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A method to synthesize CdSe nanocrystals

XIE Chuang, CHEN Wei, WANG Jingkang

《化学科学与工程前沿（英文）》 2007年第1卷第4期页码 377-380 doi: 10.1007/s11705-007-0068-7

摘要： CdSe nanocrystals (NCs) have great application prospects in various fields due to their novel properties. Some high-cost and toxic materials such as --octylphosphine oxide (TOPO) are used in the popular method to synthesize CdSe NCs. Based on this, a new low-cost, environment-friendly and safe solvent was introduced in the synthesis of CdSe NCs in this paper. The prepared CdSe NCs were characterized by ultraviolet-visible spectra (UV-Vis), photoluminescence (PL), transmission electron micrograph (TEM), energy disperse X-ray spectra (EDX) and X-ray diffraction (XRD). The CdSe NCs obtained which show a good PL property are monodisperse, size-tunable and of high crystallinity. It indicates that the new solvent A is a good substitute for the solvent used in the classic route and achieves a greener synthesis of CdSe NCs.

关键词： octylphosphine greener synthesis substitute electron micrograph low-cost

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Roles of glutathione and L-cysteine in the biomimetic green synthesis of CdSe quantum dots

Ling-Li Li, Yin-Hua Cui, Jie-Jie Chen, Han-Qing Yu

《环境科学与工程前沿（英文）》 2017年第11卷第6期 doi: 10.1007/s11783-017-0948-0

摘要： Biological synthesis of quantum dots (QDs) as an environmental-friendly and facile preparation method has attracted increasing interests. However, it is difficult to distinguish the roles of bio-thiols in QDs synthesis process because of the complex nature in organisms. In this work, the CdSe QDs synthesis conditions in organisms were reconstructed by using a simplified in vitro approach to uncover the roles of two small bio-thiols in the QDs formation. CdSe QDs were synthesized with glutathione (GSH) and L-cysteine (Cys) respectively. Compared with Cys at the same molar concentration, the CdSe QDs synthesized by GSH had a larger and broader particle size distribution with improved optical properties and crystal structure. Furthermore, quantum chemical calculations indicate that the stronger Cd2+ binding capacity of GSH contributed a lot to the CdSe QDs formation despite of the greater capability Cys for selenite reduction. This work clearly demonstrates the different roles of small thiols in the Cd2+ stabilization in the environment and biomimetic QDs synthesis process.

关键词： CdSe Quantum dots (QDs) Biomimetic synthesis Bio-thiols Glutathione (GSH) Cysteine (Cys)