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期刊论文 11

会议视频 1

年份

2023 1

2022 4

2021 3

2020 1

2019 1

2003 1

关键词

乳液 2

胶体 2

Pickering乳液 1

丙烯酰胺 1

乳液共聚合 1

二维纳米颗粒 1

光催化 1

分子间力和表面力 1

分子间和表面间相互作用 1

原子力显微镜 1

反相微乳液聚合 1

工程过程 1

微粒子和纳米颗粒 1

提高生物利用度 1

机理 1

模型 1

氟原子 1

水处理 1

水过滤 1

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Pickering乳液的发展趋势——颗粒形态及其应用 Review

Danae Gonzalez Ortiz, Celine Pochat-Bohatier, Julien Cambedouzou, Mikhael Bechelany, Philippe Miele

《工程（英文）》 2020年第6卷第4期页码 468-482 doi: 10.1016/j.eng.2019.08.017

摘要：

近年来，Pickering乳液因其易于制备和强稳定性的特点引起了人们的广泛关注。与经典乳液不同，在Pickering乳液中，位于液体界面处的固体微粒或纳米颗粒被用作稳定剂，而不是表面活性剂，从而增加了液滴的寿命。此外，与由表面活性剂稳固的乳液相比，Pickering乳液具有更高的稳定性、更低的毒性和刺激反应性。因此，它们可以被认为是具有广泛用途的理想成分，如光催化和新材料的制备。此外，纳米颗粒的形貌对Pickering乳液的稳定性及其潜在利用率有很大的影响。在本文中，我们回顾了近年来关于Pickering乳液的一些研究成果，重点介绍了纳米颗粒的形态，如立方体、椭球体、纳米片、球体、圆柱体、棒状、花生状，如何影响这种乳液的类型和稳定性，以及它们在抗菌活性、蛋白质识别

关键词： Pickering乳液颗粒形态二维纳米颗粒光催化水过滤

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The construction of pseudo-Janus silica/surfactant assembly and their application to stabilize Pickering

《化学科学与工程前沿（英文）》 2022年第16卷第7期页码 1101-1113 doi: 10.1007/s11705-021-2095-1

摘要： Nanoparticles with high surface energy and chemical activity have drawn substantial attention in petroleum industry. Recently, Janus nanoparticles exhibited tremendous potential in enhanced oil recovery (EOR) due to their asymmetric structures and properties. In this study, a series of amphiphilic pseudo-Janus@OTAB (PJ@C18) nanoparticles with different concentrations of stearyltrimethylammoium bromide (OTAB) were successfully fabricated. The structures and properties of PJ@C18 were characterized by Fourier transform infrared spectroscopy and ζ-potential measurements. Based on the emulsification experimental results, the interaction models and the self-assembly behavior between hydrophilic nanoparticles (SiO₂@NH₂) and OTAB molecules at the oil/water interface were proposed, which was further confirmed via the measurements of the contact angle and dynamic interfacial tension. Interestingly, it was found that the change of pH value from 7.5 to 4.0 caused the type reversal of the PJ@C18-1000 stabilized Pickering emulsions. Furthermore, the PJ@C18-1000 stabilized Pickering emulsion system with excellent salt and temperature tolerances (10000 mg∙L^–1, 90 °C) significantly improved the oil recovery in the single-tube (more than 17%) and double-tube (more than 25%) sand pack model flooding tests. The findings of this study could help to better understand the construction mechanism of pseudo-Janus silica/surfactant assembly and the potential application of PJ@C18-1000 stabilized Pickering emulsions for EOR.

关键词： Janus nanoparticles surfactant double phase inversion self-assembly enhanced oil recovery

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反相微乳液聚合机理及模型化处理

李晓,张卫英,袁惠根

《中国工程科学》 2003年第5卷第1期页码 69-73

摘要：

在阐述反相微乳液聚合液滴成核及粒子增长机理的基础上，提出了丙烯酰胺反相微乳液聚合过程的物理模式，并对反相微乳液聚合模型化处理时的关键问题作了扼要讨论。

关键词：反相微乳液聚合机理模型丙烯酰胺

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膜接触破乳——用于油包水乳液分离的超疏水ZIF-8@rGO膜 Article

顾佳慧, 瞿周, 张祥宁, 范红玮, 李春喜, Jürgen Caro, 孟洪

《工程（英文）》 2023年第23卷第4期页码 73-81 doi: 10.1016/j.eng.2022.02.017

摘要：

水-油界面不平衡是实现油包水乳液破乳的关键。传统膜通常是依赖较高的跨膜压力破坏界面平衡而实现破乳。由于ZGS表面为微纳米阶层结构，所制备的ZIF-8@rGO@PDMS/PTFE（ZGPP）膜表面展现出超疏水性特性，当表面活性剂稳定的油包水乳液接触到膜表面时，微纳结构的超疏水膜表面会引起水-油界面不平衡ZGPP膜对油包水乳液具有良好的分离破乳性能，在0.15 bar（15 kPa）的低跨膜压力下，分离效率可以达到99.57%，通量可达到2254 L·m^‒2·h^‒1，且对于表面活性剂稳定的纳米级甲苯水乳液（平均液滴尺寸为57 nm）的体系也可以实现破乳分离。“接触破乳”概念的提出有望为开发新一代油包水乳液分离的破乳膜提供新的思路。

关键词：油包水乳液破乳油水分离超疏水膜

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Gas marbles: ultra-long-lasting and ultra-robust bubbles formed by particle stabilization

《化学科学与工程前沿（英文）》页码 1681-1687 doi: 10.1007/s11705-022-2180-0

摘要： Bubbles and foams are ubiquitous in daily life and industrial processes. Studying their dynamic behaviors is of key importance for foam manufacturing processes in food packaging, cosmetics and pharmaceuticals. Bare bubbles are inherently fragile and transient; enhancing their robustness and shelf lives is an ongoing challenge. Their rupture can be attributed to liquid evaporation, thin film drainage and the nuclei of environmental dust. Inspired by particle-stabilized interfaces in Pickering emulsions, armored bubbles and liquid marble, bubbles are protected by an enclosed particle-entrapping liquid thin film, and the resultant soft object is termed gas marble. The gas marble exhibits mechanical strength orders of magnitude higher than that of soap bubbles when subjected to overpressure and underpressure, owing to the compact particle monolayer straddling the surface liquid film. By using a water-absorbent glycerol solution, the resulting gas marble can persist for 465 d in normal atmospheric settings. This particle-stabilizing approach not only has practical implications for foam manufacturing processes but also can inspire the new design and fabrication of functional biomaterials and biomedicines.

关键词： bubble particles interfaces armored bubble liquid marble gas marble Pickering emulsion

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TiO@palygorskite composite for the efficient remediation of oil spills via a dispersion-photodegradation synergy

《环境科学与工程前沿（英文）》 2021年第15卷第4期 doi: 10.1007/s11783-020-1365-3

摘要：

• A novel and multi-functional clay-based oil spill remediation system was constructed.

关键词： Palygorskite TiO₂ Pickering emulsion Oil spill Dispersion Photodegradation

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Optimising the oil phases of aluminium hydrogel-stabilised emulsions for stable, safe and efficient vaccine adjuvant

《化学科学与工程前沿（英文）》 2022年第16卷第6期页码 973-984 doi: 10.1007/s11705-021-2123-1

摘要： To increase antibody secretion and dose sparing, squalene-in-water aluminium hydrogel (alum)-stabilised emulsions (ASEs) have been developed, which offer increased surface areas and cellular interactions for higher antigen loading and enhanced immune responses. Nevertheless, the squalene (oil) in previous attempts suffered from limited oxidation resistance, thus, safety and stability were compromised. From a clinical translational perspective, it is imperative to screen the optimal oils for enhanced emulsion adjuvants. Here, because of the varying oleic to linoleic acid ratio, soybean oil, peanut oil, and olive oil were utilised as oil phases in the preparation of aluminium hydrogel-stabilised squalene-in-water emulsions, which were then screened for their stability and immunogenicity. Additionally, the underlying mechanisms of oil phases and emulsion stability were unravelled, which showed that a higher oleic to linoleic acid ratio increased anti-oxidative capabilities but reduced the long-term storage stability owing to the relatively low zeta potential of the prepared droplets. As a result, compared with squalene-in-water ASEs, soybean-in-water ASEs exhibited comparable immune responses and enhanced stability. By optimising the oil phase of the emulsion adjuvants, this work may offer an alternative strategy for safe, stable, and effective emulsion adjuvants.

关键词： pickering emulsion vaccine adjuvant alum-stabilised emulsion oleic to linoleic acid ratio stability

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载有穿心莲内酯的微乳液和纳米乳液制剂——改善“苦味之王” 的生物利用度、靶组织分布及功效 Review

Marta Casamonti, Laura Risaliti, Giulia Vanti, Veri Piazzini, Maria Camilla Bergonzi, Anna Rita Bilia

《工程（英文）》 2019年第5卷第1期页码 69-75 doi: 10.1016/j.eng.2018.12.004

摘要： NP包括囊泡（脂质体和类脂质体）、聚合NP（基于聚乙烯醇、聚合苯基硼酸、PLGA、人血清白蛋白、聚氰基丙烯酸乙酯和聚合物胶束）、固体脂质NP、微乳液（ME）和纳米乳液（NE）、黄金NP、纳米晶体和纳米混悬液

关键词：穿心莲爵床科穿心莲内酯给药系统微粒子和纳米颗粒提高生物利用度靶组织分布

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工程过程中分子间和表面间相互作用 Review

张嘉文, 曾宏波

《工程（英文）》 2021年第7卷第1期页码 63-83 doi: 10.1016/j.eng.2020.08.017

摘要：

在复杂流体中，化学试剂、固体颗粒、气泡、液滴和固体表面间的相互作用在许多工程过程中起着至关重要的作用，如泡沫浮选、乳液和泡沫形成、吸附、污垢

关键词：分子间和表面间相互作用胶体乳液界面科学工程过程原子力显微镜表面力仪

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石油生产过程中界面力和表面相互作用机制探究 Review

杨笛灵, 彭旭雯, 彭琼瑶, 王涛, 乔辰宇, 赵子谦, 龚露, 刘月亮, 张豪, 曾宏波

《工程（英文）》 2022年第18卷第11期页码 49-61 doi: 10.1016/j.eng.2022.06.012

摘要：本文概述了通过应用表面力仪器（SFA）和原子力显微镜（AFM）等纳米力学测量技术探测几个石油生产过程（如沥青提取、乳液稳定和不稳定、结垢和防污现象以及水处理）中的界面力的最新进展。

关键词：分子间力和表面力界面乳液胶体结垢和防污水处理

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用于锂离子电池的富醚/酯/氟黏结剂配方 Article

Xianqing Zeng, Donglin Han, Zeheng Li, Hongxun Wang, Gu Wu, Yong Deng, Kai Liu, Li Xie, Chengdu Liang, Min Ling, Yuchuan Huang

《工程（英文）》 2022年第19卷第12期页码 199-206 doi: 10.1016/j.eng.2022.05.020

摘要：

由于硅阳极体积膨胀过大，无法在高能量密度电池中实现实际应用。研究人员一直专注于在阳极中添加黏结剂以限制体积膨胀，来解决这一问题，因为黏结剂的氢键和机械性能可以用来增强黏附力和适应硅阳极的体积变化。在这里，我们综合考虑了黏结剂的氢键、力学性能、稳定性以及与电解液的相容性，设计了一种富醚/酯/氟的复合聚合物P(TFEMA-co-IBVE)。该黏结剂配方具有优异的稳定性、黏结性和机械强度，能够适应硅电极体积的剧烈变化，表现出优异的电化学性能，面积容量高达5.4 mA∙h∙cm⁻²。这种新型聚合物设计可应用于下一代锂离子电池的其他电极材料。

关键词：硅阳极乳液共聚合氟原子醚酯