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《工程(英文)》 >> 2021年 第7卷 第8期 doi: 10.1016/j.eng.2021.07.001

绿色化工应用导向的金属-有机框架材料研究概述

Beijing Key Laboratory for Green Catalysis and Separation & Department of Environmental Chemical Engineering, Beijing University of Technology, Beijing 100124, China

收稿日期: 2019-11-08 修回日期: 2020-06-20 录用日期: 2020-08-06 发布日期: 2021-07-08

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摘要

快速的工业化进程导致当今全球性的能源和环境危机,以推动科技进步、解决相关挑战为目标,发展新型功能材料的重要性与日俱增。近年来,金属-有机框架(MOF)以及MOF衍生物材料引起了广泛关注,促使我们继续进行其结构设计和应用性能方面的探索。MOF材料的制备、表征和加工成型是实现其工业应用的基础。研究人员已经围绕这些主题开展了大量的工作,以绿色化工应用为导向,充分发挥功能性优势,推动MOF材料大规模的工业应用也应当被提上日程。在解决实际问题的过程中,许多经典MOF表现出了相对传统材料的优越性。文中将从MOF化学中的基本概念出发,讨论了MOF材料的工业合成进展及其在多个领域中的应用现状,旨在提供一个系统的研究概述,引导研究者逐渐将研究思路从学术研究转向实际应用。在成本、规模化生产、加工成型和稳定性等挑战被逐一突破之后,MOF及其衍生物材料有望走进工厂,成为我们日常生活中的一部分,进而为人类创造一个基于绿色生产和生活方式的新时代。

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