资源类型

期刊论文 11

年份

2022 3

2020 1

2017 1

2012 2

2008 2

2007 2

关键词

MnAl 1

呼吸性粉尘 1

增材制造 1

微观结构 1

气体雾化 1

气雾化 1

永磁体 1

湿润剂 1

球磨法 1

相变 1

磁化水 1

粉末特征 1

纳米结构 1

荷电水雾 1

超声雾化 1

铬镍铁合金 1

降尘效果 1

展开 ︾

检索范围:

排序: 展示方式:

Bicontinuous porous membranes with micro-nano composite structure using a facile atomization-assisted

《化学科学与工程前沿(英文)》 2022年 第16卷 第8期   页码 1268-1280 doi: 10.1007/s11705-022-2143-5

摘要: The micro-nano composite structure can endow separation membranes with special surface properties, but it often has the problems of inefficient preparation process and poor structural stability. In this work, a novel atomization-assisted nonsolvent induced phase separation method, which is also highly efficient and very simple, has been developed. By using this method, a bicontinuous porous microfiltration membrane with robust micro-nano composite structure was obtained via commercially available polymers of polyacrylonitrile and polyvinylpyrrolidone. The formation mechanism of the micro-nano composite structure was proposed. The microphase separation of polyacrylonitrile and polyvinylpyrrolidone components during the atomization pretreatment process and the hydrogen bonding between polyacrylonitrile and polyvinylpyrrolidone molecules should have resulted in the nano-protrusions on the membrane skeleton. The membrane exhibits superhydrophilicity in air and superoleophobicity underwater. The membrane can separate both surfactant-free and surfactant-stabilized oil-in-water emulsions with high separation efficiency and permeation flux. With excellent antifouling property and robust microstructure, the membrane can easily be recycled for long-term separation. Furthermore, the scale-up verification from laboratory preparation to continuous production has been achieved. The simple, efficient, cost-effective preparation method and excellent membrane properties indicate the great potential of the developed membranes in practical applications.

关键词: atomization     nonsolvent induced phase separation     bicontinuous porous structure     micro-nano composite structure     oil-water separation    

Preconcentration of trace elements by adsorption onto a niobium wire for electrothermal atomization atomic

Satoshi KANECO, Hiroaki KITANAGA, Hideyuki KATSUMATA, Tohru SUZUKI

《化学科学与工程前沿(英文)》 2012年 第6卷 第4期   页码 432-435 doi: 10.1007/s11705-012-1219-z

摘要: In the present work, a new preconcentration method of trace elements by adsorption onto a niobium wire has been developed for electrothermal atomization atomic absorption spectrometry (ETAAS) with a tungsten tube atomizer. Detection limits (pg·mL ) by this method combined with ETAAS were 45 for bismuth, 7.0 for cadmium, 20 for copper, 1.3 for gold, 36 for lead, 65 for manganese, 9.5 for rhodium and 19 for silver.

关键词: preconcentration     adsorption onto niobium wire     electrothermal atomization atomic absorption spectrometry     tungsten tube atomizer     trace elements    

aromatic hydrocarbons predicting from general connectivity based hierarchy with discrete correction of atomization

《化学科学与工程前沿(英文)》 2022年 第16卷 第12期   页码 1743-1750 doi: 10.1007/s11705-022-2184-9

摘要: The standard enthalpy of formation is an important predictor of the reaction heat of a chemical reaction. In this work, a high-precision method was developed to calculate accurate standard enthalpies of formation for polycyclic aromatic hydrocarbons based on the general connectivity based hierarchy (CBH) with the discrete correction of atomization energy. Through a comparison with available experimental findings and other high-precision computational results, it was found that the present method can give a good description of enthalpy of formation for polycyclic aromatic hydrocarbons. Since CBH schemes can broaden the scope of application, this method can be used to investigate the energetic properties of larger polycyclic aromatic hydrocarbons to achieve a high-precision calculation at the CCSD(T)/CBS level. In addition, the energetic properties of CBH fragments can be accurately calculated and integrated into a database for future use, which will increase computational efficiency. We hope this work can give new insights into the energetic properties of larger systems.

关键词: standard enthalpy of formation     polycyclic aromatic hydrocarbons     connectivity based hierarchy     high-precision calculation    

Review on design, preparation and performance characterization of gelled fuels for advanced propulsion

《化学科学与工程前沿(英文)》 2022年 第16卷 第6期   页码 819-837 doi: 10.1007/s11705-021-2122-2

摘要: With the increasing demand for high-performance and safe fuels in aerospace propulsion systems, gelled fuels have attracted increasing attention. Because of their unique structure, gelled fuels exhibit the advantages of both solid and liquid fuels, such as high energy density, controllable thrust and storage safety. This review provides an overview on design, preparation and performance characterization of gelled fuels. The composition, preparation process and gelation mechanism of gelled high-energy-density fuels are described. Considering these aspects, the rheology and flow behavior of gelled fuels is summarized in terms of the shear thinning property, dynamic viscoelasticity and thixotropy. Moreover, the progress of atomization of gelled fuels is reviewed with a focus on the effect of atomizing nozzles. In addition, the experiments and theoretical models of single droplet combustion and combustor combustion are described. Finally, research directions for the development and application of gelled fuels are suggested.

关键词: gelled fuels     high-energy-density fuels     rheological properties     atomization     combustion    

Impingement of hollow cone spray on hot porous medium

ZHAO Zhiguo, XIE Maozhao

《能源前沿(英文)》 2008年 第2卷 第3期   页码 273-278 doi: 10.1007/s11708-008-0048-8

摘要: To have a good understanding of the formation of homogenous mixture in a porous medium engine, the interaction between hollow cone spray and hot porous medium was studied numerically by using an improved version of KIVA-3V code. The improved KIVA-3V code is incorporated with an impingement model, heat transfer model and linearized instability sheet atomization (LISA) model to simulate the hollow cone spray. The reasonability of the impingement model and heat transfer model was validated. With a simple model to describe the structure of the porous medium, the interaction between hollow cone spray and hot porous medium was simulated under different ambient pressures and spray cone angles. Computational results show that the fuel spray could be divided into smaller ones, which provides conditions for the quick evaporation of fuel droplets and the mixing of fuel vapor with air. Differences in ambient pressure and spray cone angle affect the distribution of droplets in the porous medium.

关键词: improved version     simple     impingement     atomization     hollow    

Numerical investigation of the effects of fuel spray type on the interaction of fuel spray and hot porous medium

ZHAO Zhiguo, XIE Maozhao

《能源前沿(英文)》 2008年 第2卷 第1期   页码 59-65 doi: 10.1007/s11708-008-0022-5

摘要: The interaction between two types of fuel spray and a hot porous medium is studied numerically by using an improved version of KIVA-3V code. The improved KIVA-3V code is incorporated with an impingement model, a heat transfer model and a linearized instability sheet atomization (LISA) model to model the hollow cone spray. An evaporating fuel spray impingement on a hot plane surface was simulated under conditions of experiments performed by Senda to validate the reasonability of the KIVA-3V code. The numerical results conform well with experimental data for spray radius in the liquid and the vapor phases. Computational results on the interaction of two types of the fuel spray and the hot porous medium show that the fuel spray can be split, which provides conditions for quick evaporation of fuel droplets and mixing of fuel vapor with air. The possibility of fuel droplets from hollow cone spray crossing the porous medium reduces compared with that from solid cone spray, with the same initial kinetic energy of fuel droplets in both injection types.

关键词: improved version     impingement     atomization     hollow     radius    

Effect of extrusion temperature on the physical properties of high-silicon aluminum alloy

YANG Fuliang, GAN Weiping, CHEN Zhaoke

《机械工程前沿(英文)》 2007年 第2卷 第1期   页码 120-124 doi: 10.1007/s11465-007-0021-y

摘要: Light-weight high-silicon aluminum alloys are used for electronic packaging in the aviation and space-flight industry. Al-30Si and Al-40Si are fabricated with air-atomization and vacuum-canning hot-extrusion process. The density, thermal conductivity, hermeticity and thermal expansion coefficients of the material are measured, and the relationship between extrusion temperature and properties is obtained. Experimental results show that the density of high-silicon aluminum alloys prepared with this method is as high as 99.64% of the theory density, and increases with elevating extrusion temperature. At the same time, thermal conductivity varies between 104-140 W/(m " K); with the extrusion temperature, thermal expansion coefficient also increases but within 13?10 (at 100?C) and hermeticity of the material is high to 10 order of magnitude.

关键词: coefficient     hermeticity     temperature     relationship     air-atomization    

Spray characteristics and controlling mechanism of fuel containing CO

Zhen HUANG, Jin XIAO, Xinqi QIAO, Gaozhi JIANG, Yiming SHAO, Seiichi SHIGA, Yasuhiro DAISHO

《能源前沿(英文)》 2012年 第6卷 第1期   页码 80-88 doi: 10.1007/s11708-012-0180-3

摘要: This paper presents studies of spray characteristics and controlling mechanism of fuel containing CO . Using diesel fuel containing CO gas, experiments were conducted on diesel hole-type nozzles and simple nozzles. The steady spray and transient spray characteristics were observed and measured by instantaneous shadowgraphy, high-speed photography, phase Doppler anemometry (PDA) and LDSA respectively. The effects of CO concentration in the fuel, the injection pressure, the nozzle ratio, surrounding gas pressure and temperature on the atomization behavior and spray pattern were evaluated. The results show that the injection of fuel containing CO can greatly improve the atomization and produce a parabolic-shaped spray; and the CO gas concentration, surrounding gas pressure, temperature and nozzle configuration have dominant influences on spray characteristics of the fuel containing CO . New insight into the controlling mechanism of atomization of the fuel containing CO was provided.

关键词: spray characteristics     fuel atomization     fuel containing CO2    

冶金行业呼吸性粉尘的喷雾净化技术研究

邹声华,李刚,李孔清

《中国工程科学》 2007年 第9卷 第11期   页码 196-199

摘要:

阐述了呼吸性粉尘的特点和危害,介绍了近年来国内外在呼吸性粉尘防治和控制方面的新技术,分 析了各种降尘技术的机理并进行了比较。结果表明:在钢铁企业呼吸性粉尘的净化研究中,采用添加湿润剂 的荷电水雾降尘技术是一种较好的治理方案。通过理论分析和试验研究,将该项技术应用于某钢铁企业的 呼吸性粉尘的净化中,取得了良好的降尘效果。

关键词: 呼吸性粉尘     湿润剂     超声雾化     磁化水     荷电水雾     降尘效果    

快速球磨法高效实现各向同性气雾化MnAl 粉的纳米化制备 Article

J. Rial, E.M. Palmero, A. Bollero

《工程(英文)》 2020年 第6卷 第2期   页码 172-176 doi: 10.1016/j.eng.2019.03.013

摘要:

为了提高永磁体性能尤其是矫顽力,对气雾化MnAl粉末首次进行了30 s短时间球磨。结果表明,如此短的处理时间加上随后的退火可以高效地得到纳米结构和可控的相变。球磨过程中产生的微应变引起的缺陷与退火过程中形成的β相共同起到钉扎中心的作用,从而提高了矫顽力。研究表明,为了在磁化强度和矫顽力之间达到折中,在铁磁性τ-MnAl相和β相的形成之间找到一个平衡是很重要的。球磨(30 s)和退火后获得的矫顽力高达4.2 kOe (1 Oe = 79.6 A·m–1),与早期文献报道的球磨时间超过20 h时的矫顽力相当。球磨后粉末的退火温度降低了75 ℃,矫顽力提高了2.5倍,而退火后的气雾化材料的剩磁基本保持不变,为合成各向同性的MnAl基粉末开辟了一条新的途径。

关键词: 永磁体     纳米结构     相变     MnAl     气雾化     球磨法    

用于粉末床增材制造的铬镍铁合金粉末特征研究

Quy Bau Nguyen, Mui Ling Sharon Nai, Zhiguang Zhu, Chen-Nan Sun, Jun Wei, Wei Zhou

《工程(英文)》 2017年 第3卷 第5期   页码 695-700 doi: 10.1016/J.ENG.2017.05.012

摘要:

本研究中使用不同的粉末表征技术对铬镍铁合金的原始粉末和回收粉末在粉末床增材制造(AM)上的流动特性、行为特征进行研究。结果发现,选择性激光熔化(SLM)工艺的粒径分布(PSD)范围通常在15 ~ 63 μm 之间。原始的铬镍铁合粉末的流量约为28 s·(50 g)–1,组装密度是60%。流变测试结果表明,原始粉末与回收粉末相比具有更好的流动性。讨论了两种粉末之间的相互关系。运用铬镍铁合金粉末已经成功打印出了螺旋桨。实验结果表明铬镍铁合金粉末适用于增材制造(AM),本研究为生产增材制造粉末提供参考。

关键词: 增材制造     粉末特征     气体雾化     微观结构     铬镍铁合金    

标题 作者 时间 类型 操作

Bicontinuous porous membranes with micro-nano composite structure using a facile atomization-assisted

期刊论文

Preconcentration of trace elements by adsorption onto a niobium wire for electrothermal atomization atomic

Satoshi KANECO, Hiroaki KITANAGA, Hideyuki KATSUMATA, Tohru SUZUKI

期刊论文

aromatic hydrocarbons predicting from general connectivity based hierarchy with discrete correction of atomization

期刊论文

Review on design, preparation and performance characterization of gelled fuels for advanced propulsion

期刊论文

Impingement of hollow cone spray on hot porous medium

ZHAO Zhiguo, XIE Maozhao

期刊论文

Numerical investigation of the effects of fuel spray type on the interaction of fuel spray and hot porous medium

ZHAO Zhiguo, XIE Maozhao

期刊论文

Effect of extrusion temperature on the physical properties of high-silicon aluminum alloy

YANG Fuliang, GAN Weiping, CHEN Zhaoke

期刊论文

Spray characteristics and controlling mechanism of fuel containing CO

Zhen HUANG, Jin XIAO, Xinqi QIAO, Gaozhi JIANG, Yiming SHAO, Seiichi SHIGA, Yasuhiro DAISHO

期刊论文

冶金行业呼吸性粉尘的喷雾净化技术研究

邹声华,李刚,李孔清

期刊论文

快速球磨法高效实现各向同性气雾化MnAl 粉的纳米化制备

J. Rial, E.M. Palmero, A. Bollero

期刊论文

用于粉末床增材制造的铬镍铁合金粉末特征研究

Quy Bau Nguyen, Mui Ling Sharon Nai, Zhiguang Zhu, Chen-Nan Sun, Jun Wei, Wei Zhou

期刊论文