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Biomimetic mineralization and cytocompatibility of nanorod hydroxyapatite/graphene oxide composites

Peizhen Duan, Juan Shen, Guohong Zou, Xu Xia, Bo Jin

《化学科学与工程前沿（英文）》 2018年第12卷第4期页码 798-805 doi: 10.1007/s11705-018-1708-9

摘要： Nanorod hydroxyapatite (NRHA)/graphene oxide (GO) composites with weight ratios of 0.4, 1.5, and 5 have been fabricated by a facile ultrasonic-assisted method at room temperature and atmospheric pressure. The chemical structure properties and morphology of the composites were characterized by field emission source scanning electron microscope, X-ray diffraction, transmission electron microscopy, and high-resolution transmission electron microscopy. The results indicate that the NNRHA/GO composites have an irregular surface with different degree wrinkles and are stable, and NRHA are well combined with GO. In addition, the biomimetic mineralization mechanism of hydroxyapatite on the NNRHA/GO composites in simulated body fluid (SBF) is presented. The presence of a bone-like apatite layer on the composite surface indicate that the NNRHA/GO composites facilitate the nucleation and growth of hydroxyapatite crystals in SBF for biomimetic mineralization. Moreover, the NNRHA-1.5/GO composite and pure GO were cultured with MC3T3-E1 cells to investigate the proliferation and adhesion of cells. In vitro cytocompatibility evaluation demonstrated that the NNRHA/GO composite can act as a good template for the growth and adhesion of cells. Therefore, the NNRHA/GO composite could be applied as a GO-based, free-template, non-toxic, and bioactive composite to substitute for a damaged or defect bone.

关键词： hydroxyapatite graphene oxide biomimetic mineralization cytocompatibility

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growth of a-few-layered MoS on CdS nanorod for high efficient photocatalytic H production

《能源前沿（英文）》 2021年第15卷第3期页码 752-759 doi: 10.1007/s11708-021-0779-3

摘要： An ultrathin MoS₂ was grown on CdS nanorod by a solid state method using sulfur powder as sulfur source for photocatalytic H₂ production. The characterization result reveals that the ultrathin MoS₂ nanosheets loaded on CdS has a good contact state. The photoelectrochemical result shows that MoS₂ not only are beneficial for charge separation, but also works as active sites, thus enhancing photocatalytic activity. Compared with pure CdS, the photocatalytic activity of MoS₂ loaded CdS was significantly improved. The hydrogen evolution rate on m(MoS₂): m(CdS) = 1: 50 (m is mass) reaches 542 μmol/h, which is 6 times of that on pure CdS (92 μmol/h). This work provides a new design for photocatalysts with high photocatalytic activities and provides a deeper understanding of the effect of MoS₂ on enhancing photocatalytic activity.

关键词： photocatalytic H₂ production CdS MoS₂ cocatalyst charge separation

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g-CN-coated MnO hollow nanorod cathode for stable aqueous Zn-ion batteries

《化学科学与工程前沿（英文）》 2023年第17卷第2期页码 217-225 doi: 10.1007/s11705-022-2214-7

摘要： Aqueous zinc-ion batteries are attracting considerable attention because of their high safety compared with conventional lithium-ion batteries. Manganese-based materials have been widely developed for zinc-ion batteries cathode owning to their low cost, high security and simple preparation. However, the severe volume expansion and poor stability during charging and discharging limit the further development of manganese-based cathodes. Herein, superior α-MnO₂@g-C₃N₄ was successfully prepared for stable zinc-ion batteries (ZIBs) cathode by introducing g-C₃N₄ nanosheets. Compared with pure α-MnO₂, α-MnO₂@g-C₃N₄ has a specific capacity of 298 mAh·g^–1 at 0.1 A·g^–1. Even at 1 A·g^–1, the α-MnO₂@g-C₃N₄ still retains 100 mAh·g^–1 (83.4% retention after 5000 cycles), implying its excellent cycling stability. The α-MnO₂@g-C₃N₄-based cathode has the highest energy density (563 Wh·kg^–1) and power energy density (2170 W·kg^–1). This work provides new avenues for the development of a wider range of cathode materials for ZIBs.

关键词： α-MnO₂ hollow nanorods g-C₃N₄ heterojunction aqueous Zn-ion batteries

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Analytical and numerical investigation into the longitudinal vibration of uniform nanotubes

null

《机械工程前沿（英文）》 2014年第9卷第2期页码 142-149 doi: 10.1007/s11465-014-0292-z

摘要：

In recent years, prediction of the behaviors of micro and nanostructures is going to be a matter of increasing concern considering their developments and uses in various engineering fields. Since carbon nanotubes show the specific properties such as strength and special electrical behaviors, they have become the main subject in nanotechnology researches. On the grounds that the classical continuum theory cannot accurately predict the mechanical behavior of nanostructures, nonlocal elasticity theory is used to model the nanoscaled systems. In this paper, a nonlocal model for nanorods is developed, and it is used to model the carbon nanotubes with the aim of the investigating into their longitudinal vibration. Following the derivation of governing equation of nanorods and estimation of nondimensional frequencies, the effect of nonlocal parameter and the length of the nanotube on the obtained frequencies are studied. Furthermore, differential quadrature method, as a numerical solution technique, is used to study the effect of these parameters on estimated frequencies for both classical and nonlocal theories.

关键词： continuum theory differential quadrature method nanorod longitudinal vibration

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Hydrothermal synthesis of crystalline α-/β-MnO2 nanorods via γ-MnOOH nanorod precursors

ZHANG Weixin, REN Xiangbin, YANG Zeheng, WANG Hua, WANG Qiang, HUANG Fei

《化学科学与工程前沿（英文）》 2007年第1卷第4期页码 365-371 doi: 10.1007/s11705-007-0066-9

摘要： The crystalline -MnO and -MnO nanorods have been successfully prepared via a facile hydrothermal method from -MnOOH nanorods precursor, respectively. The samples were characterized by means of X-ray diff raction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM), field emission scanning electron microscope (FESEM) and Fourier transformed infrared spectra (FTIR). The morphology and structure of -MnOOH nanorods precursors have a great influence on the crystal structure of the obtained products. The -MnO nanorods are prepared from the 100°C -MnOOH precursor, while the -MnO nanorods are obtained from the 150°C -MnOOH precursor, respectively. Besides, the catalytic activity of the prepared -MnO and -MnO nanorods for the HO decomposition has been investigated comparatively, and the latter shows better catalytic activity.

关键词： obtained -MnOOH precursor Besides high-resolution transmission precursor

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Fabrication of titania thin film with composite nanostructure and its ability to photodegrade rhodamine B in water

ZHANG Gaojie, WU Jinming, LIU Shaoguang, YAN Mi

《化学科学与工程前沿（英文）》 2008年第2卷第1期页码 44-48 doi: 10.1007/s11705-008-0001-8

摘要： A titania nanorod film was synthesized by direct oxidation of metallic Ti with hydrogen peroxide solution under a low temperature. Titania nanoparticles were then filled into the gaps among the nanorods through an infiltration sol-gel procedure to form a composite titania film with an ordered nanostructure. X-ray diffraction spectra indicate that the composite film was a mixture of anatase and rutile while the titania film obtained by only using a sol-gel procedure was pure anatase. Field emission scanning electron microscopy observations show that titania nanoparticles were embedded into the titania nanorod film. Photoluminescence spectra suggest the enhanced separation of electron and hole pairs for the obtained composite titania film over the corresponding titania nanorod film. The composite titania film exhibited improved ability to photodegrade rhodamine B in water compared with the titania nanorod film. The apparent photodegradation rate constant, fitting a pseudo-first-order, was 3 times of that obtained by the sol-gel derived titania film at the same weight. The improved photocatalytic activity for the composite titania film could be attributed to the enhanced separation of electron and hole pairs due to the embedding of the titania nanoparticles within the titania nanorods.

关键词： constant weight apparent photodegradation hydrogen nanorod

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Morphology selective construction of

Maher Darwish, Ali Mohammadi, Navid Assi, Samer Abuzerr, Youssef Alahmad

《化学科学与工程前沿（英文）》 2020年第14卷第4期页码 561-578 doi: 10.1007/s11705-019-1808-1

摘要： Controlled growth of Bi WO nanorods with exposed [0 0 1] facets and the fabrication of an Fe O -Bi WO magnetic composite by a microwave-assisted polyol process, were achieved in this study. The adsorptivity and photocatalytic performance of the composite toward sunset yellow dye degradation were greatly enhanced by the -cyclodextrin cavities on its surface, firmly anchored through a cetyltrimethylammonium bromide linkage. A series of examinations and characterizations were carried out to determine the influence of various factors on the morphological modulation-photocatalytic behavior of the pure Bi WO prior to final functionalization. Changing the pH of the precursor solution impacted the formation of 0D, 2D, and 3D structures; however, the presence of hexamethylenetetramine surfactant induced the development of 1D nanorod structure. A reasonable crystal growth mechanism was proposed to elucidate the formation process. Conversely, the mechanism of the activity enhancement of -cyclodextrin functionalized Fe O -Bi WO , compared to that of the non-functionalized samples, could be realized with the assistance of chemical trapping experiments on sunset yellow, and was confirmed on the colorless antibiotic (sulfamethoxazole). The high performance and durability of this composite can be attributed to the facet-dependent activity, large adsorption capacity due to inclusion interactions, enhanced visible light absorption, and efficient charge separation.

关键词： β-cyclodextrin Bi₂WO₆ shape controlled nanorod sunset yellow