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磁控溅射法生长的可调(GaxIn1x)2O3 Research Articles

张法碧1,孙巾寓1,李海鸥1,周娟1,王荣1,孙堂友1,傅涛1,肖功利1,李琦1,刘兴鹏1,张秀云1,郭道友2,王相虎3,秦祖军1

《信息与电子工程前沿(英文)》 2021年 第22卷 第10期   页码 1370-1378 doi: 10.1631/FITEE.2000330

摘要: 采用磁控溅射技术和热退火技术在(0001)蓝宝石衬底上制备了多组分氧化物(GaxIn1x)2O3薄膜,实现可调。详细研究了三元化合物(GaxIn1x)2O3在整个组成范围内的光学性质和能带结构演化。X射线衍射谱表明,Ga含量在0.11至0.55之间的(GaxIn1x)2O3薄膜既有立方结构,也有单斜结构,而Ga含量高于0.74的(GaxIn1x)2O3薄膜只有单斜结构。在可见光范围,所有薄膜透光率均高于86%,吸收边清晰,条纹清晰。此外,随着Ga含量增加,紫外吸收边出现380至250 nm的蓝移,表明禁能从3.61 eV增加至4.64 eV。实验结果为透明导电化合物半导体(GaxIn1x)2O3薄膜在光电和光伏行业的应用,特别是在显示器、发光二极管和太阳能电池的应用奠定了基础。

关键词: (GaxIn1x)2O3薄膜可调磁控溅射    

基于拓扑绝缘体Sb2Te3的52 nm宽谱可调被动调Q掺镱光纤激光器 Research

王涛1,俞强1,2,郭琨1,史鑫尧2,阚雪芬3,徐轶君4,5,吴坚1,4,张凯2,周朴1

《信息与电子工程前沿(英文)》 2021年 第22卷 第3期   页码 287-436 doi: 10.1631/FITEE.2000577

摘要: 拓扑绝缘体Sb2Te3具有从可见光到红外波段的宽谱可饱和吸收的优点。在本研究中,首先将拓扑绝缘体家族中的二维材料Sb2Te3可饱和吸收体应用在宽谱可调被动调Q掺镱光纤激光器中。高质量的Sb2Te3晶体通过选区熔炼法合成,进一步通过改进的机械剥离方法制备少层Sb2Te3可饱和吸收体。基于此可饱和吸收体,在掺镱光纤环形腔中获得稳定的波长可调被动调Q脉冲,其中心波长可从1040.89 nm连续调节到1092.85 nm。实验结果表明,Sb2Te3具有宽谱可饱和吸收特性,这个波长可调脉冲激光可以为实际应用提供一个方便简单的光源。

关键词: 拓扑绝缘体;Sb2Te3;光纤激光;被动调Q激光;波长可调激光    

Al2O3-MxOy硬面陶瓷涂层的喷焊制备及性能研究

王飚,王宇栋,李慧玲,张自华

《中国工程科学》 2002年 第4卷 第9期   页码 75-80

摘要:

在碳钢母材上,用氧乙炔焰喷焊镍包铝合金粉末制取预涂层,喷焊50% Al2O3+50% Ni的复合粉末制取过渡层,用等离子喷焊Al2O3 - MxOy复合粉末制取最终涂层。

关键词: Al2O3-MxOy     涂层     等离子     抗腐蚀     抗磨损    

H2 对Pt-Ba-Ce /γ-Al2O3 催化剂NOx 存储和还原机理的影响研究 Article

王攀, 裔静, 孙川, 罗鹏, 雷利利

《工程(英文)》 2019年 第5卷 第3期   页码 568-575 doi: 10.1016/j.eng.2019.02.005

摘要:

本研究采用浸渍法制备了Pt-Ba-Ce/γ-Al2O3催化剂,利用实验评价了H2 对NSR(NOx storage and reduction)催化剂存储和还原机理的影响,并采用综合表征技术研究了Pt-Ba-Ce /γ-Al2O3X 射线衍射(XRD)光谱中观察到的PtOx、CeO2 和BaCO3 峰很好地分散在γ-Al2O3 上,X 射线光电子能谱(XPS)检测到Ce3+ 和Ce4+ 之间的差异,Ce3+ 和Ce4+ 促进了活性氧在催化剂上的迁移。, 在350 ℃ 达到最大值315.3 μmol·g1

关键词: Pt–Ba–Ce/γ-Al2O3 催化剂,物理化学性质,NOx存储和还原,NOx 排放,H2 还原剂    

基于图案化 VO2薄膜的透明热可调微波吸收器 Article

陆振刚, 张怡蕾, 王赫岩, 夏超, 刘云菲, 豆书亮, 李垚, 谭久彬

《工程(英文)》 2023年 第29卷 第10期   页码 198-206 doi: 10.1016/j.eng.2022.10.005

摘要: 本文提出了一种基于二氧化钒(VO2)薄膜的透明热可调微波吸收器。理论计算和实验结果表明,所提出的吸波器在620 nm波长处可以实现84.9%的高光学透过率,同时通过控制温度,15.06 GHz频点处的反射损耗可在-4.257 dB到-60.179 dB范围内调谐并且在523.75 K温度时实现近1吸收。同时,仅通过调控图案化VO2薄膜的占空比即可改变实现近1吸收时的温度。所提出的基于VO2薄膜的吸波器具有组成简单,光学透过率高,微波吸收性能热可调,调制深度大,温度调节范围可控等优点,因此有望应用于可调传感器、热发射器、调制器、热成像仪、辐射热测定器和光电器件中

关键词: 可调微波吸收器     VO2薄膜     光学透明     1吸收     大调制深度    

Rh2O3/hexagonal CePO4 nanocatalysts for N2O decomposition

Huan Liu, Zhen Ma

《化学科学与工程前沿(英文)》 2017年 第11卷 第4期   页码 586-593 doi: 10.1007/s11705-017-1659-6

摘要: Hexagonal CePO nanorods were prepared by a precipitation method and hexagonal CePO nanowires were prepared by hydrothermal synthesis at 150 °C. Rh(NO ) was then used as a precursor for the impregnation of Rh O onto these CePO materials. The Rh O supported on the CePO nanowires was much more active for the catalytic decomposition of N O than the Rh O supported on CePO nanorods. The stability of both catalysts as a function of time on stream was studied and the influence of the co-feed (CO , O , H O or O /H O) on the N O decomposition was also investigated. The samples were characterized by N adsorption-desorption, inductively coupled plasma optical emission spectroscopy, X-ray diffraction, transmission electron microscopy, X-ray photoelectron microscopy, hydrogen temperature-programmed reduction, oxygen temperature-programmed desorption, and CO temperature-programmed desorption in order to correlate the physicochemical and catalytic properties.

关键词: Rh2O3     CePO4     N2O decomposition    

On the monolayer dispersion behavior of Co3O4 on HZSM-5 support: designing applicable

《化学科学与工程前沿(英文)》 2023年 第17卷 第11期   页码 1741-1754 doi: 10.1007/s11705-023-2332-x

摘要: Based on monolayer dispersion theory, Co3O4/ZSM-5 catalysts with different loadings have been prepared for selective catalytic reduction of nitrogen oxides by ammonia. Co3O4 can spontaneously disperse on HZSM-5 support with a monolayer dispersion threshold of 0.061 mmol 100 m–2, equaling to a weight percentage around 4.5%. It has been revealed that the quantities of surface active oxygen (O2) and acid sites are crucial for the reaction, which can adsorb and activate NOx and NH3 reactants effectively. Below the monolayer dispersion threshold, Co3O4 is finely dispersed as sub-monolayers or monolayers and in an amorphous state, which is favorable to generate the two kinds of active sites, hence promoting the performance of ammonia selective catalytic reduction of nitrogen oxide. However, the formation of crystalline Co3O4 above the capacity is harmful to the reaction performance. 4% Co3O4/ZSM-5, the catalyst close to the monolayer dispersion capacity, possesses the most abundant active O2 species and acidic sites, thereby demonstrating the best reaction performance in all the samples. It is proposed the optimal Co3O4/ZSM-5 catalyst can be prepared by loading the capacity amount of Co3O4 onto HZSM-5 support.

关键词: Co3O4/ZSM-5     NOx-SCR by NH3     monolayer dispersion threshold effect     surface acid sites     surface active O2 anions    

Effects of Pd doping on N

Mingxin Dong, Jun Wang, Jinxin Zhu, Jianqiang Wang, Wulin Wang, Meiqing Shen

《环境科学与工程前沿(英文)》 2017年 第11卷 第6期 doi: 10.1007/s11783-017-0976-9

摘要: N O is a powerful greenhouse gas and plays an important role in destructing the ozone layer. This present work investigated the effects of Pd doping on N O formation over Pt/BaO/Al O catalyst. Three types of catalysts, Pt/BaO/Al O , Pt/Pd mechanical mixing catalyst (Pt/BaO/Al O +Pd/Al O ) and Pt-Pd co-impregnation catalyst (Pt-Pd/BaO/Al O ) were prepared by incipient wetness impregnation method. These catalysts were first evaluated in NSR activity tests using H /CO as reductants and then carefully characterized by BET, CO chemisorption, CO-DRIFTs and H -TPR techniques. In addition, temperature programmed reactions of NO with H /CO were conducted to obtain further information about N O formation mechanism. Compared with Pt/BaO/Al O , (Pt/BaO/Al O +Pd/Al O ) produced less N O and more NH during NO storage and reduction process, while an opposite trend was found over (Pt-Pd/BaO/Al O +Al O ). Temperature programmed reactions of NO with H /CO results showed that Pd/Al O component in (Pt/BaO/Al O +Pd/Al O ) played an important role in NO reduction to NH , and the formed NH could reduce NO to N leading to a decrease in N O formation. Most of N O formed over (Pt-Pd/BaO/Al O +Al O ) was originated from Pd/BaO/Al O component. H -TPR results indicated Pd-Ba interaction resulted in more difficult-to-reduce PdO species over Pd/BaO/Al O , which inhibits the NO dissociation and thus drives the selectivity to N O in NO reduction.

关键词: NOx storage reduction     Pt/BaO/Al2O3     Pd doping     N2O formation     Optimization    

Brazing of ceramic-to-ceramic and ceramic-to-metal joints in air

Kirsten BOBZIN, Thomas SCHLAEFER, Lidong ZHAO, Nils KOPP, Arne SCHLEGEL

《机械工程前沿(英文)》 2010年 第5卷 第2期   页码 125-129 doi: 10.1007/s11465-010-0007-z

摘要: Reactive air brazing (RAB) is an emerging technology for the production of ceramic-to-ceramic and ceramic-to-metal joints. In this study, RAB was investigated with respect to the potential applications for solid oxide fuel cells (SOFCs) as one example of use. It was found that alumina could be well brazed by RAB with AgCu and AgCuTi brazes. Both braze composition and brazing temperature influenced significantly the wetting behavior and their mechanism of wetting. AgCu and AgCuTi braze alloys could also be used to produce brazed joints with the SOFC materials ceramic yttria stabilized zirconia and steel X1CrTiLa22. However, CuO reacts with the steel, forming a brittle oxide layer on the steel surface, which is undesirable for SOFC applications. The first trials with Ag0.5Al showed a promising solution.

关键词: reactive air brazing (RAB)     X1CrTiLa22     Al2O3     yttria stabilized zirconia (YSZ)     solid oxide fuel cell (SOFC)    

可调液晶共面波导阶梯阻抗谐振器 Research Articles

樊星叶1,李若舟1,2,严静1,方玉明1,2,于映1,2

《信息与电子工程前沿(英文)》 2021年 第22卷 第9期   页码 1270-1276 doi: 10.1631/FITEE.2000278

摘要: 提出一种液晶可调阶梯阻抗谐振器。该谐振器分别在3.367 GHz和7.198 GHz处谐振,这两个频点可通过对液晶层加载电压实现连续调节。实验表明仅需施加14 V的外加电压,即可实现52 MHz和210 MHz的调谐范围,并与仿真结果吻合;在此基础上,研究了驱动过程中电压带来的迟滞效应。该谐振器可应用于需要频率连续可调的各类通信系统中。

关键词: 可调阶梯阻抗谐振器;液晶;共面波导    

(011)取向单晶衬底上生长的非晶Sm-Co薄膜的面内各向异性调控 Article

梁文会, 周厚博, 熊杰夫, 胡凤霞, 李佳, 张健, 王晶, 孙继荣, 沈保根

《工程(英文)》 2020年 第6卷 第2期   页码 158-163 doi: 10.1016/j.eng.2019.11.010

摘要:

具有单轴面内各向异性的非晶Sm-Co薄膜在信息存储和自旋电子学领域中都具有广阔的应用前景。产生单轴面内各向异性的最有效方法是在薄膜沉积过程中施加面内磁场。然而,这种方法通常需要复杂的设备。本文中,我们报道了一种产生单轴面内各向异性的新方法,只需要将非晶Sm-Co薄膜生长在(011)取向的单晶衬底上,薄膜生长过程中不需要施加任何外部磁场。生长在LaAlO3 (011)衬底上的非晶Sm-Co薄膜的各向异性常数kA高达3.3×104 J·m3。详细分析表明,衬底各向异性应变引起的铁磁畴的择优生长,以及薄膜中Sm-Co、Co-Co取向对的有序化,在非晶Sm-Co薄膜单轴面内各向异性的产生上起到了重要作用。

关键词: 非晶Sm-Co膜,面内单轴各向异性,磁控溅射    

The stabilization effect of Al2O3 on unconventional Pb/SiO2 catalyst

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1423-1429 doi: 10.1007/s11705-023-2315-y

摘要: Similar to Sn, Pb located at the same group (IVA) in the periodic table of elements, can also catalyze propane dehydrogenation to propene, while a fast deactivation can be observed. To enhance the stability, the traditional carrier Al2O3 with a small amount, was introduced into Pb/SiO2 catalyst in this study. It has been proved that Al2O3 can inhibit the reduction of PbO, and weaken the agglomeration and loss of Pb species due to its enhanced interaction with Pb species. As a result, 3Al15Pb/SiO2 catalyst exhibits a much higher stability up to more than 150 h. In addition, a simple schematic diagram of the change of surface species on the catalyst surface after Al2O3 addition was also proposed.

关键词: Pb/SiO2     Al2O3     propane dehydrogenation     propene     stability    

空间衍射望远系统发展现状 Review Article

赵维1,3,4,王新1,刘华‡2,4,陆子凤2,4,卢振武5

《信息与电子工程前沿(英文)》 2020年 第21卷 第6期   页码 809-962 doi: 10.1631/FITEE.1900529

摘要: 基底微结构制作的薄膜衍射光学元件具备超轻质量(面密度小于0.1 kg/m2)和宽松表面形状公差(厘米级表面精度需求)两个重要特性,将其作为大口径望远镜的主镜可实现超大口径,超轻量化,同时降低发射成本。

关键词: 薄膜衍射光学元件;衍射望远系统;超大口径    

双级驱动半主动隔振系统的可调反共振频率控制器 Research Articles

赵勃1,2,史维佳1,2,王丙泉1,2,谭久彬1,2

《信息与电子工程前沿(英文)》 2021年 第22卷 第10期   页码 1390-1401 doi: 10.1631/FITEE.2000373

摘要: 本文提出一种用于双级驱动半主动隔振系统的可调反共振频率控制器。双级驱动半主动隔振系统具有显著的反共振特性,在一个特定频率——即所谓反共振频率——振幅可降至接近零。本控制器的设计目的是增加一个可调的控制器反共振频率,以充分利用这种独特的反共振特性。实验结果表明了本方案的可行性,闭环传递率从0 Hz到初始反共振频率小于−15 dB。

关键词: 半主动隔振;双级驱动;动态吸振;可调反共振频率控制器    

含稀释剂的Al-Cr2O3体系燃烧合成反应热力学分析与反应模型

张衍诚,潘冶,张传

《中国工程科学》 2004年 第6卷 第6期   页码 63-67

摘要:

对含稀释剂Al203和Cr<sub>2</sub>0<sub>3</sub>的Al-Cr<sub>2</sub>0<sub>3</sub>体系燃烧合成反应进行了热力学计算与分析,讨论了起始反应温度T<sub>0</sub>、稀释剂Al<sub>2</sub>O<sub>3</sub>和Cr<sub>2</sub>O<sub>3</sub>的含量对绝热反应温度7^的影响,并得出T<

关键词: 金属陶瓷     燃烧合成     Al-Cr203体系     热力学     反应模型    

标题 作者 时间 类型 操作

磁控溅射法生长的可调(GaxIn1x)2O3

张法碧1,孙巾寓1,李海鸥1,周娟1,王荣1,孙堂友1,傅涛1,肖功利1,李琦1,刘兴鹏1,张秀云1,郭道友2,王相虎3,秦祖军1

期刊论文

基于拓扑绝缘体Sb2Te3的52 nm宽谱可调被动调Q掺镱光纤激光器

王涛1,俞强1,2,郭琨1,史鑫尧2,阚雪芬3,徐轶君4,5,吴坚1,4,张凯2,周朴1

期刊论文

Al2O3-MxOy硬面陶瓷涂层的喷焊制备及性能研究

王飚,王宇栋,李慧玲,张自华

期刊论文

H2 对Pt-Ba-Ce /γ-Al2O3 催化剂NOx 存储和还原机理的影响研究

王攀, 裔静, 孙川, 罗鹏, 雷利利

期刊论文

基于图案化 VO2薄膜的透明热可调微波吸收器

陆振刚, 张怡蕾, 王赫岩, 夏超, 刘云菲, 豆书亮, 李垚, 谭久彬

期刊论文

Rh2O3/hexagonal CePO4 nanocatalysts for N2O decomposition

Huan Liu, Zhen Ma

期刊论文

On the monolayer dispersion behavior of Co3O4 on HZSM-5 support: designing applicable

期刊论文

Effects of Pd doping on N

Mingxin Dong, Jun Wang, Jinxin Zhu, Jianqiang Wang, Wulin Wang, Meiqing Shen

期刊论文

Brazing of ceramic-to-ceramic and ceramic-to-metal joints in air

Kirsten BOBZIN, Thomas SCHLAEFER, Lidong ZHAO, Nils KOPP, Arne SCHLEGEL

期刊论文

可调液晶共面波导阶梯阻抗谐振器

樊星叶1,李若舟1,2,严静1,方玉明1,2,于映1,2

期刊论文

(011)取向单晶衬底上生长的非晶Sm-Co薄膜的面内各向异性调控

梁文会, 周厚博, 熊杰夫, 胡凤霞, 李佳, 张健, 王晶, 孙继荣, 沈保根

期刊论文

The stabilization effect of Al2O3 on unconventional Pb/SiO2 catalyst

期刊论文

空间衍射望远系统发展现状

赵维1,3,4,王新1,刘华‡2,4,陆子凤2,4,卢振武5

期刊论文

双级驱动半主动隔振系统的可调反共振频率控制器

赵勃1,2,史维佳1,2,王丙泉1,2,谭久彬1,2

期刊论文

含稀释剂的Al-Cr2O3体系燃烧合成反应热力学分析与反应模型

张衍诚,潘冶,张传

期刊论文