Herein, we report a new concept, constricted interfacial polymerization to study the formation of polyamide thin film composite membranes. Delayed diffusion of protected polyfunctional amine reacts with acyl chloride to produce a transition surface structure. Hydrophilic macromolecules and amphiphilic template induced interfacial polymerization reacted in a limited zone, the aggregation state of polymer chains transform from a random state to a regular stateand membrane permeability increases without a loss of salt rejection. Zeolite nanoparticles dispersed in RO composite membrane changed film morphology and water permeability is increased nearly 50% with equivalent salt rejection.