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Experimental study on compaction-induced anisotropic mechanical property of rockfill material

Xiangtao ZHANG, Yizhao GAO, Yuan WANG, Yu-zhen YU, Xun SUN

《结构与土木工程前沿（英文）》 2021年 第15卷 第1期   页码 109-123 doi: 10.1007/s11709-021-0693-0

摘要： The anisotropy of rockfill materials has a significant influence on the performance of engineering structures. However, relevant research data are very limited, because of the difficulty with preparing specimens with different inclination angles using traditional methods. Furthermore, the anisotropy test of rockfill materials is complex and complicated, especially for triaxial tests, in which the major principal stress plane intersects with the compaction plane at different angles. In this study, the geometric characteristics of a typical particle fraction consisting of a specific rockfill material were statistically investigated, and the distribution characteristics of particle orientation in specimens prepared via different compaction methods were examined. For high-density rockfill materials, a set of specimen preparation devices for inclined compaction planes was developed, and a series of conventional triaxial compression tests with different principal stress direction angles were conducted. The results reveal that the principal stress direction angle has a significant effect on the modulus, shear strength, and dilatancy of the compacted rockfill materials. Analysis of the relationship between the principal stress direction angles, change in the stress state, and change in the corresponding dominant shear plane shows that the angle between the compacted surface and dominant shear plane is closely related to interlocking resistance associated with the particle orientation. In addition, different principal stress direction angles can change the extent of the particle interlocking effect, causing the specimen to exhibit different degrees of anisotropy.

关键词： rockfill     inclination of specimen preparation     anisotropy     mechanical property     mechanism    

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A novel strategy for the construction of silk fibroin–SiO composite aerogel with enhanced mechanicalproperty and thermal insulation performance

《化学科学与工程前沿（英文）》 2023年 第17卷 第3期   页码 288-297 doi: 10.1007/s11705-022-2222-7

摘要： The practical application of silica aerogels is an enormous challenge due to the difficulties in improving both mechanical property and thermal insulation performance. In this work, silk fibroin was used as scaffold to improve the mechanical property and thermal insulation performance of silica aerogels. The ungelled SiO2 precursor solution was impregnated into silk fibroin to prepare silk fibroin–SiO2 composite aerogels via sol−gel method followed by freeze-drying. By virtue of the interfacial hydrogen-bonding interactions and chemical reactions between silk fibroin and silica nanoparticles, SiO2 was well-dispersed in the silk fibroin aerogel and composite aerogels exhibited enhanced mechanical property. By increasing the loading of silk fibroin from 15 wt % to 21 wt %, the maximum compressive stress was enhanced from 0.266 to 0.508 MPa when the strain reached 50%. The thermal insulation performance of the composite aerogels was improved compared with pure silica aerogel, as evidenced that the thermal conductivity was decreased from 0.0668 to 0.0341 W∙m‒1∙K‒1. Moreover, the composite aerogels exhibited better hydrophobicity and fire retardancy compared to pure silica aerogel. Our work provides a novel approach to preparing silk fibroin–SiO2 composite aerogels with enhanced mechanical property and thermal insulation performance, which has potential application as thermal insulation material.

关键词： silica aerogel     silk fibroin     impregnation     thermal insulation     mechanical property    

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Experimental research on the mechanical property of prestressing steel wire during and after heating

ZHENG Wenzhong, HU Qiong, ZHANG Haoyu

《结构与土木工程前沿（英文）》 2007年 第1卷 第2期   页码 247-254 doi: 10.1007/s11709-007-0031-1

摘要： The mechanical property of prestressing steel wire during and after heating is the key factor in the design of fire resistance and after-fire damage evaluation of prestressed structures. Tensile experiment of 16 prestressing steel wires ( = 1770 N/mm, = 5 mm, low relaxation of stress) at high temperature and tensile experiment of 14 prestressed steel wires after heating are carried out. According to the experiment, the shapes of stress-strain curves of steel wire at high temperature go smooth and the mechanical property indexes of the steel wire such as strength, modulus of elasticity, etc., degenerate continuously as temperature increased. According to the experiment after heating, the mechanical property of steel wire varies little when the highest temperature that the steel wire has ever been heated to is lower than 300vH; while the stress-strain curves of steel wire become more ductile and the mechanical property indexes of the steel wire degenerate gradually when the highest temperature is higher than 300vH. By applying the theory of viscoelastic mechanics, stress-strain curves of steel wire at high temperatures without loading rate influence are obtained. The law of mechanical property indexes of the wire is presented. The mathematical models of the stress-strain relationship of the pre-stressed steel wire are established. All can serve as basic data for the analysis of fire resistance and after-fire damage evaluation of pre-stressed structures.
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Facile synthesis of polyaniline nanorods to simultaneously enhance the mechanical properties and wear

《化学科学与工程前沿（英文）》 2023年 第17卷 第9期   页码 1254-1266 doi: 10.1007/s11705-023-2297-3

摘要： To enhance the mechanical properties and wear resistance of epoxy resin, polyaniline nanorods were first synthesized using a facile route, and then introduced into the epoxy matrix to yield composites via solution mixing. Several measurements were conducted to investigate the phase structures and compositions of polyaniline nanorods, and their positive influences on the mechanical and tribological properties of epoxy resin were also characterized. The results confirmed that the as-synthesized polyaniline exhibited representative rod-like morphologies and dispersed well in the epoxy matrix, leading to significant enhancements in the tensile strength and elastic modulus of epoxy composites. The highest values of 110.33 MPa and 2.04 GPa were obtained by adding 5%–7% polyaniline nanorods, which were 43% and 62% higher than the pure sample, respectively. The wear rate was increased first and then decreased along with polyaniline nanorods, presenting the lowest value of 2.12 × 10−5 mm3·Nm–1 by adding 5% filler, which was markedly reduced by ca. 70% compared to the control sample. Finally, the possible wear mechanism was proposed and discussed in detail. This study tried to broaden the applications of polyaniline nanorods in the field of tribology.

关键词： epoxy resin     polyaniline nanorods     mechanical property     tribological performance     wear mechanism    

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phosphorus-containing nickel phyllosilicate whiskers to enhance the flame retardancy of epoxy composites with excellent mechanical

《化学科学与工程前沿（英文）》 2024年 第18卷 第3期 doi: 10.1007/s11705-024-2391-7

摘要： To enhance the fire safety and wear resistance of epoxy, phosphorus-containing nickel phyllosilicate whiskers (FP-NiPS) were synthesized using a facile hydrothermal technology, with 9,10-dihydro-9-oxa-10-phosphaphenanthrene as the organic modifier. The impacts of FP-NiPS on the thermal stability, flame retardancy, and mechanical and tribological properties of EP composites were explored. The findings demonstrated that 5 wt % FP-NiPS elevated the limiting oxygen index of the EP composite from 23.8% to 28.4%, achieving a V-0 rating during vertical burning tests. FP-NiPS could enhance the thermal stability of epoxy resin (EP) and facilitate the development of a dense and continuous carbon layer, thereby significantly improving the fire safety of the EP composites. The FP-NiPS led to an 8.2% increase in the tensile strength and a 38.8% increase in the elastic modulus of the EP composite, showing outstanding mechanical properties. Furthermore, FP-NiPS showed remarkable potential in enhancing the wear resistance of EP. The wear rate of 1 wt % FP-NiPS is 2.34 × 10−5 mm3·N–1·m–1, a decrease of 66.7% compared to EP. This work provides a novel promising modification method to enhance the fire safety, mechanical and wear resistance properties of EP.

关键词： nickel phyllosilicate     epoxy resin     flame retardant     wear resistance     mechanical property    

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Effects of sheet thickness and material on the mechanical properties of flat clinched joint

Chao CHEN, Huiyang ZHANG, Shengdun ZHAO, Xiaoqiang REN

《机械工程前沿（英文）》 2021年 第16卷 第2期   页码 410-419 doi: 10.1007/s11465-020-0618-y

摘要： The flat clinching process is attracting a growing attention in the joining field of lightweight materials because it avoids the geometric protrusion that appears in the conventional clinching process. In this paper, the effects of sheet thickness and material on the mechanical properties of the clinched joint were studied. Al1060 and Al2024 sheets with 2 mm thickness were employed to develop the clinched joint by using different material configurations, and Al1060 sheets with 2.5- and 1.5-mm thicknesses were used to produce the clinched joint by using different thickness configurations. The clinched joints using various sheet configurations were sectioned, and dimensional analysis was conducted. Cross-tensile and shearing tests were carried out to analyze the mechanical properties of the clinched joint, including tensile strength, shearing strength, and absorbed energy. In addition, the failure modes of the clinched joints were discussed. Results indicated that the clinched joint with a stiff top sheet had increased static strength regardless of the test type. The clinched joint with a thick top sheet demonstrated lower static strength than the joint with a thick bottom sheet in the cross-tensile test. However, this result was reversed in the shearing tests. The flat clinching process has a great potential in joining dissimilar and various thickness materials.

关键词： clinched joint     flat clinching process     thickness configuration     material configuration     mechanical property    

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Micro-nanoarchitectonic of aluminum-hydrogel propellant with static stability and dynamic rheology

《化学科学与工程前沿（英文）》 2024年 第18卷 第4期 doi: 10.1007/s11705-024-2404-6

摘要： The aluminum-water system is a promising propellant due to high energy and low signal characteristics, and the gel form is easier to store and utilize. In this work, hydrogels of water and aluminum particles were prepared using the low-molecular-weight gellant agarose. The various physical properties of gel systems, including the water loss rate, phase transition temperature, and centrifugal stability at different gellant and aluminum contents, were examined. Rheological properties were assessed through shear thinning tests, thixotropy tests, strain sweep analysis, and frequency sweep experiments. The microstructure of the gel was obtained through scanning electron microscopy images. The results show that the aluminum-hydrogel network structure is composed of micron-scale aluminum and agarose nanosheets, and the unique micro-nanostructure endows the gel with excellent mechanical strength and thermal stability, which improve with increasing gellant and aluminum contents. Notably, the gel with 2% agarose and 20% aluminum had the best performance; the storage modulus reached 90647 Pa, which was within the linear viscoelastic region, and the maximum withstand pressure was 111.2 kPa, which was 118.8% greater than that of the pure hydrogel. Additionally, the gel demonstrates remarkable shear thinning behavior and can undergo gel-sol transformation upon shearing or heating to exceeding 114 °C.

关键词： aluminum-water propellant     gelled propellant     rheological property     mechanical strength    

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Nickel-based metal−organic framework-derived whisker-shaped nickel phyllosilicate toward efficiently enhanced mechanical

《化学科学与工程前沿（英文）》 2022年 第16卷 第10期   页码 1493-1504 doi: 10.1007/s11705-022-2168-9

摘要： Metal−organic framework-derived materials have attracted significant attention in the applications of functional materials. In this work, the rod-like nickel-based metal−organic frameworks were first synthesized and subsequently employed as the hard templates and nickel sources to prepare the whisker-shaped nickel phyllosilicate using a facile hydrothermal technology. Then, the nickel phyllosilicate whiskers were evaluated to enhance the mechanical, thermal, flammable, and tribological properties of epoxy resin. The results show that adequate nickel phyllosilicate whiskers can disperse well in the matrix, improving the tensile strength and elastic modulus by 13.6% and 56.4%, respectively. Although the addition of nickel phyllosilicate whiskers could not obtain any UL-94 ratings, it enhanced the difficulty in burning the resulted epoxy resin nanocomposites and considerably enhanced thermal stabilities. Additionally, it was demonstrated that such nickel phyllosilicate whiskers preferred to improve the wear resistance instead of the antifriction feature. Moreover, the wear rate of epoxy resin nanocomposites was reduced significantly by 80% for pure epoxy resin by adding 1 phr whiskers. The as-prepared nickel phyllosilicate whiskers proved to be promising reinforcements in preparing of high-performance epoxy resin nanocomposites.

关键词： metal−organic framework     nickel phyllosilicate     whisker     epoxy resin     mechanical response     tribological performance     flammable property    

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Composition design and performance evaluation of rubber-particle cement-stabilized gravel

《结构与土木工程前沿（英文）》 2024年 第18卷 第9期   页码 1466-1477 doi: 10.1007/s11709-024-1112-0

摘要： To improve the mechanical properties and durability of the cement-stabilized base, rubber particles of three different sizes and with three different contents were optimally selected, the evolution laws of the mechanical strength and toughness of rubber-particle cement-stabilized gravel (RCSG) under different schemes were determined, and the optimal particle size and content of rubber particles were obtained. On this basis, the durability of the RCSG base was clarified. The results show that with an increase in the rubber particle size and content, the mechanical strength of RCSG gradually decreased, whereas the toughness and transverse deformation ability gradually increased. 1% content and 2–4 mm sized RCSG can better balance the relationship between mechanical strength and toughness. The 7 d unconfined compressive strength was 17.7% higher than that of the 4–8 mm RCSG. The 28 d toughness index and ultimate splitting strain can be increased by 9.8% and 6.3 times, respectively, compared with ordinary cement-stabilized gravel (CSG). In terms of durability, compared with CSG, RCSG showed a 3.7% increase in the water stability property of cement-stabilized base with 1% content and 2–4 mm rubber particles, 5.5% increase in the frozen coefficient, and 80.6% and 37.9% increase in the fatigue life at 0.70 and 0.85 stress ratio levels, respectively.

关键词： pavement materials     cement-stabilized gravel     rubber particles     material components     mechanical property     durability performance    

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Properties and printability evaluation of three-dimensional printing magnesium oxychloride cement by fully utilizing aeolian sand

《结构与土木工程前沿（英文）》 2023年 第17卷 第11期   页码 1675-1689 doi: 10.1007/s11709-023-0994-6

摘要： Three-dimensional concrete printing (3DCP) is increasingly being applied in harsh environments and isolated regions. However, the effective utilization of aeolian sand (AS) resources and by-products derived from arid zones for 3DCP is yet to be fully realized. This study developed a three-dimensional (3D) printing composite using AS and magnesium oxychloride cement (MOC) from local materials. The effects of the mole ratio of MgO/MgCl2 and sand/binder (S/B) ratio on the mechanical properties such as water resistance, drying shrinkage strain, rheology, and printability, were investigated systematically. The results indicated that the optimal mole ratio of MgO/MgCl2 was 8, which yielded the desired mechanical performance and water resistance. Furthermore, the S/B ratio can be increased to three within the desired printability to increase the AS utilization rate. The rheological recovery and buildability of the 3D-printed MOC with AS were verified. These findings provide a promising strategy for construction in remote deserts.

关键词： 3DCP     AS     magnesium oxychloride cement     mechanical behavior     drying shrinkage     rheological property    

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面向地外建造的星壤基材料性能与表征 Review

周诚, 高玉月, 周燕, 佘伟, 史玉升, 丁烈云, 缪昌文

《工程（英文）》 2024年 第37卷 第6期   页码 159-181 doi: 10.1016/j.eng.2023.11.019

摘要：

随着深空探测技术的不断发展，地外基地的建设将成为人类深空探索进程中的里程碑。相较于其他建造方法，原位建造技术成本低、效益高，具有更优异的可持续发展潜能。本研究总结与梳理了地外星壤基材料关键工程性能及其表征的研究进展，介绍了十三种典型星壤基材料的原位固化成形方法，系统总结了地外星壤基材料的三大类关键工程性能，即力学性能、热、光学性能以及辐射屏蔽性能，进而分析指出了各类性能的影响因素和优化方法。总体而言，现有的挑战在于如何全面、长期与真实地表征地外星壤基材料关键工程性能。相应地，建议的未来研究方向包括：多物理场耦合条件下的高通量表征、极端环境下的加速寿命试验与真实地外场景下的原位实验。 

关键词： 地外建造     性能表征     力学性能     热学性能     光学性能     辐射屏蔽性能    

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Physical and mechanical properties of municipal solid waste incineration residues with cement and coal

Toshifumi MUKUNOKI, Ta Thi HOAI, Daisuke FUKUSHIMA, Teppei KOMIYA, Takayuki SHIMAOKA

《结构与土木工程前沿（英文）》 2019年 第13卷 第3期   页码 640-652 doi: 10.1007/s11709-018-0502-6

摘要： A significant volume of Municipal Solid Waste incineration bottom ash and fly ash (i.e., incineration residues) are commonly disposed as landfill. Meanwhile, reclamation of landfill sites to create a new land space after their closure becomes an important goal in the current fewer and fewer land availability scenario in many narrow countries. The objective of this study is to reclaim incineration residue materials in the landfill site by using cement and coal fly ash as stabilizers aiming at performing quality check as new developed materials before future construction. Indeed, physical and mechanical properties of these new materials should be initially examined at the micro scale, which is the primary fundamental for construction at larger scale. This research examines quantitative influences of using the combination of cement and coal fly ash at different ratio on the internal structure and ability of strength enhancement of incineration residues when suffering from loading. Couple of industrial and micro-focus X-ray computed tomography (CT) scanners combined with an image analysis technique were utilized to characterize and visualize the behavior and internal structure of the incineration residues-cement-coal fly ash mixture under the series of unconfined compression test and curing period effect. Nine types of cement solidified incineration residues in term of different curing period (i.e., 7, 14, 28 days) and coal fly ash addition content (i.e., 0%, 9%, 18%) were scanned before and after unconfined compression tests. It was shown that incineration residues solidified by cement and coal fly ash showed an increase in compression strength and deformation modulus with curing time and coal fly ash content. Three-dimension computed tomography images observation and analysis confirmed that solidified incineration residues including incineration bottom and fly ash as well as cement and coal fly ash have the deliquescent materials. Then, it was studied that stabilized parts play a more important role than spatial void distribution in increment or reduction of compression strength.

关键词： mechanical property     municipal solid waste incineration residues     coal fly ash     unconfined compression test     image analysis     X-Ray Computed Tomography scanners    

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Review of recent developments in cement composites reinforced with fibers and nanomaterials

Jianzhuang XIAO, Nv HAN, Yan LI, Zhongsen ZHANG, Surendra P. SHAH

《结构与土木工程前沿（英文）》 2021年 第15卷 第1期   页码 1-19 doi: 10.1007/s11709-021-0723-y

摘要： The quest for high-performance construction materials is led by the development and application of new reinforcement materials for cement composites. Concrete reinforcement with fibers has a long history. Nowadays, many new fibers associated with high performance and possessing eco-environmental characteristics, such as basalt fibers and plant fibers, have received much attention from researchers. In addition, nanomaterials are considered as a core material in the modification of cement composites, specifically in the enhancement of the strength and durability of composites. This paper provides an overview of the recent research progress on cement composites reinforced with fibers and nanomaterials. The influences of fibers and nanomaterials on the fresh and hardened properties of cement composites are summarized. Moreover, future trends in the application of these fibers or of nanomaterial-reinforced cement composites are proposed.

关键词： cement composites     fiber     nanomaterial     mechanical property     durability    

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Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance reinforcements in epoxy nanocomposites

《化学科学与工程前沿（英文）》 2022年 第16卷 第4期   页码 484-497 doi: 10.1007/s11705-021-2074-6

摘要： The nanocomposites of flower-like nickel phyllosilicate particles incorporated into epoxy resin were fabricated via an in-situ mixing process. The flower-like nickel phyllosilicate particles were firstly synthesized using a mild self-sacrificial templating method, and the morphology and lamellar structure were examined carefully. Several properties of mechanical, thermal and tribological responses of epoxy nanocomposites were performed. It was demonstrated that adequate flower-like nickel phyllosilicate particles dispersed well in the matrix, and the nanocomposites displayed enhanced tensile strength and elastic modulus but decreased elongation at break as expected. In addition, friction coefficient and wear rate were increased first and then decreased along with the particle content, and showed the lowest values at a mass fraction of 5%. Nevertheless, the incorporated flower-like nickel phyllosilicate particles resulted in the continuously increasing thermal stability of epoxy resin (EP) nanocomposites. This study revealed the giant potential of flower-like particles in preparing high-quality EP nanocomposites.

关键词： nickel phyllosilicate     flow-like structure     mechanical property     thermal stability     tribological performance    

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多相复合陶瓷刀具材料的设计与制备

许崇海,艾兴

《中国工程科学》 2001年 第3卷 第3期   页码 71-74

摘要：

陶瓷材料的多相复合与计算机辅助设计是21世纪先进陶瓷材料的重要发展趋势。文章采用理论与实验相结合的方法，建立了多相复合陶瓷刀具材料力学性能与材料组分之间关系的数学模型，采用计算机辅助优 化设计技术求得材料的最优组分。在此基础上，利用热压技术制得一种Al2〇3-SiC-(W,Ti) C多相复合陶瓷刀具材料，该材料具有良好的综合力学性能。

关键词： 陶瓷刀具材料     多相复合     材料设计     模型     力学性能    

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标题 作者 时间 类型 操作

Experimental study on compaction-induced anisotropic mechanical property of rockfill material

Xiangtao ZHANG, Yizhao GAO, Yuan WANG, Yu-zhen YU, Xun SUN

期刊论文

A novel strategy for the construction of silk fibroin–SiO composite aerogel with enhanced mechanicalproperty and thermal insulation performance

期刊论文

Experimental research on the mechanical property of prestressing steel wire during and after heating

ZHENG Wenzhong, HU Qiong, ZHANG Haoyu

期刊论文

Facile synthesis of polyaniline nanorods to simultaneously enhance the mechanical properties and wear

期刊论文

phosphorus-containing nickel phyllosilicate whiskers to enhance the flame retardancy of epoxy composites with excellent mechanical

期刊论文

Effects of sheet thickness and material on the mechanical properties of flat clinched joint

Chao CHEN, Huiyang ZHANG, Shengdun ZHAO, Xiaoqiang REN

期刊论文

Micro-nanoarchitectonic of aluminum-hydrogel propellant with static stability and dynamic rheology

期刊论文

Nickel-based metal−organic framework-derived whisker-shaped nickel phyllosilicate toward efficiently enhanced mechanical

期刊论文

Composition design and performance evaluation of rubber-particle cement-stabilized gravel

期刊论文

Properties and printability evaluation of three-dimensional printing magnesium oxychloride cement by fully utilizing aeolian sand

期刊论文

面向地外建造的星壤基材料性能与表征

周诚, 高玉月, 周燕, 佘伟, 史玉升, 丁烈云, 缪昌文

期刊论文

Physical and mechanical properties of municipal solid waste incineration residues with cement and coal

Toshifumi MUKUNOKI, Ta Thi HOAI, Daisuke FUKUSHIMA, Teppei KOMIYA, Takayuki SHIMAOKA

期刊论文

Review of recent developments in cement composites reinforced with fibers and nanomaterials

Jianzhuang XIAO, Nv HAN, Yan LI, Zhongsen ZHANG, Surendra P. SHAH

期刊论文

Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance reinforcements in epoxy nanocomposites

期刊论文

多相复合陶瓷刀具材料的设计与制备

许崇海,艾兴

期刊论文