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Kinetics and mechanism of nitrobenzene degradation by hydroxyl radicals-based ozonation process enhanced

Weizhou Jiao, Shengjuan Shao, Peizhen Yang, Kechang Gao, Youzhi Liu

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 5,   Pages 1197-1205 doi: 10.1007/s11705-020-1998-6

Abstract: OH, resulting in an increase in the indirect oxidation rate of NB by ·OH and consequently effective degradation

Keywords: high gravity technology     hydroxyl radicals     nitrobenzene     reaction kinetics    

Simultaneous removal of trihalomethanes by bimetallic Ag/Zn: kinetics study

Ahmed H A DABWAN, Satoshi KANECO, Hideyuki KATSUMATA, Kiyoyuki EGUSA, Tohru SUZUKI, Kiyohisa OHTA,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 3,   Pages 322-327 doi: 10.1007/s11705-009-0261-y

Abstract: In the present work, bimetallic silver/zinc was applied into the degradation of trihalomethanes, THMsThe kinetics reaction rates and removal efficiencies of the THM compound mixtures, in the aqueous solutionsThe primary degradation reaction followed a pseudo-first-order kinetic law.The first-order rate constants and the degradation efficiencies followed the decreasing order of CHBrhydrophobic characteristics of the THM compounds may become the most important parameters affecting the degradation

Keywords: reaction     first-order     dissociation     degradation reaction     aqueous    

New insight into effect of potential on degradation of Fe-N-C catalyst for ORR

Yanyan GAO, Manman QI, Liang HE, Haiping CHEN, Wenzhe LUO, Ming HOU, Zhigang SHAO

Frontiers in Energy 2021, Volume 15, Issue 2,   Pages 421-430 doi: 10.1007/s11708-021-0727-2

Abstract: In recent years, Fe-N-C catalyst is particularly attractive due to its high oxygen reduction reactionAlthough considerable work has been done to investigate the degradation mechanisms of Fe-N-C catalystthe ORR process of Fe-N-C catalyst would result in the formation of H O , which is proved to be a key degradationIn this paper, a new insight into the effect of potential on degradation of Fe-N-C catalyst was provided

Keywords: proton exchange membrane fuel cells (PEMFCs)     oxygen reduction reaction (ORR)     Fe-N-C catalyst     potential     H2O2     degradation    

Influence of construction-induced damage on the degradation of freeze–thawed lightweight cellular concrete

Frontiers of Structural and Civil Engineering 2021, Volume 15, Issue 3,   Pages 781-792 doi: 10.1007/s11709-021-0733-9

Abstract: construction of lightweight cellular concrete (LCC), material damage frequently occurs, causing the degradation

Keywords: lightweight cellular concrete     construction-induced damage     freeze-thaw action     microstructure     degradation    

Efficient degradation of orange II by ZnMn

Qingzhuo Ni, Hao Cheng, Jianfeng Ma, Yong Kong, Sridhar Komarneni

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 6,   Pages 956-966 doi: 10.1007/s11705-019-1907-z

Abstract: Its catalytic activity has been investigated for the degradation of orange II dye using three differentThe last system exhibits the maximum degradation efficiency of 90%, much higher than the photocatalysisFurthermore, the potential degradation mechanisms applicable to the three systems are discussed withactive species such as Mn(III), O , h , e , SO and HO are proposed to be responsible for the excellent degradation

Keywords: ZnMn2O4     photo-chemical catalysis     bisulfite     dye degradation    

Synergetic PVA degradation and H2 evolution in photocatalytic fuel cells using Ag@Fe2

Likun Sun;Kesi Xiong;Baoning Zhang;Jinghong Fang;Yingchao He;Min Wang;Zhixing Gan;Fanglin Du;Qiong Sun;Liyan Yu;Lifeng Dong

Frontiers of Chemical Science and Engineering 2024, Volume 18, Issue 1,   Pages 8-8 doi: 10.1007/s11705-023-2374-0

Abstract: In a dual-chamber photocatalytic fuel cell device, polyvinyl alcohol degradation and H2 evolutionAdditionally, the feasibility of a Fenton-like reaction in the cathode, utilizing Fe2+ ionshighlighted photoinduced holes (h+) and OH· radicals as pivotal contributions to polyvinyl alcohol degradation

Keywords: photocatalytic fuel cell     PVA     Ag@Fe2O3     cathode materials     Fenton-like reaction    

Promotive effect of pyridine on indole degradation by activated sludge under anoxic conditions

LI Yongmei, GU Guowei, LI Wenshu

Frontiers of Environmental Science & Engineering 2007, Volume 1, Issue 4,   Pages 493-497 doi: 10.1007/s11783-007-0079-0

Abstract: Batch experiments were carried out to investigate the promotive effect of pyridine on indole degradation

Keywords: wastewater treatment     coal-coking wastewater     promotive     degradation    

Sustainable wood-based nanotechnologies for photocatalytic degradation of organic contaminants in aquatic

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 4, doi: 10.1007/s11783-020-1346-6

Abstract:

•Wood and its reassemblies are ideal substrates to develop novel photocatalysts.

Keywords: Wood     Nanocatalysts     Photodegradation     Organic contaminants     Composites    

anchored alginate/poly(acrylic acid/acrylamide) double-network hydrogel composites for efficient catalytic degradation

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 7,   Pages 893-905 doi: 10.1007/s11705-022-2290-8

Abstract: In the tap water system and simulated seawater system, the degradation time of p-nitrophenol atMoreover, the catalyst exhibited outstanding performance in the degradation experiment of four typical

Keywords: double-network hydrogel     dye degradation     silver nanoparticles     alginate    

Thermal degradation kinetics and lifetime estimation for polycarbonate/polymethylphenylsilsesquioxane

Jiangbo WANG, Zhong XIN

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 2,   Pages 167-171 doi: 10.1007/s11705-009-0006-y

Abstract: The thermal degradation behaviors of polycarbonate/polymethylphenylsilsesquioxane (FRPC) composites wereThe isothermal kinetics equation was used to describe the thermal degradation process.The results showed that activation energy ( ), in the case of isothermal degradation, was a quick increasingisothermal condition, the addition of polymethylphenylsilsesquioxane (PMPSQ) retardanted the thermal degradationand enhanced the thermal stability of PC during the early and middle stages of thermal degradation.

Keywords: polycarbonate     polymethylphenylsilsesquioxane     thermal degradation kinetics     activation energy     lifetime    

UV-LED/P25-based photocatalysis for effective degradation of isothiazolone biocide

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 5, doi: 10.1007/s11783-020-1379-x

Abstract:

• UV-LED with shorter wavelength was beneficial for photocatalytic degradation

Keywords: Degradation     Photocatalytic     LED     CMIT     P25    

bismuth oxyiodide with highly exposed (110) facets on curved carbon nitride for the photocatalytic degradation

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 7,   Pages 1125-1138 doi: 10.1007/s11705-021-2116-0

Abstract: (110) facet and abundant oxygen vacancies were successfully designed to enhance the photocatalytic degradationOxytetracycline (OTC) and methyl blue dyes were used as targets for pollutant degradation, and 85.6%and 96.5% photocatalytic degradation efficiencies, respectively, were observed in the optimal proportionAdditionally, high-resolution liquid chromatography-mass spectrography was used to identify the reactionintermediates of OTC, and the possible degradation pathway of this pollutant was proposed.

Keywords: high-exposure (110) facet     oxygen vacancy-rich     BiOI-110/DCN heterojunction     photocatalytic degradation    

Mechanistic insights into the selective photocatalytic degradation of dyes over TiO/ZSM-11

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 8, doi: 10.1007/s11783-023-1701-5

Abstract:

● TiO2/ZSM-11 was prepared by a facile solid state dispersion method.

Keywords: Selective dye degradation     Photocatalysis     TiO2     ZSM-11     Chemisorption    

Advances in catalysts and reaction systems for electro/photocatalytic ammonia production

Frontiers of Chemical Science and Engineering doi: 10.1007/s11705-024-2463-8

Abstract: However, the efficiency of electro/photocatalytic nitrogen reduction reaction is hindered by the challengesadvancements in electro/photocatalytic nitrogen reduction are summarized, encompassing the complex reactionmechanisms, as well as the effective strategies for developing electro/photocatalytic catalysts and advanced reaction

Keywords: ammonia synthesis     electro/photocatalysis     nitrogen fixation     reaction system     economic and efficiency    

Thermodynamic analysis of reaction pathways and equilibrium yields for catalytic pyrolysis of naphtha

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 12,   Pages 1700-1712 doi: 10.1007/s11705-022-2207-6

Abstract: Herein, for a better catalyst design and operation parameters optimization, the reaction pathways andThe results revealed that the thermodynamically favorable reaction pathways for n/iso-paraffinsThe results are thus useful as a direction for future catalyst improvements, facilitating superior reaction

Keywords: naphtha     catalytic pyrolysis     reaction pathway     equilibrium yield    

Title Author Date Type Operation

Kinetics and mechanism of nitrobenzene degradation by hydroxyl radicals-based ozonation process enhanced

Weizhou Jiao, Shengjuan Shao, Peizhen Yang, Kechang Gao, Youzhi Liu

Journal Article

Simultaneous removal of trihalomethanes by bimetallic Ag/Zn: kinetics study

Ahmed H A DABWAN, Satoshi KANECO, Hideyuki KATSUMATA, Kiyoyuki EGUSA, Tohru SUZUKI, Kiyohisa OHTA,

Journal Article

New insight into effect of potential on degradation of Fe-N-C catalyst for ORR

Yanyan GAO, Manman QI, Liang HE, Haiping CHEN, Wenzhe LUO, Ming HOU, Zhigang SHAO

Journal Article

Influence of construction-induced damage on the degradation of freeze–thawed lightweight cellular concrete

Journal Article

Efficient degradation of orange II by ZnMn

Qingzhuo Ni, Hao Cheng, Jianfeng Ma, Yong Kong, Sridhar Komarneni

Journal Article

Synergetic PVA degradation and H2 evolution in photocatalytic fuel cells using Ag@Fe2

Likun Sun;Kesi Xiong;Baoning Zhang;Jinghong Fang;Yingchao He;Min Wang;Zhixing Gan;Fanglin Du;Qiong Sun;Liyan Yu;Lifeng Dong

Journal Article

Promotive effect of pyridine on indole degradation by activated sludge under anoxic conditions

LI Yongmei, GU Guowei, LI Wenshu

Journal Article

Sustainable wood-based nanotechnologies for photocatalytic degradation of organic contaminants in aquatic

Journal Article

anchored alginate/poly(acrylic acid/acrylamide) double-network hydrogel composites for efficient catalytic degradation

Journal Article

Thermal degradation kinetics and lifetime estimation for polycarbonate/polymethylphenylsilsesquioxane

Jiangbo WANG, Zhong XIN

Journal Article

UV-LED/P25-based photocatalysis for effective degradation of isothiazolone biocide

Journal Article

bismuth oxyiodide with highly exposed (110) facets on curved carbon nitride for the photocatalytic degradation

Journal Article

Mechanistic insights into the selective photocatalytic degradation of dyes over TiO/ZSM-11

Journal Article

Advances in catalysts and reaction systems for electro/photocatalytic ammonia production

Journal Article

Thermodynamic analysis of reaction pathways and equilibrium yields for catalytic pyrolysis of naphtha

Journal Article