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The construction of pseudo-Janus silica/surfactant assembly and their application to stabilize Pickering

《化学科学与工程前沿（英文）》 2022年 第16卷 第7期   页码 1101-1113 doi: 10.1007/s11705-021-2095-1

摘要： Nanoparticles with high surface energy and chemical activity have drawn substantial attention in petroleum industry. Recently, Janus nanoparticles exhibited tremendous potential in enhanced oil recovery (EOR) due to their asymmetric structures and properties. In this study, a series of amphiphilic pseudo-Janus@OTAB (PJ@C18) nanoparticles with different concentrations of stearyltrimethylammoium bromide (OTAB) were successfully fabricated. The structures and properties of PJ@C18 were characterized by Fourier transform infrared spectroscopy and ζ-potential measurements. Based on the emulsification experimental results, the interaction models and the self-assembly behavior between hydrophilic nanoparticles (SiO2@NH2) and OTAB molecules at the oil/water interface were proposed, which was further confirmed via the measurements of the contact angle and dynamic interfacial tension. Interestingly, it was found that the change of pH value from 7.5 to 4.0 caused the type reversal of the PJ@C18-1000 stabilized Pickering emulsions. Furthermore, the PJ@C18-1000 stabilized Pickering emulsion system with excellent salt and temperature tolerances (10000 mg∙L–1, 90 °C) significantly improved the oil recovery in the single-tube (more than 17%) and double-tube (more than 25%) sand pack model flooding tests. The findings of this study could help to better understand the construction mechanism of pseudo-Janus silica/surfactant assembly and the potential application of PJ@C18-1000 stabilized Pickering emulsions for EOR.

关键词： Janus nanoparticles     surfactant     double phase inversion     self-assembly     enhanced oil recovery    

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Progress in use of surfactant in nearly static conditions in natural gas hydrate formation

Zhen PAN, Yi WU, Liyan SHANG, Li ZHOU, Zhien ZHANG

《能源前沿（英文）》 2020年 第14卷 第3期   页码 463-481 doi: 10.1007/s11708-020-0675-2

摘要： Natural gas hydrate is an alternative energy source with a great potential for development. The addition of surfactants has been found to have practical implications on the acceleration of hydrate formation in the industrial sector. In this paper, the mechanisms of different surfactants that have been reported to promote hydrate formation are summarized. Besides, the factors influencing surfactant-promoted hydrate formation, including the type, concentration, and structure of the surfactant, are also described. Moreover, the effects of surfactants on the formation of hydrate in pure water, brine, porous media, and systems containing multiple surfactants are discussed. The synergistic or inhibitory effects of the combinations of these additives are also analyzed. Furthermore, the process of establishing kinetic and thermodynamic models to simulate the factors affecting the formation of hydrate in surfactant-containing solutions is illustrated and summarized.

关键词： gas hydrate     kinetic hydrate promoter     compounding     model     surfactant     mechanism    

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Stability of three-dimensional printable foam concrete as function of surfactant characteristics

《结构与土木工程前沿（英文）》   页码 935-947 doi: 10.1007/s11709-023-0964-z

摘要： Extrudability is one of the most critical factors when designing three-dimensional printable foam concrete. The extrusion process likely affects the foam stability which necessitates the investigation into surfactant properties particularly for concrete mixes with high foam contents. Although many studies have been conducted on traditional foam concrete in this context, studies on three-dimensional printed foam concrete are scarce. To address this research gap, the effects of surfactant characteristics on the stability, extrudability, and buildability of three-dimensional printed foam concrete mixes with two design densities (1000 and 1300 kg/m3) using two different surfactants and stabilizers (synthetic-based sodium lauryl sulfate stabilized with carboxymethyl cellulose sodium salt, and natural-based hingot surfactant stabilized with xanthan gum) were investigated in this study. Fresh density tests were conducted before and after the extrusion to determine stability of the foam concrete. The results were then correlated with surfactant qualities, such as viscosity and surface tension, to understand the importance of key parameters in three-dimensional printing of foam concrete. Based on the experimental results, surfactant solu1tion with viscosity exceeding 5 mPa·s and surface tension lower than 31 mN/m was recommended to yield stable three-dimensional printable foam concrete mixes. Nevertheless, the volume of foam in the mix significantly affected the printability characteristics. Unlike traditional foam concrete, the variation in the stabilizer concentration and density of concrete were found to have insignificant effect on the fresh-state-characteristics (slump, slump flow, and static yield stress) and air void microstructure of the stable mixes.

关键词： foam concrete     3D printable concrete     stability     rheology     air void microstructure    

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Multiphase surfactant-assisted reaction-separation system in a microchannel reactor

Salah ALJBOUR, Tomohiko TAGAWA, Mohammad MATOUQ, Hiroshi YAMADA

《化学科学与工程前沿（英文）》 2009年 第3卷 第1期   页码 33-38 doi: 10.1007/s11705-009-0108-6

摘要： The Lewis acid-catalyzed addition of trimethylsilyl cyanide to -chlorobenzaldehyde in a microchannel reactor was investigated. The microchannel was integrated to promote both reaction and separation of the biphase system. FeF and Cu(triflate) were used as water-stable Lewis acid catalysts. Sodium dodecyl sulfate was incorporated in the organic-aqueous system to enhance the reactivity and to manipulate the multiphase flow inside the microchannel. It was found that the dynamics and the kinetics of the multiphase reaction were affected by the new micellar system. Parallel multiphase flow inside the microchannel was obtained, allowing for continuous and acceptable phase separation. Enhanced selectivity was achieved by operating at lower conversion values.

关键词： Lewis acid catalysis     multiphase reactions     process intensification     microchannel reactor     green engineering    

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study on the control of black smoke pollution from the ceramic kilns based on the mechanism of the surfactant

CUI Xiao, LI Caiting, WANG Fei, LI Shanhong, XIAO Chenchang, PENG Yu, ZHAI Yunbo

《环境科学与工程前沿（英文）》 2008年 第2卷 第1期   页码 109-115 doi: 10.1007/s11783-008-0021-0

摘要： Aiming at the characteristics of carbon black, a new method of controlling the black smoke from the industrial coal-burning ceramic kilns by wetting was brought forward. The carbon black in the flue of coal-burning ceramic kiln was collected for the experiments, and its physical and chemical properties were studied in detail. In order to change the sedimentation and wettability state of the carbon black, the complex solution of the coagulant and surfactant was applied. After a series of orthogonal experiments, the complex solutions with better effects were chosen. Then, the sedimentation percentage of carbon black treated by the selected complex solutions was measured. The optimized complex solutions included NaSO (100 mmol/L), sodium dodecyl benzenesulfonate (SDBS) (1.2 mmol/L) and polyacrylamide (PAM) (40 mg/L). After carbon black was absorbed, the complex solutions were clear and colorless. The complex solutions can be recycled, and the sedimentation percentage of carbon black is 94%.
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Organosilane surfactant-assisted synthesis of mesoporous SSZ-39 zeolite with enhanced catalytic performance

Hao Xu, Chi Lei, Qinming Wu, Qiuyan Zhu, Xiangju Meng, Daniel Dai, Stefan Maurer, Andrei-Nicolae Parvulescu, Ulrich Müller, Fengshou Xiao

《化学科学与工程前沿（英文）》 2020年 第14卷 第2期   页码 267-274 doi: 10.1007/s11705-019-1845-9

摘要： SSZ-39 zeolite with AEI framework structure is a good catalyst candidate for the methanol-to-olefins (MTO) reaction. However, the diffusion limitation and coke formation often results in fast deactivation of the SSZ-39 zeolite catalyst. One solution for this challenge is to introduce mesoporosity in the SSZ-39 zeolite. Herein, we report the synthesis of mesoporous SSZ-39 zeolite using an organosilane surfactant, , -dimethyl- -(3-(trimethoxysilyl)propyl)octan-1-aminium chloride, as a mesopore template and , -dimethyl- -2,6-dimethylpiperidinium as a micropore template. The obtained zeolites were characterized by X-ray diffraction, N sorption, scanning electron microscopy, temperature programmed desorption of ammonia, and magic angle spinning nuclear magnetic resonance of Al. The results show that the mesoporous SSZ-39 zeolite has high crystallinity, meso/microporosity, high surface area, cuboid morphology, and abundant acidic sites. More importantly, this mesoporous SSZ-39 zeolite exhibits enhanced catalyst lifetime in the MTO reaction due to the presence of mesoporosity for fast mass transfer, compared with a conventional SSZ-39 zeolite without mesoporosity.

关键词： SSZ-39 zeolite     mesopores     organosilane surfactant     MTO reaction     soft template     mass transfer    

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利用液相透射电子显微镜技术研究纳米气泡在表面活性剂水溶液中的动力机制 Letter

Yuna Bae, Sungsu Kang, Byung Hyo Kim, Kitaek Lim, Sungho Jeon, Sangdeok Shim, Won Chul Lee, Jungwon Park

《工程（英文）》 2021年 第7卷 第5期   页码 630-635 doi: 10.1016/j.eng.2021.02.006

摘要：

纳米气泡因其超长的寿命和作为纳米级载体的潜力而在各种工业应用中受到广泛关注。纳米气泡的稳定性和理化性质对表面活性剂的存在高度敏感，表面活性剂可降低其表面张力或提高其静电稳定性。在本文中，我们报道了在存在可溶性表面活性剂的条件下纳米气泡动态行为的实时观察结果。利用多室石墨烯液体池液相透射电子显微镜（TEM），在相同的成像条件下观察了体相纳米气泡和表面纳米气泡。对纳米气泡的直接观察结果表明，稳定的气体传输在没有界面融合的情况下经常发生，而在相互作用的含表面活性剂的纳米气泡界面之间存在狭窄的距离。结果也阐明了纳米气泡的界面曲率是决定其界面稳定性的重要因素。

关键词： 纳米气泡     原位透射电镜     液相透射电镜     表面活性剂    

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Formation of reverse micelles in supercritical carbon dioxide and its thermodynamics

WEN Zhen, DANG Zhi, ZHU Zhixin, ZONG Minhua

《化学科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 283-286 doi: 10.1007/s11705-007-0051-3

摘要： The solubilization behavior of methyl orange as a solvation probe in multiple systems composed of supercritical carbon dioxide, surfactants and co-solvents, is studied. It is concluded that some surfactants, such as sodium bis-(2-ethylhexyl) sulfosuccinate (AOT) and isooctyl phenol polyethoxylate (TX-10), could form reverse micelles in supercritical carbon dioxide under the action of butanol. The formation of reverse micelles is a spontaneous process thermodynamically. Specifically for the nonionic surfactant TX-10, the formation of reverse micelles is dependent on the entropy increase in the system, while for the anionic surfactant AOT, the micellization is mainly dominated by the increase in enthalpy at higher temperatures, but by the increase in entropy at lower temperatures.

关键词： micellization     surfactant AOT     TX-10     sulfosuccinate     solubilization    

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Reinforcement of the two-stage leaching of laterite ores using surfactants

Peiyu Zhang, Hairui Wang, Jingcheng Hao, Jiwei Cui

《化学科学与工程前沿（英文）》 2021年 第15卷 第3期   页码 562-570 doi: 10.1007/s11705-020-1946-5

摘要： A two-stage leaching process, namely, high-pressure acid leaching-atmospheric acid leaching, was used to treat laterite ores under mild conditions. The leaching ratio of Ni was low because of adsorption and incomplete leaching. In this work, surfactants were used as additives to boost the leaching ratio of Ni. The effect of surfactant type (cationic, anionic, and nonionic surfactants) on the leaching ratio of Ni was investigated. Leaching results showed that stearyl trimethyl ammonium chloride (STAC) apparently increased the leaching ratios of valuable metals. The variation in the physicochemical properties of the lixiviant and the residue improved the leaching ratio of Ni in the presence of STAC. Kinetics analysis indicated that the leaching process was controlled by chemical reaction.

关键词： laterite ore     Ni     surfactant     acid leaching    

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Influences of spinel type and polymeric surfactants on the size evolution of colloidal magnetic nanocrystals (MFe

Tahereh R. BASTAMI,Mohammad H. ENTEZARI,Chiwai KWONG,Shizhang QIAO

《化学科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 378-385 doi: 10.1007/s11705-014-1441-y

摘要： Two types of polymeric surfactants, PEG and PVP , were used for the preparation of magnetic ferrite MFe O (M= Mn, Fe) colloidal nanocrystals using a solvothermal reaction method. The effect of spinel type effect on the size evolution of various nanoparticles was investigated. It was found that Fe O nanoparticles exhibited higher crystalinity and size evolution than MnFe O nanoparticles with use of the two surfactants. It is proposed that this observation is due to fewer tendencies of surfactants on the surface of Fe O building blocks nanoparticles than MnFe O . Less amounts of surfactant or capping agent on the surface of nanoparticles lead to the higher crystalibity and larger size. It is also suggested that the type of spinel (normal or inverted spinel) plays a key role on the affinity of the polymeric surfactant on the surface of building blocks.

关键词： spinel type     polymeric surfactant     size evolution     mangnetic ferrite nanoparticle    

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Rheological behavior of mixed system of ionic liquid [C

Zimeng HE,Ling YUE,Meng LI,Yazhuo SHANG,Honglai LIU

《化学科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 232-241 doi: 10.1007/s11705-015-1511-9

摘要： We report on the rheological behavior of wormlike micelles constructed by ionic liquid surfactant [C mim]Br (1-octyl-3-methylimidazolium bromide) and anionic surfactant sodium oleate (NaOA) in aqueous solution. The effects of surfactant composition, total surfactant concentration, added salts, and temperature were investigated. The prevailing surfactant effect at lower concentration and the leading cosolvent effect at higher concentration of [C mim]Br may be the main reasons for appearance of well-established maximum in key rheological parameters with variation of surfactant composition and total surfactant concentration. The Cole-Cole plots demonstrate that the systems (total surfactant concentration falls within 0.17–0.35 mol·L and molar ratio 0.33≤ ≤0.50) fit the Maxwell’s mechanical model as linear viscoelastic fluid. The addition of NaBr or sodium salicylate decreases significantly the viscosity and the relaxation time of the wormlike micelle solution but cannot change the value of plateau modulus . The present system has low rheological tolerance to temperature. The increase of temperature decreases the average contour length and viscosity of wormlike micelles and thus strengthens the relaxation progress of diffusion and weakens the relaxation progress of reptation. Increasing the temperature also decreases the value of plateau modulus and shifts the minimum value of the loss modulus to higher frequencies.

关键词： rheological behavior     ionic liquid surfactant     sodium oleate     wormlike micelles     viscoelasticity    

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New insights into different surfactants’ impacts on sludge fermentation: Focusing on the particular metabolic processes and microbial genetic traits

《环境科学与工程前沿（英文）》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1527-6

摘要：

• The promoting effects for VFA generation follow the order of APG>SDBS>HTAB.

关键词： Waste activated sludge (WAS)     Volatile fatty acids (VFA)     Surfactant types     Functional microorganisms     Metabolic activity upregulation    

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Controlled synthesis of uniform silver nanowires with high aspect ratios in aqueous solutions of gemini surfactant

XU Jian, LIU Weijun, LIU Honglai, HU Ying

《化学科学与工程前沿（英文）》 2007年 第1卷 第3期   页码 221-227 doi: 10.1007/s11705-007-0040-6

摘要： A simple solution-phase approach has been demonstrated for the large-scale synthesis of silver nanowires with diameters in the range of 15 25 nm, and lengths usually in the range of tens of micrometers. In the presence of gemini surfactant 1,3-bis(cetyldimethylammonium) propane dibromide (16-3-16), the growth of silver could be directed into a highly anisotropic mode to form uniform nanowires with aspect ratios up to about 2,000. X-ray photoelectron spectroscopy (XPS), transmission electron microscopy (TEM), energy-dispersive X-ray (EDX), X-ray powder diffraction (XRD), electron diffraction (ED), and UV-vis absorption spectroscopy, were used to characterize the as-prepared silver nanowires, indicating the formation of a highly pure phase, good crystallinity, as well as a uniform diameter.

关键词： solution-phase     photoelectron spectroscopy     16-3-16     surfactant     transmission    

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Synthesis and characterization of castor oil-based polymeric surfactants

Xujuan HUANG,He LIU,Shibin SHANG,Zhaosheng CAI,Jie SONG,Zhanqian SONG

《农业科学与工程前沿（英文）》 2016年 第3卷 第1期   页码 46-54 doi: 10.15302/J-FASE-2016083

摘要： Dehydrated castor oil was epoxidized using phosphoric acid as a catalyst and acetic acid peroxide as an oxidant to produce epoxidized castor oil (ECO). Ring-opening polymerization with stannic chloride was used to produce polymerized ECO (PECO), and sodium hydroxide used to give hydrolyzed PECO (HPECO). The HPECO was characterized by Fourier transform infrared, H and C nuclear magnetic resonance spectroscopies, gel permeation chromatography, and differential scanning calorimetry. The weight-average molecular weight of soluble PECO and HPECO were 5026 and 2274 g·mol , respectively. PECO and HPECO exhibited glass transition. Through neutralizing the carboxylic acid of HPECO with different counterions, castor oil-based polymeric surfactants (HPECO-M, where M= Na , K or triethanolamine ion) exhibited high efficiency to reduce the surface tension of water. The critical micelle concentration (CMC) values of HPECO-M ranged from 0.042 to 0.098 g·L and the minimum equilibrium surface tensions at CMC ( ) of HPECO-M ranged from 25.6 to 30.0 mN·m . The water-hexadecane interfacial energy was calculated from measured surface tension using harmonic and geometric mean methods. Measured values of water-hexadecane interfacial tension agreed well with those calculated using the harmonic and geometric mean methods.

关键词： epoxidized vegetable oil     ring-opening polymerization     interfacial tension     polymeric surfactant    

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绿色表面活性剂在农药加工中的应用

高楠,张春华,张宗俭

《中国工程科学》 2009年 第11卷 第4期   页码 36-38

摘要：

对绿色表面活性剂在农药加工中的应用进行了简要介绍，对应用脂肪醇聚氧乙烯醚（AEO）、脂肪醇聚氧乙烯醚硫酸盐（AES）、α-烯基磺酸盐（AOS）、烷基糖苷（APG）的农药制剂进行了开发，并与传统表面活性剂进行比较，提出此类表面活性剂在农药加工中的应用对于环境保护具有重要意义。

关键词： 绿色表面活性剂     农药加工     环境保护    

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标题 作者 时间 类型 操作

The construction of pseudo-Janus silica/surfactant assembly and their application to stabilize Pickering

期刊论文

Progress in use of surfactant in nearly static conditions in natural gas hydrate formation

Zhen PAN, Yi WU, Liyan SHANG, Li ZHOU, Zhien ZHANG

期刊论文

Stability of three-dimensional printable foam concrete as function of surfactant characteristics

期刊论文

Multiphase surfactant-assisted reaction-separation system in a microchannel reactor

Salah ALJBOUR, Tomohiko TAGAWA, Mohammad MATOUQ, Hiroshi YAMADA

期刊论文

study on the control of black smoke pollution from the ceramic kilns based on the mechanism of the surfactant

CUI Xiao, LI Caiting, WANG Fei, LI Shanhong, XIAO Chenchang, PENG Yu, ZHAI Yunbo

期刊论文

Organosilane surfactant-assisted synthesis of mesoporous SSZ-39 zeolite with enhanced catalytic performance

Hao Xu, Chi Lei, Qinming Wu, Qiuyan Zhu, Xiangju Meng, Daniel Dai, Stefan Maurer, Andrei-Nicolae Parvulescu, Ulrich Müller, Fengshou Xiao

期刊论文

利用液相透射电子显微镜技术研究纳米气泡在表面活性剂水溶液中的动力机制

Yuna Bae, Sungsu Kang, Byung Hyo Kim, Kitaek Lim, Sungho Jeon, Sangdeok Shim, Won Chul Lee, Jungwon Park

期刊论文

Formation of reverse micelles in supercritical carbon dioxide and its thermodynamics

WEN Zhen, DANG Zhi, ZHU Zhixin, ZONG Minhua

期刊论文

Reinforcement of the two-stage leaching of laterite ores using surfactants

Peiyu Zhang, Hairui Wang, Jingcheng Hao, Jiwei Cui

期刊论文

Influences of spinel type and polymeric surfactants on the size evolution of colloidal magnetic nanocrystals (MFe

Tahereh R. BASTAMI,Mohammad H. ENTEZARI,Chiwai KWONG,Shizhang QIAO

期刊论文

Rheological behavior of mixed system of ionic liquid [C

Zimeng HE,Ling YUE,Meng LI,Yazhuo SHANG,Honglai LIU

期刊论文

New insights into different surfactants’ impacts on sludge fermentation: Focusing on the particular metabolic processes and microbial genetic traits

期刊论文

Controlled synthesis of uniform silver nanowires with high aspect ratios in aqueous solutions of gemini surfactant

XU Jian, LIU Weijun, LIU Honglai, HU Ying

期刊论文

Synthesis and characterization of castor oil-based polymeric surfactants

Xujuan HUANG,He LIU,Shibin SHANG,Zhaosheng CAI,Jie SONG,Zhanqian SONG

期刊论文

绿色表面活性剂在农药加工中的应用

高楠,张春华,张宗俭

期刊论文