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Vanadium(IV) solvent extraction enhancement in high acidity using di-(2-ethylhexyl)phosphoric acid with

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 1,   Pages 56-67 doi: 10.1007/s11705-022-2185-8

Abstract: Under the conditions of pH 0.8, di-(2-ethylhexyl)phosphoric acid concentration of 20%, phase ratio of1:2, and extraction time of 8 min, the vanadium extraction could reach 80.00%.Among Cl−–V, SO42−–V, and H2O–V, the V–Cl bond is longerTherefore, VO2+ gets easily desorbed with chloride ions and enter the organic phase.At the same time, the hydrogen ions of di-(2-ethylhexyl)phosphoric acid also enter the water phase more

Keywords： vanadium     black shale     solvent extraction     high acidity extraction    

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Selective removal of iron(III) from highly salted chloride acidic solutions by solvent extraction using di(2-ethylhexylethylhexyl) phosphate

Guoping Hu, Yue Wu, Desheng Chen, Yong Wang, Tao Qi, Lina Wang

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 3,   Pages 528-537 doi: 10.1007/s11705-020-1955-4

Abstract: Di(2-ethylhexyl)phosphate acid (D2EHPA) showed high extraction rate and selectivity of Fe over otherThe enthalpy for the extraction of Fe using D2EHPA was 19.50 kJ/mol.

Keywords： solvent extraction     iron     di(2-ethylhexyl)phosphate acid     separation    

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microextraction approach for rapid extraction and separation of Mn(II) and Co(II) using saponified D2EHPA

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 6,   Pages 963-972 doi: 10.1007/s11705-021-2081-7

Abstract: sulfate solution simulating leachate of spent lithium-ion battery cathode materials using saponified di-(2-ethylhexylethylhexyl)phosphoric acid system.

Keywords： extraction equilibrium     mass transfer coefficient     microextraction     multicomponent extraction     di-(2-ethylhexylethylhexyl)phosphoric acid    

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Phytotoxicity in seven higher plant species exposed to di-

Tingting MA,Ying TENG,Peter CHRISTIE,Yongming LUO

Frontiers of Environmental Science & Engineering 2015, Volume 9, Issue 2,   Pages 259-268 doi: 10.1007/s11783-014-0652-2

Abstract: species exposed to a range of concentrations (0– 500 mg·kg soil) of di- -butyl phthalate (DnBP) or bis (2-ethylhexylethylhexyl) phthalate (DEHP), two representative phthalate esters (PAEs) nominated by USEPA as priority

Keywords： phytotoxicity     di-n-butyl phthalate     bis(2-ethylhexyl) phthalate     malondialdehyde     plant pigments    

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Estrogenic activities of di-2-ethylhexyl phthalate

JIN Qiumei, LI Yan, SUN Zengrong

Frontiers of Medicine 2008, Volume 2, Issue 3,   Pages 303-308 doi: 10.1007/s11684-008-0058-2

Abstract: Particularly, di-2-ethylhexyl phthalate (DEHP) has been shown to cause reproductive and developmentalDi-2-ethylhexyl phthalate enhanced the proliferation of human breast cancer MCF-7 cells and might demonstrate
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Preparation and photocatalytic kinetics of nano-ZnO powders by precipitation stripping process

ZHANG Dongxiang, XUE Min, XU Hang, XU Wenguo, TARASOV V

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 3,   Pages 319-324 doi: 10.1007/s11705-008-0051-y

Abstract: Ultra-fine zinc oxalate powders were prepared through a precipitation stripping method with bis(2-ethylhexyl

Keywords： 2-ethylhexyl     micro-multipore     Photo-Layer     hexagonal     methylene    

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Improvement in the synthesis of 2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl

GAO Shihao, SUN Chenghui, ZHAO Xinqi, GAO Changquan

Frontiers of Chemical Science and Engineering 2008, Volume 2, Issue 1,   Pages 80-84 doi: 10.1007/s11705-008-0017-0

Abstract: 2-(5-Amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl thioester(III), an importantintermediate of the fourth generation cephalosporins, was efficiently synthesized by reacting 2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid (I) with 2,2′-dibenzothiazole disulfide (II) in

Keywords： 5-Amino-1     2     4-thiadiazol-3-yl     1     2-dichloroethane     important intermediate     2-benzothiazolyl thioester     temperature    

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Effect of TiO 2 loading on the activity of V/TiO 2 -Al 2 O 3 in the catalytic oxidehydrogenation of ethylbenzene

Xiaohong LI, Wenying LI,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 2,   Pages 142-146 doi: 10.1007/s11705-009-0233-2

Abstract: TiO-AlOmixed oxides with different compositions ranging from 40wt-% to 95wt-% of TiO were prepared by sol-gel method and impregnated with different amounts of VO. Supports and catalysts were characterized by X-ray diffraction (XRD), physisorption, temperature preprogrammed reduction (H-TPR), and ammonia temperature programmed desorption (NH-TPD). TiO content in the support had obvious effect on the crystal structure, texture characteristic, acid property, and catalytic activity in dehydrogenation of ethylbenzene (EB) with carbon dioxide. The highest catalytic activity was acquired when the TiO content was 50 wt-%.

Keywords： desorption     different     TiO-AlOmixed     physisorption     ethylbenzene    

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Al2O3 and CeO2-promoted MgO sorbents for CO2 capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 1,   Pages 83-93 doi: 10.1007/s11705-017-1691-6

Abstract: A series of Al O and CeO modified MgO sorbents was prepared and studied for CO sorption at moderate temperatures. The CO sorption capacity of MgO was enhanced with the addition of either Al O or CeO . Over Al O -MgO sorbents, the best capacity of 24.6 mg-CO /g-sorbent was attained at 100 °C, which was 61% higher than that of MgO (15.3 mg-CO /g-sorbent). The highest capacity of 35.3 mg-CO /g-sorbent was obtained over the CeO -MgO sorbents at the optimal temperature of 200 °C. Combining with the characterization results, we conclude that the promotion effect on CO sorption with the addition of Al O and CeO can be attributed to the increased surface area with reduced MgO crystallite size. Moreover, the addition of CeO increased the basicity of MgO phase, resulting in more increase in the CO capacity than Al O promoter. Both the Al O -MgO and CeO -MgO sorbents exhibited better cyclic stability than MgO over the course of fifteen CO sorption-desorption cycles. Compared to Al O , CeO is more effective for promoting the CO capacity of MgO. To enhance the CO capacity of MgO sorbent, increasing the basicity is more effective than the increase in the surface area.

Keywords： CO2 capture     MgO sorbents     Al2O3     CeO2     flue gas    

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A Storage-Driven CO2 EOR for a Net-Zero Emission Target Article

Yueliang Liu, Zhenhua Rui

Engineering 2022, Volume 18, Issue 11,   Pages 79-87 doi: 10.1016/j.eng.2022.02.010

Abstract: >2 emissions by storing CO2 in oil reservoirs.CO2 EOR—whose main target is to realize net-zero or even negative CO2 emissionsStorage-driven CO2 EOR is superior to conventional CO2 EOR in improving sweepingthan conventional CO2 EOR.Moreover, the amount of sequestrated CO2 in storage-driven CO2 EOR exceeds the amount

Keywords： CO2     EOR     Net CO2     emissions     Dimethyl ether     Storage-driven CO2     EOR     CO2     sequestration    

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The stabilization effect of Al2O3 on unconventional Pb/SiO2 catalyst

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1423-1429 doi: 10.1007/s11705-023-2315-y

Abstract: To enhance the stability, the traditional carrier Al2O3 with a small amount, wasintroduced into Pb/SiO2 catalyst in this study.It has been proved that Al2O3 can inhibit the reduction of PbO, and weaken theAs a result, 3Al15Pb/SiO2 catalyst exhibits a much higher stability up to more than 150 h.addition, a simple schematic diagram of the change of surface species on the catalyst surface after Al2<

Keywords： Pb/SiO2     Al2O3     propane dehydrogenation     propene     stability    

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Biodegradation of 2-methylisoborneol by bacteria enriched from biological activated carbon

Rongfang YUAN, Beihai ZHOU, Chunhong SHI, Liying YU, Chunlei ZHANG, Junnong GU

Frontiers of Environmental Science & Engineering 2012, Volume 6, Issue 5,   Pages 701-710 doi: 10.1007/s11783-011-0367-6

Abstract: One of the most common taste and odour compounds (TOCs) in drinking water is 2-methylisoborneol (2-MIBFour bacterial strains for degrading 2-MIB were isolated from the surface of a biological activated carbonThe removal efficiencies of 2-MIB with initial concentrations of 515 ng·L were 98.4%, 96.3%, 95.0%,The kinetic model showed that biodegradation of 2-MIB at an initial dose of 4.2 mg·L was a pseudo-first-orderThese degraders decomposed 2-MIB to form 2-methylenebornane and 2-methyl-2-bornane as the products.

Keywords： 2-methylisoborneol (2-MIB)     biodegradation     2-methylenebornane     2-methyl-2-bornane     pseudo-first-order reaction    

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Encapsulation of 2-amino-2-methyl-1-propanol with tetraethyl orthosilicate for CO2 capture

Sidra Rama, Yan Zhang, Fideline Tchuenbou-Magaia, Yulong Ding, Yongliang Li

Frontiers of Chemical Science and Engineering 2019, Volume 13, Issue 4,   Pages 672-683 doi: 10.1007/s11705-019-1856-6

Abstract: The conventional emulsion technique was selected for the microcapsule formulation by using 2-amino-2-

Keywords： carbon capture     microencapsulated sorbents     emulsion technique     low temperature adsorption and absorption    

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Cu-doped Bi/Bi2WO6 catalysts for efficient N2 fixation by photocatalysis

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1412-1422 doi: 10.1007/s11705-023-2312-1

Abstract: In this paper, Cu-doped Bi2WO6 was synthesized via a solvothermal method and appliedit in photocatalytic N2 immobilization.metallic Bi in the photocatalyst, indicating that the synthesized photocatalyst is actually Bi/Cu-Bi22 and most likely substituted the position of Bi3+.Cu did not affect the metallic Bi content, but mainly influenced the energy band structure of Bi2<

Keywords： Bi2WO6     Cu doping     work function     photocatalytic N2 fixation     charge    

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Fenton oxidation of 2,4- and 2,6-dinitrotoluene and acetone inhibition

HE Yiliang, ZHAO Bin, HUGHES Joseph B., HAN Sung Soo

Frontiers of Environmental Science & Engineering 2008, Volume 2, Issue 3,   Pages 326-332 doi: 10.1007/s11783-008-0038-4

Abstract: The performances and kinetic parameters of Fenton oxidation of 2,4- and 2,6-dinitrotoluene (DNT) in water-acetone- and 2,6-DNT.- and 2,6-DNT completely, mainly due to the competition of hydroxyl radicals.Fenton oxidation of 2,4- and 2,6-DNT fit well with the first-order kinetics and the presence of acetone-DNT primary degradation was proposed: 2,4-DNT → 2,4-dinitro-benzaldehyde → 2,4-dinitrobenzoic acid →

Keywords： presence     2     4-DNT     competition     laboratory     scavenger    

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Title Author Date Type Operation

Vanadium(IV) solvent extraction enhancement in high acidity using di-(2-ethylhexyl)phosphoric acid with

Journal Article

Selective removal of iron(III) from highly salted chloride acidic solutions by solvent extraction using di(2-ethylhexylethylhexyl) phosphate

Guoping Hu, Yue Wu, Desheng Chen, Yong Wang, Tao Qi, Lina Wang

Journal Article

microextraction approach for rapid extraction and separation of Mn(II) and Co(II) using saponified D2EHPA

Journal Article

Phytotoxicity in seven higher plant species exposed to di-

Tingting MA,Ying TENG,Peter CHRISTIE,Yongming LUO

Journal Article

Estrogenic activities of di-2-ethylhexyl phthalate

JIN Qiumei, LI Yan, SUN Zengrong

Journal Article

Preparation and photocatalytic kinetics of nano-ZnO powders by precipitation stripping process

ZHANG Dongxiang, XUE Min, XU Hang, XU Wenguo, TARASOV V

Journal Article

Improvement in the synthesis of 2-(5-amino-1,2,4-thiadiazol-3-yl)-2-(Z)-methoxyiminoacetic acid 2-benzothiazolyl

GAO Shihao, SUN Chenghui, ZHAO Xinqi, GAO Changquan

Journal Article

Effect of TiO 2 loading on the activity of V/TiO 2 -Al 2 O 3 in the catalytic oxidehydrogenation of ethylbenzene

Xiaohong LI, Wenying LI,

Journal Article

Al2O3 and CeO2-promoted MgO sorbents for CO2 capture at moderate

Huimei Yu, Xiaoxing Wang, Zhu Shu, Mamoru Fujii, Chunshan Song

Journal Article

A Storage-Driven CO2 EOR for a Net-Zero Emission Target

Yueliang Liu, Zhenhua Rui

Journal Article

The stabilization effect of Al2O3 on unconventional Pb/SiO2 catalyst

Journal Article

Biodegradation of 2-methylisoborneol by bacteria enriched from biological activated carbon

Rongfang YUAN, Beihai ZHOU, Chunhong SHI, Liying YU, Chunlei ZHANG, Junnong GU

Journal Article

Encapsulation of 2-amino-2-methyl-1-propanol with tetraethyl orthosilicate for CO2 capture

Sidra Rama, Yan Zhang, Fideline Tchuenbou-Magaia, Yulong Ding, Yongliang Li

Journal Article

Cu-doped Bi/Bi2WO6 catalysts for efficient N2 fixation by photocatalysis

Journal Article

Fenton oxidation of 2,4- and 2,6-dinitrotoluene and acetone inhibition

HE Yiliang, ZHAO Bin, HUGHES Joseph B., HAN Sung Soo

Journal Article