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腐蚀 3

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On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

《能源前沿（英文）》 2010年 第4卷 第2期   页码 181-184 doi: 10.1007/s11708-009-0065-2

摘要： A calcium chloride solution with a different extender, which is made up of either pure calcium chloride, calcium chloride with expanded graphite, or calcium chloride with activated carbon, acts differently on stainless steel. The mass ratio between calcium chloride with expanded graphite or activated carbon is almost 4∶1, which is demonstrated to be the optimum ratio. The experimental research in this paper reveals that, of the three solutions, which are pure calcium chloride, calcium chloride with expanded graphite, and calcium chloride with activated carbon, the strongest oxidation creation and pitting corrosion happened in the solution of calcium chloride with expanded graphite, the weakest oxidation creation happened in the solution of calcium chloride with activated carbon, and pitting corrosion was stronger than oxidation creation in the solution of pure calcium chloride. This paper gives the reasons for these phenomena. Furthermore, based on theory analysis, multiple means and approaches are provided to prevent stainless steel from further corroding.

关键词： stainless steel     corrosion     calcium chloride     expanded graphite     activated carbon     oxidation creation     pitting corrosion    

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Monitoring corrosion of reinforcement in concrete structures via fiber Bragg grating sensors

Zhupeng ZHENG, Xiaoning SUN, Ying LEI

《机械工程前沿（英文）》 2009年 第4卷 第3期   页码 316-319 doi: 10.1007/s11465-009-0040-y

摘要： Corrosion of steel and rebar in concrete structures is one of the most frequent reasons for civil infrastructure failures. Thus, improving the effective corrosion sensor technology can greatly reduce cost and provide safe structures with long service lives. However, assessing the corrosion condition of rebars is not simple because they are buried in concrete. In this paper, using fiber Bragg grating (FBG), a corrosion sensor for monitoring steel rebars embedded in a concrete structure is developed and validated by experiments. Based on the fact that the volume and diameter of a rebar embedded in concrete will enlarge due to corrosion, an FBG packaged with fiber-reinforced plastics (FRP) is wrapped on the steel bar. During corrosion, the increase in the bar diameter leads to the increase in fiber strain, which can be measured by the shift of the wavelength of FBG. Performances of the corrosion sensor are validated by accelerating corrosion in lab experiments. The corrosion sensor is embedded in a concrete specimen put in a 5% sodium chloride solution with a constant current. Experimental results show that the corrosion sensor can monitor the concurrence of corrosion of rebars in concrete. The corrosion extent can be quantitatively evaluated through the change in the wavelength of FBG. Therefore, the corrosion sensor developed in this paper is feasible for monitoring the early corrosion of rebars in concrete.

关键词： fiber Bragg grating (FBG)     corrosion     concrete structures     accelerated corrosion test    

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Corrosion mechanisms of candidate structural materials for supercritical water-cooled reactor

Lefu ZHANG, Fawen ZHU, Rui TANG

《能源前沿（英文）》 2009年 第3卷 第2期   页码 233-240 doi: 10.1007/s11708-009-0024-y

摘要： Nickel-based alloys, austenitic stainless steel, ferritic/martensitic heat-resistant steels, and oxide dispersion strengthened steel are presently considered to be the candidate structural or fuel-cladding materials for supercritical water-cooled reactor (SCWR), one of the promising generation IV reactor for large-scale electric power production. However, corrosion and stress corrosion cracking of these candidate alloys still remain to be a major problem in the selection of nuclear fuel cladding and other structural materials, such as water rod. Survey of literature and experimental results reveal that the general corrosion mechanism of those candidate materials exhibits quite complicated mechanism in high-temperature and high-pressure supercritical water. Formation of a stable protective oxide film is the key to the best corrosion-resistant alloys. This paper focuses on the mechanism of corrosion oxide film breakdown for SCWR candidate materials.

关键词： supercritical water-cooled reactor     general corrosion     oxide film     corrosion mechanism    

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Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated

Wenjin Ding, Alexander Bonk, Thomas Bauer

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 564-576 doi: 10.1007/s11705-018-1720-0

摘要：

Recently, more and more attention is paid on applications of molten chlorides in concentrated solar power (CSP) plants as high-temperature thermal energy storage (TES) and heat transfer fluid (HTF) materials due to their high thermal stability limits and low prices, compared to the commercial TES/HTF materials in CSP-nitrate salt mixtures. A higher TES/HTF operating temperature leads to higher efficiency of thermal to electrical energy conversion of the power block in CSP, however causes additional challenges, particularly increased corrosiveness of metallic alloys used as containers and structural materials. Thus, it is essential to study corrosion behaviors and mechanisms of metallic alloys in molten chlorides at operating temperatures (500–800 °C) for realizing the commercial application of molten chlorides in CSP. The results of studies on hot corrosion of metallic alloys in molten chlorides are reviewed to understand their corrosion behaviors and mechanisms under various conditions (e.g., temperature, atmosphere). Emphasis has also been given on salt purification to reduce corrosive impurities in molten chlorides and development of electrochemical techniques to in-situ monitor corrosive impurities in molten chlorides, in order to efficiently control corrosion rates of metallic alloys in molten chlorides to meet the requirements of industrial applications.

关键词： corrosion mechanisms     impurities     metallic corrosion     salt purification     electrochemical techniques    

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Synergistic effects of sodium hypochlorite disinfection and iron-oxidizing bacteria on early corrosion

《环境科学与工程前沿（英文）》 2022年 第16卷 第6期 doi: 10.1007/s11783-021-1506-3

摘要：

• The early corrosion process in the cast iron pipes was investigated.

关键词： Cast iron pipe corrosion     Drinking water distribution systems     Chlorine disinfection     Iron-oxidizing bacteria     Coupling effects    

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我国腐蚀管理体系研究

马秀敏,朱桂雨,路东柱,段继周,侯保荣

《中国工程科学》 2022年 第24卷 第1期   页码 190-197 doi: 10.15302/J-SSCAE-2022.01.020

摘要：

腐蚀管理关乎安全生产，关乎国民经济，关乎生态文明，关乎资源节约和国家建设。虽然少数行业在腐蚀管理方面已经进行了一些卓有成效的探索和实践，但是总体上腐蚀管理在我国发展十分不平衡，存在着腐蚀管理意识薄弱、专业人才短缺和管理系统不健全等问题。因此，有必要进一步明确腐蚀管理的内涵，明确我国腐蚀管理体系化发展的基本要求，推动腐蚀管理体系化持续健康发展。本文基于中国工程院重点咨询项目“我国腐蚀管理状况与对策战略研究”主要研究成果，阐述了腐蚀管理的内涵及体系化发展的重要意义，分析了我国腐蚀管理的现状及问题，总结提出了腐蚀管理体系基本框架及管理要点，提出了将腐蚀管理纳入国家安全战略，成立腐蚀管理战略研究常设机构；加强腐蚀学科建设，强化人才战略；建立健全腐蚀防护相关法规标准，强化标准意识；加强腐蚀数据库建设，畅通沟通渠道；搭建腐蚀管理信息及大数据交流平台，打造共享管理新模式等对策建议。

关键词： 腐蚀管理，腐蚀管理体系，腐蚀防护，腐蚀控制，腐蚀安全    

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Synthesis of mono and bis-4-methylpiperidiniummethyl-urea as corrosion inhibitors for steel in acidic

Abbas TEIMOURI, Nasrin SOLTANI, Alireza Najafi CHERMAHINI

《化学科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 43-50 doi: 10.1007/s11705-010-0532-7

摘要： Mono and bis-4-methylpiperidiniummethyl urea were synthesized, characterized and used as new corrosion inhibitors of mild steel in the acidic media. Inhibitory effect of two compounds on mild steel surface in the 1 mol·L sulphuric acid has been studied by a series of techniques, such as potentiodynamic polarization, weight loss and quantum chemical calculation methods. Potentiodynamic polarization measurements showed that two inhibitors are mixed type. All measurements showed that inhibition efficiencies enhanced with increase of inhibitor concentration. This reveals that inhibitive actions of inhibitors were mainly due to adsorption on mild steel surface. Density functional (DFT) calculations have been carried out for the title compounds by performing HF and DFT levels of theory using the standard 6-31G* basis set.

关键词： corrosion inhibitors     mild steel     acidic medium     theoretical studies     DFT    

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Corrosion behavior of Fe–Cr–Ni based alloys exposed to molten MgCl2–KCl–NaCl salt with over-addedMg corrosion inhibitor

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1608-1619 doi: 10.1007/s11705-023-2349-1

摘要： MgCl2–NaCl–KCl salts mixture shows great potential as a high-temperature (> 700 °C) thermal energy storage material in next-generation concentrated solar power plants. Adding Mg into molten MgCl2–NaCl–KCl salt as a corrosion inhibitor is one of the most effective and cost-effective methods to mitigate the molten salt corrosion of commercial Fe–Cr–Ni alloys. However, it is found in this work that both stainless steel 310 and Incoloy 800H samples were severely corroded after 500 h immersion test at 700 °C when the alloy samples directly contacted with the over-added Mg in the liquid form. The corrosion attack is different from the classical impurity-driven corrosion in molten chloride salts found in previous work. Microscopic analysis indicates that Ni preferentially leaches out of alloy matrix due to the tendency to form MgNi2/Mg2Ni compounds. The Ni-depletion leads to the formation of a porous corrosion layer on both alloys, with the thickness around 204 µm (stainless steel 310) and 1300 µm (Incoloy 800H), respectively. These results suggest that direct contact of liquid Mg with Ni-containing alloys should be avoided during using Mg as a corrosion inhibitor for MgCl2–NaCl–KCl or other chlorides for high temperature heat storage and transfer.

关键词： concentrated solar power (CSP)     Mg corrosion inhibitor     Mg–Ni intermetallic     salt purification     thermal energy storage (TES)    

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Corrosion damage assessment and monitoring of large steel space structures

Bo CHEN, You-Lin XU, Weilian QU,

《结构与土木工程前沿（英文）》 2010年 第4卷 第3期   页码 354-369 doi: 10.1007/s11709-010-0088-0

摘要： Large steel space structures, when exposed to a harsh corrosive environment, are inevitably subjected to atmospheric corrosion and stress corrosion cracking. This paper proposes a framework for assessing the corrosion damage of large steel space structures subjected to both stress corrosion cracking and atmospheric corrosion. The empirical model for estimating atmospheric corrosion based on measured information is briefly introduced. The proposed framework is applied to a real large steel space structure built in the southern coastal area in China to assess its corrosion damage and investigate the effects of atmospheric corrosion on stress corrosion cracking. Based on the results, the conceptual design of the corrosion monitoring system of large steel space structures is finally conducted as the first step for a real corrosion monitoring system.

关键词： large steel space structure     atmospheric corrosion     stress corrosion cracking     corrosion damage     damage assessment     monitoring system    

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Inverse Gaussian process-based corrosion growth modeling and its application in the reliability analysis

Hao QIN, Shenwei ZHANG, Wenxing ZHOU

《结构与土木工程前沿（英文）》 2013年 第7卷 第3期   页码 276-287 doi: 10.1007/s11709-013-0207-9

摘要： This paper describes an inverse Gaussian process-based model to characterize the growth of metal-loss corrosion defects on energy pipelines. The model parameters are evaluated using the Bayesian methodology by combining the inspection data obtained from multiple inspections with the prior distributions. The Markov Chain Monte Carlo (MCMC) simulation techniques are employed to numerically evaluate the posterior marginal distribution of each individual parameter. The measurement errors associated with the ILI tools are considered in the Bayesian inference. The application of the growth model is illustrated using an example involving real inspection data collected from an in-service pipeline in Alberta, Canada. The results indicate that the model in general can predict the growth of corrosion defects reasonably well. Parametric analyses associated with the growth model as well as reliability assessment of the pipeline based on the growth model are also included in the example. The proposed model can be used to facilitate the development and application of reliability-based pipeline corrosion management.

关键词： pipeline     metal-loss corrosion     inverse Gaussian process     measurement error     hierarchical Bayesian     Markov Chain Monte Carlo (MCMC)    

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现役飞机结构腐蚀疲劳及寿命研究

穆志韬,金平,段成美

《中国工程科学》 2000年 第2卷 第4期   页码 34-38

摘要：

文章分析研究了在环境腐蚀介质中飞机的疲劳损伤特性和基本破坏失效模式，阐述了现役军用飞机地面停放使用环境谱的编制以及在腐蚀环境条件下飞机腐蚀疲劳寿命的估算方法，并对未来几年我军飞机结构的腐蚀疲劳研究的发展提出了一些看法。

关键词： 腐蚀     飞机结构     腐蚀疲劳     疲劳寿命     腐蚀环境谱    

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Influence of steel corrosion on axial and eccentric compression behavior of coral aggregate concrete

《结构与土木工程前沿（英文）》 2021年 第15卷 第6期   页码 1415-1425 doi: 10.1007/s11709-021-0786-9

摘要： To study the behavior of coral aggregate concrete (CAC) column under axial and eccentric compression, the compression behavior of CAC column with different types of steel and initial eccentricity (ei) were tested, and the deformation behavior and ultimate bearing capacity (Nu) were studied. The results showed that as the ei increases, the Nu of CAC column decreases nonlinearly. Besides, the steel corrosion in CAC column is severe, which reduces the steel section and steel strength, and decreases the Nu of CAC column. The durability of CAC structures can be improved by using new organic coated steel. Considering the influence of steel corrosion and interfacial bond deterioration, the calculation models of Nu under axial and eccentric compression were presented.

关键词： coral aggregate concrete column     axial compression     eccentric compression     steel corrosion     calculation model    

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Chloride ingress and macro-cell corrosion of steel in concrete made with recycled brick aggregate

《结构与土木工程前沿（英文）》 2021年 第15卷 第6期   页码 1358-1371 doi: 10.1007/s11709-021-0769-x

摘要： An investigation on chloride ingress and macro-cell corrosion of steel bars in concrete made with recycled brick aggregate (RBA) was carried out. As control cases, virgin brick aggregate (BA) and stone aggregate (SA) were also investigated. Both cylindrical and cracked prism specimens were studied for 16 different cases. The prism specimens were made with a segmented steel bar providing electrical connection from outside of the specimens to measure macro-cell corrosion current continuously under seawater splash exposure for a period of 30 d using a data logger. Cylindrical specimens were submerged in 3% NaCl solution at a temperature of 40°C to investigate chloride ingress in concrete made with RBA, BA, and SA after 120 and 180 d. Half-cell potential, corrosion area, and depths of corrosion were also investigated. The chloride ingress as well as corrosion of steel bars in concrete made with the different types of aggregate is ordered as RBA > BA > SA.

关键词： brick aggregate     chloride ingress     macro-cell corrosion     recycled brick aggregate    

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Erosion-corrosion failure of REAC pipes under multiphase flow

Ping TANG, Jian YANG, Jinyang ZHENG, Shizheng HE, Jianjun YE, Guofu OU, Ieong WONG, Yanbao MA,

《能源前沿（英文）》 2009年 第3卷 第4期   页码 389-395 doi: 10.1007/s11708-009-0045-6

摘要： By using computational fluid dynamics (CFD) modeling and simulation, a predictive method was proposed to explore the erosion failure of reactor effluent air cooler (REAC) pipes with liner under multiphase flow. A theoretical model based on the erosion-corrosion effects of REAC on mixture turbulent flow was proposed for multiphase flow. Effects of various working conditions, liner shapes, and structures, as well as flow parameters on numerical simulations were investigated. Besides, the pipe’s erosion-corrosion rules under multiphase flow and the relationship between multiphase flow and erosion-corrosion under dangerous working conditions were studied. By CFD numerical simulations, the exact position where some typical pipes thinned and failed rapidly by erosion was found and the main factors causing erosion-corrosion failure were discussed. Finally, numerical results obtained by using the proposed method were compared with experimental results.

关键词： multiphase flow     erosion-corrosion     pipes     reactor effluent air cooler (REAC)     computational fluid dynamics (CFD)    

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The defect-length effect in corrosion detection with magnetic method for bridge cables

Qiwei ZHANG, Rongya XIN

《结构与土木工程前沿（英文）》 2018年 第12卷 第4期   页码 662-671 doi: 10.1007/s11709-018-0512-4

摘要：

Quantitative evaluation of the steel corrosion in cables is significant for the safe operation of cable-supported bridges. The magnetic flux (MF) examination shows great potential to detect the corrosion defect, or loss of metallic cross-sectional area (LMA). An LMA defect in steel cables can be measured accurately when it is longer than a certain length. However, for defects in early stage, where the length of corrosion area is short, the MF examination may produce unacceptable error. In this study, the effect of defect length on the MF examination for corrosion detection of bridge cables is investigated through theoretical analysis and model experiments. An original analytical model to quantify the influence of defect length is proposed based on the equivalent magnetic circuit method. Then, MF examination experiments are performed on a series of cable models with different defect lengths and locations to verify the analytical model. Further, parameter study is conducted based on the proposed analytical model to clarify the mechanism of the defect-length effect. The results show that the area loss caused by short corrosion damage will be underestimated if the defect-length effect is neglected, and this effect can be quantified efficiently with the proposed analytical model.

关键词： bridge cable     corrosion detection     defect length     MF examination     quantitative evaluation    

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标题 作者 时间 类型 操作

On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

期刊论文

Monitoring corrosion of reinforcement in concrete structures via fiber Bragg grating sensors

Zhupeng ZHENG, Xiaoning SUN, Ying LEI

期刊论文

Corrosion mechanisms of candidate structural materials for supercritical water-cooled reactor

Lefu ZHANG, Fawen ZHU, Rui TANG

期刊论文

Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated

Wenjin Ding, Alexander Bonk, Thomas Bauer

期刊论文

Synergistic effects of sodium hypochlorite disinfection and iron-oxidizing bacteria on early corrosion

期刊论文

我国腐蚀管理体系研究

马秀敏,朱桂雨,路东柱,段继周,侯保荣

期刊论文

Synthesis of mono and bis-4-methylpiperidiniummethyl-urea as corrosion inhibitors for steel in acidic

Abbas TEIMOURI, Nasrin SOLTANI, Alireza Najafi CHERMAHINI

期刊论文

Corrosion behavior of Fe–Cr–Ni based alloys exposed to molten MgCl2–KCl–NaCl salt with over-addedMg corrosion inhibitor

期刊论文

Corrosion damage assessment and monitoring of large steel space structures

Bo CHEN, You-Lin XU, Weilian QU,

期刊论文

Inverse Gaussian process-based corrosion growth modeling and its application in the reliability analysis

Hao QIN, Shenwei ZHANG, Wenxing ZHOU

期刊论文

现役飞机结构腐蚀疲劳及寿命研究

穆志韬,金平,段成美

期刊论文

Influence of steel corrosion on axial and eccentric compression behavior of coral aggregate concrete

期刊论文

Chloride ingress and macro-cell corrosion of steel in concrete made with recycled brick aggregate

期刊论文

Erosion-corrosion failure of REAC pipes under multiphase flow

Ping TANG, Jian YANG, Jinyang ZHENG, Shizheng HE, Jianjun YE, Guofu OU, Ieong WONG, Yanbao MA,

期刊论文

The defect-length effect in corrosion detection with magnetic method for bridge cables

Qiwei ZHANG, Rongya XIN

期刊论文