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期刊论文 9

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催化剂活化 1

原位谱学 1

甲烷化 1

结晶性 1

镍-氧化铈催化剂 1

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Enhanced methanation stability of nano-sized MoS

Zhenhua LI, Jia HE, Haiyang WANG, Baowei WANG, Xinbin MA

《化学科学与工程前沿（英文）》 2015年 第9卷 第1期   页码 33-39 doi: 10.1007/s11705-014-1446-6

摘要： A series of unsupported MoS catalysts with or without Al O modification was prepared using a modified thermal decomposition approach. The catalysts were tested for the methanation of carbon monoxide and the optimum one has 25.6 wt-% Al O content. The catalysts were characterized by nitrogen adsorption measurement, X-ray diffraction and transmission electron microscopy. The results show that adding appropriate amount of Al O increases the dispersion of MoS , and the increased interaction force between MoS and Al O can inhibit the sintering of active MoS to some extent.

关键词： unsupported catalyst     molybdenum sulfide     stability     alumina     methanation    

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CO2 methanation and co-methanation of CO and CO2 over Mn-promoted Ni/Al2

Kechao Zhao,Zhenhua Li,Li Bian

《化学科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 273-280 doi: 10.1007/s11705-016-1563-5

摘要： A series of Mn-promoted 15 wt-% Ni/Al O catalysts were prepared by an incipient wetness impregnation method. The effect of the Mn content on the activity of the Ni/Al O catalysts for CO methanation and the co-methanation of CO and CO in a fixed-bed reactor was investigated. The catalysts were characterized by N physisorption, hydrogen temperature-programmed reduction and desorption, carbon dioxide temperature-programmed desorption, X-ray diffraction and high-resolution transmission electron microscopy. The presence of Mn increased the number of CO adsorption sites and inhibited Ni particle agglomeration due to improved Ni dispersion and weakened interactions between the nickel species and the support. The Mn-promoted 15 wt-% Ni/Al O catalysts had improved CO methanation activity especially at low temperatures (250 to 400 °C). The Mn content was varied from 0.86% to 2.54% and the best CO conversion was achieved with the 1.71Mn-Ni/Al O catalyst. The co-methanation tests on the 1.71Mn-Ni/Al O catalyst indicated that adding Mn markedly enhanced the CO methanation activity especially at low temperatures but it had little influence on the CO methanation performance. CO methanation was more sensitive to the reaction temperature and the space velocity than the CO methanation in the co-methanation process.

关键词： Mn promotion     nickel catalysts     CO2 methanation     co-methanation of CO and CO2    

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Methanation of carbon dioxide: an overview

Wei WANG, Jinlong GONG

《化学科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 2-10 doi: 10.1007/s11705-010-0528-3

摘要： Although being very challenging, utilization of carbon dioxide (CO ) originating from production processes and flue gases of CO -intensive sectors has a great environmental and industrial potential due to improving the resource efficiency of industry as well as by contributing to the reduction of CO emissions. As a renewable and environmentally friendly source of carbon, catalytic approaches for CO fixation in the synthesis of chemicals offer the way to mitigate the increasing CO buildup. Among the catalytic reactions, methanation of CO is a particularly promising technique for producing energy carrier or chemical. This article focuses on recent developments in catalytic materials, novel reactors, and reaction mechanism for methanation of CO .

关键词： CO2 methanation     hydrogenation     catalysis     methane     environmental science    

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Effect of a promoter on the methanation activity of a Mo-based sulfur-resistant catalyst

Can LIN, Haiyang WANG, Zhenhua LI, Baowei WANG, Xinbin MA, Shaodong QIN, Qi SUN

《化学科学与工程前沿（英文）》 2013年 第7卷 第1期   页码 88-94 doi: 10.1007/s11705-013-1301-1

摘要： The effect of adding Co, Ni or La on the methanation activity of a Mo-based sulfur-resistant catalyst was investigated. As promoters, Co, Ni and La all improved the methanation activity of a 15% MoO /Al O catalyst but to different extents. Similar improvements were also found when Co, Ni or La was added to a 15% MoO /25%-CeO -Al O catalyst. The promotion effects of Co and Ni were better than that of La. However, the catalytic methanation activity deteriorated the most with time for the Ni-promoted catalyst. The used catalysts were analyzed by nitrogen adsorption measurement, X-ray diffraction and X-ray photoelectron spectroscopy.

关键词： sulfur-resistant     methanation     promoter    

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Bimetallic Ni-Fe catalysts derived from layered double hydroxides for CO methanation from syngas

Honggui Tang, Shuangshuang Li, Dandan Gong, Yi Guan, Yuan Liu

《化学科学与工程前沿（英文）》 2017年 第11卷 第4期   页码 613-623 doi: 10.1007/s11705-017-1664-9

摘要： Carbon deposition and sintering of active components such as nano particles are great challenges for Ni-based catalysts for CO methanation to generate synthetic natural gas from syngas. Facing the challenges, bimetallic catalysts with different Fe content derived from layered double hydroxide containing Ni, Fe, Mg, Al elements were prepared by co-precipitation method. Nanoparticles of Ni-Fe alloy were supported on mixed oxides of aluminium and magnesium after calcination and reduction. The catalysts were characterized by Brunner-Emmett-Teller (BET), X-ray diffraction, hydrogen temperature programmed reduction, inductively coupled plasma, X-ray photoelectron spectroscopy, transmission electron microscopy and thermogravimetric techniques, and their catalytic activity for CO methanation was investigated. The results show that the Ni-Fe alloy catalysts exhibit better catalytic performance than monometallic catalysts except for the Ni4Fe-red catalyst. The Ni2Fe-red catalyst shows the highest CO conversion (100% at 260–350 °C), as well as the highest CH selectivity (over 95% at 280–350 °C), owing to the formation of Ni-Fe alloy. In stability test, the Ni2Fe-red catalyst exhibits great improvement in both anti-sintering and resistance to carbon formation compared with the Ni0Fe-red catalyst. The strong interaction between Ni and Fe element in alloy and surface distribution of Fe element not only inhibits the sintering of nanoparticles but restrains the formation of Ni clusters.

关键词： methanation     layered double hydroxide     bimetal Ni-Fe alloy     sintering     carbon deposition    

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用于CO甲烷化的Ni/CeO2催化剂还原过程重构行为调控研究 Article

曹昕宇, 浦天成, Bar Mosevitzky Lis, Israel E. Wachs, 彭冲, 朱明辉, 胡永康

《工程（英文）》 2022年 第14卷 第7期   页码 94-99 doi: 10.1016/j.eng.2021.08.023

摘要：

还原预处理是活化负载型金属催化剂的重要步骤，但很少受到关注。本研究发现负载型镍催化剂的重构过程对预处理条件非常敏感。与使用氢气的传统活化方式相比，用合成气活化催化剂可以产生具有多晶结构的负载型镍纳米颗粒，其中包含丰富的晶界。独特的活化方式使得催化剂上CO吸附得到增强，提高了CO甲烷化率。通过操纵活化条件来调整催化剂结构的策略也可以被用于指导其他负载型金属催化剂的理性设计。

关键词： 镍-氧化铈催化剂     催化剂活化     结晶性     甲烷化     原位谱学    

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Methanation and chemolitrophic nitrogen removal by an anaerobic membrane bioreactor coupled partial nitrification

《环境科学与工程前沿（英文）》 2023年 第17卷 第6期 doi: 10.1007/s11783-023-1668-2

摘要：

● Efficient carbon methanation and nitrogen removal was achieved in AnMBR-PN/A system.

关键词： Anaerobic membrane bioreactor     Partial nitrification/Anammox     Carbon separation     Chemolitrophic nitrogen removal    

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Performance assessment of a power-to-gas process based on reversible solid oxide cell

Hanaâ Er-rbib, Nouaamane Kezibri, Chakib Bouallou

《化学科学与工程前沿（英文）》 2018年 第12卷 第4期   页码 697-707 doi: 10.1007/s11705-018-1774-z

摘要：

Due to the foreseen growth of sustainable energy utilization in the upcoming years, storage of the excess production is becoming a rather serious matter. In this work, a promising solution to this issue is investigated using one of the most emerging technologies of electricity conversion: reversible solid oxide cells (RSOC). A detailed model was created so as to study the RSOC performance before implementing it in the global co-electrolysis Aspen PlusTM model. The model was compared to experimental results and showed good agreement with the available data under steady state conditions. The system was then scaled up to a 10 MW co-electrolysis unit operating at 1073 K and 3 bar. The produced syngas is subsequently directed to a methanation unit to produce a synthetic natural gas (SNG) with an equivalent chemical power of 8.3 MWth. Additionally, as a result of a heat integration analysis, the methanation process provides steam and electricity to operate the rest of the units in the process. A final CO2 capture step is added to ensure the required specifications of the produced SNG for gas network injection. Lastly, the overall performance of the power-to-gas process was evaluated taking into account the energy consumption of each unit.

关键词： renewable electricity     storage     co-electrolysis     methanation     carbone capture    

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Characterization and catalytic activity of soft-templated NiO-CeO

Luciano Atzori, Maria Giorgia Cutrufello, Daniela Meloni, Barbara Onida, Delia Gazzoli, Andrea Ardu, Roberto Monaci, Maria Franca Sini, Elisabetta Rombi

《化学科学与工程前沿（英文）》 2021年 第15卷 第2期   页码 251-268 doi: 10.1007/s11705-020-1951-8

摘要： Nanosized NiO, CeO and NiO-CeO mixed oxides with different Ni/Ce molar ratios were prepared by the soft template method. All the samples were characterized by different techniques as to their chemical composition, structure, morphology and texture. On the catalysts submitted to the same reduction pretreatment adopted for the activity tests the surface basic properties and specific metal surface area were also determined. NiO and CeO nanocrystals of about 4 nm in size were obtained, regardless of the Ni/Ce molar ratio. The Raman and X-ray photoelectron spectroscopy results proved the formation of defective sites at the NiO-CeO interface, where Ni species are in strong interaction with the support. The microcalorimetric and Fourier transform infrared analyses of the reduced samples highlighted that, unlike metallic nickel, CeO is able to effectively adsorb CO , forming carbonates and hydrogen carbonates. After reduction in H at 400 °C for 1 h, the catalytic performance was studied in the CO and CO co-methanation reaction. Catalytic tests were performed at atmospheric pressure and 300 °C, using CO/CO /H molar compositions of 1/1/7 or 1/1/5, and space velocities equal to 72000 or 450000 cm ∙h ∙g . Whereas CO was almost completely hydrogenated in any investigated experimental conditions, CO conversion was strongly affected by both the CO/CO /H ratio and the space velocity. The faster and definitely preferred CO hydrogenation was explained in the light of the different mechanisms of CO and CO methanation. On a selected sample, the influence of the reaction temperature and of a higher number of space velocity values, as well as the stability, were also studied. Provided that the Ni content is optimized, the NiCe system investigated was very promising, being highly active for the CO co-methanation reaction in a wide range of operating conditions and stable (up to 50 h) also when submitted to thermal stress.

关键词： soft template method     NiO-CeO2 catalysts     CO and CO2 co-methanation     synthetic natural gas production    

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标题 作者 时间 类型 操作

Enhanced methanation stability of nano-sized MoS

Zhenhua LI, Jia HE, Haiyang WANG, Baowei WANG, Xinbin MA

期刊论文

CO2 methanation and co-methanation of CO and CO2 over Mn-promoted Ni/Al2

Kechao Zhao,Zhenhua Li,Li Bian

期刊论文

Methanation of carbon dioxide: an overview

Wei WANG, Jinlong GONG

期刊论文

Effect of a promoter on the methanation activity of a Mo-based sulfur-resistant catalyst

Can LIN, Haiyang WANG, Zhenhua LI, Baowei WANG, Xinbin MA, Shaodong QIN, Qi SUN

期刊论文

Bimetallic Ni-Fe catalysts derived from layered double hydroxides for CO methanation from syngas

Honggui Tang, Shuangshuang Li, Dandan Gong, Yi Guan, Yuan Liu

期刊论文

用于CO甲烷化的Ni/CeO2催化剂还原过程重构行为调控研究

曹昕宇, 浦天成, Bar Mosevitzky Lis, Israel E. Wachs, 彭冲, 朱明辉, 胡永康

期刊论文

Methanation and chemolitrophic nitrogen removal by an anaerobic membrane bioreactor coupled partial nitrification

期刊论文

Performance assessment of a power-to-gas process based on reversible solid oxide cell

Hanaâ Er-rbib, Nouaamane Kezibri, Chakib Bouallou

期刊论文

Characterization and catalytic activity of soft-templated NiO-CeO

Luciano Atzori, Maria Giorgia Cutrufello, Daniela Meloni, Barbara Onida, Delia Gazzoli, Andrea Ardu, Roberto Monaci, Maria Franca Sini, Elisabetta Rombi

期刊论文