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2018 2

2010 1

2008 1

2007 1

2006 1

2004 1

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催化裂化 2

烯烃 2

FCC汽油 1

RIDOS 1

两个反应区 1

催化剂 1

反应化学 1

多维反应结构 1

异构化 1

异构烷烃 1

汽油 1

硫 1

芳烃 1

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Desulfurization mechanism of FCC gasoline: A review

Liang ZHAO, Yan CHEN, Jinsen GAO, Yu CHEN,

《化学科学与工程前沿（英文）》 2010年第4卷第3期页码 314-321 doi: 10.1007/s11705-009-0271-9

摘要： This paper reviews the most important developments on the desulfurization mechanism of Fluid Catalytic Cracking (FCC) gasoline. First, the origin of sulfur compounds in FCC gasoline and the current developed desulfurization approaches and technologies are briefly introduced, and then the researches on desulfurization mechanism are summarized from experimental and theoretical perspectives. Further researches on the desulfurization mechanism will lay a foundation for optimizing desulfurization sorbents and technologies.

关键词： Catalytic Cracking foundation developed desulfurization desulfurization mechanism important

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Constitutive Model for an FCC Single-Crystal Material

DING Zhi-ping, LIU Yi-lun, YIN Ze-yong, YANG Zhi-guo, CHENG Xiao-ming

《机械工程前沿（英文）》 2006年第1卷第1期页码 40-47 doi: 10.1007/s11465-005-0012-9

摘要：

Taking into account the effects that the components of tension stresses couple with components of torsion stresses when off-axis loads are applied to orthotropic materials, Hill s yield criterion for plastically orthotropic solids is modified by adding an invariant that is composed of the product item of quadratic components of the deviatoric stress tensor, and a new yield criterion is put forward in terms of the characteristics of the face-centered cubic (FCC) single-crystal material. The correlation of prediction and experiments is very good, and the new criterion is used to predict the yield stresses of an internal single-crystal, Nickel-based superalloy, DD3, which is more accurate than that of Hill s at 760?C. Equivalent stress and strain that adapt to the new criterion are defined. Thinking of the yield function as a plastic potential function from the associated flow rule, the elastic plastic constitutive model for the FCC single-crystal material is constructed, and the corresponding elastic plastic matrix is educed. The new yield criterion and its equivalent stress and strain will be reduced to Von Mises yield criterion and corresponding equivalent stress and strain for isotropic materials.

关键词： orthotropic Thinking accurate prediction corresponding

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生产低硫低烯烃汽油的RIDOS技术

李大东,石亚华,杨清雨

《中国工程科学》 2004年第6卷第4期页码 1-8

摘要：

通过研究高烯烃含量FCC汽油的烃类组成和结构，针对性地开发了具有深度脱硫和烯烃饱和能力并减少辛烷值损失的RIDOS技术。

关键词： FCC汽油 RIDOS 烯烃硫异构化

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Gas-solids separation model of a novel FCC riser terminator device: super short quick separator (SSQS

LU Chunxi, LI Ruxin, SHI Mingxian, LIU Xiancheng

《化学科学与工程前沿（英文）》 2008年第2卷第4期页码 462-467 doi: 10.1007/s11705-008-0068-2

摘要： The gas flow field and the separation efficiency of a novel fluid catalytic cracking (FCC) riser terminal device, named as Super Short Quick Separator (SSQS), were studied. On the basis of above investigations, a section-lateral-mixing separation model was proposed, which included both the effect of inertia and structure of gas outlet on particles capture. After final modification, the results predicted with this model could be in good agreement with the cold experimental data. According to this model, the separation efficiency of SSQS is mainly influenced by the difference between the arc radius and the center pipe radius as well as the magnitude of particle tangential velocity.

关键词： catalytic cracking separation efficiency tangential velocity agreement magnitude

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A novel fluid catalytic cracking process for maximizing

Youhao Xu, Shouye Cui

《化学科学与工程前沿（英文）》 2018年第12卷第1期页码 9-23 doi: 10.1007/s11705-017-1696-1

摘要： The maximizing iso-paraffins (MIP) developed by RIPP has improved gasoline quality to meet the demand of motor gasoline specification. A concept that two different reaction zones include cracking zone and conversion zone is proposed as the fundamental of MIP by research on fluid catalytic cracking (FCC) reaction chemistry. Based on the concept, the MIP process is featured by applying a novel sequential two-zone riser in conjunction with proprietary catalyst and engineering technique. The developed MIP process can not only improve gasoline yield or gasoline plus propylene yields but also produce gasoline with a higher content of -paraffins and a lower content of sulfur. A minimum octane number loss is achieved when MIP gasoline is treated by downstream desulfurization technology (RSDS/S Zorb). The combination of MIP and RSDS/S Zorb processes creates a very competitive route, which is different from the technical route used by other developed countries, to upgrade the quality of motor gasoline with the lowest economic costs in China. In just one decade, the processing capacity of MIP units has accounted for about 60% of the domestic total processing capacity of FCC units. The MIP process is gradually becoming a new generation of FCC technology.

关键词： gasoline iso-paraffins FCC desulfurization octane number

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催化裂化过程反应化学的进展

许友好,汪燮卿

《中国工程科学》 2007年第9卷第8期页码 6-14

摘要：

面对催化裂化工艺所遇到的挑战，提出了催化裂化过程反应化学的多维反应结构模式。多维反应结构模式的建立是基于对烃类在酸性催化剂上反应化学认识而进行的知识创新，但多维反应结构不同于烃类在酸性催化剂上反应化学。具有多维反应结构的催化裂化工艺更具有多样性和灵活性，基于此已成功地开发了多产异构烷烃的催化裂化工艺和生产清洁汽油和多产丙烯的催化裂化工艺。

关键词：催化裂化反应化学催化剂多维反应结构两个反应区

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多产异构烷烃的催化裂化工艺技术开发与工业应用

许友好,张久顺,龙军,何鸣元,徐惠,郝希仁

《中国工程科学》 2003年第5卷第5期页码 55-58

摘要：

从催化裂化反应机理出发，提出了两个反应区的概念，设计了具有两个反应区的串联提升管反应器并形成相应的工程技术，在此基础上进行了中小型探索试验和工业试验。1.4 Mt/a多产异构烷烃的催化裂化装置试验标定结果表明：与现有的催化裂化工艺相比，该工艺不仅优化了产物分布，干气和油浆产率分别下降了0.41%和0.99%，液体收率增加了1.17%，而且所生产的汽油烯烃含量下降约14.1%，异构烷烃增加约为12.9%，硫的质量分数ω（s）下降26.5%,诱导期增加,汽油的RON下降而MON增加,总的抗爆指数略有下降。

关键词：催化裂化汽油烯烃异构烷烃芳烃