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Preparation and swelling properties of a starch-g-poly(acrylic acid)/organo-mordenite hydrogel composite

Yan Zhang,Pingqiang Gao,Lin Zhao,Yizhong Chen

《化学科学与工程前沿（英文）》 2016年 第10卷 第1期   页码 147-161 doi: 10.1007/s11705-015-1546-y

摘要： A novel hydrogel composite was prepared via inverse suspension polymerization using starch, acrylic acid and organo-mordenite micropowder with the crosslinker, , ′-methylenebisacrylamide and the initiator, potassium persulfate. Fourier transform infrared spectroscopy, X-ray diffraction spectroscopy, scanning electron microscopy, and energy dispersive spectroscopy confirmed that the acrylic acid was grafted onto the backbone of the corn starch, that the organo-mordenite participated in the polymerization, and that the addition of organo-mordenite improved the surface morphology of the hydrogel composite. The swelling capacity of the hydrogel composite was evaluated in distilled water, and solutions with different pH values, and various salt solutions. It was found that the incorporation of 10 wt-% organo-mordenite enhanced the water absorbency by 144% (from 268 to 655 g·g ) and swelling was extremely sensitive to the pH values, the concentration of the salt solution and cation type. Swelling kinetics and water diffusion mechanism of the hydrogel composite in distilled water were also discussed. Moreover, the hydrogel composite showed excellent reversibility of water absorption even after five repetitive cycles and the hydrogel composite exhibited significant environmental-responsiveness by changing the swelling medium from distilled water to 0.1 mol·L NaCl solution. In addition, the loading and release of urea by the hydrogel composite were tested and the nutrient-slow-release capability of this material was found to be suitable for many potential applications.

关键词： hydrogel composite     environmental-responsiveness     organo-mordenite     starch     acrylic acid    

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Not asthma, but GERD: case report

WANG Zhonggao

《医学前沿（英文）》 2007年 第1卷 第1期   页码 115-119 doi: 10.1007/s11684-007-0022-6

摘要： Asthma is a disorder of the lungs characterized by increased responsiveness of the airways, as manifested by episodes of wheezing and increased resistance to expiratory airflow because of varying degrees of smooth muscle contraction, edema of the mucosa, and mucus in the lumen of the bronchi and bronchioles. The stimuli vary widely and include antigens, infection, air pollutants, respiratory tract irritants, exercise, and emotional factors. This condition is completely different from distress breathing because of laryngotracheal spasm. One of its causes is the gastric content reflux through the pharynx to the larynx because of gastroesophageal reflux disease (GERD), in addition to the typical human avian flu that may cause immediate suffocation by laryngospasm owing to acute larygotrachitis. A patient suffered from GERD without esophageal symptoms, which was diagnosed and treated as bronchial asthma during his five emergency admissions. The admissions were because of episodic attacks of severe air hunger owing to an extreme throat tightening. The patient was being treated for as long as two years. After the correct diagnosis was made and treatment of laporascopic fundaplication was performed, the longstanding bronchial asthma , after all, completely disappeared. The concept of not asthma, but GERD seems undervalued, unappreciated, even misunderstood among patients with intractable asthma. Therefore, such a case is reported in detail, similar cases are mentioned briefly as well, and a mechanism responsible for GERD-originated larryngo- or laryngotracho-spasm is proposed.

关键词： resistance     mechanism responsible     unappreciated     responsiveness     different    

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Genetic and clinical markers for predicting treatment responsiveness in rheumatoid arthritis

Xin Wu, Xiaobao Sheng, Rong Sheng, Hongjuan Lu, Huji Xu

《医学前沿（英文）》 2019年 第13卷 第4期   页码 411-419 doi: 10.1007/s11684-018-0659-3

摘要： Although many drugs and therapeutic strategies have been developed for rheumatoid arthritis (RA) treatment, numerous patients with RA fail to respond to currently available agents. In this review, we provide an overview of the complexity of this autoimmune disease by showing the rapidly increasing number of genes associated with RA. We then systematically review various factors that have a predictive value (predictors) for the response to different drugs in RA treatment, especially recent advances. These predictors include but are certainly not limited to genetic variations, clinical factors, and demographic factors. However, no clinical application is currently available. This review also describes the challenges in treating patients with RA and the need for personalized medicine. At the end of this review, we discuss possible strategies to enhance the prediction of drug responsiveness in patients with RA.

关键词： rheumatoid arthritis     gene     clinical markers     therapy    

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Synthesis of MnFe

Jian LI,Yue JIAO,Caichao WAN

《农业科学与工程前沿（英文）》 2017年 第4卷 第1期   页码 116-120 doi: 10.15302/J-FASE-2017141

摘要： Cellulose aerogel, with abundant three-dimensional architecture, has been considered as a class of ideal eco-friendly matrix materials to encapsulate various nanoparticles for synthesis of miscellaneous functional materials. In the present paper, hexagonal single-crystalline MnFe O was fabricated and inserted into the cellulose aerogel using an chemical precipitation method. The as-prepared MnFe O nanoparticles were well dispersed and immobilized in the micro/nanoscale pore structure of the aerogel, and exhibited superparamagnetic behavior. In addition, the nanocomposite was easily actuated under the effect of an external magnetic field, revealing its strong magnetic responsiveness. Combined with the advantages of environmental benefits, facile synthesis method, strong magnetic responsiveness, and unique structural feature, this class of MnFe O /cellulose aerogel nanocomposite has possible uses for applications such as magnetically actuated adsorbents.

关键词： cellulose aerogel     MnFe2O4     magnetic responsiveness     nanocomposite    

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Reconfigurable manufacturing systems: Principles, design, and future trends

Yoram KOREN, Xi GU, Weihong GUO

《机械工程前沿（英文）》 2018年 第13卷 第2期   页码 121-136 doi: 10.1007/s11465-018-0483-0

摘要：

Reconfigurable manufacturing systems (RMSs), which possess the advantages of both dedicated serial lines and flexible manufacturing systems, were introduced in the mid-1990s to address the challenges initiated by globalization. The principal goal of an RMS is to enhance the responsiveness of manufacturing systems to unforeseen changes in product demand. RMSs are cost-effective because they boost productivity, and increase the lifetime of the manufacturing system. Because of the many streams in which a product may be produced on an RMS, maintaining product precision in an RMS is a challenge. But the experience with RMS in the last 20 years indicates that product quality can be definitely maintained by inserting in-line inspection stations. In this paper, we formulate the design and operational principles for RMSs, and provide a state-of-the-art review of the design and operations methodologies of RMSs according to these principles. Finally, we propose future research directions, and deliberate on how recent intelligent manufacturing technologies may advance the design and operations of RMSs.

关键词： reconfigurable manufacturing systems     responsiveness     intelligent manufacturing    

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An overview of the environmental finance policies in China: retrofitting an integrated mechanism forenvironmental management

LI Wei,HU Mengze

《环境科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 316-328 doi: 10.1007/s11783-014-0625-5

摘要： Considering the significant roles of the policies in developing environmental finance, an overview is conducted on the environmental finance policies (EFPs) in China. This paper analyzed the definition, scope, evolution and main instruments of EFPs. The implementation progress of financial activities on each instrument are investigated respectively. Then the experiences learned from and failures discovered in the development of the EFPs are discussed well recommendations for further improvement of the EFPs and their implementation are provided. Our study found that the EFPs have been established in China after a four-phase evolution since the early 1980s. The policies have played a critical role in leading to a rapid development in environmental finance by involving more financial instruments to accomplish the objective-led environmental plans. Driven by the policies, the new green credit (GC), green security (GS), and green insurance (GI) instruments have been phased in as supplements to the conventional command and control approaches to improve the environmental governance of financial activities and pollution sources. However, the market mechanism of financial institution is limited due to their defensive and incapable performance on implementation some of EFP instruments. To further strengthen the effectiveness of EFPs in facilitating environmental management, recommendations are made mainly on the aspects including developing more specific policy guidelines, enhancing information sharing and disclosure, providing sufficient economic incentives, establishing environmental liabilities with financial activities, and involving issues related to climate change, and biodiversity and ecosystem service.

关键词： environmental finance policy     integrated mechanism     phased evolution     implementation progress     financial institution     environmental management    

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Trends of environmental accidents and impact factors in China

Pengli XUE, Weihua ZENG

《环境科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 266-276 doi: 10.1007/s11783-010-0267-1

摘要： An overview of the spatial and temporal variations of the environmental accidents in China in recent years was presented in this paper using available data. The results showed that the frequency of pollution accidents was significantly decreased, from 3462 in 1990 to 462 in 2007. The water and air pollution accidents were found to be the dominant types, accounting for more than 80% of the total accidents. Considering the classification of environmental accidents at 4 scales, the general environmental accident, i.e., the least serious type, was the most frequent event, taking up 58.98% of the total pollution accidents. In addition, the distribution of environmental accidents was generally in accordance with the industrial layout in the country during the past decade. It is very important to note that the extraordinarily severe environmental accidents showed an increasing trend in underdeveloped regions, which was caused by the transfer and the development of heavy polluted industry in these areas. As to the losses of environmental accidents, the casualties presented an obvious reduction tendency, while the direct economic loss per accident tended to climb up. Furthermore, some key factors that affect the spatial and temporal tendencies of environmental accidents in China were discussed and some suggestions were put forward, hoping to shed light on environmental risk management and emergency plans making associated with environmental accidents in China.

关键词： environmental accidents     spatial and temporal trends     environmental risk    

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Why does environmental compliance cost more than penalty?—A legal analysis on environmental acts of enterprises in China

DONG Hongwei

《环境科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 434-442 doi: 10.1007/s11783-007-0069-2

摘要： In the environmental protection field of China, due to lower law-breaking cost but higher law-abiding cost , it is a common case that the enterprise chooses to break through the law on purpose. The punishment to the unlawful pr

关键词： law-abiding     punishment     environmental protection     law-breaking     enterprise    

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Analysis of the current situation of environmental policy of China and establishment of distributed environmental

Chaoyang FU,Wangfeng LI

《环境科学与工程前沿（英文）》 2015年 第9卷 第2期   页码 310-316 doi: 10.1007/s11783-014-0658-9

摘要： In this study, China’s current macro-environmental policies as well as their implementation and management tools are analyzed. By using the basic economic methodology, detailed studies are conducted focusing on the implementation effect of contemporary China’s typical environmental policy of the total pollutant discharge quantity control type, and also the two types of environmental management tools are compared from the perspective of implementation costs and policy uncertainty. By introduction of distributed management tools into the implementation of environmental policies, market-oriented means and the methods of economic analysis are introduced into environmental policy decision-making mechanisms, which could afford a new method for changing the current relatively low efficiency of environmental policy, solving the problem of “government failure” in environmental policy implementation, and providing a new way to make environmental policy system more flexible and more efficient. It is of great practical significance to solve China's current structural, complex and accumulative environmental problems.

关键词： environmental policy     distributed environment policy     distributed parameter model     lumped parameter model    

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Reducing environmental impacts through socioeconomic transitions: critical review and prospects

《环境科学与工程前沿（英文）》 2023年 第17卷 第2期 doi: 10.1007/s11783-023-1624-1

摘要：

● Reducing environmental impacts through socioeconomic structural transitions.

关键词： Environmental pressures     Environmental impacts     Nexus     Supply chains     Trade     Coupled systems    

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Hydrogel photocatalysts for efficient energy conversion and environmental treatment

《能源前沿（英文）》 2021年 第15卷 第3期   页码 577-595 doi: 10.1007/s11708-021-0756-x

摘要： Photocatalysts have attracted great research interest owing to their excellent properties and potential for simultaneously addressing challenges related to energy needs and environmental pollution. Photocatalytic particles need to be in contact with their respective media to exhibit efficient photocatalytic performances. However, it is difficult to separate nanometer-sized photocatalytic materials from reaction media later, which may lead to secondary pollution and a poor recycling performance. Hydrogel photocatalysts with a three-dimensional (3D) network structures are promising support materials for photocatalysts based on features such as high specific surface areas and adsorption capacities and good environmental compatibility. In this review, hydrogel photocatalysts are classified into two different categories depending on their elemental composition and recent progresses in the methods for preparing hydrogel photocatalysts are summarized. Moreover, current applications of hydrogel photocatalysts in energy conversion and environmental remediation are reviewed. Furthermore, a comprehensive outlook and highlight future challenges in the development of hydrogel photocatalysts are presented.

关键词： hydrogel     photocatalysts     energy conversion     environmental treatment    

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Synthesis of novel magneto-hybrid polyoxometalate composite membrane with simultaneous photocatalytic self-cleaning and antifouling functionalities

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1450-1459 doi: 10.1007/s11705-023-2310-3

摘要： Membrane technology is ideal for removing aqueous humic acid, but humic acid deposits cause membrane fouling, a significant challenge that limits its application. Herein, this work proposed an alternative approach to the controllably magnetically induced magneto-hybrid polyoxometalate (magneto-HPOM) nanocomposite migration toward the polyethersulfone (PES) membrane surface under a magnetic field to enhance the self-cleaning and antifouling functionalities of the membrane. Before incorporating magneto-HPOM nanocomposite into the PES casting solution, functionalized magnetite nanoparticles (F-MNP) were first coated with HPOM photocatalyst to fabricate a magneto-HPOM-PES membrane. It was shown that the apparent impacts of this novel magneto-HPOM-PES membrane on the hydrophilic behavior and photocatalytic properties of the magneto-HPOM nanocomposite improve the hydrophilicity, separation performance, antifouling and self-cleaning properties of the membrane compared with neat PES membrane. Furthermore, after exposure to ultraviolet light, the magneto-HPOM-PES membrane can be recovered after three cycles with a flux recovery ratio of 107.95%, 100.06%, and 95.56%, which is attributed to the temporal super hydrophilicity effect. Meanwhile, the magneto-HPOM-PES membrane could efficiently maintain 100% humic acid rejection for the first and second cycles and 99.81% for the third cycle. This study revealed a novel approach to fabricating membranes with high antifouling and self-cleaning properties for water treatment.

关键词： magneto-hybrid polyoxometalate nanocomposite     composite membrane     antifouling     self-cleaning     magnetic and photocatalytic responsiveness    

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NewIndustrial Revolution and Environmental Protection

Qian Yi

《工程管理前沿（英文）》 2014年 第1卷 第1期   页码 71-75 doi: 10.15302/J-FEM-2014011

摘要： Serious environmental problems have appeared in China since the rapid economic growth 30 years ago, which affect human's health and become a limiting factor for further development. It has brought about the rethinking of traditional ways for economy development and environmental protection, and realized that the change in the model of development and environment protection is of significance. A new industrial revolution is needed for protecting the environment and promoting sustainable development. This paper discusses the characteristics of the new industrial revolution for sustainable development including cleaner production, circular economy, and industrial ecology. Lessons from China and abroad will be introduced to prove that new strategies for environment protection and economic development are needed.

关键词： industrial ecology     new industrial revolution     environmental protection     cleaner production     circular economy    

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Addressing the environmental risk of persistent organic pollutants in China

Bin WANG, Jun HUANG, Shubo DENG, Xiaoling YANG, Gang YU

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 2-16 doi: 10.1007/s11783-011-0370-y

摘要： The Stockholm Convention on persistent organic pollutants (POPs) was adopted in 2001. This year is the 10th anniversary of the adoption of the Convention. Until now, 22 chemicals or chemical categories have been listed as POPs in the Stockholm Convention. The POPs Research Center was established in Tsinghua University in the same year when the Convention was adopted. In the last ten years, much work has been done by Chinese researchers to understand the environmental risk of POPs in China. This article aims to review the recent research progress of our POPs Research Center and some other Chinese researchers’ studies in addressing the environmental risk of POPs, including the priority screening and inventory study of POPs, monitoring and modeling of POPs pollution and exposure, and environmental risk assessment and modeling of POPs. Although great advances in addressing the environmental risk of POPs have been made in recent years, we are still facing quite a few problems, such as data scarcity and uncertainty in environmental risk assessment of POPs. The study on the effect of POPs mixtures is in its infancy and currently POPs are usually assessed from legal perspective by risk assessment of single chemicals. These problems should be well addressed by further efforts. Further studies should also be taken in future to study environment risk of POPs by considering aspects of coupled dynamics between climate processes and POPs. Such sound scientific, risk-based information can support decision-making aiming to effectively minimize the risk level of POPs.

关键词： persistent organic pollutant (POPs)     environmental risk assessment     inventory     environmental monitoring     fugacity model     emerging POPs    

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Insight of chemical environmental risk and its management from the vinyl chloride accident

《环境科学与工程前沿（英文）》 2023年 第17卷 第4期 doi: 10.1007/s11783-023-1652-x

摘要： The combustion of vinyl chloride (VC) after the train derailment accident in Ohio, USA in February, 2023 has caused widespread concern around the world. This paper tried to analyze several issues concerning the accident, including the appropriateness of the VC combustion in the emergency response in this accident, the meanings of so-called “controlled combustion”, the potential environmental risks caused by VC and combustion by-products, and follow-up work. In our view, this accident had surely caused environmental and health risks to some extent. Hence, a comprehensive environmental risk assessment is necessary, and then the site with risk should be comprehensively remediated, hazardous waste should be harmlessly treated as soon as possible. Finally, this accident suggests that further efforts should be taken to bridge the gap between chemical safety management and their environmental risk management.

关键词： Vinyl chloride     Combustion     Chemical safety management     Environmental risk     Emerging contaminants    

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标题 作者 时间 类型 操作

Preparation and swelling properties of a starch-g-poly(acrylic acid)/organo-mordenite hydrogel composite

Yan Zhang,Pingqiang Gao,Lin Zhao,Yizhong Chen

期刊论文

Not asthma, but GERD: case report

WANG Zhonggao

期刊论文

Genetic and clinical markers for predicting treatment responsiveness in rheumatoid arthritis

Xin Wu, Xiaobao Sheng, Rong Sheng, Hongjuan Lu, Huji Xu

期刊论文

Synthesis of MnFe

Jian LI,Yue JIAO,Caichao WAN

期刊论文

Reconfigurable manufacturing systems: Principles, design, and future trends

Yoram KOREN, Xi GU, Weihong GUO

期刊论文

An overview of the environmental finance policies in China: retrofitting an integrated mechanism forenvironmental management

LI Wei,HU Mengze

期刊论文

Trends of environmental accidents and impact factors in China

Pengli XUE, Weihua ZENG

期刊论文

Why does environmental compliance cost more than penalty?—A legal analysis on environmental acts of enterprises in China

DONG Hongwei

期刊论文

Analysis of the current situation of environmental policy of China and establishment of distributed environmental

Chaoyang FU,Wangfeng LI

期刊论文

Reducing environmental impacts through socioeconomic transitions: critical review and prospects

期刊论文

Hydrogel photocatalysts for efficient energy conversion and environmental treatment

期刊论文

Synthesis of novel magneto-hybrid polyoxometalate composite membrane with simultaneous photocatalytic self-cleaning and antifouling functionalities

期刊论文

NewIndustrial Revolution and Environmental Protection

Qian Yi

期刊论文

Addressing the environmental risk of persistent organic pollutants in China

Bin WANG, Jun HUANG, Shubo DENG, Xiaoling YANG, Gang YU

期刊论文

Insight of chemical environmental risk and its management from the vinyl chloride accident

期刊论文