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电渗析 2

反渗透 1

头孢氨苄 1

废水 1

有机酸 1

氨基酸 1

盐度差能，压力延缓渗透，反向电渗析 1

离子交换膜 1

重金属废水 1

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Tracing the impact of stack configuration on interface resistances in reverse electrodialysis by in situ

《环境科学与工程前沿（英文）》 2022年 第16卷 第4期 doi: 10.1007/s11783-021-1480-9

摘要：

• RED performance and stack resistance were studied by EIS and LSV.

关键词： Reverse electrodialysis     Electrochemical impedance spectroscopy     Concentration polarization     Spacer shadow effect    

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Efficient production of hydrogen peroxide in microbial reverse-electrodialysis cells coupled with thermolytic

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1708-y

摘要：

● Appreciable H2O2 production rate was achieved in MRCs utilizing NH4HCO3 solutions.

关键词： Microbial reverse-electrodialysis cell     Hydrogen peroxide production     Ammonium bicarbonate     Electrolysis cell     Optimization    

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Multistage-batch bipolar membrane electrodialysis for base production from high-salinity wastewater

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 764-773 doi: 10.1007/s11705-021-2114-2

摘要： Bipolar membrane electrodialysis (BMED) is considered a state-of-the-art technology for the conversion of salts into acids and bases. However, the low concentration of base generated from a traditional BMED process may limit the viability of this technology for a large-scale application. Herein, we report an especially designed multistage-batch (two/three-stage-batch) BMED process to increase the base concentration by adjusting different volume ratios in the acid (Vacid), base (Vbase), and salt compartments (Vsalt). The findings indicated that performance of the two-stage-batch with a volume ratio of Vacid:Vbase:Vsalt = 1:1:5 was superior in comparison to the three-stage-batch with a volume ratio of Vacid:Vbase:Vsalt = 1:1:2. Besides, the base concentration could be further increased by exchanging the acid produced in the acid compartment with fresh water in the second stage-batch process. With the two-stage-batch BMED, the maximum concentration of the base can be obtained up to 3.40 mol∙L–1, which was higher than the most reported base production by BMED. The low energy consumption and high current efficiency further authenticate that the designed process is reliable, cost-effective, and more productive to convert saline water into valuable industrial commodities.

关键词： bipolar membrane electrodialysis     multistage-batch     base production     high-salinity wastewater    

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Salinity exchange between seawater/brackish water and domestic wastewater through electrodialysis for

《环境科学与工程前沿（英文）》 2023年 第17卷 第2期 doi: 10.1007/s11783-023-1616-1

摘要：

● Present a general concept called “salinity exchange”.

关键词： Desalination     Potable water reuse     Ion-exchange membrane     Salinity gradient energy     Wastewater discharge    

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Fluoride removal from secondary effluent of the graphite industry using electrodialysis: Optimization

Xiaomeng Wang, Ning Li, Jianye Li, Junjun Feng, Zhun Ma, Yuting Xu, Yongchao Sun, Dongmei Xu, Jian Wang, Xueli Gao, Jun Gao

《环境科学与工程前沿（英文）》 2019年 第13卷 第4期 doi: 10.1007/s11783-019-1132-5

摘要：

RSM was utilized to optimize and model influential parameters on fluoride removal.

Regression models involving independent variables and main response were developed.

Interactive effects and optimum of process factors were illuminated and determined.

Fluoride removal efficiency of 99.69% was observed in optimal process conditions.

关键词： Response surface methodology     Fluoride removal     Electrodialysis     Box-Behnken design    

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电渗析组合反渗透过程处理头孢氨苄酶法母液废水的研究

阮慧敏,黄杰,李健,沈江南,王家德,高从堦

《中国工程科学》 2014年 第16卷 第7期   页码 42-46

摘要：

利用电渗析技术脱除头孢氨苄酶法母液废水中的盐分，研究了操作电压、浓缩室与淡化室流速比、温度等因素对电渗析脱盐过程的影响，并研究了反渗透膜法处理脱盐母液废水的膜通量变化趋势。实验结果表明，当淡化室、浓缩室流量均为500 L/h（流速比1∶1），操作电压为25 V，温度＜30 ℃时，电渗析在高效脱盐的同时具有理想的有机物截留率达99.50 %以上，能耗3.65 kW · h/kg；反渗透膜法在处理脱盐母液废水时，膜通量衰减较慢，水回收率达到75.67 %。实验结果表明，利用电渗析、反渗透组合工艺处理头孢氨苄酶法母液废水具有良好的可行性。

关键词： 头孢氨苄     废水     电渗析     反渗透    

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Electrochemical removal of nitrate in industrial wastewater

Dong Xu, Yang Li, Lifeng Yin, Yangyuan Ji, Junfeng Niu, Yanxin Yu

《环境科学与工程前沿（英文）》 2018年 第12卷 第1期 doi: 10.1007/s11783-018-1033-z

摘要： A number of recent studies have demonstrated that electrochemical technologies, including electroreduction (ER), electrocoagulation (EC), and electrodialysis (ED), are effective in nitrate elimination in wastewater due to their high reactivity. To obtain the maximal elimination efficiency and current efficiency, many researchers have conducted experiments to investigate the optimal conditions (i.e., potential, current density, pH value, plate distance, initial nitrate concentration, electrolyte, and other factors) for nitrate elimination. The mechanism of ER, EC and ED for nitrate removal has been fully elucidated. The ER mechanism of nitrate undergoes electron transfer and hydrogenation reduction. The EC pathways of nitrate removal include reduction, coagulation and flotation. The ED pathways of nitrate include redox reaction and dialysis. Although the electrochemical technology can remove nitrate from wastewater efficiently, many problems (such as relatively low selectivity toward nitrogen, sludge production and brine generation) still hinder electrochemical treatment implementation. This paper critically presents an overview of the current state-of-the-art of electrochemical denitrification to enhance the removal efficiency and overcome the shortages, and will significantly improve the understanding of the detailed processes and mechanisms of nitrate removal by electrochemical treatment and provide useful information to scientific research and actual practice.

关键词： Nitrate removal     Electroreduction     Electrocoagulation     Electrodialysis    

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盐度差能：现状和新趋势

Olivier Schaetzle, Cees J. N. Buisman

《工程（英文）》 2015年 第1卷 第2期   页码 164-166 doi: 10.15302/J-ENG-2015046

摘要：

在本文中，我们概述了盐度梯度技术的最新发展情况。在描述最先进盐度梯度技术的发展现状之前，我们首先介绍了盐度差能概念。本文以盐度梯度技术新兴领域中的新趋势作为结尾。

关键词： 盐度差能，压力延缓渗透，反向电渗析    

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Comparison of the removal of monovalent and divalent cations in the microbial desalination cell

Shanshan CHEN,Haiping LUO,Yanping HOU,Guangli LIU,Renduo ZHANG,Bangyu QIN

《环境科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 317-323 doi: 10.1007/s11783-013-0596-y

摘要： Microbial desalination cell (MDC) is a promising technology to desalinate water and generate electrical power simultaneously. The objectives of this study were to investigate the desalination performance of monovalent and divalent cations in the MDC, and discuss the effect of ion characteristics, ion concentrations, and electrical characteristics. Mixed salt solutions of NaCl, MgCl , KCl, and CaCl with the same concentration were used in the desalination chamber to study removal of cations. Results showed that in the mixed salt solutions, the electrodialysis desalination rates of cations were: Ca >Mg >Na >K . Higher ionic charges and smaller hydrated ionic radii resulted in higher desalination rates of the cations, in which the ionic charge was more important than the hydrated ionic radius. Mixed solutions of NaCl and MgCl with different concentrations were used in the desalination chamber to study the effect of ion concentrations. Results showed that when ion concentrations of Na were one-fifth to five times of Mg , ion concentration influenced the dialysis more profoundly than electrodialysis. With the current densities below a certain value, charge transfer efficiencies became very low and the dialysis was the main process responsible for the desalination. And the phosphate transfer from the anode chamber and potassium transfer from the cathode chamber could balance 1%–3% of the charge transfer in the MDC.

关键词： divalent ion     electrodialysis     ion characteristic     microbial desalination cell     monovalent ion    

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新型通用离子交换膜的研究与实践

汪耀明,吴亮,徐铜文

《中国工程科学》 2014年 第16卷 第12期   页码 76-86

摘要：

基于离子交换膜的电膜技术，由于其独特的离子传递特性，可以进行离子物系的分离分级，在清洁生产、节能减排、环境保护、能量转换等方面有着广泛的应用前景。然而，目前国内相关均相离子膜产品尚处于起步阶段，以日本为首的国家对我国进行相关技术封锁和价格垄断。正是基于这样的产业背景和现实意义，开发出新型的均相离子膜制备路线尤为重要。本课题组提出了一种简单而通用的侧链型离子化芳香族聚合物的合成方法，即“离子单体聚酰基化”均相离子交换膜制备路线，并通过ATRP法来设计离子交换膜的主链憎水、侧链亲水的接枝结构，通过对接枝密度和接枝长度进行调节，实现对膜性能的调控，以满足不同的应用过程对膜性能的要求。此种均相离子交换膜的制备工艺及产业化生产攻关，可以打破以日本为首的国家对我国离子膜产品的技术封锁，实现具有我国自主知识产权的离子膜技术的产业化。制备条件温和、制备工艺简单、快捷，而且整个过程没有传统方法中常用的季铵化或磺化步骤，有效地简化工艺和降低环境污染，可用于扩散渗析、普通电渗析以及双极膜电渗析过程对高性能离子交换膜材料的需求。该系列离子交换膜在特种废水处理、有机酸生产、氨基酸分离纯化、重金属废水处理等诸多领域得到了广泛的使用，均取得了较为满意的使用效果。

关键词： 离子交换膜     电渗析     有机酸     氨基酸     重金属废水    

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标题 作者 时间 类型 操作

Tracing the impact of stack configuration on interface resistances in reverse electrodialysis by in situ

期刊论文

Efficient production of hydrogen peroxide in microbial reverse-electrodialysis cells coupled with thermolytic

期刊论文

Multistage-batch bipolar membrane electrodialysis for base production from high-salinity wastewater

期刊论文

Salinity exchange between seawater/brackish water and domestic wastewater through electrodialysis for

期刊论文

Fluoride removal from secondary effluent of the graphite industry using electrodialysis: Optimization

Xiaomeng Wang, Ning Li, Jianye Li, Junjun Feng, Zhun Ma, Yuting Xu, Yongchao Sun, Dongmei Xu, Jian Wang, Xueli Gao, Jun Gao

期刊论文

电渗析组合反渗透过程处理头孢氨苄酶法母液废水的研究

阮慧敏,黄杰,李健,沈江南,王家德,高从堦

期刊论文

Electrochemical removal of nitrate in industrial wastewater

Dong Xu, Yang Li, Lifeng Yin, Yangyuan Ji, Junfeng Niu, Yanxin Yu

期刊论文

盐度差能：现状和新趋势

Olivier Schaetzle, Cees J. N. Buisman

期刊论文

Comparison of the removal of monovalent and divalent cations in the microbial desalination cell

Shanshan CHEN,Haiping LUO,Yanping HOU,Guangli LIU,Renduo ZHANG,Bangyu QIN

期刊论文

新型通用离子交换膜的研究与实践

汪耀明,吴亮,徐铜文

期刊论文