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Preparation and influence of performance of anodic catalysts for direct methanol fuel cell

WANG Zhenbo, YIN Geping, SHI Pengfei

Frontiers of Chemical Science and Engineering 2007, Volume 1, Issue 1,   Pages 20-25 doi: 10.1007/s11705-007-0005-9

Abstract: This research aims at increasing the utilization of platinum-ruthenium alloy (Pt-Ru) catalysts and thusThe structure of the catalyst was modified, and there was an increase in the conversion of ruthenium

Keywords: catalyst prepared     stability     ascension     potentiostatic polarization     platinum-ruthenium    

Platinum on nitrogen doped graphene and tungsten carbide supports for ammonia electro-oxidation reaction

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 6,   Pages 930-938 doi: 10.1007/s11705-021-2130-2

Abstract: Platinum has been established as the best electrocatalyst for ammonia oxidation in aqueous alkaline media

Keywords: Ammonia electro-oxidation reaction     electrocatalyst supports     platinum     nitrogen doped graphene     tungsten    

Study on the growth of platinum nanowires as cathode catalysts in proton exchange membrane fuel cells

Ruiqing Wang, Xiaolan Cao, Sheng Sui, Bing Li, Qingfeng Li

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 3,   Pages 364-375 doi: 10.1007/s11705-021-2052-z

Abstract: The platinum nanowires have been verified to be a promising catalyst to promote the performance of proton

Keywords: Pt nanowires     morphology     structure control     in situ growth mechanism     proton exchange membrane fuel cells    

Hydro-pyrolysis of lignocellulosic biomass over alumina supported Platinum, Mo

Songbo He, Jeffrey Boom, Rolf van der Gaast, K. Seshan

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 155-161 doi: 10.1007/s11705-017-1655-x

Abstract: In-line hydro-treatment of bio-oil vapor from fast pyrolysis of lignocellulosic biomass (hydro-pyrolysis of biomass) is studied as a method of upgrading the liquefied bio-oil for a possible precursor to green fuels. The nobel metal (Pt) and non-noble metal catalysts (Mo C and WC) were compared at 500 °C and atmospheric pressure which are same as the reaction conditions for fast pyrolysis of biomass. Results indicated that under the pyrolysis conditions, the major components, such as acids and carbonyls, of the fast pyrolysis bio-oil can be completely and partially hydrogenated to form hydrocarbons, an ideal fossil fuel blend, in the hydro-treated bio-oil. The carbide catalysts perform equally well as the Pt catalyst regarding to the aliphatic and aromatic hydrocarbon formation (ca. 60%), showing the feasibility of using the cheap non-noble catalysts for hydro-pyrolysis of biomass.

Keywords: bio-oil     pyrolysis     hydro-deoxygenation (HDO)     non-noble metal catalysts     hydro-treatment    

Oxygen reduction electrocatalysis: From conventional to single-atomic platinum-based catalysts for proton

Frontiers in Energy doi: 10.1007/s11708-023-0907-3

Abstract: Platinum (Pt)-based materials are still the most efficient and practical catalysts to drive the sluggish

Keywords: oxygen reduction electrocatalysis     Pt single-atom catalysts     conventional Pt-based catalysts     design thoughts and synthesis     metal-support interactions    

Synthesis and electrocatalytic property of cubic and spherical nanoparticles of cobalt platinum alloys

Xiaowei TENG, Hong YANG,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 1,   Pages 45-51 doi: 10.1007/s11705-009-0308-0

Abstract: Both cubic and spherical CoPt nanoparticles were made using cobalt carbonyl and platinum 2,4-pentanedionateformation of different shapes of CoPt particles could be attributed to the affinity between cobalt and platinum

Keywords: spherical     2     4-pentanedionate     adamantanecarboxylic     acetylacetonate     electrocatalytic    

Light olefins synthesis from С

Anton SHALYGIN, Evgenii PAUKSHTIS, Evgenii KOVALYOV, Bair BAL’ZHINIMAEV

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 3,   Pages 279-288 doi: 10.1007/s11705-013-1338-1

Abstract: A two-step process was employed to convert methane or ethane to light olefins via the formation of an intermediate monoalkyl halide. A novel K RuOCl /TiO catalyst was tested for the oxidative chlorination of methane and ethane. The catalyst had high selectivity for methyl and ethyl chlorides, 80% and 90%, respectively. During the oxychlorination of ethane at ≥250°C, the formation of ethylene as a reaction product along with ethyl chloride was observed. In situ Fourier transform infrared studies showed that the key intermediate for monoalkyl chloride and ethylene formation is the alkoxy group. The reaction mechanism for the oxidative chlorination of methane and ethane over the Ru-oxychloride catalyst was proposed. The novel fiber glass catalyst was also tested for the dehydrochlorination of alkyl chlorides to ethylene and propylene. Very high selectivities (up to 94%–98%) for ethylene and propylene formation as well as high stability were demonstrated.

Keywords: oxychlorination     methane     ethane     light olefins     ruthenium catalyst    

Bevacizumab in combination with pemetrexed and platinum for elderly patients with advanced non-squamous

Frontiers of Medicine 2022, Volume 16, Issue 4,   Pages 610-617 doi: 10.1007/s11684-021-0827-8

Abstract: were included in the present retrospective study, 22 patients in the bevacizumab plus pemetrexed and platinum(B+PP) group, and 37 patients in the pemetrexed and platinum (PP) group.

Keywords: bevacizumab     elderly patient     advanced non-small-cell lung cancer     overall survival     toxicity    

Toward a Platinum Society: Challenges for Engineering Science

Hiroshi Komiyama

Engineering 2015, Volume 1, Issue 1,   Pages 18-20 doi: 10.15302/J-ENG-2015019

Catalytic reduction of water pollutants: knowledge gaps, lessons learned, and new opportunities

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 2, doi: 10.1007/s11783-023-1626-z

Abstract:

● Advances, challenges, and opportunities for catalytic water pollutant reduction.

Keywords: Molybdenum     Rhenium     Rhodium     Ruthenium     Catalyst Support     Bromate    

Catalytic ozonation of organic compounds in water over the catalyst of RuO

Jianbing WANG,Guoqing WANG,Chunli YANG,Shaoxia YANG,Qing HUANG

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 4,   Pages 615-624 doi: 10.1007/s11783-014-0706-5

Abstract: This research investigates the performances of RuO /ZrO -CeO in catalytic ozonation for water treatment. The results show that RuO /ZrO -CeO was active for the catalytic ozonation of oxalic acid and possessed higher stability than RuO /Al O and Ru/AC. In the catalytic ozonation of dimethyl phthalate (DMP), RuO /ZrO -CeO did not enhance the DMP degradation rate but significantly improved the total organic carbon (TOC) removal rate. The TOC removal in catalytic ozonation was 56% more than that in noncatalytic ozonation. However this does not mean the catalyst was very active because the contribution of catalysis to the overall TOC removal was only 30%. The adsorption of the intermediates on RuO /ZrO -CeO played an important role on the overall TOC removal while the adsorption of DMP on it was negligible. This adsorption difference was due to their different ozonation rates. In the catalytic ozonation of disinfection byproduct precursors with RuO /ZrO -CeO , the reductions of the haloacetic acid and trihalomethane formation potentials (HAAFPs and THMFPs) for the natural water samples were 38%–57% and 50%–64%, respectively. The catalyst significantly promoted the reduction of HAAFPs but insignificantly improved the reduction of THMFPs as ozone reacts fast with the THMs precursors. These results illustrate the good promise of RuO /ZrO -CeO in catalytic ozonation for water treatment.

Keywords: ozonation     ruthenium     oxalic acid     dimethyl phthalate     disinfection byproduct    

Recent advances in cathode electrocatalysts for PEM fuel cells

Junliang ZHANG

Frontiers in Energy 2011, Volume 5, Issue 2,   Pages 137-148 doi: 10.1007/s11708-011-0153-y

Abstract: This review article is focused on recent advances made in the kinetic-activity improvement on platinum

Keywords: proton exchange membrane fuel cells (PEMFCs)     cathode electrocatalysts     platinum     oxygen reduction reaction    

Concentrations of anthropogenic Pt and Pd in urban roadside soils in Xuzhou, China

WANG Xuesong, SUN Cheng

Frontiers of Environmental Science & Engineering 2008, Volume 2, Issue 4,   Pages 475-479 doi: 10.1007/s11783-008-0071-3

Abstract: The potential accumulation of platinum group elements (PGE) in the environment from automobile catalysts

Keywords: platinum     detailed     different     Hierarchical     automobile catalytic    

Fabrication of ionic polymer-metal composites (IPMCs) and robot design

Hanmin PENG, Qingjun Ding, Huafeng LI

Frontiers of Mechanical Engineering 2009, Volume 4, Issue 3,   Pages 332-338 doi: 10.1007/s11465-009-0046-5

Abstract: This paper describes a method for preliminary manufacturing experiments on a type of smart materials—ionic polymer-metal composites (IPMCs). They belong to EAP materials and are famous for their capability of huge displacement within a low voltage (1–3 V). With best operation quality in the humid environment, they can be made as underwater robots in simple structures. In this paper, two purposes are embodied. One focuses on the research on the IPMCs characteristics, including the actuating principle, manufacturing process, and parameters of performance. The other is that a relevant robot driven by IPMCs strips is designed. According to imitation propulsion mechanism of undulatory fins, IPMCs are designed for a novel bionic water vehicle propelled by undulatory multiple fish-like fins (made by IPMCs). The robot consists of three fins on the bottom tightly contacting by plastic foils with each other.

Keywords: ionic polymer-metal composites (IPMCs)     artificial muscles     actuator     bionic robot     platinum-plated    

A review of Pt-based electrocatalysts for oxygen reduction reaction

Changlin ZHANG, Xiaochen SHEN, Yanbo PAN, Zhenmeng PENG

Frontiers in Energy 2017, Volume 11, Issue 3,   Pages 268-285 doi: 10.1007/s11708-017-0466-6

Abstract: Development of active and durable electrocatalyst for oxygen reduction reaction (ORR) remains one challenge for the polymer electrolyte membrane fuel cell (PEMFC) technology. Pt-based nanomaterials show the greatest promise as electrocatalyst for this reaction among all current catalytic structures. This review focuses on Pt-based ORR catalyst material development and covers the past achievements, current research status and perspectives in this research field. In particular, several important categories of Pt-based catalytic structures and the research advances are summarized. Key factors affecting the catalyst activity and durability are discussed. An outlook of future research direction of ORR catalyst research is provided.

Keywords: oxygen reduction reaction (ORR)     electrocatalysis     platinum catalyst     activity     durability    

Title Author Date Type Operation

Preparation and influence of performance of anodic catalysts for direct methanol fuel cell

WANG Zhenbo, YIN Geping, SHI Pengfei

Journal Article

Platinum on nitrogen doped graphene and tungsten carbide supports for ammonia electro-oxidation reaction

Journal Article

Study on the growth of platinum nanowires as cathode catalysts in proton exchange membrane fuel cells

Ruiqing Wang, Xiaolan Cao, Sheng Sui, Bing Li, Qingfeng Li

Journal Article

Hydro-pyrolysis of lignocellulosic biomass over alumina supported Platinum, Mo

Songbo He, Jeffrey Boom, Rolf van der Gaast, K. Seshan

Journal Article

Oxygen reduction electrocatalysis: From conventional to single-atomic platinum-based catalysts for proton

Journal Article

Synthesis and electrocatalytic property of cubic and spherical nanoparticles of cobalt platinum alloys

Xiaowei TENG, Hong YANG,

Journal Article

Light olefins synthesis from С

Anton SHALYGIN, Evgenii PAUKSHTIS, Evgenii KOVALYOV, Bair BAL’ZHINIMAEV

Journal Article

Bevacizumab in combination with pemetrexed and platinum for elderly patients with advanced non-squamous

Journal Article

Toward a Platinum Society: Challenges for Engineering Science

Hiroshi Komiyama

Journal Article

Catalytic reduction of water pollutants: knowledge gaps, lessons learned, and new opportunities

Journal Article

Catalytic ozonation of organic compounds in water over the catalyst of RuO

Jianbing WANG,Guoqing WANG,Chunli YANG,Shaoxia YANG,Qing HUANG

Journal Article

Recent advances in cathode electrocatalysts for PEM fuel cells

Junliang ZHANG

Journal Article

Concentrations of anthropogenic Pt and Pd in urban roadside soils in Xuzhou, China

WANG Xuesong, SUN Cheng

Journal Article

Fabrication of ionic polymer-metal composites (IPMCs) and robot design

Hanmin PENG, Qingjun Ding, Huafeng LI

Journal Article

A review of Pt-based electrocatalysts for oxygen reduction reaction

Changlin ZHANG, Xiaochen SHEN, Yanbo PAN, Zhenmeng PENG

Journal Article