资源类型

期刊论文 75

会议视频 1

年份

2023 6

2022 4

2021 3

2020 3

2019 4

2018 2

2017 2

2014 8

2013 16

2012 4

2011 2

2010 3

2009 5

2008 6

2007 2

2005 1

2004 1

2000 2

1999 1

展开 ︾

关键词

微波遥感 7

微波散射计 6

微波辐射计 4

HY-2 2

HY-2 卫星 2

HY-2A 2

HY-2A卫星 2

人工神经网络 2

微波无线能量传输 2

微波湿度计 2

扫描微波辐射计 2

系统设计 2

ACMR 1

BG算法 1

FY-3湿度仪 1

HY-2卫星 1

Nelder-Mead单纯形法 1

VO2薄膜 1

[BMIm]PF6 1

展开 ︾

检索范围：

排序： 展示方式：

Decomposition of perfluorooctanoic acid by microwave-activated persulfate: Effects of temperature, pH

Yuchi LEE, Shanglien LO, Jeff KUO, Chinghong HSIEH

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 17-25 doi: 10.1007/s11783-011-0371-x

摘要： Microwave-hydrothermal treatment of persistent and bioaccumulative perfluorooctanoic acid (PFOA) in water with persulfate ( ) has been found effective. However, applications of this process to effectively remediate PFOA pollution require a better understanding on free-radical scavenging reactions that also take place. The objectives of this study were to investigate the effects of pH (pH= 2.5, 6.6, 8.8, and 10.5), chloride concentrations (0.01–0.15 mol·L ), and temperature (60°C, 90°C, and 130°C) on persulfate oxidation of PFOA under microwave irradiation. Maximum PFOA degradation occurred at pH 2.5, while little or no degradation at pH 10.5. Lowering system pH resulted in an increase in PFOA degradation rate. Both high pH and chloride concentrations would result in more scavenging of sulfate free radicals and slow down PFOA degradation. When chloride concentrations were less than 0.04 mol·L at 90°C and 0.06 mol·L at 60°C, presence of chloride ions had insignificant impacts on PFOA degradation. However, beyond these concentration levels, PFOA degradation rates reduced significantly with an increase in chloride concentrations, especially under the higher temperature.

关键词： microwave     perfluorooctanoic acid     pH     persulfate     chloride ions     perfluorocarboxylic acids    

HTML PDF 收藏

Study on the microwave-assisted extraction of polyphenols from tea

Liyun WANG, Peiyong QIN, Yan HU,

《化学科学与工程前沿（英文）》 2010年 第4卷 第3期   页码 307-313 doi: 10.1007/s11705-009-0282-6

摘要： This study demonstrated a promising method for quickly extracting tea polyphenol (TP) by microwave-assisted extraction (MAE) technology. Some influential parameters, including MAE temperature, microwave power, concentration of extraction solvent, MAE time and the solid/liquid ratio, were investigated. The optimum condition of MAE was obtained by dual extraction with 60% ethanol (v/v) and the solid/liquid ratio 1:12 g/mL at 80°C for 10 minutes under the microwave power 600 W. The yield of TP was 96.5% under the described condition. Compared with traditional methods, including hot reflux extraction (HRE), ultrasound-assisted extraction (UAE) and supercritical fluid extraction (SFE), the extraction time was saved 8 times than that of HRE, and the yield was increased by 17.5%. The extraction time at comparable levels of production was saved 2 times, and the energy consumption was one fourth that of UAE. The extraction time was saved 5 times than that of SFE, and the yield of TP was increased by 40%. Moreover, compared with MAE of TP studied by others, it decreased the solid/liquid ratio from 1 ∶ 20 to 1 ∶ 12 g/mL without 90-min pre-leaching time, and the yield of TP was increased by 6%–40%.

关键词： energy consumption     microwave-assisted extraction     optimum condition     pre-leaching     concentration    

HTML PDF 收藏

Characterisation of a microwave induced plasma torch for glass surface modification

Adam BENNETT, Nan YU, Fengzhou FANG, Marco CASTELLI, Guoda CHEN, Alessio BALLERI, Takuya URAYAMA

《机械工程前沿（英文）》 2021年 第16卷 第1期   页码 122-132 doi: 10.1007/s11465-020-0603-5

摘要： Microwave induced plasma torches find wide applications in material and chemical analysis. Investigation of a coaxial electrode microwave induced plasma (CE–MIP) torch is conducted in this study, making it available for glass surface modification and polishing. A dedicated nozzle is designed to inject secondary gases into the main plasma jet. This study details the adaptation of a characterisation process for CE–MIP technology. Microwave spectrum analysis is used to create a polar plot of the microwave energy being emitted from the coaxial electrode, where the microwave energy couples with the gas to generate the plasma jet. Optical emission spectroscopy analysis is also employed to create spatial maps of the photonic intensity distribution within the plasma jet when different additional gases are injected into it. The CE–MIP torch is experimentally tested for surface energy modification on glass where it creates a super-hydrophilic surface.

关键词： microwave induced plasma     spectrum analysis     surface modification    

HTML PDF 收藏

Soybean drying characteristics in microwave rotary dryer with forced convection

Ruifang WANG, Zhanyong LI, Yanhua LI, Jingsheng YE

《化学科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 289-292 doi: 10.1007/s11705-009-0022-y

摘要： A new hybrid drying technique by combining microwave and forced convection drying within a rotary drum, i.e., microwave rotary drying, was developed with the purpose to improve the uniformity of microwave drying. In a laboratory microwave rotary dryer, rewetted soybean was utilized as experimental material to study the effects of drum rotating speed, ventilation flow rate, and specific microwave power on the drying kinetics and cracking ratio of soybean. It was found that, with rotation, the cracking ratio can be lowered but without distinct improvement in the drying rate. Increasing ventilation flow rate and specific microwave power can improve the drying rate, but the cracking ratio also increases as a negative result. The cracking ratio lower than 10% can be attained for ventilation flow rate lower than 2.0 m ·h or specific microwave energy lower than 0.4 kW·kg in the present experiments.

关键词： cracking     microwave     rotary drying     soybean    

HTML PDF 收藏

Degradation of trace nitrobenzene in water by microwave-enhanced H

Honghu ZENG, Lanjing LU, Meina LIANG, Jie LIU, Yanghong LI

《环境科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 477-483 doi: 10.1007/s11783-012-0395-x

摘要： To evaluate possible use of microwave-enhanced H O -based (MW/H O ) process to degrade trace nitrobenzene (NB) in water, a series of batch experiments were conducted. The results showed that 2450MHz microwave irradiation significantly enhanced oxidative decomposition of nitrobenzene (NB) in a H O system. About 90% NB was degraded by the MW/ H O process in 30 min. Moreover, the MW/ H O process could enhanced the oxidative degradation of NB even at relatively low temperature (50°C). When the initial concentration of NB was 300μg/L, the optimum ratio of H O to NB and MW power were 70 and 300 W respectively. The presence of humic acid significantly increased H O dosage. The ultraviolet absorbance at 254 nm (UV ) indicated degradation of NB was stepwise and some intermediates were produced. The gas chromatography-mass spectrometric (GC-MS) analysis showed that main intermediates were nitrophenolic and carbonyl compounds.

关键词： microwave     hydrogen peroxide     nitrobenzene     humic acid    

HTML PDF 收藏

Experimental and theoretical study of microwave enhanced catalytic hydrodesulfurization of thiophene

Hui Shang, Pengfei Ye, Yude Yue, Tianye Wang, Wenhui Zhang, Sainab Omar, Jiawei Wang

《化学科学与工程前沿（英文）》 2019年 第13卷 第4期   页码 744-758 doi: 10.1007/s11705-019-1839-7

摘要： Hydrodesulfurization (HDS) of thiophene, as a gasoline model oil, over an industrial Ni-Mo/Al O catalyst was investigated in a continuous system under microwave irradiation. The HDS efficiency was much higher (5%‒14%) under microwave irradiation than conventional heating. It was proved that the reaction was enhanced by both microwave thermal and non-thermal effects. Microwave selective heating caused hot spots inside the catalyst, thus improved the reaction rate. From the analysis of the non-thermal effect, the molecular collisions were significantly increased under microwave irradiation. However, instead of being reduced, the apparent activation energy increased. This may be due to the microwave treatment hindering the adsorption though upright S-bind (η ) and enhancing the parallel adsorption (η ), both adsorptions were considered to favor to the direct desulfurization route and the hydrogenation route respectively. Therefore, the HDS process was considered to proceed along the hydrogenation route under microwave irradiation.

关键词： thiophene     microwave irradiation     hydrodesulfurization     non-thermal microwave effect    

HTML PDF 收藏

Improved film evaporator for mechanistic understanding of microwave-induced separation process

Xin Gao, Dandan Shu, Xingang Li, Hong Li

《化学科学与工程前沿（英文）》 2019年 第13卷 第4期   页码 759-771 doi: 10.1007/s11705-019-1816-1

摘要： Microwave-induced film evaporation separation process has been reported recently to separate the polar/nonpolar mixture. However, the efficiency of the separation is still too low for practical applications, which requires further enhancement via different strategies such as optimization design of evaporator structure. In addition the depth understanding of the separation mechanisms is great importance for better utilization of the microwave-induced separation process. To carry out these investigations, a novel microwave-induced falling film evaporation instrument was developed in this paper. The improvement of the enhancement effect of microwave-induced separation was observed based on the improved film evaporator. The systematic experiments on microwave-induced separation with different binary azeotropic mixtures (ethanol-ethyl acetate system and dimethyl carbonate (DMC)-H O system) were conducted based on the new evaporator. For the ethanol-ethyl acetate system, microwave irradiation shift the direction of evaporation separation at higher ethanol content in the starting liquid mixture. Moreover, for DMC-H O system microwave-induced separation process broke through the limitations of the traditional distillation process. The results clearly demonstrated the microwave-induced evaporation separation process could be commendably applied to the separation of binary azeotrope with different dielectric properties. Effects of operating parameters are also investigated to trigger further mechanism understanding on the microwave-induced separation process.

关键词： process intensification     microwave     falling film evaporation     separation     azeotrope    

HTML PDF 收藏

Microwave enhanced stabilization of copper in artificially contaminated soil

Hua ZHANG, Zhiliang ZHU, Noboru YOSHIKAWA

《环境科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 205-211 doi: 10.1007/s11783-010-0290-2

摘要： Microwave processing was used to stabilize copper ions in soil samples. Its effects on the stabilization efficiency were studied as a function of additive, microwave power, process time, and reaction atmosphere. The stabilization efficiency of the microwave process was evaluated based on the results of the toxicity characteristic leaching procedure (TCLP) test. The results showed that the optimal experimental condition contained a 700 W microwave power, 20 min process time and 3 iron wires as the additive, and that the highest stabilization efficiency level was more than 70%. In addition, the different reaction atmospheres showed no apparent effect on the stabilization efficiency of copper in the artificially contaminated soil. According to the result of the Tessier sequential extraction, the partial species of copper in the contaminated soil was deduced to transform from unstable species to stable states after the microwave process.

关键词： microwave     copper     stabilization    

HTML PDF 收藏

CuO/zeolite catalyzed oxidation of gaseous toluene under microwave heating

Longli BO, Jianbo LIAO, Yucai ZHANG, Xiaohui WANG, Quan YANG

《环境科学与工程前沿（英文）》 2013年 第7卷 第3期   页码 395-402 doi: 10.1007/s11783-012-0417-8

摘要： The development of a combined process of catalytic oxidation and microwave heating for treatment of toluene waste gas was described in this work. Toluene, a typical toxic volatile organic compound, was oxidized through a fixed bed reaction chamber containing zeolite-supported copper oxide (CuO/zeolite) catalyst mixed with silicon carbide (SiC), an excellent microwave-absorbing material. The target compound was efficiently degraded on the surface of the catalyst at high reaction temperature achieved by microwave-heated SiC. A set of experimental parameters, such as microwave power, air flow and the loading size of CuO etc., were investigated, respectively. The study demonstrated these parameters had critical impact on toluene degradation. Under optimal condition, 92% toluene was removed by this combined process, corresponding to an 80%–90% TOC removal rate. Furthermore, the catalyst was highly stable even after eight consecutive 6-h runs. At last, a hypothetical degradation pathway of toluene was proposed based on the experimental data obtained from gas chromatography-mass spectrum and Fourier transform infrared spectroscopy analyses.

关键词： microwave     catalytic oxidation     CuO/zeolite catalyst     silicon carbide (SiC)     toluene    

HTML PDF 收藏

Wastewater treatment by catalytic wet air oxidation process over Al-Fe pillared clays synthesized using microwave

Halima Sassi, Gwendoline Lafaye, Hédi Ben Amor, Abdelaziz Gannouni, Mohamed Razak Jeday, Jacques Barbier-Jr

《环境科学与工程前沿（英文）》 2018年 第12卷 第1期 doi: 10.1007/s11783-017-0971-1

摘要： Microwave irradiation has been used to prepare Al, Fe-pillared clays from a natural Tunisian smectite from the El Hicha deposit (province of Gabes). Chemical analysis, XRD spectra and surface properties evidenced the success of pillaring process. The obtained solids present higher surface area and pore volume than conventionally prepared Al-Fe pillared clays. The main advantages of the microwave methodology are the considerable reduction of the synthesis time and the consumption of water. The microwave-derived Al-Fe pillared clays have been tested for catalytic wet air oxidation (CWAO) of phenol in a stirred tank at 160°C and 20 bar of pure oxygen pressure. These materials are efficient for CWAO of phenol and are highly stable despite the severe operating conditions (acidic media, high pressure, high temperature). The catalyst deactivation was also significantly hindered when compared to conventionally prepared clays. Al-Fe pillared clays prepared by microwave methodology are promising as catalysts for CWAO industrial water treatment.

关键词： Water     Catalytic wet air oxidation     Pillared clays     Microwave     Phenol    

HTML PDF 收藏

Microwave-induced high-energy sites and targeted energy transition promising for efficient energy deployment

《能源前沿（英文）》 2022年 第16卷 第6期   页码 931-942 doi: 10.1007/s11708-021-0771-y

摘要： Diverse interactions between microwaves and irradiated media provide a solid foundation for identifying novel organization pathways for energy flow. In this study, a high-energy-site phenomenon and targeted-energy transition mechanism were identified in a particular microwave heating (MH) process. Intense discharges were observed when microwaves were imposed on irregularly sized SiC particles, producing tremendous heat that was 8-fold the amount generated in the discharge-free case. Energy efficiency was thereby greatly improved in the electricity-microwaves-effective heat transition. Meanwhile, the dispersed microwave field energy concentrated in small sites, where local temperatures could reach 2000°C– 4000°C, with the energy density reaching up to 4.0 × 105 W/kg. This can be called a high-energy site phenomenon which could induce further processes or reactions enhancement by coupling effects of heat, light, and plasma. The whole process, including microwave energy concentration and intense site-energy release, shapes a targeted-energy transition mechanism that can be optimized in a controlled manner through morphology design. In particular, the discharge intensity, frequency, and high-energy sites were strengthened through the fabrication of sharp nano/microstructures, conferring twice the energy efficiency of untreated metal wires. The microwave-induced high-energy sites and targeted energy transition provide an important pathway for high-efficiency energy deployment and may lead to promising applications.

关键词： microwave discharge     high-energy sites     targeted-energy transition     morphology design     energy efficiency    

HTML PDF 收藏

Optimization of microwave pretreatment of lignocellulosic waste for enhancing methane production: Hyacinth

Bai-Hang Zhao, Jie Chen, Han-Qing Yu, Zhen-Hu Hu, Zheng-Bo Yue, Jun Li

《环境科学与工程前沿（英文）》 2017年 第11卷 第6期 doi: 10.1007/s11783-017-0965-z

摘要： The effect of microwave pretreatment on the anaerobic degradation of hyacinth was investigated using response surface methodology (RSM). The components of lignin and the other constituents of hyacinth were altered by microwave pretreatment. Comparison of the near-infrared spectra of hyacinth pretreated by microwave irradiation and water-heating pretreatment revealed that no new compounds were generated during hyacinth pretreatment by microwave irradiation. Atomic force microscopy observations indicated that the physical structures of hyacinth were disrupted by microwave pretreatment. The yield of methane per gram of the microwave-irradiated substrate increased by 38.3% as compared to that of the substrate pretreated via water-heating. A maximum methane yield of 221 mL·g-sub was obtained under the optimum pretreatment conditions (substrate concentration (PSC) = 20.1 g·L and pretreatment time (PT) = 14.6 min) using RSM analysis. A maximum methane production rate of 0.76 mL·h ·g-sub was obtained by applying PSC= 9.5 g·L and PT= 11 min. Interactive item coefficient analysis showed that methane production was dependent on the PSC and PT, separately, whereas the interactive effect of the PSC and PT on methane production was not significant. The same trend was also observed for the methane production rate.

关键词： Microwave pretreatment     Response surface methodology     Methane production     Hyacinth     Anaerobic digestion    

HTML PDF 收藏

NiBO (B = Mn or Co) catalysts for NH-SCR of NO at low-temperature in microwave field

《环境科学与工程前沿（英文）》 2023年 第17卷 第8期 doi: 10.1007/s11783-023-1696-y

摘要：

● Microwave-assisted catalytic NH3-SCR reaction over spinel oxides is carried out.

关键词： Microwave field     Spinel oxides     NOx     Selective catalytic reduction    

HTML PDF 收藏

Kinetics of microwave-enhanced oxidation of phenol by hydrogen peroxide

Deming ZHAO, Jie CHENG, Michael R. HOFFMANN

《环境科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 57-64 doi: 10.1007/s11783-010-0251-9

摘要： Aqueous solutions of phenol were oxidized by hydrogen peroxide assisted by microwave (MW) irradiation. A simple kinetic model for the overall degradation of phenol in the presence of excess H O is proposed in which the degradation rate of phenol is expressed as a linear function of the concentrations of phenol and H O . A detailed parametric study showed that the degradation rate of phenol increased with increasing [H O ] until saturation was observed. Phenol degradation followed apparent zero-order kinetics under MW radiation or H O oxidation. However, after 90 min of irradiation, the observed kinetics shifted to pseudo first order. The overall reaction rates were significantly enhanced in the combined MW/H O system, mainly because microwave could accelerate H O to generate hydroxyl radical ( OH) and other reactive oxygen intermediates. The observed synergetic effects of the MW/H O process resulted in an increased in the net reaction rate by a factor of 5.75. When hydrogen peroxide is present in a large stoichiometric excess, the time required to achieve complete mineralization is reduced significantly.

关键词： microwave (MW) irradiation     hydrogen peroxide     phenol     synergetic effects     kinetic model    

HTML PDF 收藏

Optimization of microwave-assisted extraction for picroside I and picroside II from

Pravin WAKTE,Ajit PATIL,Bhusari SACHIN,Munnaza QUAZI,Shraddha JABDE,Devanand SHINDE

《化学科学与工程前沿（英文）》 2014年 第8卷 第4期   页码 445-453 doi: 10.1007/s11705-014-1458-2

摘要： The response surface methodology was employed to study the optimization of microwave-assisted extraction of picroside I and picroside II from Royle rhizomes. The effects of solid to solvent ratio, and extraction temperature, time and solvent on the yields of picroside I and picroside II have been investigated using Box-Behnken experimental design. The experimental data were fitted to second-order polynomial equations using multiple regression analysis and analyzed using the appropriate statistical method. By solving the regression equation and analyzing 3-D plots, the optimum extraction conditions were found to be: solid to solvent ratio, 10 : 90 (w/v); temperature, 60 °C; and extraction time, 60 s. Under the optimal conditions, the yields of picroside I and picroside II are 41.23 and 6.12 mg·g feed respectively, which are in good agreement with the predicted values. The ratio of solid to solvent significantly affects the yields of picroside I and picroside II. Application of microwave-assisted extraction of picroside I and picroside II from would dramatically reduce extraction time and solvent consumption.

关键词： Box-Behnken design     microwave-assisted extraction     picroside I     picroside II     Picrorrhiza kurroa    

HTML PDF 收藏

标题 作者 时间 类型 操作

Decomposition of perfluorooctanoic acid by microwave-activated persulfate: Effects of temperature, pH

Yuchi LEE, Shanglien LO, Jeff KUO, Chinghong HSIEH

期刊论文

Study on the microwave-assisted extraction of polyphenols from tea

Liyun WANG, Peiyong QIN, Yan HU,

期刊论文

Characterisation of a microwave induced plasma torch for glass surface modification

Adam BENNETT, Nan YU, Fengzhou FANG, Marco CASTELLI, Guoda CHEN, Alessio BALLERI, Takuya URAYAMA

期刊论文

Soybean drying characteristics in microwave rotary dryer with forced convection

Ruifang WANG, Zhanyong LI, Yanhua LI, Jingsheng YE

期刊论文

Degradation of trace nitrobenzene in water by microwave-enhanced H

Honghu ZENG, Lanjing LU, Meina LIANG, Jie LIU, Yanghong LI

期刊论文

Experimental and theoretical study of microwave enhanced catalytic hydrodesulfurization of thiophene

Hui Shang, Pengfei Ye, Yude Yue, Tianye Wang, Wenhui Zhang, Sainab Omar, Jiawei Wang

期刊论文

Improved film evaporator for mechanistic understanding of microwave-induced separation process

Xin Gao, Dandan Shu, Xingang Li, Hong Li

期刊论文

Microwave enhanced stabilization of copper in artificially contaminated soil

Hua ZHANG, Zhiliang ZHU, Noboru YOSHIKAWA

期刊论文

CuO/zeolite catalyzed oxidation of gaseous toluene under microwave heating

Longli BO, Jianbo LIAO, Yucai ZHANG, Xiaohui WANG, Quan YANG

期刊论文

Wastewater treatment by catalytic wet air oxidation process over Al-Fe pillared clays synthesized using microwave

Halima Sassi, Gwendoline Lafaye, Hédi Ben Amor, Abdelaziz Gannouni, Mohamed Razak Jeday, Jacques Barbier-Jr

期刊论文

Microwave-induced high-energy sites and targeted energy transition promising for efficient energy deployment

期刊论文

Optimization of microwave pretreatment of lignocellulosic waste for enhancing methane production: Hyacinth

Bai-Hang Zhao, Jie Chen, Han-Qing Yu, Zhen-Hu Hu, Zheng-Bo Yue, Jun Li

期刊论文

NiBO (B = Mn or Co) catalysts for NH-SCR of NO at low-temperature in microwave field

期刊论文

Kinetics of microwave-enhanced oxidation of phenol by hydrogen peroxide

Deming ZHAO, Jie CHENG, Michael R. HOFFMANN

期刊论文

Optimization of microwave-assisted extraction for picroside I and picroside II from

Pravin WAKTE,Ajit PATIL,Bhusari SACHIN,Munnaza QUAZI,Shraddha JABDE,Devanand SHINDE

期刊论文