits superhydrophilicity in air and superoleophobicity underwater. The membrane can separate both surfactant-free and surfactant-stabilized oil-in-water emulsions with high separation efficiency and permeation flux. With excellent antifouling property and robust microstructure, the membrane can easily be recycled for long-term separation. Furthermore, the scale-up verification from laboratory preparation to continuous production has been achieved. The simple, efficient, cost-effective preparation method and excellent membrane properties indicate the great potential of the developed membranes in practical applications.

关键词: atomization     nonsolvent induced phase separation     bicontinuous porous structure     micro-nano composite structure     oil-water separation    

Preconcentration of trace elements by adsorption onto a niobium wire for electrothermal atomization atomic

Satoshi KANECO, Hiroaki KITANAGA, Hideyuki KATSUMATA, Tohru SUZUKI

《化学科学与工程前沿(英文)》 2012年 第6卷 第4期   页码 432-435 doi: 10.1007/s11705-012-1219-z

摘要: In the present work, a new preconcentration method of trace elements by adsorption onto a niobium wire has been developed for electrothermal atomization atomic absorption spectrometry (ETAAS) with a tungsten tube atomizer. Detection limits (pg·mL ) by this method combined with ETAAS were 45 for bismuth, 7.0 for cadmium, 20 for copper, 1.3 for gold, 36 for lead, 65 for manganese, 9.5 for rhodium and 19 for silver.

关键词: preconcentration     adsorption onto niobium wire     electrothermal atomization atomic absorption spectrometry     tungsten tube atomizer     trace elements    

aromatic hydrocarbons predicting from general connectivity based hierarchy with discrete correction of atomization

《化学科学与工程前沿(英文)》 2022年 第16卷 第12期   页码 1743-1750 doi: 10.1007/s11705-022-2184-9

摘要: The standard enthalpy of formation is an important predictor of the reaction heat of a chemical reaction. In this work, a high-precision method was developed to calculate accurate standard enthalpies of formation for polycyclic aromatic hydrocarbons based on the general connectivity based hierarchy (CBH) with the discrete correction of atomization energy. Through a comparison with available experimental findings and other high-precision computational results, it was found that the present method can give a good description of enthalpy of formation for polycyclic aromatic hydrocarbons. Since CBH schemes can broaden the scope of application, this method can be used to investigate the energetic properties of larger polycyclic aromatic hydrocarbons to achieve a high-precision calculation at the CCSD(T)/CBS level. In addition, the energetic properties of CBH fragments can be accurately calculated and integrated into a database for future use, which will increase computational efficiency. We hope this work can give new insights into the energetic properties of larger systems.

关键词: standard enthalpy of formation     polycyclic aromatic hydrocarbons     connectivity based hierarchy     high-precision calculation    

Review on design, preparation and performance characterization of gelled fuels for advanced propulsion

《化学科学与工程前沿(英文)》 2022年 第16卷 第6期   页码 819-837 doi: 10.1007/s11705-021-2122-2

摘要: With the increasing demand for high-performance and safe fuels in aerospace propulsion systems, gelled fuels have attracted increasing attention. Because of their unique structure, gelled fuels exhibit the advantages of both solid and liquid fuels, such as high energy density, controllable thrust and storage safety. This review provides an overview on design, preparation and performance characterization of gelled fuels. The composition, preparation process and gelation mechanism of gelled high-energy-density fuels are described. Considering these aspects, the rheology and flow behavior of gelled fuels is summarized in terms of the shear thinning property, dynamic viscoelasticity and thixotropy. Moreover, the progress of atomization of gelled fuels is reviewed with a focus on the effect of atomizing nozzles. In addition, the experiments and theoretical models of single droplet combustion and combustor combustion are described. Finally, research directions for the development and application of gelled fuels are suggested.

关键词: gelled fuels     high-energy-density fuels     rheological properties     atomization     combustion    

Impingement of hollow cone spray on hot porous medium

ZHAO Zhiguo, XIE Maozhao

《能源前沿(英文)》 2008年 第2卷 第3期   页码 273-278 doi: 10.1007/s11708-008-0048-8

摘要: To have a good understanding of the formation of homogenous mixture in a porous medium engine, the interaction between hollow cone spray and hot porous medium was studied numerically by using an improved version of KIVA-3V code. The improved KIVA-3V code is incorporated with an impingement model, heat transfer model and linearized instability sheet atomization (LISA) model to simulate the hollow cone spray. The reasonability of the impingement model and heat transfer model was validated. With a simple model to describe the structure of the porous medium, the interaction between hollow cone spray and hot porous medium was simulated under different ambient pressures and spray cone angles. Computational results show that the fuel spray could be divided into smaller ones, which provides conditions for the quick evaporation of fuel droplets and the mixing of fuel vapor with air. Differences in ambient pressure and spray cone angle affect the distribution of droplets in the porous medium.

关键词: improved version     simple     impingement     atomization     hollow    

Numerical investigation of the effects of fuel spray type on the interaction of fuel spray and hot porous medium

ZHAO Zhiguo, XIE Maozhao

《能源前沿(英文)》 2008年 第2卷 第1期   页码 59-65 doi: 10.1007/s11708-008-0022-5

摘要: The interaction between two types of fuel spray and a hot porous medium is studied numerically by using an improved version of KIVA-3V code. The improved KIVA-3V code is incorporated with an impingement model, a heat transfer model and a linearized instability sheet atomization (LISA) model to model the hollow cone spray. An evaporating fuel spray impingement on a hot plane surface was simulated under conditions of experiments performed by Senda to validate the reasonability of the KIVA-3V code. The numerical results conform well with experimental data for spray radius in the liquid and the vapor phases. Computational results on the interaction of two types of the fuel spray and the hot porous medium show that the fuel spray can be split, which provides conditions for quick evaporation of fuel droplets and mixing of fuel vapor with air. The possibility of fuel droplets from hollow cone spray crossing the porous medium reduces compared with that from solid cone spray, with the same initial kinetic energy of fuel droplets in both injection types.

关键词: improved version     impingement     atomization     hollow     radius    

Intercontinental transport of air pollution

Lin ZHANG,

《环境科学与工程前沿(英文)》 2010年 第4卷 第1期   页码 20-29 doi: 10.1007/s11783-010-0014-7

摘要: There is an increasing interest on the intercontinental transport of air pollution among the three main emission regions at northern mid-latitudes: North America, Europe, and East Asia. Air pollutants with sufficient long lifetime can be transported from one continent to another. Observations from ground sites, aircraft and satellites have demonstrated this intercontinental-scale transport of air pollutants in the free troposphere. Numerical models have been applied to understand the pathways of the transport and the impact of intercontinental pollution transport. This paper reviews current observational evidence and modeling studies of intercontinental transport of ozone and its precursors, and the resulting impacts on air quality.

关键词: intercontinental transport     ozone     air pollution    

Health impacts of air pollution in China

《环境科学与工程前沿(英文)》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1367-1

摘要:

•Impacts of air pollution on various body systems health in China were highlighted.

关键词: Health impacts     Air pollution     China     Advances    

Experimental investigation on desiccant air-conditioning system in India

Vijay MITTAL, B. Kant KHAN,

《能源前沿(英文)》 2010年 第4卷 第2期   页码 161-165 doi: 10.1007/s11708-009-0070-5

摘要: An experimental investigation in India was presented to evaluate the performance and energy saving capacity of a desiccant air-conditioning system composed of a silica gel bed, a split type air-conditioner (1.0 ton refrigeration) installed in a room with a volume of 86.4 m, air ducts and a blower. The experiment was made in such a way that the percentages of return air, outdoor air and indoor air mixed with the air leaving the desiccant and desiccant bed thickness could be adjusted. Tests were conducted on several days with relatively similar ambient conditions. Under the test conditions in this experiment, a 7cm bed thickness is recommended with a maximum adsorption rate of 403g/h. The optimum percentages of air ratios were as follows: 10% of outdoor air, 10% of return air (mixed together at the desiccant bed inlet) and 80% of indoor air mixed with the dry air leaving the desiccant. The corresponding electricity saving was about 19%. As expected, simple economic analysis indicates that the desiccant air-conditioning is not viable for smaller cooling capacities.

关键词: air ratios     ambient conditions     desiccant air-conditioning     silica gel    

Phenolic compounds removal by wet air oxidation based processes

Linbi Zhou, Hongbin Cao, Claude Descorme, Yongbing Xie

《环境科学与工程前沿(英文)》 2018年 第12卷 第1期 doi: 10.1007/s11783-017-0970-2

摘要: Wet air oxidation (WAO) and catalytic wet air oxidation (CWAO) are efficient processes to degrade organic pollutants in water. In this paper, we especially reviewed the WAO and CWAO processes for phenolic compounds degradation. It provides a comprehensive introduction to the CWAO processes that could be beneficial to the scientists entering this field of research. The influence of different reaction parameters, such as temperature, oxygen pressure, pH, stirring speed are analyzed in detail; Homogenous catalysts and heterogeneous catalysts including carbon materials, transitional metal oxides and noble metals are extensively discussed, among which Cu based catalysts and Ru catalysts were shown to be the most active. Three different kinds of the reactor implemented for the CWAO (autoclave, packed bed and membrane reactors) are illustrated and compared. To enhance the degradation efficiency and reduce the cost of the CWAO process, biological degradation can be combined to develop an integrated technology.

关键词: Wet air oxidation     Catalytic wet air oxidation     Phenolic compounds     Heterogeneous catalysts     Mechanism    

API-based assessment on urban air environment bearing capability in China

Jinnan WANG,Jing ZHANG,Hongqiang JIANG,Yaling LU

《环境科学与工程前沿(英文)》 2015年 第9卷 第6期   页码 1049-1055 doi: 10.1007/s11783-014-0662-0

摘要: Given the complexity and time-consuming of the conventional environmental capacity based assessment on air environment carrying capacity; a new method for assessing urban air environment carrying capacity based on air pollution index (API) is presented. By using this new method, the air environmental bearing capability of 333 cities at the prefecture level and above is assessed. The results show that of the 333 cities 9.6% is of high bearing capability, 34.5% relatively high bearing capability, 52.6% medium bearing capability, 2.7% low capability, and 0.6% is of weak bearing capability; in terms of regional distribution, the western region is of relatively high air environment bearing capability, followed by north-eastern and eastern regions, and the ambient air quality in the middle region is quite poor; among the 12 urban agglomerations in key regions, Pearl River delta, west side of Taiwan Strait and Chengdu-Chongqing agglomerations are of relatively high carrying capacity while other agglomerations are of medium bearing capability. The assessment results imply that the existing air quality standard (GB3095-1996) is quite unsound.

关键词: air pollution index (API)     air environment bearing capability     key city     assessment method    

Development of an integrated policy making tool for assessing air quality and human health benefits ofair pollution control

Xuezhen QIU,Yun ZHU,Carey JANG,Che-Jen LIN,Shuxiao WANG,Joshua FU,Junping XIE,Jiandong WANG,Dian DING,Shicheng LONG

《环境科学与工程前沿(英文)》 2015年 第9卷 第6期   页码 1056-1065 doi: 10.1007/s11783-015-0796-8

摘要: Efficient air quality management is critical to protect public health from the adverse impacts of air pollution. To evaluate the effectiveness of air pollution control strategies, the US Environmental Protection Agency (US EPA) has developed the Software for Model Attainment Test-Community Edition (SMAT-CE) to assess the air quality attainment of emission reductions, and the Environmental Benefits Mapping and Analysis Program-Community Edition (BenMAP-CE) to evaluate the health and economic benefits of air quality improvement respectively. Since scientific decision-making requires timely and coherent information, developing the linkage between SMAT-CE and BenMAP-CE into an integrated assessment platform is desirable. To address this need, a new module linking SMAT-CE to BenMAP-CE has been developed and tested. The new module streamlines the assessment of air quality and human health benefits for a proposed air pollution control strategy. It also implements an optimized data gridding algorithm which significantly enhances the computational efficiency without compromising accuracy. The performance of the integrated software package is demonstrated through a case study that evaluates the air quality and associated economic benefits of a national-level control strategy of PM . The results of the case study show that the proposed emission reduction reduces the number of nonattainment sites from 379 to 25 based on the US National Ambient Air Quality Standards, leading to more than US$334 billion of economic benefits annually from improved public health. The integration of the science-based software tools in this study enhances the efficiency of developing effective and optimized emission control strategies for policy makers.

关键词: air quality assessment     human health benefit     economic benefit     air quality attainment assessment     air pollution control strategy     decision support system    

Clean air captures attention whereas pollution distracts: evidence from brain activities

《环境科学与工程前沿(英文)》 2023年 第18卷 第4期 doi: 10.1007/s11783-024-1801-x

摘要:

● We find air pollution distracts attention and reveal the neurocognitive mechanisms.

关键词: Air pollution     Attention     Disengagement     Performance     Event-related potential    

Investigation on regeneration and energy storage characteristics of a solar liquid desiccant air-conditioning

SHI Mingheng, DU Bin, ZHAO Yun

《能源前沿(英文)》 2007年 第1卷 第1期   页码 85-90 doi: 10.1007/s11708-007-0008-8

摘要: Solar liquid desiccant air-conditioner is a new air-conditioning system in which liquid desiccant can be regenerated by solar energy and energy can be stored in the form of chemical energy in the liquid desiccant. In this paper regeneration and energy storage characteristics were studied theoretically and experimentally. Two criterion equations for heat and mass transfer in the regeneration process were obtained. The main factors that influence the regeneration process were analyzed. A principal solar liquid desiccant air-conditioning system under energy storage operating mode is proposed.

关键词: desiccant air-conditioning     regeneration process     air-conditioning system     energy     regeneration    

标题 作者 时间 类型 操作

Effect of extrusion temperature on the physical properties of high-silicon aluminum alloy

YANG Fuliang, GAN Weiping, CHEN Zhaoke

期刊论文

Bicontinuous porous membranes with micro-nano composite structure using a facile atomization-assisted

期刊论文

Preconcentration of trace elements by adsorption onto a niobium wire for electrothermal atomization atomic

Satoshi KANECO, Hiroaki KITANAGA, Hideyuki KATSUMATA, Tohru SUZUKI

期刊论文

aromatic hydrocarbons predicting from general connectivity based hierarchy with discrete correction of atomization

期刊论文

Review on design, preparation and performance characterization of gelled fuels for advanced propulsion

期刊论文

Impingement of hollow cone spray on hot porous medium

ZHAO Zhiguo, XIE Maozhao

期刊论文

Numerical investigation of the effects of fuel spray type on the interaction of fuel spray and hot porous medium

ZHAO Zhiguo, XIE Maozhao

期刊论文

Intercontinental transport of air pollution

Lin ZHANG,

期刊论文

Health impacts of air pollution in China

期刊论文

Experimental investigation on desiccant air-conditioning system in India

Vijay MITTAL, B. Kant KHAN,

期刊论文

Phenolic compounds removal by wet air oxidation based processes

Linbi Zhou, Hongbin Cao, Claude Descorme, Yongbing Xie

期刊论文

API-based assessment on urban air environment bearing capability in China

Jinnan WANG,Jing ZHANG,Hongqiang JIANG,Yaling LU

期刊论文

Development of an integrated policy making tool for assessing air quality and human health benefits ofair pollution control

Xuezhen QIU,Yun ZHU,Carey JANG,Che-Jen LIN,Shuxiao WANG,Joshua FU,Junping XIE,Jiandong WANG,Dian DING,Shicheng LONG

期刊论文

Clean air captures attention whereas pollution distracts: evidence from brain activities

期刊论文

Investigation on regeneration and energy storage characteristics of a solar liquid desiccant air-conditioning

SHI Mingheng, DU Bin, ZHAO Yun

期刊论文