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Lifecycle carbon footprint and cost assessment for coal-to-liquid coupled with carbon capture, storage

《能源前沿（英文）》 2023年 第17卷 第3期   页码 412-427 doi: 10.1007/s11708-023-0879-3

摘要： The coal-to-liquid coupled with carbon capture, utilization, and storage technology has the potential to reduce CO2 emissions, but its carbon footprint and cost assessment are still insufficient. In this paper, coal mining to oil production is taken as a life cycle to evaluate the carbon footprint and levelized costs of direct-coal-to-liquid and indirect-coal-to-liquid coupled with the carbon capture utilization and storage technology under three scenarios: non capture, process capture, process and public capture throughout the life cycle. The results show that, first, the coupling carbon capture utilization and storage technology can reduce CO2 footprint by 28%–57% from 5.91 t CO2/t·oil of direct-coal-to-liquid and 24%–49% from 7.10 t CO2/t·oil of indirect-coal-to-liquid. Next, the levelized cost of direct-coal-to-liquid is 648–1027 $/t of oil, whereas that of indirect-coal-to-liquid is 653–1065 $/t of oil. When coupled with the carbon capture utilization and storage technology, the levelized cost of direct-coal-to-liquid is 285–1364 $/t of oil, compared to 1101–9793 $/t of oil for indirect-coal-to-liquid. Finally, sensitivity analysis shows that CO2 transportation distance has the greatest impact on carbon footprint, while coal price and initial investment cost significantly affect the levelized cost of coal-to-liquid.

关键词： coal-to-liquid     carbon capture     utilization and storage (CCUS)     carbon footprint     levelized cost of liquid     lifecycle assessment    

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NICE’s Indirect Coal-to-Liquid Process for Producing Clean Transportation Fuels Using Fischer-Tropsch

Omar M. Basha,Li Weng,Zhuo-wu Men,Wayne Xu,Badie I. Morsi

《工程管理前沿（英文）》 2016年 第3卷 第4期   页码 362-376 doi: 10.15302/J-FEM-2016049

摘要： China is currently the world’s top coal consumer and the largest oil importer to sustain its rising economy and meet the mounting demand for transportation fuels. However, the increasing emissions due to the huge fossil fuels consumption, coupled with oil market instability, could derail China’s economic growth and jeopardize its national energy security. To face such a hurdle, China has been aggressively supporting low-carbon businesses opportunuties over the past decade, has recently announced several plans to cap coal utilization, and is currently the biggest investor in clean energy technologies. Coal-to-Liquid (CTL) is one of the most promising clean coal technologies, offering an ideal solution that can meet China’s energy demands and environmental expectations. It is widely known that the Shenhua Group has pioneered and is currently leading the commercialization of the Direct Coal Liquefaction (DCL) process in China. This paper highlights a part of the joint research effort undertaken by the National Institute of Clean-and-Low-Carbon Energy (NICE) and University of Pittsburgh in order to develop and commercialize the Indirect Coal Liquefaction (ICL) process. In this mission, NICE has built and operated an ICL plant including a large-scale (5.8-m ID and 30-m height) Slurry-Bubble-Column Reactor (SBCR) for Fischer-Tropsch synthesis using iron catalyst. The research, conducted at the University of Pittsburgh over the past few years, allowed building a user-friendly Simulator, based on a comprehensive SBCR model integrated with Aspen Plus and is validated using data from the NICE actual ICL plant. In this paper, the Simulator predictions of the performance of the NICE SBCR, operating with iron and cobalt catalysts under four different tail gas recycle strategies: (1) direct recycle; (2) using a Pressure Swing Adsorption (PSA) unit; (3) using a reformer; and (4) using a Chemical looping Combustion (CLC) process, are presented. It should be mentioned also that our joint research effort has laid the foundation for the design of a commercial-scale SBCR for producing one-million tons per annum of environmentally friendly and ultraclean (no sulfur, no nitrogen and virtually no aromatics) transportation fuels, which could greatly contribute to ensuring China’s national energy security while curbing its lingering emission problems.

关键词： Fischer-Tropsch synthesis     tail gas recycle     simulations     process design    

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新型煤化工的生命周期碳排放趋势分析

武娟妮,张岳玲,田亚峻,谢克昌

《中国工程科学》 2015年 第17卷 第9期   页码 69-74

摘要：

近年来新型煤化工的发展势头强劲，不仅使煤转化过程的碳排放有大幅增长的趋势，更会带动整个产业链碳排放的增长。为了全面认识新型煤化工发展给气候变化带来的潜在影响，本文采用生命周期评价的方法，以煤制烯烃、煤间接液化、煤直接液化、煤制天然气作为新型煤化工的代表，分析了从煤炭生产到产品消费的整个产业链的碳排放现状和趋势。结果显示，从生命周期的角度认识煤化工发展带来的碳排放潜力，中期新型煤化工生命周期CO2eq（CO2当量）排放量是现状的10倍，远期甚至达到现状的21倍，新型煤化工发展呈现过热势头，这给我国的碳减排目标带来不容忽视的压力，其中尤以煤制天然气、煤经甲醇制烯烃和间接液化发展潜力较大；分析表明，整个产业链的碳排放主要来自于煤转化过程，约占54 %~63 %，然而该环节排放的CO2纯度较高，适于碳捕集、利用和封存(CCUS)，可以显著降低新型煤化工快速发展给气候变化带来的影响；其次，新型煤化工上下游产业链碳排放约占37 %~46 %，其中用电导致的间接排放占7 %~15 %，可通过推广超临界和超超临界发电技术以及高压和超高压输电技术减排。

关键词： 煤制烯烃；煤间接液化；煤直接液化；煤制天然气；生命周期；碳排放    

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Chemical probe systems for assessing liquid–liquid mixing efficiencies of reactors

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1323-1335 doi: 10.1007/s11705-022-2275-7

摘要： Liquid–liquid mixing, including homogeneous and heterogeneous mixing, widely exists in the chemical industry. How to quantitatively characterize the mixing performance is important for reactor assessment and development. As a convenient and direct method for mixing characterization, the chemical probe method uses some special test reactions to characterize the mixing results. Here, the working principle and selection requirements of this method are introduced, and some common chemical probe systems for homogeneous and heterogeneous mixing processes are reviewed. The characteristics and applications of these systems are illustrated. Finally, the development of the new system is proposed.

关键词： mixing     chemical probe     liquid–liquid     heterogeneous    

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Microfluidic production of liposomes through liquid–liquid phase separation in ternary droplets

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 1017-1022 doi: 10.1007/s11705-021-2118-y

摘要： Liposomes, the self-assembled phospholipid vesicles, have been extensively used in various fields such as artificial cells, drug delivery systems, biosensors and cosmetics. However, current microfluidic routes to liposomes mostly rely on water-in-oil-in-water double emulsion droplets as templates, and require complex fabrication of microfluidic devices, and tedious manipulation of multiphase fluids. Here we present a simple microfluidic approach to preparing monodisperse liposomes from oil-in-water droplets. For demonstration, we used butyl acetate-water-ethanol ternary mixtures as inner phase and an aqueous solution of surfactants as outer phase to make oil-in-water droplets, which can evolve into water-in-oil-in-water double emulsion droplets by liquid–liquid phase separation of ternary mixtures. Subsequently, the resultant water-in-oil-in-water droplets underwent a dewetting transition to form separated monodisperse liposomes and residual oil droplets, with the assistance of surfactants. The method is simple, does not require complex microfluidic devices and tedious manipulation, and provides a new platform for controllable preparation of liposomes.

关键词： microfluidics     liposomes     ternary droplets     phase separation    

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Energy distribution between liquid hydrogen and liquid oxygen temperatures in a Stirling/pulse tube refrigerator

《能源前沿（英文）》 2023年 第17卷 第4期   页码 516-526 doi: 10.1007/s11708-022-0844-6

摘要： A two-stage gas-coupled Stirling/pulse tube refrigerator (SPR), whose first and second stages respectively involve Stirling and pulse tube refrigeration cycles, is a very promising spaceborne refrigerator. The SPR has many advantages, such as a compact structure, high reliability, and high performance, and is expected to become an essential refrigerator for space applications. In research regarding gas-coupled regenerative refrigerator, the energy flow distribution between the two stages, and optimal phase difference between the pressure wave and volume flow, are two critical parameters that could widely influence refrigerator performance. The effects of displacer displacement on the pressure wave, phase difference, acoustic power distribution, and inter-stage cooling capacity shift of the SPR have been investigated experimentally. Notably, to obtain the maximum first-stage cooling capacity, an inflection point in displacement exists. When the displacer displacement is larger than the inflection point, the cooling capacity could be distributed between the first and second stages. In the present study, an SPR was designed and manufactured to work between the liquid hydrogen and liquid oxygen temperatures, which can be used to cool small-scale zero boil-off systems and space detectors. Under appropriate displacer displacement, the SPR can reach a no-load cooling temperature of 15.4 K and obtain 2.6 W cooling capacity at 70 K plus 0.1 W cooling capacity at 20 K with 160 W compressor input electric power.

关键词： Stirling/pulse tube refrigerator     displacer displacement     space application     phase shift     energy distribution    

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Studies on the liquid-liquid interfacial mass transfer process using holographic interferometry

ZHAO Chaofan, ZHU Chunying, MA Youguang

《化学科学与工程前沿（英文）》 2008年 第2卷 第1期   页码 1-4 doi: 10.1007/s11705-008-0006-3

摘要： This paper aims at the interfacial phenomena of liquid-liquid mass transfer and its characteristic. By using the real-time holographic technique, the concentration distributions on the aqueous side were obtained according to holographic diagrams of mass transfer of ethanol through the interface of oil and water at different initial concentrations. Furthermore, the concentrations near the interface and the mass transfer coefficients were attained. A correlation of concentration near the interface to the concentration of the solute in the oil side was proposed. An approach of interfacial energy with solute concentration was established, and the calculated results are at good agreement with the experimental data. It is indicated that the liquid-liquid mass transfer process is approximately in accordance with two-film theory, the interfacial performance may be changed by the addition of the solute, and the interface of liquid-liquid is non-equilibrium thermodynamically during the mass transfer process.

关键词： liquid-liquid     different     real-time holographic     addition     transfer    

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Perspective on gallium-based room temperature liquid metal batteries

《能源前沿（英文）》 2022年 第16卷 第1期   页码 23-48 doi: 10.1007/s11708-022-0815-y

摘要： Recent years have witnessed a rapid development of deformable devices and epidermal electronics that are in urgent request for flexible batteries. The intrinsically soft and ductile conductive electrode materials can offer pivotal hints in extending the lifespan of devices under frequent deformation. Featuring inherent liquidity, metallicity, and biocompatibility, Ga-based room-temperature liquid metals (GBRTLMs) are potential candidates to fulfill the requirement of soft batteries. Herein, to illustrate the glamour of liquid components, high-temperature liquid metal batteries (HTLMBs) are briefly summarized from the aspects of principle, application, advantages, and drawbacks. Then, Ga-based liquid metals as main working electrodes in primary and secondary batteries are reviewed in terms of battery configurations, working mechanisms, and functions. Next, Ga-based liquid metals as auxiliary working electrodes in lithium and nonlithium batteries are also discussed, which work as functional self-healing additives to alleviate the degradation and enhance the durability and capacity of the battery system. After that, Ga-based liquid metals as interconnecting electrodes in multi-scenarios including photovoltaics solar cells, generators, and supercapacitors (SCs) are interpreted, respectively. The summary and perspective of Ga-based liquid metals as diverse battery materials are also focused on. Finally, it was suggested that tremendous endeavors are yet to be made in exploring the innovative battery chemistry, inherent reaction mechanism, and multifunctional integration of Ga-based liquid metal battery systems in the coming future.

关键词： liquid metals     soft electrodes     flexible batteries     deformable energy supply devices     epidermal electronics    

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Advances and perspectives in catalysts for liquid-phase oxidation of cyclohexane

Hui LI, Yuanbin SHE, Tao WANG

《化学科学与工程前沿（英文）》 2012年 第6卷 第3期   页码 356-368 doi: 10.1007/s11705-012-0903-3

摘要： The latest progress and developments in catalysts for the oxidation of cyclohexane are reviewed. Catalytic systems for the oxidation of cyclohexane including metal supported, metal oxides, molecular sieves, metal substituted polyoxometalates, photocatalysts, organocatalysts, Gif systems, metal-organic catalysts and metalloporphyrins are discussed with a particular emphasis on metalloporphyrin catalytic systems. The advantages and disadvantages of these methods are summarized and analyzed. Finally, the development trends in the oxidation technology of cyclohexane are examined.

关键词： cyclohexane     liquid-phase oxidation     catalysis    

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Residence time distribution and modeling of the liquid phase in an impinging stream reactor

Xingjun WANG, Xianhui HU, Lishun HU, Guangsuo YU, Fuchen WANG,

《化学科学与工程前沿（英文）》 2010年 第4卷 第3期   页码 353-359 doi: 10.1007/s11705-009-0262-x

摘要： Based on some experimental investigations of liquid phase residence time distribution (RTD) in an impinging stream reactor, a two-dimensional plug-flow dispersion model for predicting the liquid phase RTD in the reactor was proposed. The calculation results of the model can be in good agreement with the experimental RTD under different operating conditions. The axial liquid dispersion coefficient increases monotonously with the increasing liquid flux, but is almost independent of gas flux. As the liquid flux and the gas flux increase, the liquid dispersion coefficient of center-to-wall decreases. The axial liquid dispersion coefficient is much larger than that of center-to-wall, which indicates that the liquid RTD is dominated mainly by axial liquid dispersion in the impinging stream reactor.

关键词： RTD     liquid dispersion     reactor     liquid     independent    

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Review of the direct thermochemical conversion of lignocellulosic biomass for liquid fuels

Jianchun JIANG,Junming XU,Zhanqian SONG

《农业科学与工程前沿（英文）》 2015年 第2卷 第1期   页码 13-27 doi: 10.15302/J-FASE-2015050

摘要： Increased demand for liquid transportation fuels, environmental concerns and depletion of petroleum resources requires the development of efficient conversion technologies for production of second-generation biofuels from non-food resources. Thermochemical approaches hold great potential for conversion of lignocellulosic biomass into liquid fuels. Direct thermochemical processes convert biomass into liquid fuels in one step using heat and catalysts and have many advantages over indirect and biological processes, such as greater feedstock flexibility, integrated conversion of whole biomass, and lower operation costs. Several direct thermochemical processes are employed in the production of liquid biofuels depending on the nature of the feedstock properties: such as fast pyrolysis/liquefaction of lignocellulosic biomass for bio-oil, including upgrading methods, such as catalytic cracking and hydrogenation. Owing to the substantial amount of liquid fuels consumed by vehicular transport, converting biomass into drop-in liquid fuels may reduce the dependence of the fuel market on petroleum-based fuel products. In this review, we also summarize recent progress in technologies for large-scale equipment for direct thermochemical conversion. We focus on the technical aspects critical to commercialization of the technologies for production of liquid fuels from biomass, including feedstock type, cracking catalysts, catalytic cracking mechanisms, catalytic reactors, and biofuel properties. We also discuss future prospects for direct thermochemical conversion in biorefineries for the production of high grade biofuels.

关键词： lignocellulosic biomass     thermochemical     liquid fuels     upgrading     biofuels    

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Emerging roles of liquid metals in carbon neutrality

《能源前沿（英文）》 2022年 第16卷 第3期   页码 393-396 doi: 10.1007/s11708-022-0829-5

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Trace analysis of off-flavor/odor compounds in water using liquid-liquid microextraction coupled with

Jian LU,Paul S. WILLS,P. CHRIS WILSON

《环境科学与工程前沿（英文）》 2016年 第10卷 第3期   页码 477-481 doi: 10.1007/s11783-015-0820-z

摘要： A rapid, inexpensive and laboratory friendly method was developed for analysis of off-flavor/odor compounds in fresh and salt water using gas chromatography with chemical ionization-tandem mass spectrometry. Off-flavor/odor compounds included geosmin, 2-methylisoborneol (MIB), 2-isobutyl-3-methyoxypyrazine (IBMP), and 2-isopropyl-3-methoxypyrazine (IPMP). Using this method, a single sample can be extracted within minutes using only 1 mL of organic solvent. The ion transitions for IPMP, IBMP, MIB, and geosmin were 153>121, 167>125, 152>95, and 165>109, respectively. The linearity of this method for analyzing MIB ranged from 4 to 200 ng·L , and from 0.8 to 200 ng·L for the other analytes. Method recoveries ranged from 97% to 111% and percent relative standard deviations ranged from 3% to 9%, indicating that the method is accurate, precise, and reliable.

关键词： off-flavor/odor compounds     liquid-liquid microextraction     gas chromatography-tandem mass spectrometry    

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A multiscale material model for heterogeneous liquid droplets in solid soft composites

《结构与土木工程前沿（英文）》 2021年 第15卷 第5期   页码 1292-1299 doi: 10.1007/s11709-021-0771-3

摘要： Liquid droplets in solid soft composites have been attracting increasing attention in biological applications. In contrary with conventional composites, which are made of solid elastic inclusions, available material models for composites including liquid droplets are for highly idealized configurations and do not include all material real parameters. They are also all deterministic and do not address the uncertainties arising from droplet radius, volume fraction, dispersion and agglomeration. This research revisits the available models for liquid droplets in solid soft composites and presents a multiscale computational material model to determine their elastic moduli, considering nearly all relevant uncertainties and heterogeneities at different length scales. The effects of surface tension at droplets interface, their volume fraction, size, size polydispersity and agglomeration on elastic modulus, are considered. Different micromechanical material models are incorporated into the presented computational framework. The results clearly indicate both softening and stiffening effects of liquid droplets and show that the model can precisely predict the effective properties of liquid droplets in solid soft composites.

关键词： liquid in solid     soft composite     computational modeling     multiscale model     heterogeneity    

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标题 作者 时间 类型 操作

Lifecycle carbon footprint and cost assessment for coal-to-liquid coupled with carbon capture, storage

期刊论文

NICE’s Indirect Coal-to-Liquid Process for Producing Clean Transportation Fuels Using Fischer-Tropsch

Omar M. Basha,Li Weng,Zhuo-wu Men,Wayne Xu,Badie I. Morsi

期刊论文

新型煤化工的生命周期碳排放趋势分析

武娟妮,张岳玲,田亚峻,谢克昌

期刊论文

Chemical probe systems for assessing liquid–liquid mixing efficiencies of reactors

期刊论文

Microfluidic production of liposomes through liquid–liquid phase separation in ternary droplets

期刊论文

Energy distribution between liquid hydrogen and liquid oxygen temperatures in a Stirling/pulse tube refrigerator

期刊论文

Studies on the liquid-liquid interfacial mass transfer process using holographic interferometry

ZHAO Chaofan, ZHU Chunying, MA Youguang

期刊论文

Innovative approach of low carbon and efficient utilization of coal resources: The polygeneration systemof a combination of the gasified coal gas and the pyrolyzed coal gas to form the synthetic gas

Kechang XIE, Fan LI

期刊论文

Perspective on gallium-based room temperature liquid metal batteries

期刊论文

Advances and perspectives in catalysts for liquid-phase oxidation of cyclohexane

Hui LI, Yuanbin SHE, Tao WANG

期刊论文

Residence time distribution and modeling of the liquid phase in an impinging stream reactor

Xingjun WANG, Xianhui HU, Lishun HU, Guangsuo YU, Fuchen WANG,

期刊论文

Review of the direct thermochemical conversion of lignocellulosic biomass for liquid fuels

Jianchun JIANG,Junming XU,Zhanqian SONG

期刊论文

Emerging roles of liquid metals in carbon neutrality

期刊论文

Trace analysis of off-flavor/odor compounds in water using liquid-liquid microextraction coupled with

Jian LU,Paul S. WILLS,P. CHRIS WILSON

期刊论文

A multiscale material model for heterogeneous liquid droplets in solid soft composites

期刊论文