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2023 1

2017 1

2015 2

2013 1

2007 1

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Fe、Co、Ru 碳化物 1

尺寸效应 1

晶相结构 1

费托合成 1

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Light olefins synthesis from С

Anton SHALYGIN, Evgenii PAUKSHTIS, Evgenii KOVALYOV, Bair BAL’ZHINIMAEV

《化学科学与工程前沿（英文）》 2013年第7卷第3期页码 279-288 doi: 10.1007/s11705-013-1338-1

摘要： A two-step process was employed to convert methane or ethane to light olefins via the formation of an intermediate monoalkyl halide. A novel K RuOCl /TiO catalyst was tested for the oxidative chlorination of methane and ethane. The catalyst had high selectivity for methyl and ethyl chlorides, 80% and 90%, respectively. During the oxychlorination of ethane at ≥250°C, the formation of ethylene as a reaction product along with ethyl chloride was observed. In situ Fourier transform infrared studies showed that the key intermediate for monoalkyl chloride and ethylene formation is the alkoxy group. The reaction mechanism for the oxidative chlorination of methane and ethane over the Ru-oxychloride catalyst was proposed. The novel fiber glass catalyst was also tested for the dehydrochlorination of alkyl chlorides to ethylene and propylene. Very high selectivities (up to 94%–98%) for ethylene and propylene formation as well as high stability were demonstrated.

关键词： oxychlorination methane ethane light olefins ruthenium catalyst

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Catalytic reduction of water pollutants: knowledge gaps, lessons learned, and new opportunities

《环境科学与工程前沿（英文）》 2023年第17卷第2期 doi: 10.1007/s11783-023-1626-z

摘要：

● Advances, challenges, and opportunities for catalytic water pollutant reduction.

关键词： Molybdenum Rhenium Rhodium Ruthenium Catalyst Support Bromate

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Catalytic ozonation of organic compounds in water over the catalyst of RuO

Jianbing WANG,Guoqing WANG,Chunli YANG,Shaoxia YANG,Qing HUANG

《环境科学与工程前沿（英文）》 2015年第9卷第4期页码 615-624 doi: 10.1007/s11783-014-0706-5

摘要： This research investigates the performances of RuO /ZrO -CeO in catalytic ozonation for water treatment. The results show that RuO /ZrO -CeO was active for the catalytic ozonation of oxalic acid and possessed higher stability than RuO /Al O and Ru/AC. In the catalytic ozonation of dimethyl phthalate (DMP), RuO /ZrO -CeO did not enhance the DMP degradation rate but significantly improved the total organic carbon (TOC) removal rate. The TOC removal in catalytic ozonation was 56% more than that in noncatalytic ozonation. However this does not mean the catalyst was very active because the contribution of catalysis to the overall TOC removal was only 30%. The adsorption of the intermediates on RuO /ZrO -CeO played an important role on the overall TOC removal while the adsorption of DMP on it was negligible. This adsorption difference was due to their different ozonation rates. In the catalytic ozonation of disinfection byproduct precursors with RuO /ZrO -CeO , the reductions of the haloacetic acid and trihalomethane formation potentials (HAAFPs and THMFPs) for the natural water samples were 38%–57% and 50%–64%, respectively. The catalyst significantly promoted the reduction of HAAFPs but insignificantly improved the reduction of THMFPs as ozone reacts fast with the THMs precursors. These results illustrate the good promise of RuO /ZrO -CeO in catalytic ozonation for water treatment.

关键词： ozonation ruthenium oxalic acid dimethyl phthalate disinfection byproduct

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Preparation and influence of performance of anodic catalysts for direct methanol fuel cell

WANG Zhenbo, YIN Geping, SHI Pengfei

《化学科学与工程前沿（英文）》 2007年第1卷第1期页码 20-25 doi: 10.1007/s11705-007-0005-9

摘要： This research aims at increasing the utilization of platinum-ruthenium alloy (Pt-Ru) catalysts and thus lowering the catalyst loading in anodes for methanol electrooxidation. The direct methanol fuel cell s (DMFC) anodic catalysts, Pt-Ru/C, were prepared by chemical reduction with a reducing agent added in two kinds of solutions under different circumstances. The reducing agent was added in hot solution with the protection of inert gases or just air, and in cold solution with inert gases. The catalysts were treated at different temperatures. Their performance was tested by cyclic voltammetry and potentiostatic polarization by utilizing their inherent powder microelectrode in 0.5 mol/L CHOH and 0.5 mol/L HSO solution. The structures and micro-surface images of the catalysts were determined and observed by X-ray diffraction and transmission electron microscopy, respectively. The catalyst prepared in inert gases showed a better catalytic performance for methanol electrooxidation than that prepared in air. It resulted in a more homogeneous distribution of the Pt-Ru alloy in carbon. Its size is small, only about 4.5 nm. The catalytic performance is affected by the order of the reducing agent added. The performance of the catalyst prepared by adding the reductant at constant temperature of the solution is better than that prepared by adding it in the solution at 0?C and then heating it up to the reducing temperature. The structure of the catalyst was modified, and there was an increase in the conversion of ruthenium into the alloyed state and an increase in particle size with the ascension of heat treatment temperature. In addition, the stability of the catalyst was improved after heat treatment.

关键词： catalyst prepared stability ascension potentiostatic polarization platinum-ruthenium

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费托合成催化剂的尺寸与晶相效应

Liu Jin-Xun,Wang Peng,Xu Wayne,Hensen Emiel J. M.

《工程（英文）》 2017年第3卷第4期页码 467-476 doi: 10.1016/J.ENG.2017.04.012

摘要：

费托合成（FTS）是近年来越发重要的能源转化途径，它可将一氧化碳和氢气的合成气转化为液态燃料和化学品，合成气的原料来自煤炭、天然气或生物质。在费托合成反应中，分散的过渡金属纳米粒子作为催化剂，用于催化以碳- 碳键生成为基础的反应。催化剂的催化活性和选择性与纳米粒子的电子结构和几何结构密切相关，具体取决于纳米粒子的尺寸、形态和晶相。在本文中，我们将回顾近期关于费托合成反应催化剂的体相和表面敏感性方面的工作。通过深入理解以上参数对不同催化剂行为的影响，有助于指导设计开发出更高活性、稳定性以及更优选择性的催化剂。

关键词：费托合成 Fe、Co、Ru 碳化物尺寸效应晶相结构

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Selective conversion of cellulose to hexitols over bi-functional Ru-supported sulfated zirconia and silica-zirconia catalysts

Zhiqiang Song,Hua Wang,Yufei Niu,Xiao Liu,Jinyu Han

《化学科学与工程前沿（英文）》 2015年第9卷第4期页码 461-466 doi: 10.1007/s11705-015-1543-1

摘要： We report a process of selective conversion of microcrystalline cellulose to hexitols over bi-functional Ru-supported sulfated zirconia and silica-zirconia catalysts. A 58.1% yield of hexitols and a 71.0% conversion of cellulose were achieved over Ru/SZSi(100:15)-773 catalyst at 443 K. The as-synthesized catalysts were characterized by X-ray diffraction (XRD), BET, thermogravimetric analysis and pyridine adsorption Fourier transform infrared spectroscopy (FTIR). XRD results indicated that the sulfated catalysts were pure tetragonal phase of ZrO when calcined at 773 K. Monoclinic zirconia appeared at the calcination temperature of 873 K, and the content of monoclinic phase increased with the elevating temperature. Compared with sulfated zirconia catalyst, sulfated silica-zirconia catalysts possessed a higher ratio of Brønsted to Lewis on the surface of catalysts, as shown from pyridine adsorption FTIR results. The reaction results indicated that the tetragonal zirconia, which is necessary for the formation of superacidity, was the active phase to cellulose conversion. The higher amounts of Brønsted acid sites can remarkably accelerate the cellulose depolymerization and promote side reactions that convert C5–C6 alcohols into the unknown soluble degradation products.

关键词： hexitols cellulose hydrogenation sulfated zirconia ruthenium