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Insight into the effect of surface carboxyl and amino groups on the adsorption of titanium dioxide for

Wenlong Zhang, Xuyang Zhao, Lin Zhang, Jinwei Zhu, Shanshan Li, Ping Hu, Jiangtao Feng, Wei Yan

《化学科学与工程前沿（英文）》 2021年第15卷第5期页码 1147-1157 doi: 10.1007/s11705-020-1978-x

摘要： In this study, TiO functionalized with organic groups were prepared to study the effect of carboxyl and amino groups on the adsorption behavior of TiO for the removal of acid red G (ARG) as an anionic dye from aqueous solution. TiO was successfully modified with carboxyl and amino groups by using the hydrolysis method with oxalic acid (OAD, with two carboxyl groups), ethylenediamine (EDA, with two amino groups) and DL-alanine (DLA, with one carboxyl group and one amino group) at low temperature (65 °C) and labeled as OAD-TiO , EDA-TiO and DLA-TiO , respectively. The ARG uptake by the functionalized TiO samples was largely dependent on the functional groups. The interaction between ARG and the functional organic groups on the TiO samples plays an important role in the adsorption process, which leads to the excellent adsorption performance (higher capacity and faster adsorption rate) of the functionalized TiO samples than that of P25 (commercial TiO without modification). Furthermore, there is no obvious loss of the adsorption capacity for the functionalized TiO even after 5 adsorption-desorption cycles, which indicated the good reusability of the modified TiO samples for anionic dye removal from aqueous solution.

关键词： amino group carboxylic group titanium dioxide ARG adsorption

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The catalytic effect of both oxygen-bearing functional group and ash in carbonaceous catalyst on CH 4 -CO 2 reforming

Weidong ZHANG, Yongfa ZHANG,

《化学科学与工程前沿（英文）》 2010年第4卷第2期页码 147-152 doi: 10.1007/s11705-009-0242-1

摘要： A kind of new catalyst—carbonaceous catalyst—for CH-CO reformation has been developed in our laboratory. The effect of both oxygen-bearing functional group such as phenolic hydroxyl, carbonyl, carboxyl, and lactonic, and ash such as FeO, NaCO, and KCO in the carbonaceous catalyst on the CH-CO reforming has been investigated with a fixed-bed reactor. It has been found that the carbonaceous catalyst is an efficient catalyst on CO-CH reforming. With the decrease of oxygen-bearing functional group, the catalytic activity of carbonaceous catalyst decreases quickly. The oxygen-bearing functional groups play a significant role in the carbonaceous-catalyzed CO-CH reforming; the ash components in carbonaceous catalyst also have an important influence on the CO-CH reforming. FeO, NaCO, and KCO in the ash can catalyze the CO-CH reforming reaction; CaO has little effect on CO-CH reforming reaction. CaO can catalyze the gasification between carbonaceous catalyst and CO; AlO and MgO inhibit the CO-CH reforming.

关键词： oxygen-bearing functional carboxyl phenolic hydroxyl CH-CO reformation CO-CH reforming