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Anatase (001) 1

Dichloromethane 1

Disproportionation 1

Mechanism 1

Water dissociation 1

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Mechanism of dichloromethane disproportionation over mesoporous TiO

Yuzhou Deng, Shengpan Peng, Haidi Liu, Shuangde Li, Yunfa Chen

Frontiers of Environmental Science & Engineering 2019, Volume 13, Issue 2, doi: 10.1007/s11783-019-1113-8

Abstract:

• Mechanism of DCM disproportionation over mesoporous TiO2 was studied.

• DCM was completely eliminated at 350℃ under 1 vol.% humidity.

• Anatase (001) was the key for disproportionation.

• A competitive oxidation route co-existed with disproportionation.

• Disproportionation was favored at low temperature.

Keywords： Dichloromethane     Disproportionation     Mechanism     Anatase (001)     Water dissociation    

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Mechanism of dichloromethane disproportionation over mesoporous TiO

Yuzhou Deng, Shengpan Peng, Haidi Liu, Shuangde Li, Yunfa Chen

Journal Article