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Enrichment and transfer of polycyclic aromatic hydrocarbons (PAHs) through dust aerosol generation from

《环境科学与工程前沿（英文）》 2023年 第17卷 第1期 doi: 10.1007/s11783-023-1610-7

摘要：

● Compositional patterns of PAHs in dust aerosol vary from soil during dust generation.

关键词： Dust aerosols     Enrichment factors (EFs)     Polycyclic aromatic hydrocarbons (PAHs)    

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The transformation of PAHs in the sewage sludge incineration treatment

Hui ZHANG,Le XU,Yifei ZHANG,Mengchan JIANG

《环境科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 336-340 doi: 10.1007/s11783-014-0766-6

摘要： The release of pollutants from sewage sludge in the treatment process is a worldwide tricky problem in the field of sludge treatment. In this paper, the release and reaction between monomers of polycyclic aromatic hydrocarbons (PAHs) in the sewage sludge incineration treatment were studied based on simulated experiments. The result indicates that the transformation may occurre between monomers of PAHs during their release in the treatment. Over 90% of total PAHs in sewage sludge are released at the the temperature of 300°C–750°C. The possible transformation of Naphthalene to indeno(1, 2, 3-cd)pyrene was related to the temperature of the treatment system. Here, we showed that the output rate of transformation reactions for indeno(1, 2, 3-cd)pyrene is 94% at 300°C. These findings, by identifying corresponding treatment conditions as well as techniques, can help to understand the reactions and control real outputs of PAHs in the treatment process.

关键词： release of monomers     transformation of monomers     PAHs     sewage sludge     incineration treatment    

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Investigation on sampling artifacts of particle associated PAHs using ozone denuder systems

Kai LIU, Fengkui DUAN, Kebin HE, Yongliang MA, Yuan CHENG

《环境科学与工程前沿（英文）》 2014年 第8卷 第2期   页码 284-292 doi: 10.1007/s11783-013-0555-7

摘要： Polycyclic aromatic hydrocarbons (PAHs) are complex organic compounds which are identified as significant carcinogenic to human health. PAHs (mainly in particle phase) are susceptible to atmospheric oxidant gases, especially ozone, nitrogen oxides (NO ), hydroxyl radical (OH), and could be degraded on filters during sampling process, leading to an underestimation of ambient PAH concentrations. The goal of this work was to investigate particle associated PAHs sampling artifacts caused by ozone in summer of Beijing. Comparative sampling systems were operated simultaneously during the whole campaign, one with activated carbon ozone denuder, the other being set as conventional sampling system. Activated carbon denuder was testified to be highly efficient to eliminate ozone from air stream. In general, nine particle-bound PAHs observed from conventional sampler were all lower than those from ozone denuder system. The total PAHs (particle phase) concentration was averagely underestimated by 35.9% in conventional sampling procedure. Benzo[a]pyrene (BaP) had the highest percentage of mass loss. Ambient temperature was founded to have influences on PAHs sampling artifacts. High temperature can increase loss of particle associated PAHs during sampling.

关键词： particle associated polycyclic aromatic hydrocarbons (PAHs)     ozone     denuder     sampling artifacts    

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Multiphase redistribution differences of polycyclic aromatic hydrocarbons (PAHs) between two successive

Rufeng LI,Chenghong FENG,Dongxin WANG,Baohua LI,Zhenyao SHEN

《环境科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 381-389 doi: 10.1007/s11783-015-0817-7

摘要： Successive sediment suspensions often happen in estuary, yet little research has probed into the difference in the release behaviors of organic compounds among different suspensions. This study took polycyclic aromatic hydrocarbons (PAHs) as typical organic contaminants and investigated the release behaviors between two successive suspensions with a particle entrainment simulator (PES). Results showed that successive sediment suspensions lowered the concentration of dissolved PAHs in the overlying water via facilitating the re-adsorption of dissolved PAHs onto the suspended particles. Fast-release and slow-release periods of PAHs were successively observed in the both suspensions. The concentration changes of dissolved PAHs in the second suspension were generally similar with but hysteretic to those in the first suspension. More vigorous desorption and re-absorption of PAHs were induced in the second suspension. Successive sediment suspensions obviously decreased the concentrations of mineral composition and organic matters in the overlying water, which significantly affects multiphase distribution of PAHs.

关键词： sediment suspension     PAHs     multiphase distribution     distribution coefficients    

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Biologic risk and source diagnose of 16 PAHs from Haihe River Basin, China

Qiuying CHEN,Jingling LIU,Feng LIU,Binbin WANG,Zhiguo CAO

《环境科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 46-52 doi: 10.1007/s11783-014-0717-2

摘要： Surface sediments of rivers can exhibit spatial and temporal variations in contaminant concentrations that may significantly affect risk evaluations. As to pollution control and remediation of watershed, large-scale and further background data on PAHs in China were required urgently. Spatial distribution and compositional characteristics of 16 polycyclic aromatic hydrocarbons (PAHs) in surface sediments from Haihe River Basin were investigated. A method based on effects range (ER) was used to assess ecosystem risk of ∑PAHs (the total of 16 PAH) sensitively and accurately. The results indicated that ∑PAHs content levels ranged from 257 to 16901 μg·kg dry weight. The lower rings predominated in the samples, and 2-, 3-, 4-, 5- and 6-ring PAHs accounted for 12%, 21%, 30%, 30%, and 7% respectively in total PAHs. The ratio of Fl / (Fl+ Py) uniformly distributed in the interval 0.20–0.80, indicating that it may be affected by petroleum origin, oil combustion, biomass and coal combustion jointly. ∑PAHs in Cetian (S6), Dongwushi (S19), Handan (S20), Aixinzhuang (S21) and Tianjin (S37) exceeded effects range low (ERL), in which biologic effects were in a medium level with an adverse effect on biologic organisms. Thus, it is necessary to strengthen the PAHs monitoring and research of the Haihe River Basin.

关键词： polycyclic aromatic hydrocarbons (PAHs)     biological effects     sediment     Haihe River    

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Impact of solids on biphasic biodegradation of phenanthrene in the presence of hydroxypropyl- β -cyclodextrin (HPCD)

Zhenyi ZHANG, Chihiro INOUE, Guanghe LI,

《环境科学与工程前沿（英文）》 2010年 第4卷 第3期   页码 329-333 doi: 10.1007/s11783-010-0232-z

摘要： The consequence of polycyclic aromatic hydrocarbons (PAHs) in the environment is of great concern. The hydrophobic properties of PAHs significantly impact phase distribution causing limited bioavailability. Enhanced biodegradation has been extensively carried out by surfactants and the redeployment effect was recognized. However, the quantitative relationship concerning the impact of solids was rarely reported. A batch of biphasic tests were carried out by introducing PYR-1 and hydroxypropyl--cyclodextrin (HPCD) into a mixture of phenanthrene solution and various glass beads (GB37-63, GB105-125, and GB350-500). The comparative results demonstrated that HPCD had little effect on microbial growth and was not degradable by bacterium. A model was proposed to describe the biodegradation process. The regression results indicated that the partition coefficient (1.234, 0.726 and 0.448 L·g) and the degradation rate (0 mmol·L: 0.055, 0.094, and 0.112; 20 mmol·L: 0.126, 0.141, and 0.156; 40 mmol·L: 0.141, 0.156 and 0.184 d) were positively and negatively correlated with the calculated total surface area (TSA) of solids, respectively. Degradation enhanced in the presence of HPCD, and the enhancing factor was calculated (20 mmol·L: 15.16, 40.01, and 145.5; 40 mmol·L: 13.29, 37.97, and 138.4), indicating that the impact of solids was significant for the enhancement of biodegradation.

关键词： biphasic biodegradation     hydroxypropyl-β     -cyclodextrin (HPCD)     polycyclic aromatic hydrocarbons (PAHs)    

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Application of probabilistic risk assessment at a coking plant site contaminated by Polycyclic Aromatic Hydrocarbons

XIA Tianxiang,JIANG Lin,JIA Xiaoyang,ZHONG Maosheng,LIANG Jing

《环境科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 441-450 doi: 10.1007/s11783-013-0572-6

摘要： Application of Probabilistic Risk Assessment (PRA) and Deterministic Risk Assessment (DRA) at a coking plant site was compared. By DRA, Hazard Quotient (HQ) following exposure to Naphthalene (Nap) and Incremental Life Cancer Risk (ILCR) following exposure to Benzo(a)pyrene (Bap) were 1.87 and 2.12 × 10 . PRA revealed valuable information regarding the possible distribution of risk, and risk estimates of DRA located at the 99.59th and 99.76th percentiles in the risk outputs of PRA, which indicated that DRA overestimated the risk. Cleanup levels corresponding acceptable HQ level of 1 and ILCR level of 10 were also calculated for both DRA and PRA. Nap and Bap cleanup levels were 192.85 and 0.14 mg·kg by DRA, which would result in only 0.25% and 0.06% of the exposed population to have a risk higher than the acceptable risk, according to the outputs of PRA. The application of PRA on cleanup levels derivation would lift the cleanup levels 1.9 times for Nap and 2.4 times for Bap than which derived by DRA. For this coking plant site, the remediation scale and cost will be reduced in a large portion once the method of PRA is used. Sensitivity analysis was done by calculating the contribution to variance for each exposure parameter and it was found that contaminant concentration in the soil ( ), exposure duration ( ), total hours spent outdoor per day ( ), soil ingestion rate ( ), the air breathing rate ( ) and bodyweight ( ) were the most important parameters for risk and cleanup levels calculations.

关键词： Probabilistic Risk Assessment (PRA)     a coking plant     risk     cleanup level     sensitivity analysis     polycyclic aromatic hydrocarbons (PAHs)    

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Particle-bound polycyclic aromatic hydrocarbons in typical urban of Yunnan-Guizhou Plateau: Characterization, sources and risk assessment

《环境科学与工程前沿（英文）》 2022年 第16卷 第9期 doi: 10.1007/s11783-022-1535-6

摘要：

• The sampling was conducted in city on the Yunnan-Guizhou Plateau for one year.

关键词： Particle-associated PAHs     Fine particle     Source appointment     Group analysis     Risk assessment     Biomass burning    

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Persistent free radicals in humin under redox conditions and their impact in transforming polycyclic aromatic hydrocarbons

Hanzhong Jia, Yafang Shi, Xiaofeng Nie, Song Zhao, Tiecheng Wang, Virender K. Sharma

《环境科学与工程前沿（英文）》 2020年 第14卷 第4期 doi: 10.1007/s11783-020-1252-y

摘要： Abstract • Regulation of redox conditions promotes the generation of free radicals on HM. • HM-PFRs can be fractionated into active and inactive types depending on stability. • The newly produced PFRs readily release electrons to oxygen and generate ROS. • PFR-induced ROS mediate the transformation of organic contaminants adsorbed on HM. The role of humic substance-associated persistent free radicals (PFRs) in the fate of organic contaminants under various redox conditions remains unknown. This study examined the characterization of original metal-free peat humin (HM), and HM treated with varying concentrations of H2O2 and L-ascorbic acid (VC) (assigned as H2O2-HM and VC-HM). The concentration of PFRs in HM increased with the addition of VC/H2O2 at concentrations less than 0.08 M. The evolution of PFRs in HM under different environmental conditions (e.g., oxic/anoxic and humidity) was investigated. Two types of PFRs were detected in HM: a relatively stable radical existed in the original sample, and the other type, which was generated by redox treatments, was relatively unstable. The spin densities of VC/H2O2-HM readily returned to the original value under relatively high humidity and oxic conditions. During this process, the HM-associated “unstable” free radicals released an electron to O2, inducing the formation of reactive oxygen species (ROS, i.e., •OH and •O2−). The generated ROS promoted the degradation of polycyclic aromatic hydrocarbons based on the radical quenching measurements. The transformation rates followed the order naphthalene>phenanthrene>anthracene>benzo[a]pyrene. Our results provide valuable insight into the HM-induced transformation of organic contaminants under natural conditions.

关键词： Humic substance     Polycyclic aromatic hydrocarbons (PAHs)     Persistent free radicals (PFRs)     Redox     Reactive oxygen species (ROS)    

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Removal of high concentrations of polycyclic aromatic hydrocarbons from contaminated soil by biodiesel

Jinbao WU, Zongqiang GONG, Liyan ZHENG, Yanli YI, Jinghua JIN, Xiaojun LI, Peijun LI

《环境科学与工程前沿（英文）》 2010年 第4卷 第4期   页码 387-394 doi: 10.1007/s11783-010-0269-z

摘要： Solubilizing experiments were carried out to evaluate the ability of biodiesel to remove polycyclic aromatic hydrocarbons (PAHs) from highly contaminated manufactured gas plant (MGP) and PAHs spiked soils with hydroxypropyl-β-cyclodextrin (HPCD) and tween 80 as comparisons. Biodiesel displayed the highest solubilities of phenanthrene (420.7 mg·L ), pyrene (541.0 mg·L ), and benzo(a)pyrene (436.3 mg·L ). These corresponded to several fold increases relative to 10% HPCD and tween 80. Biodiesel showed a good efficiency for PAH removal from the spiked and MGP soils for both low molecular weight and high molecular weight PAHs at high concentrations. Biodiesel was the best agent for PAH removal from the spiked soils as compared with HPCD and tween 80; as over 77.9% of individual PAH were removed by biodiesel. Tween 80 also showed comparable capability with biodiesel for PAH solubilization at a concentration of 10% for the spiked soils. Biodiesel solubilized a wider range of PAHs as compared to HPCD and tween 80 for the MPG soils. At PAH concentrations of 229.6 and 996.9 mg·kg , biodiesel showed obvious advantage over the 10% HPCD and tween 80, because it removed higher than 80% of total PAH. In this study, a significant difference between PAH removals from the spiked and field MGP soils was observed; PAH removals from the MGP soil by HPCD and tween 80 were much lower than those from the spiked soil. These results demonstrate that the potential for utilizing biodiesel for remediation of highly PAH-contaminated soil has been established.

关键词： polycyclic aromatic hydrocarbons (PAHs)     biodiesel     soil     removal     solubilization    

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Determination of persistent organic pollutants by gas chromatography/laser multiphoton ionization/time-of-flight mass spectrometry

Osamu SHITAMICHI, Taiki MATSUI, Yamei HUI, Weiwei CHEN, Totaro IMASAKA

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 26-31 doi: 10.1007/s11783-011-0374-7

摘要： An authentic mixture of polychlorinated biphenyls was measured using a short wide-bore capillary column for the group separation of major components present in an actual sample of Kanechlor. The limits of detection were improved by ca. 2 fold in comparison with those obtained using a conventional capillary column, since the retention time was reduced and the amount of analytes introduced into the mass spectrometer per unit time could be increased. On the other hand, surface-water and sediment samples containing polycyclic aromatic hydrocarbons (PAHs) were collected from the river located in the vicinity of a waste water treatment plant. Even acenaphthylene, a minor component of the mixture could be measured for the sediment sample, and the concentrations were determined for several heavy PAHs. As demonstrated, a technique involving laser multiphoton ionization/time-of-flight mass spectrometry was useful as a sensitive and selective analytical tool for the trace analysis of persistent organic pollutants in an environmental sample.

关键词： polychlorinated biphenyls (PCBs)     polycyclic aromatic hydrocarbons (PAHs)     laser multiphoton ionization/time-of-flight mass spectrometry (MPI/TOF-MS)    

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标题 作者 时间 类型 操作

Enrichment and transfer of polycyclic aromatic hydrocarbons (PAHs) through dust aerosol generation from

期刊论文

The transformation of PAHs in the sewage sludge incineration treatment

Hui ZHANG,Le XU,Yifei ZHANG,Mengchan JIANG

期刊论文

Investigation on sampling artifacts of particle associated PAHs using ozone denuder systems

Kai LIU, Fengkui DUAN, Kebin HE, Yongliang MA, Yuan CHENG

期刊论文

Multiphase redistribution differences of polycyclic aromatic hydrocarbons (PAHs) between two successive

Rufeng LI,Chenghong FENG,Dongxin WANG,Baohua LI,Zhenyao SHEN

期刊论文

Biologic risk and source diagnose of 16 PAHs from Haihe River Basin, China

Qiuying CHEN,Jingling LIU,Feng LIU,Binbin WANG,Zhiguo CAO

期刊论文

Impact of solids on biphasic biodegradation of phenanthrene in the presence of hydroxypropyl- β -cyclodextrin (HPCD)

Zhenyi ZHANG, Chihiro INOUE, Guanghe LI,

期刊论文

Application of probabilistic risk assessment at a coking plant site contaminated by Polycyclic Aromatic Hydrocarbons

XIA Tianxiang,JIANG Lin,JIA Xiaoyang,ZHONG Maosheng,LIANG Jing

期刊论文

Particle-bound polycyclic aromatic hydrocarbons in typical urban of Yunnan-Guizhou Plateau: Characterization, sources and risk assessment

期刊论文

Persistent free radicals in humin under redox conditions and their impact in transforming polycyclic aromatic hydrocarbons

Hanzhong Jia, Yafang Shi, Xiaofeng Nie, Song Zhao, Tiecheng Wang, Virender K. Sharma

期刊论文

Removal of high concentrations of polycyclic aromatic hydrocarbons from contaminated soil by biodiesel

Jinbao WU, Zongqiang GONG, Liyan ZHENG, Yanli YI, Jinghua JIN, Xiaojun LI, Peijun LI

期刊论文

Determination of persistent organic pollutants by gas chromatography/laser multiphoton ionization/time-of-flight mass spectrometry

Osamu SHITAMICHI, Taiki MATSUI, Yamei HUI, Weiwei CHEN, Totaro IMASAKA

期刊论文