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Tribological properties of onion like fullerenes and NiFe

Ruixiang WANG,Yihao ZHANG,Haizhou WU

《能源前沿(英文)》 2021年 第15卷 第1期   页码 208-212 doi: 10.1007/s11708-017-0454-x

摘要: A novel way for a compressor to improve its coefficient of performance and enhance its reliability by employing nano-refrigeration lubricant oil was proposed. Onion like fullerenes (OLFs) and NiFe O nano-composites, modified by Span 80, were dispersed in refrigeration oil KFR22 by solid grinding (SG). Morphologies of NiFe O nano-composites were characterized by using transmission electron microscope (TEM). The tribological properties as a refrigeration lubricants additive were investigated using SRV (II), a multi-functional reciprocating friction and wear tester. The results showed that the friction coefficient was decreased from 0.15 to 0.04.

关键词: refrigeration lubricants     friction coefficient     nano-composites     reciprocating motion     onion like fullerenes    

Mixed mode properties of CNT reinforced composites using Arcan test rig

Jacob MUTHU

《结构与土木工程前沿(英文)》 2015年 第9卷 第4期   页码 397-404 doi: 10.1007/s11709-015-0321-y

摘要: Composite materials reinforced with carbon nanotubes were mechanical tested using Arcan test rig under Mode-I, Mode-II and mixed mode loading conditions to obtain their fracture properties. The butterfly composite specimens were fabricated with 0.02, 0.05 and 0.1 wt % CNTs. The polyester/CNT composite was fabricated using VRTM (Vacuum Resin Transfer Molding) where the CNTs were first functionalised to reach an optimum properties. Arcan test rig was designed and fabricated to work with the Shimadzu testing machine. The results show that the functionalised CNTs have improved the fracture behavior by acting as bridge between the cracked face. In addition, the fracture properties were not improved for the higher weight fraction of 0.1 wt% CNTs.

关键词: CNT     composites     Arcan test rig     stress intensity factor    

Numerical modeling of nonlinear deformation of polymer composites based on hyperelastic constitutive

Qingsheng YANG, Fang XU

《机械工程前沿(英文)》 2009年 第4卷 第3期   页码 284-288 doi: 10.1007/s11465-009-0067-0

摘要: Fiber reinforced polymer (FRP) composites exhibit nonlinear and hyperelastic characteristics under finite deformation. This paper investigates the macroscopic hyperelastic behavior of fiber reinforced polymer composites using a micromechanical model and finite deformation theory based on the hyperelastic constitutive law. The local stress and deformation of a representative volume element are calculated by the nonlinear finite element method. Then, an averaging procedure is used to find the homogenized stress and strain, and the macroscopic stress-strain curves are obtained. Numerical examples are given to demonstrate hyperelastic behavior and deformation of the composites, and the effects of the distribution pattern of fibers are also investigated to model the mechanical behavior of FRP composites.

关键词: composites     hyperelastic     finite deformation     homogenization     micromechanics    

Water-dispersible nano-pollutions reshape microbial metabolism in type-specific manners: A metabolic

《环境科学与工程前沿(英文)》 2022年 第16卷 第9期 doi: 10.1007/s11783-022-1548-1

摘要:

• Water-dispersible nano-pollutions exhibit type-specific toxic effects on E. coli.

关键词: Nano-toxicity     Nano-plastics     Quantum dots     Microbial metabolite     Metabolic dysregulation    

Laboratory investigation of emulsified asphalt binder modified with wood-derived nano-cellulose and nano

Yunge WEI; Jiayu WANG; Ruoyu LI; Ling XU; Feipeng XIAO

《结构与土木工程前沿(英文)》 2022年 第16卷 第11期   页码 1474-1485 doi: 10.1007/s11709-022-0869-2

摘要: Emulsified asphalt is the primary material for preventive maintenance and cold-mix paving, but its low cohesive strength and poor mechanical properties limit its wide application, even with polymer modification. In this study, Styrene-Butadiene Rubber (SBR) emulsified asphalt was modified with nano-cellulose materials, namely nano paper-cellulose (NPC) and wood-derived nano-cellulose (WDC), to improve its properties. A novel preparation method of nano-cellulose solution was developed, including blending, ultrasonic stirring, and centrifugal treatment. Four types of nano-cellulose solution (0.5% NPC, 0.5%, 1.0%, and 1.5% WDC by weight of water) were selected. The microscopy analysis indicated that 0.5% WDC emulsion had a smaller particle size than 1.5% WDC emulsion. The rheology test indicated that WDC modified residue improved rutting resistance with the increased solution dosage due to the cross-linking effect, but its creep-and-recovery performance was worse than that of SBR emulsion residue. The NPC modified binder had a higher rutting factor than WDC modified binder at the same dosage after short-term aging. In addition, 1.0% WDC could be regarded as the optimal dosage in terms of fatigue and low-temperature performance. Furthermore, Fourier Transform Infrared Spectroscopy (FTIR) results showed that 0.5% NPC modified residue performed better in long-term aging resistance compared with 0.5%WDC modified asphalt.

关键词: nano-cellulose     emulsified asphalt binder     dispersion     rheological properties     Fourier transform infrared spectroscopy    

Fiber-reinforced composites in milling and grinding: machining bottlenecks and advanced strategies

《机械工程前沿(英文)》 2022年 第17卷 第2期 doi: 10.1007/s11465-022-0680-8

摘要: Fiber-reinforced composites have become the preferred material in the fields of aviation and aerospace because of their high-strength performance in unit weight. The composite components are manufactured by near net-shape and only require finishing operations to achieve final dimensional and assembly tolerances. Milling and grinding arise as the preferred choices because of their precision processing. Nevertheless, given their laminated, anisotropic, and heterogeneous nature, these materials are considered difficult-to-machine. As undesirable results and challenging breakthroughs, the surface damage and integrity of these materials is a research hotspot with important engineering significance. This review summarizes an up-to-date progress of the damage formation mechanisms and suppression strategies in milling and grinding for the fiber-reinforced composites reported in the literature. First, the formation mechanisms of milling damage, including delamination, burr, and tear, are analyzed. Second, the grinding mechanisms, covering material removal mechanism, thermal mechanical behavior, surface integrity, and damage, are discussed. Third, suppression strategies are reviewed systematically from the aspects of advanced cutting tools and technologies, including ultrasonic vibration-assisted machining, cryogenic cooling, minimum quantity lubrication (MQL), and tool optimization design. Ultrasonic vibration shows the greatest advantage of restraining machining force, which can be reduced by approximately 60% compared with conventional machining. Cryogenic cooling is the most effective method to reduce temperature with a maximum reduction of approximately 60%. MQL shows its advantages in terms of reducing friction coefficient, force, temperature, and tool wear. Finally, research gaps and future exploration directions are prospected, giving researchers opportunity to deepen specific aspects and explore new area for achieving high precision surface machining of fiber-reinforced composites.

关键词: milling     grinding     fiber-reinforced composites     damage formation mechanism     delamination     material removal mechanism     surface integrity     minimum quantity lubrication    

Strengthening of the concrete face slabs of dams using sprayable strain-hardening fiber-reinforced cementitious composites

《结构与土木工程前沿(英文)》 2022年 第16卷 第2期   页码 145-160 doi: 10.1007/s11709-022-0806-4

摘要: In this study, sprayable strain-hardening fiber-reinforced cementitious composites (FRCC) were applied to strengthen the concrete slabs in a concrete-face rockfill dam (CFRD) for the first time. Experimental, numerical, and analytical investigations were carried out to understand the flexural properties of FRCC-layered concrete slabs. It was found that the FRCC layer improved the flexural performance of concrete slabs significantly. The cracking and ultimate loads of a concrete slab with an 80 mm FRCC layer were 132% and 69% higher than those of the unstrengthened concrete slab, respectively. At the maximum crack width of 0.2 mm, the deflection of the 80-mm FRCC strengthened concrete slab was 144% higher than that of the unstrengthened concrete slab. In addition, a FE model and a simplified analytical method were developed for the design and analysis of FRCC-layered concrete slabs. Finally, the test result of FRCC leaching solution indicated that the quality of the water surrounding FRCC satisfied the standard for drinking water. The findings of this study indicate that the sprayable strain-hardening FRCC has a good potential for strengthening hydraulic structures such as CFRDs.

关键词: strain-hardening cementitious composites     engineered cementitious composites     sprayable     shotcrete     strengthening     concrete-face rockfill dam     digital image correlation    

Pd nano-catalyst supported on biowaste-derived porous nanofibrous carbon microspheres for efficient catalysis

《化学科学与工程前沿(英文)》 2023年 第17卷 第9期   页码 1289-1300 doi: 10.1007/s11705-023-2299-7

摘要: Environmental pollution caused by the presence of aromatic aldehydes and dyes in wastewater is a serious global concern. An effective strategy for the removal of these pollutants is their catalytic conversion, possibly to valuable compounds. Therefore, the design of efficient, stable and long-lifetime catalysts is a worthwhile research goal. Herein, we used nanofibrous carbon microspheres (NCM) derived from the carbohydrate chitin present in seafood waste, and characterized by interconnected nanofibrous networks and N/O-containing groups, as carriers for the manufacture of a highly dispersed, efficient and stable Pd nano-catalyst (mean diameter ca. 2.52 nm). Importantly, the carbonised chitin’s graphitized structure, defect presence and large surface area could promote the transport of electrons between NCM and Pd, thereby endowing NCM supported Pd catalyst with high catalytic activity. The NCM supported Pd catalyst was employed in the degradation of some representative dyes and the chemoselective hydrogenation of aromatic aldehydes; this species exhibited excellent catalytic activity and stability, as well as applicability to a broad range of aromatic aldehydes, suggesting its potential use in green industrial catalysis.

关键词: biowaste chitin     nanofibrous     palladium     nano-catalyst     catalysis    

Deformation characteristics of corrugated composites for morphing wings

Ruijun GE, Bangfeng WANG, Changwei MOU, Yong ZHOU,

《机械工程前沿(英文)》 2010年 第5卷 第1期   页码 73-78 doi: 10.1007/s11465-009-0063-4

摘要: To meet the needs of morphing and withstand aerodynamic loads of a morphing wing skin, a corrugated glass fabric-epoxy laminated composite is prepared and investigated in this paper. This composite is flexible in the corrugated direction and stiff in the transverse direction to the corrugation. FEM models are established and solved to predict the characteristics of the composites by the commercial FEM software ANSYS. The relationship between the configuration of elongation and tensile load along the corrugation direction is obtained through numerical simulation. To reflect the stretching superiority of the configuration, the elongation of corrugated and flat composites is calculated and compared under the same tensile load. The linear cumulative effect of corrugated composites deformation is proved by calculating the elongation of the composites with several different corrugation numbers. Several corrugated composite specimens were manufactured and tested to verify the results of numerical analysis and the equivalent elastic modulus of the composites were also evaluated through the specimen tests. Results of simulation and experiments show that the corrugated composite provided in this paper can afford obviously larger deformation than the flat one. The corrugated composite can provide a possible choice for morphing wing skin.

关键词: corrugated composites     deformation characteristic     numerical analysis     experiment    

Effects of different types of biochar on the properties and reactivity of nano zero-valent iron in soil

《环境科学与工程前沿(英文)》 2021年 第15卷 第5期 doi: 10.1007/s11783-021-1388-4

摘要:

• Biochar enhanced the mobility and stability of zero-valent iron nanoparticles.

关键词: Nano zero-valent iron     Biochar     BDE209     Transport     Soil    

Immunological effects of nano-enabled hyperthermia for solid tumors: opportunity and challenge

《化学科学与工程前沿(英文)》 2022年 第16卷 第3期   页码 333-344 doi: 10.1007/s11705-021-2059-5

摘要: Compared to conventional hyperthermia that is limited by low selectivity and severe side effects, nano-enabled hyperthermia yields great potentials to tackle these limitations for cancer treatment. Another major advance is the observation of immunological responses associated with nano-enabled hyperthermia, which introduces a new avenue, allowing a potential paradigm shift from the acutely effective and cytotoxicity-centric response to the next-phase discovery, i.e., long-lasting and/or systemic anti-tumor immunity. This perspective first discusses the temperature-gradient and the spatially-structured immunological landscape in solid tumors receiving nano-enabled hyperthermia. This includes the discussion about underlying mechanism such as immunogenic cell death, which initiates a profound immunological chain reaction. In order to propagate the immune activation as a viable therapeutic principle, we further discussed the tumor type-specific complexity in the immunological tumor microenvironment, including the creative design of nano-enabled combination therapy to synergize with nano-enabled hyperthermia.

关键词: nano-enabled hyperthermia     immunogenic cell death     heterogeneous immunological landscape     tumor microenvironment    

Fabrication of ionic polymer-metal composites (IPMCs) and robot design

Hanmin PENG, Qingjun Ding, Huafeng LI

《机械工程前沿(英文)》 2009年 第4卷 第3期   页码 332-338 doi: 10.1007/s11465-009-0046-5

摘要: This paper describes a method for preliminary manufacturing experiments on a type of smart materials—ionic polymer-metal composites (IPMCs). They belong to EAP materials and are famous for their capability of huge displacement within a low voltage (1–3 V). With best operation quality in the humid environment, they can be made as underwater robots in simple structures. In this paper, two purposes are embodied. One focuses on the research on the IPMCs characteristics, including the actuating principle, manufacturing process, and parameters of performance. The other is that a relevant robot driven by IPMCs strips is designed. According to imitation propulsion mechanism of undulatory fins, IPMCs are designed for a novel bionic water vehicle propelled by undulatory multiple fish-like fins (made by IPMCs). The robot consists of three fins on the bottom tightly contacting by plastic foils with each other.

关键词: ionic polymer-metal composites (IPMCs)     artificial muscles     actuator     bionic robot     platinum-plated    

Behavior of aqueous stable colloidal nano-C

Jing HUO,Ye YU,Ling GE,Bo ZHANG,Yiliang HE

《环境科学与工程前沿(英文)》 2015年 第9卷 第2期   页码 197-205 doi: 10.1007/s11783-014-0624-6

摘要: C , as one of carbon nanomaterials widely used in various fields, could be released into the water environment thus exerting some potential health risks to human beings. This work examined the behavior of aqueous stable colloidal nano-C (nC ) aggregates under different environmental conditions including Polyethylene glycol octylphenol ether (TX100) micelles concentration, pH, and reaction time when exposed to TX100 micelles. Results show that the nC aggregates became more dispersive and restored the capability of generating the singlet oxygen when exposed to TX100 micelles. With the increase of TX100 concentration, smaller average size of nC aggregates was observed in dynamic light scattering (DLS) analysis, the fluorescence intensity of TX100 was more quenched by nC aggregates, and the kinetic rate constant of generating the singlet oxygen for nC aggregates was improved. The mean size of nC aggregates in the presence of TX100 had no obvious variations when the pH ranged from 4 to 8. The longer reaction time between nC aggregates and TX100 led to a higher kinetic rate constant of generating the singlet oxygen. Collective data suggest that variations in physicochemical properties of nC aggregates are strongly dependent on the surrounding media under different environmental conditions and directly govern nC ’s transport behavior and potential toxicity.

关键词: nano-C60 (nC60) aggregates     photochemical reactivity     artificial biological membrane    

Review of recent developments in cement composites reinforced with fibers and nanomaterials

Jianzhuang XIAO, Nv HAN, Yan LI, Zhongsen ZHANG, Surendra P. SHAH

《结构与土木工程前沿(英文)》 2021年 第15卷 第1期   页码 1-19 doi: 10.1007/s11709-021-0723-y

摘要: The quest for high-performance construction materials is led by the development and application of new reinforcement materials for cement composites. Concrete reinforcement with fibers has a long history. Nowadays, many new fibers associated with high performance and possessing eco-environmental characteristics, such as basalt fibers and plant fibers, have received much attention from researchers. In addition, nanomaterials are considered as a core material in the modification of cement composites, specifically in the enhancement of the strength and durability of composites. This paper provides an overview of the recent research progress on cement composites reinforced with fibers and nanomaterials. The influences of fibers and nanomaterials on the fresh and hardened properties of cement composites are summarized. Moreover, future trends in the application of these fibers or of nanomaterial-reinforced cement composites are proposed.

关键词: cement composites     fiber     nanomaterial     mechanical property     durability    

Mechanical behavior and semiempirical force model of aerospace aluminum alloy milling using nano biological

《机械工程前沿(英文)》 2023年 第18卷 第1期 doi: 10.1007/s11465-022-0720-4

摘要: Aerospace aluminum alloy is the most used structural material for rockets, aircraft, spacecraft, and space stations. The deterioration of surface integrity of dry machining and the insufficient heat transfer capacity of minimal quantity lubrication have become the bottleneck of lubrication and heat dissipation of aerospace aluminum alloy. However, the excellent thermal conductivity and tribological properties of nanofluids are expected to fill this gap. The traditional milling force models are mainly based on empirical models and finite element simulations, which are insufficient to guide industrial manufacturing. In this study, the milling force of the integral end milling cutter is deduced by force analysis of the milling cutter element and numerical simulation. The instantaneous milling force model of the integral end milling cutter is established under the condition of dry and nanofluid minimal quantity lubrication (NMQL) based on the dual mechanism of the shear effect on the rake face of the milling cutter and the plow cutting effect on the flank surface. A single factor experiment is designed to introduce NMQL and the milling feed factor into the instantaneous milling force coefficient. The average absolute errors in the prediction of milling forces for the NMQL are 13.3%, 2.3%, and 7.6% in the x-, y-, and z-direction, respectively. Compared with the milling forces obtained by dry milling, those by NMQL decrease by 21.4%, 17.7%, and 18.5% in the x-, y-, and z-direction, respectively.

关键词: milling     force     nanofluid minimum quantity lubrication     aerospace aluminum alloy     nano biological lubricant    

标题 作者 时间 类型 操作

Tribological properties of onion like fullerenes and NiFe

Ruixiang WANG,Yihao ZHANG,Haizhou WU

期刊论文

Mixed mode properties of CNT reinforced composites using Arcan test rig

Jacob MUTHU

期刊论文

Numerical modeling of nonlinear deformation of polymer composites based on hyperelastic constitutive

Qingsheng YANG, Fang XU

期刊论文

Water-dispersible nano-pollutions reshape microbial metabolism in type-specific manners: A metabolic

期刊论文

Laboratory investigation of emulsified asphalt binder modified with wood-derived nano-cellulose and nano

Yunge WEI; Jiayu WANG; Ruoyu LI; Ling XU; Feipeng XIAO

期刊论文

Fiber-reinforced composites in milling and grinding: machining bottlenecks and advanced strategies

期刊论文

Strengthening of the concrete face slabs of dams using sprayable strain-hardening fiber-reinforced cementitious composites

期刊论文

Pd nano-catalyst supported on biowaste-derived porous nanofibrous carbon microspheres for efficient catalysis

期刊论文

Deformation characteristics of corrugated composites for morphing wings

Ruijun GE, Bangfeng WANG, Changwei MOU, Yong ZHOU,

期刊论文

Effects of different types of biochar on the properties and reactivity of nano zero-valent iron in soil

期刊论文

Immunological effects of nano-enabled hyperthermia for solid tumors: opportunity and challenge

期刊论文

Fabrication of ionic polymer-metal composites (IPMCs) and robot design

Hanmin PENG, Qingjun Ding, Huafeng LI

期刊论文

Behavior of aqueous stable colloidal nano-C

Jing HUO,Ye YU,Ling GE,Bo ZHANG,Yiliang HE

期刊论文

Review of recent developments in cement composites reinforced with fibers and nanomaterials

Jianzhuang XIAO, Nv HAN, Yan LI, Zhongsen ZHANG, Surendra P. SHAH

期刊论文

Mechanical behavior and semiempirical force model of aerospace aluminum alloy milling using nano biological

期刊论文