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木质素电化学生物炼制制备化学品和生物油提质 Review
胡锐, 赵玉莹, 唐晨, 石岩, 罗刚, 范佳珺, James H. Clark, 张士成
《工程(英文)》 2023年 第27卷 第8期 页码 178-198 doi: 10.1016/j.eng.2022.10.013
Recalcitrance and the inherent heterogeneity of lignin structure are the major bottlenecks to impede the popularization of lignin-based chemicals production processes. Recent works suggested a promising pathway for lignin depolymerization and lignin-derived bio-oil upgrading via an electrochemical biorefinery (a process in which lignin valorization is performed via electrochemical oxidation or reduction). This review presents the progress on chemicals synthesis and bio-oil upgrading from lignin by an electrochemical biorefinery, relating to the lignin biosynthesis pathway, reaction pathway of lignin electrochemical conversion, inner-sphere and outer-sphere electron transfer mechanism, basic kinetics and thermodynamics in electrochemistry, and the recent embodiments analysis with the emphasis on the respective feature and limitation for lignin electrochemical oxidative and reductive conversion. Lastly, the challenge and perspective associated with lignin electrochemical biorefinery are discussed. Present-day results indicate that more work should be performed to promote efficiency, selectivity, and stability in pursuing a lignin electrochemical biorefinery. One of the most promising developing directions appears to be integrating various types of lignin electrochemical conversion strategies and other existing or evolving lignin valorization technologies. This review aims to provide more references and discussion on the development for lignin electrochemical biorefinery.
Comparative lipidomic analysis of
Bin QIAO, Hong-Chi TIAN, Ying-Jin YUAN
《化学科学与工程前沿(英文)》 2012年 第6卷 第4期 页码 461-469 doi: 10.1007/s11705-012-1223-3
关键词:
lipidomics
systems biology
phospholipids
stirred-tank
Agneev Mukherjee, Guillermo Portillo-Perez, Marie-Josée Dumont
《化学科学与工程前沿(英文)》 2019年 第13卷 第3期 页码 531-542 doi: 10.1007/s11705-019-1814-3
关键词: 5-hydroxymethylfurfural hardwood softwood ferric sulphate biorefinery
Crop residues: applications of lignocellulosic biomass in the context of a biorefinery
Maria Carolina ANDRADE, Caio de Oliveira GORGULHO SILVA, Leonora Rios de SOUZA MOREIRA, Edivaldo Ximenes FERREIRA FILHO
《能源前沿(英文)》 2022年 第16卷 第2期 页码 224-245 doi: 10.1007/s11708-021-0730-7
关键词: crop residue biorefinery bioproduct biomass circular bioeconomy enzyme
标题 作者 时间 类型 操作
Synthesis of hydroxymethylfurfural and furfural from hardwood and softwood pulp using ferric sulphate as catalyst
Agneev Mukherjee, Guillermo Portillo-Perez, Marie-Josée Dumont
期刊论文