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《工程(英文)》 >> 2022年 第19卷 第12期 doi: 10.1016/j.eng.2022.05.020

用于锂离子电池的富醚/酯/氟黏结剂配方

a China Tobacco Sichuan Industrial Co., Ltd., Chengdu 610066, China
b Sichuan Sanlian New Material Co., Ltd., Chengdu 610041, China
c Key Laboratory of Biomass Chemical Engineering of the Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
d School of Metallurgy and Environment, Central South University, Changsha 410083, China

收稿日期: 2020-03-31 修回日期: 2022-05-10 录用日期: 2022-05-20 发布日期: 2022-10-18

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摘要

由于硅阳极体积膨胀过大,无法在高能量密度电池中实现实际应用。研究人员一直专注于在阳极中添加黏结剂以限制体积膨胀,来解决这一问题,因为黏结剂的氢键和机械性能可以用来增强黏附力和适应硅阳极的体积变化。在这里,我们综合考虑了黏结剂的氢键、力学性能、稳定性以及与电解液的相容性,设计了一种富醚/酯/氟的复合聚合物P(TFEMA-co-IBVE)。该黏结剂配方具有优异的稳定性、黏结性和机械强度,能够适应硅电极体积的剧烈变化,表现出优异的电化学性能,面积容量高达5.4 mA∙h∙cm−2。这种新型聚合物设计可应用于下一代锂离子电池的其他电极材料。

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