The new technology of clean burning of coal and simultaneously converting the resultants into value-added products is to add a special admixture in coal and grind them together to form affinity granules, which are sprayed into the boiler of the power plant for affinity calcination. The technology, while ensuring power and heat supply, decreases the contents of carbon residue, NO_x and CO^₂ raises the activity of pulverized coal ashes, conducts soild desulfurization, and turns all the solid resultants into quality cement clinkers in the quick burning and quick cooling boiler, thus eliminating gas and solid pollution without producing secondary pollution, and realizing clean production.