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Steff Van Loy, Koen Binnemans, Tom Van Gerven
Engineering 2018, Volume 4, Issue 3, Pages 398-405 doi: 10.1016/j.eng.2018.05.015
Rare-earth elements (REEs) are essential metals for the design and development of sustainable energy applications. Recycling these elements from waste streams enriched in them is crucial for securing an independent future supply for sustainable applications. This study compares the mechanisms of mechanical activation prior to a hydrometallurgical acid-leaching process and a solvometallurgical mechanochemical leaching process for the recovery of REEs from green lamp phosphor, LaPO4:Ce3+, Tb3+. After 60 min of processing time, the REE leaching rates showed a significant enhancement of 60% after cycled mechanical activation, and 98% after the combined mechanochemical leaching process. High-resolution transmission electron microscopy (HR-TEM) imaging disclosed the cause for the improved REE leaching rates: The improved leaching and leaching patterns could be attributed to changes in the crystal morphology from monocrystalline to polycrystalline. Reduction of the crystallite size to the nanoscale in a polycrystalline material creates irregular packing of chemical units, resulting in an increase in defect-rich grain boundaries in the crystals, which enhances the leaching process. A solvometallurgical method was developed to combine the mechanical activation and leaching process into a single step, which is beneficial for operational cost. This results in an efficient and simple process that provides an alternative and greener recycling route for lamp phosphor waste.
Keywords： Mechanochemistry Rare-earth elements Lamp phosphor waste Ball-milling Solvometallurgy
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