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Study on HCl removal for medical waste pyrolysis and combustion using a TG-FTIR analyzer

Hongmei ZHU,Weiying CHEN,Xuguang JIANG,Jianhua YAN,Yong CHI

《环境科学与工程前沿（英文）》 2015年第9卷第2期页码 230-239 doi: 10.1007/s11783-014-0651-3

摘要： Under both pyrolysis and combustion condition, HCl removal efficiency for medical waste with Ca-based additives was semi-quantitatively studied by means of TG-FTIR. Additionally, the difference of HCl removal efficiency for PVC and medical waste was compared. Experimental results showed that: 1) Thermal degradation of medical waste mainly took place in two steps under both pyrolysis and combustion condition; 2) HCl emitted at both two steps and HCl concentration increased with the increased of Cl ratio in the medical waste; 3) for the same additive, HCl concentration decreased with the increased of additives amount, that is to say, HCl removal efficiency of medical waste increased as the increased of Ca/Cl molar ratio. Fourth, when Ca(OH) was used as additive, HCl removal efficiency for medical waste combustion was a little higher than that for medical waste pyrolysis, but either CaCO or CaO was used as additive, it was just opposite, more specifically, when CaCO was used as additive with Ca/Cl=1.3, HCl removal efficiency was 5.49% under pyrolysis condition, but that was only 4.24% under combustion condition. Fifth, under the same Ca/Cl molar ratio, HCl removal efficiency for PVC was higher than that for medical waste under both pyrolysis and combustion condition, more specifically, when Ca(OH) was used as additive with Ca/Cl=1, HCl removal efficiency was 64.51% for PVC, but that was only 27.66% for medical waste pyrolysis with 4% Cl under pyrolysis condition.

关键词： pollution medical waste pyrolysis combustion TG-FTIR HCl removal

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Pyrolysis behaviors of oil sludge based on TG/FTIR and PY-GC/MS

Wei SONG, Jianguo LIU, Yongfeng NIE,

《环境科学与工程前沿（英文）》 2010年第4卷第1期页码 59-64 doi: 10.1007/s11783-009-0152-y

摘要： Pyrolysis is an alternative technology for oil sludge treatment. Thermogravimetric Analysis-Fourier Transform Infrared Spectroscopy and Pyrolysis-Gas Chromatography/Mass Spectrometry were employed to investigate the pyrolysis process and products of oil sludge. The pyrolysis process was divided into five stages: drying and gas desorption, oil volatilization, main pyrolysis, semi-coke charring, and mineral decomposition. The main reaction temperatures ranged from 497.6 K to 753.2 K. The products were mainly composed of pairs of alkane and alkene (carbon number ranges from 1 to 27). The mechanisms consisted of random chain scission followed by end chain scission at high temperatures with volatilization occurring during the whole process. This study is useful not only for the proper design of a pyrolysis system, but also for improving the utilization of liquid oil products.

关键词： oil sludge pyrolysis Thermogravimetric Analysis-Fourier Transform Infrared Spectroscopy (TG-FTIR) Pyrolysis-Gas Chromatography/Mass Spectrometry (PY-GC/MS)

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A PLATFORM TO AID SELECT THE OPTIMAL TOOL TO DESIGN GUIDE RNAS

《农业科学与工程前沿（英文）》页码 296-305 doi: 10.15302/J-FASE-2022479

摘要：

● Summaries on sgRNAs design.

关键词： CRISPR/Cas Aid-TG gene editing sgRNA design web server

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TG-MS研究生物质组分与聚乙烯共热解特性

范洪刚,顾菁,王亚琢,袁浩然,何明阳,孙富安

《中国工程科学》 2018年第20卷第3期页码 102-108 doi: 10.15302/J-SSCAE-2018.03.015

摘要：

为了探索生物质主要组分在与塑料共热解过程中的协同效应和小分子气体产物的变化规律，笔者采用热重-质谱联用（TG-MS）技术研究纤维素、木聚糖共热解样品的混合比例为1∶1（w/w），TG实验得到了各单组分以及混合组分的失重区间，通过对单组分TG数据的拟合得到理论值与实验值，比较得到混合组分在共热解过程中存在协同效应，可促进样品的分解。

关键词：纤维素木聚糖木质素聚乙烯共热解

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Investigations on dehydration processes of trisodium citrate hydrates

Junyan GAO, Yanlei WANG, Hongxun HAO

《化学科学与工程前沿（英文）》 2012年第6卷第3期页码 276-281 doi: 10.1007/s11705-012-1206-4

摘要： The dehydration processes of trisodium citrate (Na C H O ) hydrates were investigated using thermogravimetry (TG), differential scanning calorimetry (DSC) and powder X-ray diffraction (PXRD). It was found that the temperature of dehydration of trisodium citrate dihydrate was at 430.99 K. For trisodium citrate pentahydrate, there is a two-step dehydration process and the endothermal peaks appear at 337.23 K and 433.83 K, respectively. During the first step of dehydration process, the structure of trisodium citrate pentahydrate changed into the structure of trisodium citrate dihydrate. In addition, the kinetics of dehydration for trisoidum citrate hydrates was also investigated using TG data. According to the activation energies of dehydration calculated by Ozawa equation, it was found that the dehydration mechanisms of the two hydrates were different.

关键词： trisodium citrate dehydration TG/DSC PXRD

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Research on combustion characteristics of bio-oil from sewage sludge

Rui LI, Baosheng JIN, Xiangru JIA, Zhaoping ZHONG, Gang XIAO, Xufeng FU

《化学科学与工程前沿（英文）》 2009年第3卷第2期页码 161-166 doi: 10.1007/s11705-009-0057-0

摘要： Combustion characteristics of bio-oil from sewage sludge were investigated using thermogravimetry (TG) and Fourier Transform Infrared Spectroscopy (FT-IR) techniques. The combustion process could be divided into two weight loss stages. Light compounds volatilized and were oxidized in the first stage and the heterogeneous combustion between oxygen and heavy compounds happened in the second stage, which were confirmed by FT-IR technique. Most weight loss occurred in the first stage. The effect of heating rate was also studied and higher heating rates were found to facilitate the combustion process. The kinetic parameters of the two stages were calculated and the change of activation energy indicated higher heating rates benefited combustion.

关键词： bio-oil from sewage sludge fast pyrolysis combustion characteristics TG-FT-IR kinetic

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Russian school of the theory and geometry of gearing: Its origin and golden period (1935 --1975)

Dmitry BABICHEV,Sergey LAGUTIN,Natalya BARMINA

《机械工程前沿（英文）》 2016年第11卷第1期页码 44-59 doi: 10.1007/s11465-015-0360-z

摘要：

During the second half of the twentieth century, Soviet scientists were among the world leaders in the theory and geometry of gearing or the theoretical fundamentals of designing gears and gear-cutting tools. The authors of the current paper review works related to the development of the theory of gearing (TG) written in Russian from the mid-1930s to the present. Overall, the review covers more than 400 publications of nearly 200 authors (among more than 1000 studied works). This review involves some works on gear strength and accuracy to attract more experts.

This paper presents a short list of works from the seventeenth century to the nineteenth century and discusses the basic concepts of the TG. This paper also includes a review of more than 160 papers in Russian for the period of 1935–1975, which is the “golden age” of the TG. The main features and achievements during this period are also considered.

The distinctive feature of this review is the use of diagrams that visually present TG experts and the dates and themes of their published works. The diagrams also show the following aspects: 1) The most popular and important themes in a specific period, 2) the most important publications on the themes of interest to readers, and 3) the direction of the works and scope of interests of every researcher.

关键词： theory of gearing (TG) gear geometry generating surface gear synthesis gear analysis

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Mechanism study on cellulose pyrolysis using thermogravimetric analysis coupled with infrared spectroscopy

WANG Shurong, LIU Qian, LUO Zhongyang, WEN Lihua, CEN Kefa

《能源前沿（英文）》 2007年第1卷第4期页码 413-419 doi: 10.1007/s11708-007-0060-8

摘要： Based on the investigation of the polysaccharide structure of cellulose by using Fourier transform spectrum analysis, the pyrolysis behaviour of cellulose was studied at a heating rate of 20 K/min by thermogravimetric (TG) analysis

关键词： cellulose transform polysaccharide investigation TG

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Thermogravimetric coupled with Fourier transform infrared analysis study on thermal treatment of monopotassium phosphate residue

Yuheng FENG, Xuguang JIANG, Yong CHI, Xiaodong LI, Hongmei ZHU

《环境科学与工程前沿（英文）》 2011年第5卷第2期页码 186-192 doi: 10.1007/s11783-011-0322-6

摘要： In China, safe disposal of hazardous waste is more and more a necessity, urged by rapid economic development. The pyrolysis and combustion characteristics of a residue from producing monopotassium phosphate (monopotassium phosphate residue), considered as a hazardous waste, were studied using a thermogravimetric, coupled with Fourier transform infrared analyzer (TG-FTIR). Both pyrolysis and combustion runs can be subdivided into three stages: drying, thermal decomposition, and final devolatilization. The average weight loss rate during fast thermal decomposition stage in pyrolysis is higher than combustion. Acetic acid, methane, pentane, (acetyl) cyclopropane, 2,4,6-trichlorophenol, CO, and CO were distinguished in the pyrolysis process, while CO was the dominant combustion product.

关键词： hazardous waste combustion pyrolysis thermogravimetric coupled with Fourier transform infrared analysis (TG-FTIR) monopotassium phosphate residue