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共热解 1

木聚糖 1

木质素 1

纤维素 1

聚乙烯 1

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Kinetic studies of xylan hydrolysis of corn stover in a dilute acid cycle spray flow-through reactor

Hongman ZHANG, Qiang JIN, Rui XU, Lishi YAN, Zengxiang LIN

《化学科学与工程前沿（英文）》 2011年第5卷第2期页码 252-257 doi: 10.1007/s11705-010-1010-y

摘要： Xylan of corn stover was pretreated with 1%, 2% and 3% (w/w) sulfuric acid at relatively low temperatures (90°C, 95°C and 100°C) in a dilute acid cycle spray flow-through reactor (DCF). The hydrolysis of xylan to its monomeric xylose was modeled by a series of first-order reactions. Both biphasic and Saeman hydrolysis models were applied to fit the experimental data. The results confirmed that the kinetic data of xylan hydrolysis fitted a first-order irreversible reaction model and the experimental data. The reaction rates of xylose monomer formation and degradation were sensitive to catalyst concentration and temperature. Higher catalyst concentration and lower reaction temperature result in high xylose yield. The activation energy for xylose formation and degradation were determined to be 112.9 and 101.0 kJ·mol , respectively. Over 90% theoretical xylose obtained from corn stover can be used to produce ethanol, xylitol and fumaric acid by fermentation.

关键词： corn stover xylan hydrolysis biphasic model Saeman model cycle spray kinetics

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Fast and catalytic pyrolysis of xylan: Effects of temperature and M/HZSM-5 (M= Fe, Zn) catalysts on pyrolytic

Xifeng ZHU, Qiang LU, Wenzhi LI, Dong ZHANG,

《能源前沿（英文）》 2010年第4卷第3期页码 424-429 doi: 10.1007/s11708-010-0015-z

摘要： Pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) was employed to achieve fast pyrolysis of xylan and on-line analysis of pyrolysis vapors. Tests were conducted to investigate the effects of temperature on pyrolytic products, and to reveal the effect of HZSM-5 and M/HZSM-5 (M= Fe, Zn) zeolites on pyrolysis vapors. The results showed that the total yield of pyrolytic products first increased and then decreased with the increase of temperature from 350°C to 900°C. The pyrolytic products were complex, and the most abundant products included hydroxyacetaldehyde, acetic acid, 1-hydroxy-2-propanone, 1-hydroxy-2-butanone and furfural. Catalytic cracking of pyrolysis vapors with HZSM-5 and M/HZSM-5 (M= Fe, Zn) catalysts significantly altered the product distribution. Oxygen-containing compounds were reduced considerably, and meanwhile, a lot of hydrocarbons, mainly toluene and xylenes, were formed. M/HZSM-5 catalysts were more effective than HZSM-5 in reducing the oxygen-containing compounds, and therefore, they helped to produce higher contents of hydrocarbons than HZSM-5.

关键词： xylan fast pyrolysis catalytic pyrolysis Py-GC/MS HZSM-5

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TG-MS研究生物质组分与聚乙烯共热解特性

范洪刚,顾菁,王亚琢,袁浩然,何明阳,孙富安

《中国工程科学》 2018年第20卷第3期页码 102-108 doi: 10.15302/J-SSCAE-2018.03.015

摘要：

为了探索生物质主要组分在与塑料共热解过程中的协同效应和小分子气体产物的变化规律，笔者采用热重-质谱联用（TG-MS）技术研究纤维素、木聚糖、木质素与聚乙烯的共热解特性。共热解样品的混合比例为1∶1（w/w），TG实验得到了各单组分以及混合组分的失重区间，通过对单组分TG数据的拟合得到理论值与实验值，比较得到混合组分在共热解过程中存在协同效应，可促进样品的分解。MS实验数据表明，在共热解过程中聚乙烯的存在促进了生物质组分的分解，从而使小分子气体产物的产量增加。纤维素热解的小分子产物中H2O和CO2的产量增大；木聚糖和聚乙烯在共热解过程中会促进对方分解，H₂O，CH₄，H₂和C₂H₄都有更高的产量；木质素和聚乙烯的共热解过程会促进CO，C2H4和H2的产生。

关键词：纤维素木聚糖木质素聚乙烯共热解