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Deactivation and regeneration of TS-1/SiO

Hainan SHI, Yaquan WANG, Guoqiang WU, Wenping FENG, Yi Lin, Teng ZHANG, Xing JIN, Shuhai WANG, Xiaoxue WU, Pengxu YAO

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 2,   Pages 202-209 doi: 10.1007/s11705-013-1328-3

Abstract: TS-1/SiO catalyst for the epoxidation of propylene with hydrogen peroxide in a fixed-bed reactor hasframework structure and the content of titanium in the framework of the deactivated and regenerated TS-1-1/SiO catalysts were not changed.-1.The deposited materials on the deactivated TS-1/SiO catalyst could be removed by treatment with hydrogen

Keywords: TS-1/SiO<sub>2sub>     epoxidation of propylene     fixed-bed reactor     deactivation     regeneration    

Controllable synthesis of a large TS-1 catalyst for clean epoxidation of a C=C double bond under mild

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 6,   Pages 772-783 doi: 10.1007/s11705-022-2280-x

Abstract: Development of a titanium silicalite-1 (TS-1) catalyst with good crystallinity and a four-coordinateHerein, a size-controlled TS-1 zeolite (TS-1#0.1ACh (acetylcholine)) was synthesized via steam-assistedThe crystalline sizes of the as-synthesized TS-1#0.1ACh catalysts were controlled with the acetylcholinecontent, and characterization results showed that the particle sizes of highly crystalline TS-1#0.1AChThese findings may provide novel, easily separable and large TS-1 catalysts for efficient and clean industrial

Keywords: size-controlled TS-1     crystal modifier     steam-assisted crystallization     epoxidation    

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al<sub>2sub>O<sub>3sub> with a small amount, wasintroduced into Pb/SiO<sub>2sub> catalyst in this study.It has been proved that Al<sub>2sub>O<sub>3sub> can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO<sub>2sub> catalyst exhibits a much higher stability up to more than 150 h.>2sub>O<sub>3sub> addition was also proposed.

Keywords: Pb/SiO<sub>2sub>     Al<sub>2sub>O<sub>3sub>     propane dehydrogenation     propene     stability    

Synthesis of magnetic Pb/Fe

Hualiang AN, Xinqiang ZHAO, Zhiguang JIA, Changcheng WU, Yanji WANG

Frontiers of Chemical Science and Engineering 2009, Volume 3, Issue 2,   Pages 215-218 doi: 10.1007/s11705-009-0055-2

Abstract: To facilitate the recovery of Pb/SiO catalyst, magnetic Pb/Fe O /SiO samples were prepared separatelycatalytic activity was investigated in the reaction for synthesizing propylene carbonate from urea and 1,2, the Pb/Fe O /SiO sample shows good catalytic activity and magnetism.Under the reaction conditions of a reaction temperature of 180°C, reaction time of 2 h, catalyst percentageof 1.7 wt-% and a molar ratio of urea to PG of 1∶4, the yield of propylene carbonate attained was 87.7%

Keywords: Pb/Fe<sub>3sub>O<sub>4sub>/SiO<sub>2sub> magnetic particle     urea     1     2-propylene glycol     propylene    

SiO<sub>2sub> passivation layer grown by liquid phase deposition for silicon solar cell application

Yanlin CHEN,Sihua ZHONG,Miao TAN,Wenzhong SHEN

Frontiers in Energy 2017, Volume 11, Issue 1,   Pages 52-59 doi: 10.1007/s11708-016-0429-3

Abstract: In this paper, a comprehensive understanding of the SiO passivation layer grown by liquid phase depositionfound that the post-annealing process could significantly enhance the passivation effect of the LPD SiOfield-effect passivation mechanisms played important roles in outstanding passivation effect of the LPD SiOBy utilizing the LPD SiO film as surface passivation layer, a 19.5%-efficient silicon solar cell on

Keywords: Si solar cell     passivation     SiO<sub>2sub>     liquid phase deposition     carrier lifetime    

Effect of SiO

Qian WANG, Lei WANG, Hui WANG, Zengxi LI, Xiangping ZHANG, Suojiang ZHANG, Kebin ZHOU

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 1,   Pages 79-88 doi: 10.1007/s11705-010-0550-5

Abstract: A series of SAPO-34 molecular sieves with different SiO /Al O ratios have been synthesized for the methanol-to-olefinwhich show that the crystallinity and particle diameter of SAPO-34 as well as HZSM-5 increase with SiOThe variation of BET surface area of SAPO-34 is different from that of HZSM-5 and the sample with SiOWhen the SiO /Al O ratio increases, propylene and butylenes become the predominant product of the MTO

Keywords: HZSM-5     SAPO-34     methanol-to-olefin (MTO)     SiO<sub>2sub>/Al<sub>2sub>O<sub>3sub> ratio    

Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties of polyurethane matrix

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 1,   Pages 1-14 doi: 10.1007/s11705-022-2176-9

Abstract: Newly synthesized functional nanoparticles, 3-amino-1,2,4-triazole (ATA)/SiO<sub>2sub>–TiO<sub>2subThe coating resistance (R<sub>coatsub>) of PU–ATA/SiO<sub>2sub>–TiO<sub>2sub> was determinedThe R<sub>coatsub> of the PU–ATA/SiO<sub>2sub>–TiO<sub>2sub> nanocomposite coating was foundThe current measured along the scratched surface of the PU–ATA/SiO<sub>2sub>–TiO<sub>2sub> coatingWhen the concentration of ATA/SiO<sub>2sub>−TiO<sub>2sub> nanoparticles was 2 wt %, dynamic mechanical

Keywords: SiO<sub>2sub>/TiO<sub>2sub> nanoparticle     nanocomposite coatings     dynamic mechanical analysis     electrochemical    

Theoretical and experimental study on the fluidity performance of hard-to-fluidize carbon nanotubes-based CO2

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 10,   Pages 1460-1475 doi: 10.1007/s11705-022-2159-x

Abstract: CO<sub>2sub> capture capacity.The low-cost fluidizable-SiO<sub>2sub> nanoparticles are used as assistant material to improve theResults reveal that a minimum amount of 7.5 and 5 wt% SiO<sub>2sub> nanoparticles are required to achievePure carbon nanotubes + 7.5 wt% SiO<sub>2sub> and synthesized carbon nanotubes + 5 wt% SiO<sub>2subincluding the high-level bed expansion ratio, low minimum fluidization velocity (1.5 and 1.6 cm·s1<

Keywords: CO<sub>2sub> capture     CNT-based sorbents     fluidization     SiO<sub>2sub> nanoparticles     fluidized bed    

Preparation of P

Wenjiang LI, Fei XIE, Dongxu HUA, Chunli ZHANG, Chen DAI, Zhenyun YU, Meizhou QI, Shaojun YU

Frontiers of Chemical Science and Engineering 2011, Volume 5, Issue 3,   Pages 314-317 doi: 10.1007/s11705-010-0573-y

Abstract: prepared by a sol-gel/emulsion method which uses tetraethoxysilane (TEOS) as the precursor for the SiOThe hollow structure of the P O -SiO (silicophosphate) was characterized by X-ray diffraction (XRD),

Keywords: P<sub>2sub>O<sub>5sub>-SiO<sub>2sub>     hollow microspheres     sol-gel/emulsion     phosphoric acid    

Inexpensive synthesis of a high-performance Fe

Nadir Abbas, Godlisten N. Shao, Syed M. Imran, Muhammad S. Haider, Hee Taik Kim

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 3,   Pages 405-416 doi: 10.1007/s11705-016-1579-x

Abstract: A sol-gel technique has been developed for the synthesis of a magnetite-silica-titania (Fe O -SiO -TiO

Keywords: sol-gel     photocatalysis     magnetic recovery     TiO<sub>2sub>     Fe<sub>3sub>O<sub>4sub>     SiO<sub>2sub>    

Stability of Ni/SiO

Bettina Stolze,Juliane Titus,Stephan A. Schunk,Andrian Milanov,Ekkehard Schwab,Roger Gläser

Frontiers of Chemical Science and Engineering 2016, Volume 10, Issue 2,   Pages 281-293 doi: 10.1007/s11705-016-1568-0

Abstract: Ni/SiO -ZrO catalysts with Ni loadings of 1 to 13 wt-% were prepared, characterized by elemental analysisThe SiO -ZrO support as obtained through a simple and efficient sol-gel synthesis is highly porous (The Ni loading of 5 wt-% on SiO -ZrO was shown to provide an optimal balance between activity and coking

Keywords: Ni/SiO<sub>2sub>-ZrO<sub>2sub>     synthesis gas     dry reforming     coking     steaming    

Band-gap tunable (Ga<sub>xsub>In<sub>1sub><sub>xsub>)<sub>2sub>O<sub>3sub> layer Research Articles

Fabi Zhang, Jinyu Sun, Haiou Li, Juan Zhou, Rong Wang, Tangyou Sun, Tao Fu, Gongli Xiao, Qi Li, Xingpeng Liu, Xiuyun Zhang, Daoyou Guo, Xianghu Wang, Zujun Qin,zhangfabi@outlook.com,qinzj@guet.edu.cn

Frontiers of Information Technology & Electronic Engineering 2021, Volume 22, Issue 10,   Pages 1370-1378 doi: 10.1631/FITEE.2000330

Abstract: Multicomponent oxide (GaIn)O films are prepared on (0001) sapphire substrates to realize a tunable band-gap by technology followed by thermal annealing. The optical properties and band structure evolution over the whole range of compositions in ternary compounds (GaIn)O are investigated in detail. The X-ray diffraction spectra clearly indicate that (GaIn)O films with Ga content varying from 0.11 to 0.55 have both cubic and monoclinic structures, and that for films with Ga content higher than 0.74, only the monoclinic structure appears. The transmittance of all films is greater than 86% in the visible range with sharp absorption edges and clear fringes. In addition, a blue shift of ultraviolet absorption edges from 380 to 250 nm is noted with increasing Ga content, indicating increasing band-gap energy from 3.61 to 4.64 eV. The experimental results lay a foundation for the application of transparent conductive compound (GaIn)O thin films in photoelectric and photovoltaic industry, especially in display, light-emitting diode, and solar cell applications.

Keywords: (GaxIn1−x)2O3薄膜;带隙可调谐;磁控溅射    

Li<sub>4sub>SiO<sub>4sub>-coated LiNi<sub>0.5sub>Mn<sub>1.5sub>O<sub>4sub> as the high performance

Shifeng YANG, Wenfeng REN, Jian CHEN

Frontiers in Energy 2017, Volume 11, Issue 3,   Pages 374-382 doi: 10.1007/s11708-017-0494-2

Abstract: The preparation of Li SiO -coated LiNi Mn O materials by sintering the SiO -coated nickel-manganeseIt was found that a uniform and complete SiO coating layer could be obtained at a suitable pH valueof 10, which transformed to a good Li SiO coating layer afterwards.When used as the cathode materials for lithium-ion batteries, the Li SiO -coated LiNi Mn O samples deliver

Keywords: lithium-ion batteries     cathode material     LiNi<sub>0.5sub>Mn<sub>1.5sub>O<sub>4sub>     lithium-ion conductor    

Record-Breaking Frequency of 44 GHz Based on the Higher Order Mode of Surface Acoustic Waves with LiNbO<sub>3sub>/SiO<sub>2sub>/SiC Heterostructures Article

Jian Zhou,Dinghong Zhang,Yanghui Liu,Fengling Zhuo,Lirong Qian,Honglang Li,Yong-Qing Fu,Huigao Duan

Engineering 2023, Volume 20, Issue 1,   Pages 112-119 doi: 10.1016/j.eng.2022.05.003

Abstract: ., nanolithography) with a LiNbO3/SiO2/SiC heterostructure and successfully achieve a record-breakingmicro-mass sensing and obtain an extremely high sensitivity of approximately 33151.9 MHz·mm2·μg1, which is about 1011 times higher than that of a conventional

Keywords: Ultra-high frequency     SAW     Higher order mode     Hypersensitive detection    

Deciphering the Origins of P1-Induced Power Losses in Cu(In<sub>xsub>,Ga<sub>1xsub>)Se<sub>2sub> (CIGS) Modules Through Hyperspectral Luminescence Article

César Omar Ramírez Quiroz, Laura-Isabelle Dion-Bertrand, Christoph J. Brabec, Joachim Müller, Kay Orgassa

Engineering 2020, Volume 6, Issue 12,   Pages 1395-1402 doi: 10.1016/j.eng.2019.12.019

Abstract: hyperspectral high-resolution photoluminescence mapping is a powerful tool for the selection and optimiz1ationof the laser ablation processes used for the patterning interconnections of subcells on Cu(In<sub>xsub>,Ga<sub>1-xsub>)Se<sub>2sub> (CIGS) modules.We further rationalize the origins of this effect by comparing the topography of the P1 edge throughWe also investigate the laser-induced damage on P1 patterning lines performed after the deposition of

Keywords: Cu(Inx     Ga1-x)Se2     Cell-to-module efficiency gap     P1-induced power losses     Hyperspectral photoluminescence    

Title Author Date Type Operation

Deactivation and regeneration of TS-1/SiO

Hainan SHI, Yaquan WANG, Guoqiang WU, Wenping FENG, Yi Lin, Teng ZHANG, Xing JIN, Shuhai WANG, Xiaoxue WU, Pengxu YAO

Journal Article

Controllable synthesis of a large TS-1 catalyst for clean epoxidation of a C=C double bond under mild

Journal Article

The stabilization effect of Al<sub>2sub>O<sub>3sub> on unconventional Pb/SiO<sub>2sub> catalyst

Journal Article

Synthesis of magnetic Pb/Fe

Hualiang AN, Xinqiang ZHAO, Zhiguang JIA, Changcheng WU, Yanji WANG

Journal Article

SiO<sub>2sub> passivation layer grown by liquid phase deposition for silicon solar cell application

Yanlin CHEN,Sihua ZHONG,Miao TAN,Wenzhong SHEN

Journal Article

Effect of SiO

Qian WANG, Lei WANG, Hui WANG, Zengxi LI, Xiangping ZHANG, Suojiang ZHANG, Kebin ZHOU

Journal Article

Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties of polyurethane matrix

Journal Article

Theoretical and experimental study on the fluidity performance of hard-to-fluidize carbon nanotubes-based CO2

Journal Article

Preparation of P

Wenjiang LI, Fei XIE, Dongxu HUA, Chunli ZHANG, Chen DAI, Zhenyun YU, Meizhou QI, Shaojun YU

Journal Article

Inexpensive synthesis of a high-performance Fe

Nadir Abbas, Godlisten N. Shao, Syed M. Imran, Muhammad S. Haider, Hee Taik Kim

Journal Article

Stability of Ni/SiO

Bettina Stolze,Juliane Titus,Stephan A. Schunk,Andrian Milanov,Ekkehard Schwab,Roger Gläser

Journal Article

Band-gap tunable (Ga<sub>xsub>In<sub>1sub><sub>xsub>)<sub>2sub>O<sub>3sub> layer

Fabi Zhang, Jinyu Sun, Haiou Li, Juan Zhou, Rong Wang, Tangyou Sun, Tao Fu, Gongli Xiao, Qi Li, Xingpeng Liu, Xiuyun Zhang, Daoyou Guo, Xianghu Wang, Zujun Qin,zhangfabi@outlook.com,qinzj@guet.edu.cn

Journal Article

Li<sub>4sub>SiO<sub>4sub>-coated LiNi<sub>0.5sub>Mn<sub>1.5sub>O<sub>4sub> as the high performance

Shifeng YANG, Wenfeng REN, Jian CHEN

Journal Article

Record-Breaking Frequency of 44 GHz Based on the Higher Order Mode of Surface Acoustic Waves with LiNbO<sub>3sub>/SiO<sub>2sub>/SiC Heterostructures

Jian Zhou,Dinghong Zhang,Yanghui Liu,Fengling Zhuo,Lirong Qian,Honglang Li,Yong-Qing Fu,Huigao Duan

Journal Article

Deciphering the Origins of P1-Induced Power Losses in Cu(In<sub>xsub>,Ga<sub>1xsub>)Se<sub>2sub> (CIGS) Modules Through Hyperspectral Luminescence

César Omar Ramírez Quiroz, Laura-Isabelle Dion-Bertrand, Christoph J. Brabec, Joachim Müller, Kay Orgassa

Journal Article