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Erosion-corrosion failure of REAC pipes under multiphase flow

Ping TANG, Jian YANG, Jinyang ZHENG, Shizheng HE, Jianjun YE, Guofu OU, Ieong WONG, Yanbao MA,

《能源前沿(英文)》 2009年 第3卷 第4期   页码 389-395 doi: 10.1007/s11708-009-0045-6

摘要: By using computational fluid dynamics (CFD) modeling and simulation, a predictive method was proposed to explore the erosion failure of reactor effluent air cooler (REAC) pipes with liner under multiphase flow. A theoretical model based on the erosion-corrosion effects of REAC on mixture turbulent flow was proposed for multiphase flow. Effects of various working conditions, liner shapes, and structures, as well as flow parameters on numerical simulations were investigated. Besides, the pipe’s erosion-corrosion rules under multiphase flow and the relationship between multiphase flow and erosion-corrosion under dangerous working conditions were studied. By CFD numerical simulations, the exact position where some typical pipes thinned and failed rapidly by erosion was found and the main factors causing erosion-corrosion failure were discussed. Finally, numerical results obtained by using the proposed method were compared with experimental results.

关键词: multiphase flow     erosion-corrosion     pipes     reactor effluent air cooler (REAC)     computational fluid dynamics (CFD)    

Embankment dam foundation analysis for the decrease of internal erosion likelihood

Marc SMITH

《结构与土木工程前沿(英文)》 2012年 第6卷 第4期   页码 431-436 doi: 10.1007/s11709-012-0183-5

摘要: A zoned embankment dam is founded on clay underlain by a sand deposit. Major seepage phenomena were noticed in the foundation downstream from the dam where the vertical seepage forces in the sand layer were expected to exceed the downward forces due to the overlying clay. Modern technologies were applied to delineate critical zones to help design optimal rehabilitation measures. A global electromagnetic survey was carried out to detect and map the main sources, pathways and exits of seepage. Based on these global findings, a more detailed analysis was then conducted to identify zones where thickness of the foundation clay is minimal, pore pressures in sand are higher and thus where the factor of safety against uplift is lower and internal erosion is more likely to occur. Clay thickness evaluation required the determination of land surface as well as clay-sand contact elevations. A laser airborne survey was performed to model the land surface elevation. Data concerning the clay-sand contact elevation came from the interpreted stratigraphy based on a series of boreholes and cone penetration tests. This data was combined in a geostatistical model along with the measured piezometric levels in the foundation. This resulted in a contour map showing factors of safety against uplift over the entire downstream area. The use of modern technologies, namely electromagnetic and laser surveys as well as geostatistical tools, was instrumental in defining the limits of an otherwise spread-out problem and to provide an optimal solution, in terms of costs and effectiveness, for the long-term stabilization of the foundation.

关键词: seepage detection     geostatistical analysis     dam monitoring     internal erosion     LIDAR survey    

3D finite element method (FEM) simulation of groundwater flow during backward erosion piping

Kristine VANDENBOER,Vera van BEEK,Adam BEZUIJEN

《结构与土木工程前沿(英文)》 2014年 第8卷 第2期   页码 160-166 doi: 10.1007/s11709-014-0257-7

摘要: Backward erosion piping is an important failure mechanism for cohesive water retaining structures which are founded on a sandy aquifer. At present, the prediction models for safety assessment are often based on 2D assumptions. In this work, a 3D numerical approach of the groundwater flow leading to the erosion mechanism of backward erosion piping is presented and discussed. Comparison of the 2D and 3D numerical results explicitly demonstrates the inherent 3D nature of the piping phenomenon. In addition, the influence of the seepage length is investigated and discussed for both piping initiation and piping progression. The results clearly indicate the superiority of the presented 3D numerical model compared to the established 2D approach. Moreover, the 3D numerical results enable a better understanding of the complex physical mechanism involved in backward erosion piping and thus can lead to a significant improvement in the safety assessment of water retaining structures.

关键词: backward erosion piping     groundwater flow     3D finite element method (FEM)    

On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

《能源前沿(英文)》 2010年 第4卷 第2期   页码 181-184 doi: 10.1007/s11708-009-0065-2

摘要: A calcium chloride solution with a different extender, which is made up of either pure calcium chloride, calcium chloride with expanded graphite, or calcium chloride with activated carbon, acts differently on stainless steel. The mass ratio between calcium chloride with expanded graphite or activated carbon is almost 4∶1, which is demonstrated to be the optimum ratio. The experimental research in this paper reveals that, of the three solutions, which are pure calcium chloride, calcium chloride with expanded graphite, and calcium chloride with activated carbon, the strongest oxidation creation and pitting corrosion happened in the solution of calcium chloride with expanded graphite, the weakest oxidation creation happened in the solution of calcium chloride with activated carbon, and pitting corrosion was stronger than oxidation creation in the solution of pure calcium chloride. This paper gives the reasons for these phenomena. Furthermore, based on theory analysis, multiple means and approaches are provided to prevent stainless steel from further corroding.

关键词: stainless steel     corrosion     calcium chloride     expanded graphite     activated carbon     oxidation creation     pitting corrosion    

Monitoring corrosion of reinforcement in concrete structures via fiber Bragg grating sensors

Zhupeng ZHENG, Xiaoning SUN, Ying LEI

《机械工程前沿(英文)》 2009年 第4卷 第3期   页码 316-319 doi: 10.1007/s11465-009-0040-y

摘要: Corrosion of steel and rebar in concrete structures is one of the most frequent reasons for civil infrastructure failures. Thus, improving the effective corrosion sensor technology can greatly reduce cost and provide safe structures with long service lives. However, assessing the corrosion condition of rebars is not simple because they are buried in concrete. In this paper, using fiber Bragg grating (FBG), a corrosion sensor for monitoring steel rebars embedded in a concrete structure is developed and validated by experiments. Based on the fact that the volume and diameter of a rebar embedded in concrete will enlarge due to corrosion, an FBG packaged with fiber-reinforced plastics (FRP) is wrapped on the steel bar. During corrosion, the increase in the bar diameter leads to the increase in fiber strain, which can be measured by the shift of the wavelength of FBG. Performances of the corrosion sensor are validated by accelerating corrosion in lab experiments. The corrosion sensor is embedded in a concrete specimen put in a 5% sodium chloride solution with a constant current. Experimental results show that the corrosion sensor can monitor the concurrence of corrosion of rebars in concrete. The corrosion extent can be quantitatively evaluated through the change in the wavelength of FBG. Therefore, the corrosion sensor developed in this paper is feasible for monitoring the early corrosion of rebars in concrete.

关键词: fiber Bragg grating (FBG)     corrosion     concrete structures     accelerated corrosion test    

Corrosion mechanisms of candidate structural materials for supercritical water-cooled reactor

Lefu ZHANG, Fawen ZHU, Rui TANG

《能源前沿(英文)》 2009年 第3卷 第2期   页码 233-240 doi: 10.1007/s11708-009-0024-y

摘要: Nickel-based alloys, austenitic stainless steel, ferritic/martensitic heat-resistant steels, and oxide dispersion strengthened steel are presently considered to be the candidate structural or fuel-cladding materials for supercritical water-cooled reactor (SCWR), one of the promising generation IV reactor for large-scale electric power production. However, corrosion and stress corrosion cracking of these candidate alloys still remain to be a major problem in the selection of nuclear fuel cladding and other structural materials, such as water rod. Survey of literature and experimental results reveal that the general corrosion mechanism of those candidate materials exhibits quite complicated mechanism in high-temperature and high-pressure supercritical water. Formation of a stable protective oxide film is the key to the best corrosion-resistant alloys. This paper focuses on the mechanism of corrosion oxide film breakdown for SCWR candidate materials.

关键词: supercritical water-cooled reactor     general corrosion     oxide film     corrosion mechanism    

抗磨蚀材料失效过程的微观特性

王飚,王宇栋,张自华,何筱奎,诸小丽

《中国工程科学》 2001年 第3卷 第8期   页码 82-86

摘要:

用光学显微镜、扫描电镜、电子探针和X射线衍射,对抗汽蚀较优的硼不锈钢堆焊层和抗磨蚀较优的碳化钨陶瓷堆焊层的原样、汽蚀后样和磨蚀后样进行了微观分析研究。结果表明,硼不锈钢堆焊层是较好的抗汽蚀材料,但抗磨蚀效果不理想;碳化钨对磨蚀损坏有良好的屏障作用;磨蚀坑是气泡溃灭产生的脉冲式法向负压力和脉冲式泥沙冲击切向分力联合作用的结果。

关键词: 抗汽蚀     抗磨蚀     微观特性    

Effect of land use and land cover change on soil erosion and the spatio-temporal variation in Liupan

Bin QUAN, M. J. M. R?MKENS, Rui LI, Fang WANG, Jie CHEN

《环境科学与工程前沿(英文)》 2011年 第5卷 第4期   页码 564-572 doi: 10.1007/s11783-011-0348-9

摘要: The Liupan Mountains are located in the southern Ningxia Hui Autonomous Region of China, that forms an important divide between landforms and bio-geographic regions. The populated part of the Liupan Mountain Region has suffered tremendous ecological damage over time due to population pressure, excessive demand and inappropriate use of agricultural land resources. To present the relationship between land use/cover change and spatio-temporal variation of soil erosion, data sets of land use between the late 1980s and 2000 were obtained from Landsat Thematic Mapper (TM) imagery, and spatial models were used to characterize landscape and soil erosion conditions. Also, soil erosion in response to land use and land cover change were quantified and analyzed using data from geographical information systems and remote sensing. Soil erosion by water was the dominant mode of soil loss, while soil erosion by wind was only present on a relatively small area. The degree of soil erosion was classified into five severity classes: slight, light, moderate, severe, and very severe. Soil erosion in the Liupan Mountain Region increased between the late 1980s and 2000, both in terms of acreage and severity. Moderate, severe, and very severe eroded areas accounted for 54.86% of the total land area. The lightly eroded area decreased, while the moderately eroded area increased by 368817 ha (22%) followed by severe erosion with 146552 ha (8.8%), and very severe erosion by 97067.6 ha (5.8%). Soil loss on sloping cropland increased with slope gradients. About 90% of the cropland was located on slopes less than 15°. Most of the increase in soil erosion on cropland was due to conversion of steep slopes to cropland and degradation of grassland and increased activities. Soil erosion was severe on grassland with a moderate or low grass cover and on dry land. Human activities, cultivation on steep slopes, and overgrazing of pastures were the main reasons for the increase in erosion severity.

关键词: land use/land cover change     soil erosion     geographical information system     remote sensing     Liupan Mountain Region    

Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated

Wenjin Ding, Alexander Bonk, Thomas Bauer

《化学科学与工程前沿(英文)》 2018年 第12卷 第3期   页码 564-576 doi: 10.1007/s11705-018-1720-0

摘要:

Recently, more and more attention is paid on applications of molten chlorides in concentrated solar power (CSP) plants as high-temperature thermal energy storage (TES) and heat transfer fluid (HTF) materials due to their high thermal stability limits and low prices, compared to the commercial TES/HTF materials in CSP-nitrate salt mixtures. A higher TES/HTF operating temperature leads to higher efficiency of thermal to electrical energy conversion of the power block in CSP, however causes additional challenges, particularly increased corrosiveness of metallic alloys used as containers and structural materials. Thus, it is essential to study corrosion behaviors and mechanisms of metallic alloys in molten chlorides at operating temperatures (500–800 °C) for realizing the commercial application of molten chlorides in CSP. The results of studies on hot corrosion of metallic alloys in molten chlorides are reviewed to understand their corrosion behaviors and mechanisms under various conditions (e.g., temperature, atmosphere). Emphasis has also been given on salt purification to reduce corrosive impurities in molten chlorides and development of electrochemical techniques to in-situ monitor corrosive impurities in molten chlorides, in order to efficiently control corrosion rates of metallic alloys in molten chlorides to meet the requirements of industrial applications.

关键词: corrosion mechanisms     impurities     metallic corrosion     salt purification     electrochemical techniques    

Synergistic effects of sodium hypochlorite disinfection and iron-oxidizing bacteria on early corrosion

《环境科学与工程前沿(英文)》 2022年 第16卷 第6期 doi: 10.1007/s11783-021-1506-3

摘要:

• The early corrosion process in the cast iron pipes was investigated.

关键词: Cast iron pipe corrosion     Drinking water distribution systems     Chlorine disinfection     Iron-oxidizing bacteria     Coupling effects    

我国腐蚀管理体系研究

马秀敏,朱桂雨,路东柱,段继周,侯保荣

《中国工程科学》 2022年 第24卷 第1期   页码 190-197 doi: 10.15302/J-SSCAE-2022.01.020

摘要:

腐蚀管理关乎安全生产,关乎国民经济,关乎生态文明,关乎资源节约和国家建设。虽然少数行业在腐蚀管理方面已经进行了一些卓有成效的探索和实践,但是总体上腐蚀管理在我国发展十分不平衡,存在着腐蚀管理意识薄弱、专业人才短缺和管理系统不健全等问题。因此,有必要进一步明确腐蚀管理的内涵,明确我国腐蚀管理体系化发展的基本要求,推动腐蚀管理体系化持续健康发展。本文基于中国工程院重点咨询项目“我国腐蚀管理状况与对策战略研究”主要研究成果,阐述了腐蚀管理的内涵及体系化发展的重要意义,分析了我国腐蚀管理的现状及问题,总结提出了腐蚀管理体系基本框架及管理要点,提出了将腐蚀管理纳入国家安全战略,成立腐蚀管理战略研究常设机构;加强腐蚀学科建设,强化人才战略;建立健全腐蚀防护相关法规标准,强化标准意识;加强腐蚀数据库建设,畅通沟通渠道;搭建腐蚀管理信息及大数据交流平台,打造共享管理新模式等对策建议。

关键词: 腐蚀管理,腐蚀管理体系,腐蚀防护,腐蚀控制,腐蚀安全    

Synthesis of mono and bis-4-methylpiperidiniummethyl-urea as corrosion inhibitors for steel in acidic

Abbas TEIMOURI, Nasrin SOLTANI, Alireza Najafi CHERMAHINI

《化学科学与工程前沿(英文)》 2011年 第5卷 第1期   页码 43-50 doi: 10.1007/s11705-010-0532-7

摘要: Mono and bis-4-methylpiperidiniummethyl urea were synthesized, characterized and used as new corrosion inhibitors of mild steel in the acidic media. Inhibitory effect of two compounds on mild steel surface in the 1 mol·L sulphuric acid has been studied by a series of techniques, such as potentiodynamic polarization, weight loss and quantum chemical calculation methods. Potentiodynamic polarization measurements showed that two inhibitors are mixed type. All measurements showed that inhibition efficiencies enhanced with increase of inhibitor concentration. This reveals that inhibitive actions of inhibitors were mainly due to adsorption on mild steel surface. Density functional (DFT) calculations have been carried out for the title compounds by performing HF and DFT levels of theory using the standard 6-31G* basis set.

关键词: corrosion inhibitors     mild steel     acidic medium     theoretical studies     DFT    

水轮机抗磨蚀金属材料的优化设计

王飚,张自华,王宇栋

《中国工程科学》 2000年 第2卷 第2期   页码 64-67

摘要:

对抗磨蚀金属材料的基础研究表明,在10种常用结构材料的金属中,以钨、钴、铬的抗气蚀性最佳;生产应用研究结果表明,钨系材料中的火焰喷焊WC-M硬面陶瓷材料,铬系材料中的电镀稀土铬硬面材料,钴系材料中的等离子喷焊CoCrWC硬面材料,都是抗磨蚀性能较优,成本较低,并可进入工业应用的水轮机抗磨蚀结构材料。

关键词: 水轮机     磨蚀材料     设计    

Corrosion behavior of Fe–Cr–Ni based alloys exposed to molten MgCl2–KCl–NaCl salt with over-addedMg corrosion inhibitor

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1608-1619 doi: 10.1007/s11705-023-2349-1

摘要: MgCl2–NaCl–KCl salts mixture shows great potential as a high-temperature (> 700 °C) thermal energy storage material in next-generation concentrated solar power plants. Adding Mg into molten MgCl2–NaCl–KCl salt as a corrosion inhibitor is one of the most effective and cost-effective methods to mitigate the molten salt corrosion of commercial Fe–Cr–Ni alloys. However, it is found in this work that both stainless steel 310 and Incoloy 800H samples were severely corroded after 500 h immersion test at 700 °C when the alloy samples directly contacted with the over-added Mg in the liquid form. The corrosion attack is different from the classical impurity-driven corrosion in molten chloride salts found in previous work. Microscopic analysis indicates that Ni preferentially leaches out of alloy matrix due to the tendency to form MgNi2/Mg2Ni compounds. The Ni-depletion leads to the formation of a porous corrosion layer on both alloys, with the thickness around 204 µm (stainless steel 310) and 1300 µm (Incoloy 800H), respectively. These results suggest that direct contact of liquid Mg with Ni-containing alloys should be avoided during using Mg as a corrosion inhibitor for MgCl2–NaCl–KCl or other chlorides for high temperature heat storage and transfer.

关键词: concentrated solar power (CSP)     Mg corrosion inhibitor     Mg–Ni intermetallic     salt purification     thermal energy storage (TES)    

水机材料的抗磨蚀性判据研究

王飚,王宇栋,张自华,叶献国

《中国工程科学》 2003年 第5卷 第7期   页码 58-61

摘要:

为了证实水机材料的抗磨蚀和抗空蚀性能与材料的常规宏观性能之间的相依关系,选取4种具代表性的材料(碳化钨涂层、NiCr合金涂层、硼不锈钢涂层和钛),进行空蚀和磨蚀试验,并测试了它们的硬度和抗腐蚀性。试验结果表明,材料的空蚀和磨蚀抗力与硬度和抗腐蚀性有着紧密的相依关系:高硬度是抗磨蚀性优的第一判据,较强的抗腐蚀性是第二判据;高抗腐蚀性是抗空蚀性优的第一判据,较高的硬度是第二判据。

关键词: 水机材料     磨蚀     判据    

标题 作者 时间 类型 操作

Erosion-corrosion failure of REAC pipes under multiphase flow

Ping TANG, Jian YANG, Jinyang ZHENG, Shizheng HE, Jianjun YE, Guofu OU, Ieong WONG, Yanbao MA,

期刊论文

Embankment dam foundation analysis for the decrease of internal erosion likelihood

Marc SMITH

期刊论文

3D finite element method (FEM) simulation of groundwater flow during backward erosion piping

Kristine VANDENBOER,Vera van BEEK,Adam BEZUIJEN

期刊论文

On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

期刊论文

Monitoring corrosion of reinforcement in concrete structures via fiber Bragg grating sensors

Zhupeng ZHENG, Xiaoning SUN, Ying LEI

期刊论文

Corrosion mechanisms of candidate structural materials for supercritical water-cooled reactor

Lefu ZHANG, Fawen ZHU, Rui TANG

期刊论文

抗磨蚀材料失效过程的微观特性

王飚,王宇栋,张自华,何筱奎,诸小丽

期刊论文

Effect of land use and land cover change on soil erosion and the spatio-temporal variation in Liupan

Bin QUAN, M. J. M. R?MKENS, Rui LI, Fang WANG, Jie CHEN

期刊论文

Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated

Wenjin Ding, Alexander Bonk, Thomas Bauer

期刊论文

Synergistic effects of sodium hypochlorite disinfection and iron-oxidizing bacteria on early corrosion

期刊论文

我国腐蚀管理体系研究

马秀敏,朱桂雨,路东柱,段继周,侯保荣

期刊论文

Synthesis of mono and bis-4-methylpiperidiniummethyl-urea as corrosion inhibitors for steel in acidic

Abbas TEIMOURI, Nasrin SOLTANI, Alireza Najafi CHERMAHINI

期刊论文

水轮机抗磨蚀金属材料的优化设计

王飚,张自华,王宇栋

期刊论文

Corrosion behavior of Fe–Cr–Ni based alloys exposed to molten MgCl2–KCl–NaCl salt with over-addedMg corrosion inhibitor

期刊论文

水机材料的抗磨蚀性判据研究

王飚,王宇栋,张自华,叶献国

期刊论文