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New perspectives in free nitrous acid (FNA) uses for sustainable wastewater management

《环境科学与工程前沿（英文）》 2024年 第18卷 第2期 doi: 10.1007/s11783-024-1786-5

摘要：

● The historical development of free nitrous acid (FNA) technologies is reviewed.

关键词： Free nitrous acid     Acid-tolerant ammonia oxidizer     In situ generation     Wastewater management    

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Relationships of nitrous oxide fluxes with water quality parameters in free water surface constructed

Juan WU, Jian ZHANG, Wenlin JIA, Huijun XIE, Bo ZHANG

《环境科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 241-247 doi: 10.1007/s11783-009-0023-6

摘要： The effects of chemical oxygen demand (COD) concentration in the influent on nitrous oxide (N O) emissions, together with the relationships between N O and water quality parameters in free water surface constructed wetlands, were investigated with laboratory-scale systems. N O emission and purification performance of wastewater were very strongly dependent on COD concentration in the influent, and the total N O emission in the system with middle COD influent concentration was the least. The relationships between N O and the chemical and physical water quality variables were studied by using principal component scores in multiple linear regression analysis to predict N O flux. The multiple linear regression model against principal components indicated that different water parameters affected N O flux with different COD concentrations in the influent, but nitrate nitrogen affected N O flux in all systems.

关键词： free water surface constructed wetland     nitrous oxide emission     water quality parameter     principal component analysis     multiple linear regression    

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Short-term effects of excessive anaerobic reaction time on anaerobic metabolism of denitrifying polyphosphate- accumulating organisms linked to phosphorus removal and N

Gang GUO, Yayi WANG, Chong WANG, Hong WANG, Mianli PAN, Shaowei CHEN

《环境科学与工程前沿（英文）》 2013年 第7卷 第4期   页码 616-624 doi: 10.1007/s11783-013-0505-4

摘要： The short-term effect of anaerobic reaction time (AnRT) (i.e., 90, 120 and 150 min) on the denitrifying phosphorus (P) removal performance and N O production was examined using a denitrifying enhanced biologic phosphorus removal (EBPR) sludge acclimatized with mixed acetate (HAc) and propionate (Pro) (in the molar ratio 3∶1) as carbon sources. The results showed that when the AnRT was prolonged from 90 to 150 min, the anaerobic polyhydroxyalkanoate (PHA) synthesis was decreased by 15.3%. Moreover, the ineffective PHA consumption occurred in anaerobic phases and contributed to an increased accumulation and higher free nitrous acid (FNA) concentrations (≥0.001–0.0011 mg HNO -N/L) in the subsequent anoxic phases, causing a severe inhibition on anoxic P-uptake and denitrification. Accordingly, the total nitrogen (TN) and total phosphorus (TP) removal efficiencies dropped by approximately 6.3% and 85.5%, respectively; and the ratio of anoxic N O-N production to TN removal increased by approximately 3.8%. The fluorescence in situ hybridization (FISH) analysis revealed that the sludge was mainly dominated by (62.0% (SE = 1.5%)). In conclusion, the short-term excessive anaerobic reaction time negatively impacted denitrifying P removal performance and stimulated more N O production, and its effect on P removal was more obvious than that on nitrogen removal.

关键词： Denitrifying phosphorus removal     anaerobic reaction time     nitrous oxide     polyhydroxyalkanoate     free nitrous acid     fluorescence in-situ hybridization    

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Effects of acid deposition control in China: a review based on responses of subtropical forests

《环境科学与工程前沿（英文）》 2024年 第18卷 第6期 doi: 10.1007/s11783-024-1837-4

摘要：

● S and N leaching from forest soils declined due to recent decreases in anthropogenic S and N emissions in China.

关键词： Acidification     Critical load     Nitrous oxide     Surface water chemistry     Recovery    

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Enzymatic nitrous oxide emissions from wastewatertreatment

Gang Guo, Yayi Wang, Tianwei Hao, Di Wu, Guang-Hao Chen

《环境科学与工程前沿（英文）》 2018年 第12卷 第1期 doi: 10.1007/s11783-018-1021-3

摘要： Nitrous oxide (N O), a potent greenhousegas, is emitted during nitrogen removal in wastewater treatment, significantlycontributing to greenhouse effect. Nitrogen removal generally involvesnitrification and denitrification catalyzed by specific enzymes. N O production and consumption vary considerably in responseto specific enzyme-catalyzed nitrogen imbalances, but the mechanismsare not yet completely understood. Studying the regulation of relatedenzymes’ activity is essential to minimize N O emissions during wastewater treatment. This paper aims to reviewthe poorly understood related enzymes that most commonly involvedin producing and consuming N O in terms oftheir nature, structure and catalytic mechanisms. The pathways ofN O emission during wastewater treatment arebriefly introduced. The key environmental factors influencing N O emission through regulatory enzymes are summarizedand the enzyme-based mechanisms are revealed. Several enzyme-basedtechniques for mitigating N O emissions directlyor indirectly are proposed. Finally, areas for further research onN O release during wastewater treatment arediscussed.

关键词： Nitrous oxide     Mitigation     Enzyme catalysis     Nitrogen removal     Wastewater treatment    

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Efficient base-free oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over copper-doped

Feng Cheng, Dongwen Guo, Jinhua Lai, Meihui Long, Wenguang Zhao, Xianxiang Liu, Dulin Yin

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 960-968 doi: 10.1007/s11705-020-1999-5

摘要： 2,5-Furandicarboxylic acid (FDCA) is an important and renewable building block and can serve as an alternative to terephthalic acid in the production of bio-based degradable plastic. In this study, Cu-doped MnO  nanorods were prepared by a facile hydrothermal redox method and employed as catalysts for the selective oxidation of 5-hydroxymethylfurfural (HMF) to FDCA using -butyl hydroperoxide (TBHP) as an oxidant. The catalysts were characterized using X-ray diffraction analysis, Fourier transform infrared spectroscopy, thermogravimetric analysis, and transmission electron microscopy. The effects of oxidants, solvents, and reaction conditions on the oxidation of HMF were investigated, and a reaction mechanism was proposed. Experimental results demonstrated that 99.4% conversion of HMF and 96.3% selectivity of FDCA were obtained under suitable conditions, and -butanol was the most suitable solvent when TBHP was used as an oxidant. More importantly, the Cu-doped MnO catalyst can maintain durable catalytic activity after being recycled for more than ten times.

关键词： 5-hydroxymethylfurfural     25-furandicarboxylic acid     selective oxidation     Cu-doped MnO2     biomass transformation    

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剩余污泥有机质资源回收利用原位驱动晚期垃圾渗滤液深度脱氮——一种具有显著能源优势的创新生物技术 Article

张方斋, 任尚, 梁浩然, 王兆志, 严颖, 王嘉辉, 彭永臻

《工程（英文）》 2024年 第34卷 第3期   页码 120-132 doi: 10.1016/j.eng.2023.03.005

摘要：

循环经济背景下，剩余污泥生物质能源的可持续回收利用引发广泛关注。本研究提出了一种基于游离亚硝酸（FNA）的创新生物技术，通过耦合短程硝化、发酵和反硝化过程（PN/DN–F/DN）不仅完成剩余活性污泥（WAS）废弃生物质能源回收利用，同时驱动晚期垃圾渗滤液深度脱氮。首先，晚期垃圾渗滤液氨氮[(1708.5 ± 142.9) mg·L−1]在短程硝化耦合反硝化序批式反应器（PN/DN-SBR）好氧段被氧化为亚硝态氮，亚硝态氮累积率高达95.4%±2.5%。PN/DN-SBR出水[NO2−–N = (1196.9 ± 84.2) mg·L−1]与外源浓缩剩余活性污泥[挥发性固体浓度= (15119.8±2484.2) mg·L−1]共同泵送至缺氧反应器，用于发酵耦合反硝化（F/DN-SBR）。游离亚硝酸作为亚硝态氮的质子化形式，通过强烈的生物抑制作用将污泥有机质转化为高品质碳源，被反硝化细菌捕获利用，进而推动氮氧化物的还原过程。该创新技术实现了 4.89 kg·m−3·d−1超高污泥减量速率和 0.46 kg·m−3·d−1 脱氮速率。最后，富含有机物的 F/DN-SBR 出水回流至 PN/DN-SBR 后置缺氧阶段进行二次反硝化脱氮。PN/DN-F/DN系统连续运行 175 天后，每个运行周期平均回收 19350.6 mg 有机物（以COD计），脱氮效率为 95.2%，污泥减量率为 53.4%。以等效能源总量计算，每处理1吨剩余污泥可产生291.8 kW·h当量能源，对促进污水处理领域从能源消耗到能源中和模式的范式转变具有重要意义。

关键词： 剩余污泥     生物质资源回收     污水污泥协同处理     晚期垃圾渗滤液     游离亚硝酸    

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Methane, Nitrous Oxide and Ammonia generation in full-scale swine wastewater purification facilities

Takashi Osada, Makoto Shiraishi, Teruaki Hasegawa, Hirofumi Kawahara

《环境科学与工程前沿（英文）》 2017年 第11卷 第3期 doi: 10.1007/s11783-017-0933-7

摘要： The activated sludge process to remove nitrogen and biochemical oxygen demand (BOD) is reportedly cost-effective for swine wastewater treatment, and it use has thus increased in pig farming. Nitrous oxide (N O) is generated on farms as an intermediate product in nitrification and denitrification, and methane (CH ) is also generated from organic degradation under anaerobic conditions by microorganisms in manure or wastewater. This study was carried out at five activated sludge treatment facilities across Japan between August 2014 and January 2015. Measurements were conducted over several weeks at wastewater purification facilities for swine farms: two in Chiba prefecture (East Japan), two in Okayama prefecture (West Japan), and one in Saga (Southern Japan). Taking several environmental fluctuations into account, we collected measurement data continuously day and night, during both high-temperature and low-temperature periods. The results indicated that CH and N O emission factors were 0.91% (kgCH · kg volatile solids ) and 2.87% (g N O-N· kg total N ), respectively. Ammonia emissions were negligible in all of the measurements from the wastewater facilities. The N O emission factor calculated under this experiment was low compared to our previous finding (5.0%; g N O-N· kg N ) in a laboratory experiment. In contrast, the CH emission factor calculated herein was rather high compared to the laboratory measurements. There was great variation in daily GHG emission factors measured in the actual wastewater treatment facilities. In particular, the N O emission rate was affected by several environmental conditions at each facility location, as well as by the management of the wastewater treatment.

关键词： Manure     Greenhouse gas     Denitrification     BOD/N     Nitrous oxide     Methane    

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Impact of dissolved oxygen on the production of nitrous oxide in biological aerated filters

Qiang He, Yinying Zhu, Guo Li, Leilei Fan, Hainan Ai, Xiaoliu Huangfu, Hong Li

《环境科学与工程前沿（英文）》 2017年 第11卷 第6期 doi: 10.1007/s11783-017-0964-0

摘要： Polymerase chain reaction-denaturing gradient gel electrophoresis (PCR-DGGE) and microelectrode technology were employed to evaluate the Nitrous oxide (N O) production in biological aerated filters (BAFs) under varied dissolved oxygen (DO) concentrations during treating wastewater under laboratory scale. The average yield of gasous N O showed more than 4-fold increase when the DO levels were reduced from 6.0 to 2.0 mg·L , indicating that low DO may drive N O generation. PCR-DGGE results revealed that were dominant and may be responsible for N O emission from the BAFs system. While at a low DO concentration (2.0 mg·L ), might play a role. When DO concentration was the limiting factor (reduced from 6.0 to 2.0 mg·L ) for nitrification, it reduced NO -N oxidation as well as the total nitrification. The data from this study contribute to explain how N O production changes in response to DO concentration, and may be helpful for reduction of N O through regulation of DO levels.

关键词： Nitrous oxide     Biological aerated filter     Microelectrode     Dissolved oxygen     Biofilm    

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Mitigating nitrous oxide emissions from agricultural soils by precision management

Robert M. REES, Juliette MAIRE, Anna FLORENCE, Nicholas COWAN, Ute SKIBA, Tony van der WEERDEN, Xiaotang JU

《农业科学与工程前沿（英文）》 2020年 第7卷 第1期   页码 75-80 doi: 10.15302/J-FASE-2019294

摘要：

Nitrous oxide (N O) emissions make up a significant part of agricultural greenhouse gas emissions. There is an urgent need to identify new approaches to the mitigation of these emissions with emerging technology. In this short review four approaches to precision managements of agricultural systems are described based on examples of work being undertaken in the UK and New Zealand. They offer the opportunity for N O mitigation without any reduction in productivity. These approaches depend upon new sensor technology, modeling and spatial information with which to make management decisions and interventions that can both improve agricultural productivity and environmental protection.

关键词： decision support systems     mitigation     nitrous oxide     precision farming    

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Effect of the addition of organic carbon sources on nitrous oxide emission in anaerobic-aerobic (low

Hongjing LI, Xiurong CHEN, Yinguang CHEN

《环境科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 490-499 doi: 10.1007/s11783-010-0248-4

摘要： The effect of additional organic carbon sources on the production of nitrous oxide (N O) in anaerobic-aerobic (low dissolved oxygen) real wastewater treatment system was investigated. In this paper, three laboratory-scale sequencing batch reactors (SBRs) (SBR-1, SBR-2 and SBR-3) were operating under an anaerobic-aerobic (low dissolved oxygen, 0.15–0.45 mg·L ) configuration. The SBRs were ‘long-term cultured’ respectively with a single municipal wastewater sample, sodium acetate, and a waste-activated sludge alkaline fermentation liquid as the additional carbon sources of real wastewater. Off-gas analysis showed that N O was emitted into the atmosphere during the aerobic (low dissolved oxygen) period in the three SBRs, and the order of N O emission rate was SBR-2>SBR-1>SBR-3. It was observed that the higher poly-β-hydroxyvalerate fraction of polyhydroxyalkanoates, the lower glycogen transformation and less nitrite accumulation was in SBR-3, while the opposite behavior was observed in SBR-2. Further research indicated that the interaction of the factors above potentially affected the N O emission in the anaerobic-aerobic (low dissolved oxygen) system.

关键词： anaerobic-aerobic (low dissolved oxygen)     nitrous oxide (N2O) emitting rate     municipal wastewater     waste activated sludge     alkaline fermentation liquid    

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Pathways toward a pollution-free planet and challenges

《环境科学与工程前沿（英文）》 2024年 第18卷 第6期 doi: 10.1007/s11783-024-1827-0

摘要：

● Zero pollution does not mean no discharge of pollutants.

关键词： Wastewater treatment     Resources     Recovery     Greenhouse gases     Energy     Pollution-free    

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Cell-free systems in the new age of synthetic biology

Fernando Villarreal,Cheemeng Tan

《化学科学与工程前沿（英文）》 2017年 第11卷 第1期   页码 58-65 doi: 10.1007/s11705-017-1610-x

摘要： The advent of synthetic biology has ushered in new applications of cell-free transcription-translation systems. These cell-free systems are reconstituted using cellular proteins, and are amenable to modular control of their composition. Here, we discuss the historical advancement of cell-free systems, as well as their new applications in the rapid design of synthetic genetic circuits and components, directed evolution of biomolecules, diagnosis of infectious diseases, and synthesis of vaccines. Finally, we present our vision on the future direction of cell-free synthetic biology.

关键词： cell-free system     application    

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Decontamination of Cr(VI) facilitated formation of persistent free radicals on rice husk derived biochar

Kaikai Zhang, Peng Sun, Yanrong Zhang

《环境科学与工程前沿（英文）》 2019年 第13卷 第2期 doi: 10.1007/s11783-019-1106-7

摘要：

PFRs were produced on biochar during Cr(VI) decontamination.

PFRs formation on biochar was owing to the oxidization of phenolic-OH by Cr(VI).

Appearance of excessive oxidant led to the consumption of PFRs on biochar.

Biochar charred at high temperature possessed great performance to Cr(VI) removal.

关键词： Biochar     Persistent free radicals     Phenolic hydroxyl groups     Cr(VI) reduction    

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Recent advances in cycloaddition of CO with epoxides: halogen-free catalysis and mechanistic insights

《化学科学与工程前沿（英文）》 2023年 第17卷 第12期   页码 1879-1894 doi: 10.1007/s11705-023-2354-4

摘要： The atom-economical cycloaddition of CO2 with epoxides to synthesize cyclic carbonates is a promising route for valuable utilization of CO2. Halogenide such as alkali metal halides and quaternary ammonium salt have been developed as the efficient catalysts. However, the spilled halogen causes equipment corrosion and affects the product purity. To address these concerns, the halogen-free cycloaddition of CO2 with epoxides has always been desired. In this review, we systematically discussed the halogen-free catalysis for cycloaddition of CO2 with epoxides from the mechanistic insights, aiming to promote the development of efficient halogen-free catalysts. Two types of catalysts, i.e., alternatives of halogen nucleophiles for epoxide activation, and bifunctional catalysts with Lewis acid-base sites for synergistic activation of CO2 and epoxides are summarized and emphasized. Specially, metal oxides as the potential halogen-free catalysts are highlighted due to their flexible acid-base sites for synergistic activation of CO2 and epoxides, facile preparation, and low cost.

关键词： carbon dioxide     halogen-free catalysis     cyclic carbonate     mechanistic insight    

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标题 作者 时间 类型 操作

New perspectives in free nitrous acid (FNA) uses for sustainable wastewater management

期刊论文

Relationships of nitrous oxide fluxes with water quality parameters in free water surface constructed

Juan WU, Jian ZHANG, Wenlin JIA, Huijun XIE, Bo ZHANG

期刊论文

Short-term effects of excessive anaerobic reaction time on anaerobic metabolism of denitrifying polyphosphate- accumulating organisms linked to phosphorus removal and N

Gang GUO, Yayi WANG, Chong WANG, Hong WANG, Mianli PAN, Shaowei CHEN

期刊论文

Effects of acid deposition control in China: a review based on responses of subtropical forests

期刊论文

Enzymatic nitrous oxide emissions from wastewatertreatment

Gang Guo, Yayi Wang, Tianwei Hao, Di Wu, Guang-Hao Chen

期刊论文

Efficient base-free oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid over copper-doped

Feng Cheng, Dongwen Guo, Jinhua Lai, Meihui Long, Wenguang Zhao, Xianxiang Liu, Dulin Yin

期刊论文

剩余污泥有机质资源回收利用原位驱动晚期垃圾渗滤液深度脱氮——一种具有显著能源优势的创新生物技术

张方斋, 任尚, 梁浩然, 王兆志, 严颖, 王嘉辉, 彭永臻

期刊论文

Methane, Nitrous Oxide and Ammonia generation in full-scale swine wastewater purification facilities

Takashi Osada, Makoto Shiraishi, Teruaki Hasegawa, Hirofumi Kawahara

期刊论文

Impact of dissolved oxygen on the production of nitrous oxide in biological aerated filters

Qiang He, Yinying Zhu, Guo Li, Leilei Fan, Hainan Ai, Xiaoliu Huangfu, Hong Li

期刊论文

Mitigating nitrous oxide emissions from agricultural soils by precision management

Robert M. REES, Juliette MAIRE, Anna FLORENCE, Nicholas COWAN, Ute SKIBA, Tony van der WEERDEN, Xiaotang JU

期刊论文

Effect of the addition of organic carbon sources on nitrous oxide emission in anaerobic-aerobic (low

Hongjing LI, Xiurong CHEN, Yinguang CHEN

期刊论文

Pathways toward a pollution-free planet and challenges

期刊论文

Cell-free systems in the new age of synthetic biology

Fernando Villarreal,Cheemeng Tan

期刊论文

Decontamination of Cr(VI) facilitated formation of persistent free radicals on rice husk derived biochar

Kaikai Zhang, Peng Sun, Yanrong Zhang

期刊论文

Recent advances in cycloaddition of CO with epoxides: halogen-free catalysis and mechanistic insights

期刊论文