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2011 1

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微观形貌 1

梳形减水剂 1

水泥水化 1

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Chemical mapping of cement pastes by using confocal Raman spectroscopy

Fengjuan LIU,Zhihui SUN

《结构与土木工程前沿（英文）》 2016年第10卷第2期页码 168-173 doi: 10.1007/s11709-015-0323-9

摘要： In the present study, chemical mapping on the hydration process of cement paste with water-to-cement ( / ) ratio of 0.60 was implemented by Raman spectroscopy (RS). The RS was applied to study the paste from 12 hours after mixing to 28 days. Cement ingredients and hydration products, including calcium silicates (C S and C S), calcium hydroxide (CH), and ettringite, were quantitatively studied. From the research, it is observed that calcium silicates were consumed gradually with the increased hydration age. Calcium hydroxide increased and tended to cluster in the pore vicinity during hydration. Ettringite was found to form on the surface of the unreacted particles, which was shown as a mixed zone of ettringite and calcium silicates in the maps. It is concluded from the study that chemical mapping was an effective method to assist in visualizing particle dispersion and connection on top of the quantitative analysis.

关键词： chemical mapping Raman spectroscopy calcium silicates calcium hydroxide ettringite

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掺梳形减水剂水泥浆体早期水化产物形貌研究

蒋亚清

《中国工程科学》 2011年第13卷第9期页码 69-75

摘要：

为揭示梳形减水剂对水泥早期水化的影响规律，指导工程应用,通过SEM分析，研究了掺用3种典型结构的梳形减水剂的水泥浆体早期水化产物形貌及其电子特征数据。结果表明，梳形减水剂加速了水泥早期水化反应，且丙烯酸类、马来酸类共聚物分别促进了AFt、AFm的形成。因此，梳形减水剂品种对水泥早期水化和混凝土工程性能具有较大影响，应根据使用要求合理选用，必要时与缓凝剂、引气剂或消泡剂复合使用。

关键词：梳形减水剂水泥水化钙矾石微观形貌