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Engineering >> 2023, Volume 30, Issue 11 doi: 10.1016/j.eng.2023.02.018

Targeted Catalytic Cracking to Olefins (TCO): Reaction Mechanism, Production Scheme, and Process Perspectives

a Research Institute of Petroleum Processing, Sinopec, Beijing 100083, China
b Economics and Development Research Institute, Sinopec, Beijing 100029, China
c State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, National Center for Magnetic Resonance in Wuhan, Key Laboratory of Magnetic Resonance in Biological Systems, Wuhan Institute of Physics and Mathematics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan 430071, China

Received: 2022-10-15 Revised: 2022-12-31 Accepted: 2023-02-26 Available online: 2023-07-26

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Abstract

Light olefins are important organic building blocks in the chemicals industry. The main low-carbon olefin production methods, such as catalytic cracking and steam cracking, have considerable room for improvement in their utilization of hydrocarbons. This article provides a thorough overview of recent studies on catalytic cracking, steam cracking, and the conversion of crude oil processes. To maximize the production of light olefins and reduce carbon emissions, the perceived benefits of various technologies are examined. Taking olefin generation and conversion as a link to expand upstream and downstream processes, a targeted catalytic cracking to olefins (TCO) process is proposed to meet current demands for the transformation of oil refining into chemical production. The main innovations of this process include a multiple feedstock supply, the development of medium-sized catalysts, and a diameter-transformed fluidized-bed reactor with different feeding schemes. In combination with other chemical processes, TCO is expected to play a critical role in enabling petroleum refining and chemical processes to achieve low carbon dioxide emissions.

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