期刊首页 优先出版 当期阅读 过刊浏览 作者中心 关于期刊 English

《工程(英文)》 >> 2023年 第24卷 第5期 doi: 10.1016/j.eng.2021.08.029

MOF-5@Ni衍生的ZnO@Ni3ZnC0.7/PMS体系用于有机物去除——对吸附-降解过程的深入理解

a College of Architecture and Environment, Sichuan University, Chengdu 610065, China
b College of Environmental Science and Engineering, Nankai University, Tianjin 300071, China

收稿日期: 2021-03-24 修回日期: 2021-08-21 录用日期: 2021-08-27 发布日期: 2022-02-25

下一篇 上一篇

摘要

基于过一硫酸盐的非均相催化活化技术在废水处理中越来越受到关注。因此,找到一种可持续、经济、有效的活性材料用于废水处理非常重要。本研究以金属有机框架材料(MOF)-5 为前驱体,通过添加镍离子并随后煅烧制备了一种稳定、可循环利用的材料ZnO@Ni3ZnC0.7,该材料表现出良好的吸附和催化性能。为了研究和优化实际应用条件,选择了罗丹明B(RhB)在水中的降解作为模型过程。研究表明,体系中有机物的去除涉及吸附和降解过程的耦合。基于此,提出了整个去除过程的机理。扫描电子显微镜、红外光谱分析和理论分析的结果证实,范德华力、静电吸引力和氢键影响吸附过程。电子顺磁共振分析、遮蔽实验和电化学测试证实,RhB的降解路径包括自由基和非自由基途径,表面羟基是关键的活性位点。对吸附底物的降解使活性位点得到再生。用简单方法再生的材料在4 个循环测试中对有机化合物保持很高的去除效率。此外,这种材料还可以有效地去除各种有机污染物,并且由于具有磁性,材料易于回收。结果表明,使用具有良好吸附能力的非均相催化材料可能是一种经济有效的策略。

补充材料

图片

图1

图2

图3

图4

图5

图6

图7

图8

图9

参考文献

[ 1 ] Meyer MF, Powers SM, Hampton SE. An evidence synthesis of pharmaceuticals and personal care products (PPCPs) in the environment: imbalances among compounds, sewage treatment techniques, and ecosystem types. Environ Sci Technol 2019;53(22):12961‒73. 链接1

[ 2 ] Isari AA, Hayati F, Kakavandi B, Rostami M, Motevassel M, Dehghanifard EN. Cu co-doped TiO2@functionalized SWCNT photocatalyst coupled with ultrasound and visible-light: an effective sono-photocatalysis process for pharmaceutical wastewaters treatment. Chem Eng J 2020;392:123685. 链接1

[ 3 ] Sumpter JP, Johnson AC. Lessons from endocrine disruption and their application to other issues concerning trace organics in the aquatic environment. Environ Sci Technol 2005;39(12):4321‒32. 链接1

[ 4 ] Chu KH, Al-Hamadani YAJ, Park CM, Lee G, Jang M, Jang A, et al. Ultrasonic treatment of endocrine disrupting compounds, pharmaceuticals, and personal care products in water: a review. Chem Eng J 2017;327:629‒47. 链接1

[ 5 ] Bello MM, Abdul Raman AA, Purushothaman M. Applications of fluidized bed reactors in wastewater treatment―a review of the major design and operational parameters. J Clean Prod 2017;141:1492‒514. 链接1

[ 6 ] Khan AH, Khan NA, Ahmed S, Dhingra A, Singh CP, Khan SU, et al. Application of advanced oxidation processes followed by different treatment technologies for hospital wastewater treatment. J Clean Prod 2020;269:122411. 链接1

[ 7 ] Luo Y, Guo W, Ngo HH, Nghiem LD, Hai FI, Zhang J, et al. A review on the occurrence of micropollutants in the aquatic environment and their fate and removal during wastewater treatment. Sci Total Environ 2014;473‒474:619‒41.

[ 8 ] Deng J, Feng SF, Zhang K, Li J, Wang H, Zhang T, et al. Heterogeneous activation of peroxymonosulfate using ordered mesoporous Co3O4 for the degradation of chloramphenicol at neutral pH. Chem Eng J 2017;308:505‒15. 链接1

[ 9 ] Feng Y, Wu D, Deng Y, Zhang T, Shih K. Sulfate Radical-mediated degradation of sulfadiazine by CuFeO2 rhombohedral crystal-catalyzed peroxymonosulfate: synergistic effects and mechanisms. Environ Sci Technol 2016;50(6):3119‒27. 链接1

[10] Rezaei SS, Kakavandi B, Noorisepehr M, Isari AA, Zabih S, Bashardoust P. Photocatalytic oxidation of tetracycline by magnetic carbon-supported TiO2 nanoparticles catalyzed peroxydisulfate: Performance, synergy and reaction mechanism studies. Separ Purif Tech 2021;258:117936. 链接1

[11] Anipsitakis GP, Dionysiou DD. Radical generation by the interaction of transition metals with common oxidants. Environ Sci Technol 2004;38(13):3705‒12. 链接1

[12] Ding D, Liu C, Ji Y, Yang Q, Chen L, Jiang C, et al. Mechanism insight of degradation of norfloxacin by magnetite nanoparticles activated persulfate: Identification of radicals and degradation pathway. Chem Eng J 2017;308:330‒9. 链接1

[13] Ghanbari F, Moradi M. Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants. Chem Eng J 2017;310:41‒62. 链接1

[14] Oh WD, Dong Z, Lim TT. Generation of sulfate radical through heterogeneous catalysis for organic contaminants removal: Current development, challenges and prospects. Appl Catal B 2016;194:169‒201. 链接1

[15] Babaei AA, Golshan M, Kakavandi B. A heterogeneous photocatalytic sulfate radical-based oxidation process for efficient degradation of 4-chlorophenol using TiO anchored on Fe oxides@carbon. Process Saf Environ Prot 2021;149:35‒47. 链接1

[16] Rezaei SS, Dehghanifard E, Noorisepehr M, Ghadirinejad K, Kakavandi B, Esfahani AR. Efficient clean-up of waters contaminated with diazinon pesticide using photo-decomposition of peroxymonosulfate by ZnO decorated on a magnetic core/shell structure. J Environ Manage 2019;250:109472. 链接1

[17] Noorisepehr M, Ghadirinejad K, Kakavandi B, Ramazanpour Esfahani A, Asadi A. Photo-assisted catalytic degradation of acetaminophen using peroxymonosulfate decomposed by magnetic carbon heterojunction catalyst. Chemosphere 2019;232:140‒51. 链接1

[18] Qiao J, Hamaya T, Okada T. Chemically modified poly(vinyl alcohol)-poly(2-acrylamido-2-methyl-1-propanesulfonic acid) as a novel proton-conducting fuel cell membrane. Chem Mater 2005;17(9):2413‒21. 链接1

[19] Pirkanniemi K, Sillanpää M. Heterogeneous water phase catalysis as an environmental application: a review. Chemosphere 2002;48(10):1047‒60. 链接1

[20] Wang X, Qin Y, Zhu L, Tang H. Nitrogen-doped reduced graphene oxide as a bifunctional material for removing bisphenols: synergistic effect between adsorption and catalysis. Environ Sci Technol 2015;49(11):6855‒64. 链接1

[21] Peng Q, Ding Y, Zhu L, Zhang G, Tang H. Fast and complete degradation of norfloxacin by using Fe/Fe3C@NG as a bifunctional catalyst for activating peroxymonosulfate. Separ Purif Tech 2018;202:307‒17. 链接1

[22] Chen YZ, Zhang R, Jiao L, Jiang HL. Metal‍‒‍organic framework-derived porous materials for catalysis. Coord Chem Rev 2018;362:1‒23. 链接1

[23] Farrusseng D, Aguado S, Pinel C. Metal-organic frameworks: opportunities for catalysis. Angew Chem Int Ed Engl 2009;48(41):7502‒13. 链接1

[24] James SL. Metal-organic frameworks. Chem Soc Rev 2003;32(5):276‒88. 链接1

[25] Qasem NAA, Ben-Mansour R, Habib MA. An efficient CO2 adsorptive storage using MOF-5 and MOF-177. Appl Energy 2018;210:317‒26. 链接1

[26] Liu Y, Han G, Zhang X, Xing C, Du C, Cao H, et al. Co-Co3O4@carbon core‒shells derived from metal‍-‍organic framework nanocrystals as efficient hydrogen evolution catalysts. Nano Res 2017;10(9):3035‒48. 链接1

[27] Wang R, Xu H, Zhang K, Wei S, Deyong W. High-quality Al@Fe-MOF prepared using Fe-MOF as a micro-reactor to improve adsorption performance for selenite. J Hazard Mater 2019;364:272‒80. 链接1

[28] Xu H, Gao J, Qian X, Wang J, He H, Cui Y, et al. Metal-organic framework nanosheets for fast-response and highly sensitive luminescent sensing of Fe3+. J Mater Chem A Mater Energy Sustain 2016;4(28):10900‒5. 链接1

[29] Teplensky MH, Fantham M, Li P, Wang TC, Mehta JP, Young LJ, et al. Temperature treatment of highly porous zirconium-containing metal-organic frameworks extends drug delivery release. J Am Chem Soc 2017;‍139(22):7522‒32. 链接1

[30] Silva CG, Corma A, García H. Metal-organic frameworks as semiconductors. J Mater Chem 2010;20(16):3141‒56. 链接1

[31] Keskin S, Kizilel S. Biomedical applications of metal organic frameworks. Ind Eng Chem Res 2011;50(4):1799‒812. 链接1

[32] Cao X, Zheng B, Rui X, Shi W, Yan Q, Zhang H. Metal oxide-coated three-dimensional graphene prepared by the use of metal-organic frameworks as precursors. Angew Chem Int Ed Engl 2014;53(5):1404‒9. 链接1

[33] Maya F, Palomino Cabello C, Frizzarin RM, Estela JM, Turnes Palomino G, Cerdà V. Magnetic solid-phase extraction using metal-organic frameworks (MOFs) and their derived carbons. TrAC Trends Analyt Chem 2017;90:142‒52. 链接1

[34] Chen L, Li Y, Xu N, Zhang G. Metal-organic framework derived coralline-like non-precious metal catalyst for highly efficient oxygen reduction reaction. Carbon N Y 2018;132:172‒80. 链接1

[35] Zhang H, Liu X, Wu Y, Guan C, Cheetham AK, Wang J. MOF-derived nanohybrids for electrocatalysis and energy storage: current status and perspectives. Chem Commun 2018;54(42):5268‒88. 链接1

[36] Liu C, Wang Y, Zhang Y, Li R, Meng W, Song Z, et al. Enhancement of Fe@porous carbon to be an efficient mediator for peroxymonosulfate activation for oxidation of organic contaminants: Incorporation NH2-group into structure of its MOF precursor. Chem Eng J 2018;354:835‒48. 链接1

[37] Li CX, Chen CB, Lu JY, Cui S, Li J, Liu HQ, et al. Metal organic framework-derived CoMn2O4 catalyst for heterogeneous activation of peroxymonosulfate and sulfanilamide degradation. Chem Eng J 2018;337:101‒9. 链接1

[38] Hafizovic J, Bjørgen M, Olsbye U, Dietzel PDC, Bordiga S, Prestipino C, et al. The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities. J Am Chem Soc 2007;129(12):3612‒20. 链接1

[39] Qi ZP, Yang JM, Kang YS, Guo F, Sun WY. Facile water-stability evaluation of metal-organic frameworks and the property of selective removal of dyes from aqueous solution. Dalton Trans 2016;45(21):8753‒59. 链接1

[40] Li H, Shi W, Zhao K, Li H, Bing Y, Cheng P. Enhanced hydrostability in Ni-doped MOF-5. Inorg Chem 2012;51(17):9200‒7. 链接1

[41] Li J, Yan D, Hou S, Lu T, Yao Y, Chua DHC, et al. Metal-organic frameworks derived yolk-shell ZnO/NiO microspheres as high-performance anode materials for lithium-ion batteries. Chem Eng J 2018;335:579‒89. 链接1

[42] Yang LY, Dong SY, Sun JH, Feng JL, Wu QH, Sun SP. Microwave-assisted preparation, characterization and photocatalytic properties of a dumbbell-shaped ZnO photocatalyst. J Hazard Mater 2010;179(1‒3):438‒43.

[43] Sarker M, Song JY, Jhung SH. Carboxylic-acid-functionalized UiO-66-NH2: A promising adsorbent for both aqueous- and non-aqueous-phase adsorptions. Chem Eng J 2018;331:124‒31. 链接1

[44] Pan B, Xing B. Adsorption mechanisms of organic chemicals on carbon nanotubes. Environ Sci Technol 2008;42(24):9005‒13. 链接1

[45] Ghorai S, Sarkar A, Raoufi M, Panda AB, Schönherr H, Pal S. Enhanced removal of methylene blue and methyl violet dyes from aqueous solution using a nanocomposite of hydrolyzed polyacrylamide grafted xanthan gum and incorporated nanosilica. ACS Appl Mater Interfaces 2014;6(7):4766‒77. 链接1

[46] Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquerol J, et al. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity. Pure Appl Chem 1985;57(4):603‒19.

[47] Liu M, Xu J, Cheng B, Ho W, Yu J. Synthesis and adsorption performance of Mg(OH)2 hexagonal nanosheet-graphene oxide composites. Appl Surf Sci 2015;332:121‒9. 链接1

[48] Kasnavia T, Vu D, Sabatini DA. Fluorescent dye and media properties affecting sorption and tracer selection. Ground Water 1999;37(3):376‒81. 链接1

[49] Zhang T, Li W, Croué JP. Catalytic ozonation of oxalate with a cerium supported palladium oxide: an efficient degradation not relying on hydroxyl radical oxidation. Environ Sci Technol 2011;45(21):9339‒46. 链接1

[50] Liu J, Zhao Z, Shao P, Cui F. Activation of peroxymonosulfate with magnetic Fe3O4‒MnO2 core‒shell nanocomposites for 4-chlorophenol degradation. Chem Eng J 2015;262:854‒61. 链接1

[51] Mo X, Yang ZH, Xu HY, Zeng GM, Huang J, Yang X, et al. Combination of cathodic reduction with adsorption for accelerated removal of Cr(VI) through reticulated vitreous carbon electrodes modified with sulfuric acid-glycine co-doped polyaniline. J Hazard Mater 2015;286:493‒502. 链接1

[52] Wang L, Li J, Wang Z, Zhao L, Jiang Q. Low-temperature hydrothermal synthesis of α-Fe/Fe3O4 nanocomposite for fast Congo red removal. Dalton Trans 2013;42(7):2572‒9. 链接1

[53] Zhang T, Li C, Ma J, Tian H, Qiang Z. Surface hydroxyl groups of synthetic α-FeOOH in promoting ·OH generation from aqueous ozone: property and activity relationship. Appl Catal B 2008;82(1‒2):131‒7. 链接1

[54] Lu Y, Jiang B, Fang L, Ling F, Gao J, Wu F, et al. High performance NiFe layered double hydroxide for methyl orange dye and Cr(VI) adsorption. Chemosphere 2016;152:415‒22. 链接1

[55] Lei C, Zhu X, Le Y, Zhu B, Yu J, Ho W. Hierarchically porous NiO‍‒‍Al2O3 nanocomposite with enhanced Congo red adsorption in water. RSC Advances 2016;6(13):10272‒9. 链接1

[56] Ho YS, McKay G. Pseudo-second order model for sorption processes. Process Biochem 1999;34(5):451‒65. 链接1

[57] Neta P, Huie RE, Ross AB. Rate Constants for Reactions of Inorganic Radicals in Aqueous Solution. J Phys Chem Ref Data 1988;17(3):1027. 链接1

[58] Buxton GV, Greenstock CL, Helman WP, Ross AB. Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O- in Aqueous Solution. J Phys Chem Ref Data 1988;17(2):513. 链接1

[59] Hayon E, Treinin A, Wilf J. Electronic spectra, photochemistry, and autoxidation mechanism of the sulfite‒bisulfite‒pyrosulfite Systems. the SO2-, SO3-, SO4-, and SO5- radicals. J Am Chem Soc 1972;94(1):47‒57. 链接1

[60] Huang GX, Wang CY, Yang CW, Guo PC, Yu HQ. Degradation of bisphenol a by peroxymonosulfate catalytically activated with Mn1.8Fe1.2O4 nanospheres: synergism between Mn and Fe. Environ Sci Technol 2017;51(21):12611‒8. 链接1

[61] Feng M, Qu R, Zhang X, Sun P, Sui Y, Wang L, et al. Degradation of flumequine in aqueous solution by persulfate activated with common methods and polyhydroquinone-coated magnetite/multi-walled carbon nanotubes catalysts. Water Res 2015;85:1‒10. 链接1

[62] Zhong H, Brusseau ML, Wang Y, Yan N, Quig L, Johnson GR. In-situ activation of persulfate by iron filings and degradation of 1,4-dioxane. Water Res 2015;83:104‒11. 链接1

[63] Yan N, Liu F, Xue Q, Brusseau ML, Liu Y, Wang J. Degradation of trichloroethene by siderite-catalyzed hydrogen peroxide and persulfate: investigation of reaction mechanisms and degradation products. Chem Eng J 2015;274:61‒8. 链接1

[64] Evans DF, Upton MW. Studies on singlet oxygen in aqueous solution. Part 3. The decomposition of peroxy-acids. J Chem Soc, Dalton Trans 1985;(6):1151. 链接1

[65] Shao P, Tian J, Yang F, Duan X, Gao S, Shi W, et al. Identification and regulation of active sites on nanodiamonds: establishing a highly efficient catalytic system for oxidation of organic contaminants. Adv Funct Mater 2018;28(13):1705295. 链接1

[66] Anipsitakis GP, Dionysiou DD. Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt. Environ Sci Technol 2003;37(20):4790‒7. 链接1

[67] Liang P, Zhang C, Duan X, Sun H, Liu S, Tade MO, et al. An insight into metal organic framework derived N-doped graphene for the oxidative degradation of persistent contaminants: formation mechanism and generation of singlet oxygen from peroxymonosulfate. Environ Sci Nano 2017;4(2):315‒24. 链接1

[68] Montgomery RE. Catalysis of peroxymonosulfate reactions by ketones. J Am Chem Soc 1974;96(25):7820‒1. 链接1

[69] Sun H, Feng X, Wang S, Ang HM, Tadé MO. Combination of adsorption, photochemical and photocatalytic degradation of phenol solution over supported zinc oxide: effects of support and sulphate oxidant. Chem Eng J 2011;170(1):270‒7. 链接1

[70] Ramachandran R, SakthivelThangavel, LiMinzhang, ShanHaiquan, XuZong-Xiang, Wang F. Efficient degradation of organic dye using Ni-MOF derived NiCo-LDH as peroxymonosulfate activator. Chemosphere 2021;271:128509. 链接1

[71] Zhu J, Chen C, Li Y, Zhou L, Lan Y. Rapid degradation of aniline by peroxydisulfate activated with copper‍‒‍nickel binary oxysulfide. Separ Purif Tech 2019;209:1007‒15. 链接1

[72] Ding Y, Wang X, Fu L, Peng X, Pan C, Mao Q, et al. Nonradicals induced degradation of organic pollutants by peroxydisulfate (PDS) and peroxymonosulfate (PMS): recent advances and perspective. Sci Total Environ 2021;765:142794. 链接1

[73] Ren W, Xiong L, Nie G, Zhang H, Duan X, Wang S. Insights into the electron-transfer regime of peroxydisulfate activation on carbon nanotubes: the role of oxygen functional groups. Environ Sci Technol 2020;54(2):1267‒75. 链接1

[74] Kleinwechter H, Janzen C, Knipping J, Wiggers H, Roth P. Formation and properties of ZnO nano-particles from gas phase synthesis processes. J Mater Sci 2002;37(20):4349‒60. 链接1

[75] Aljawfi RN, Mollah S. Properties of Co/Ni codoped ZnO based nanocrystalline DMS. J Magn Magn Mater 2011;323(23):3126‒32. 链接1

[76] Cun T, Dong C, Huang Q. Ionothermal precipitation of highly dispersive ZnO nanoparticles with improved photocatalytic performance. Appl Surf Sci 2016;384:73‒82. 链接1

[77] Lei C, Pi M, Jiang C, Cheng B, Yu J. Synthesis of hierarchical porous zinc oxide (ZnO) microspheres with highly efficient adsorption of Congo red. J Colloid Interface Sci 2017;490:242‒51. 链接1

[78] Luo H, Lin Q, Zhang X, Huang Z, Fu H, Xiao R, et al. Determining the key factors of nonradical pathway in activation of persulfate by metal-biochar nanocomposites for bisphenol A degradation. Chem Eng J 2020;391:123555. 链接1

[79] Hong XJ, Song CL, Wu ZM, Li ZH, Cai YP, Wang CX, et al. Sulfophilic and lithophilic sites in bimetal nickel-zinc carbide with fast conversion of polysulfides for high-rate Li‒S battery. Chem Eng J 2021;404:126566. 链接1

相关研究