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Recent advances of hydrogen production through particulate semiconductor photocatalytic overall water

《能源前沿(英文)》 2022年 第16卷 第1期   页码 49-63 doi: 10.1007/s11708-022-0817-9

摘要: Solar energy-driven photocatalytic water splitting has been investigated for decades to produce clean and renewable green hydrogen. In this paper, the cutting-edge research within the overall water splitting system is summarized from the one-step photocatalytic overall water splitting (POWS) system to the two-step system and the cocatalysts research in this field. In addition, the photocatalytic reaction engineering study is also reviewed which is crucial for future scale-up. This mini-review provides a picture of survey of recent progress of relevant overall water splitting system, with particular attention paid to material system and mechanistic breakthroughs, and highlights the challenge and opportunity of the current system.

关键词: photocatalysis     overall water splitting     hydrogen    

Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties

《化学科学与工程前沿(英文)》 2022年 第16卷 第3期   页码 433-442 doi: 10.1007/s11705-021-2066-6

摘要: Copper(I) selenide-nanocrystalline semiconductor was synthesized via one-step mechanochemical synthesis after 5 min milling in a planetary ball mill. The kinetics of synthesis was followed by X-ray powder diffraction analysis and specific surface area measurements of milled 2Cu/Se mixtures. The X-ray diffraction confirmed the orthorhombic crystal structure of Cu2Se with the crystallite size ~25 nm. The surface chemical structure was studied by X-ray photoelectron spectroscopy, whereby the binding energy of the Cu 2p and Se 3d signals corresponded to Cu+ and Se2– oxidation states. Transmission electron microscopy revealed agglomerated nanocrystals and confirmed their orthorhombic structure, as well. The optical properties were studied utilizing ultraviolet-visible spectroscopy and photoluminescence spectroscopy. The direct bandgap energy 3.7 eV indicated a blue-shift phenomenon due to the quantum size effect. This type of Cu2Se synthesis can be easily adapted to production dimensions using an industrial vibratory mill. The advantages of mechanochemical synthesis represent the potential for inexpensive, environmentally-friendly, and waste-free manufacturing of Cu2Se.

关键词: Cu2Se     berzelianite     nanocrystalline semiconductor     mechanochemical synthesis     planetary ball mill    

Liquid metal printing opening the way for energy conservation in semiconductor manufacturing industry

《能源前沿(英文)》 2022年 第16卷 第4期   页码 542-547 doi: 10.1007/s11708-022-0834-8

中国先进半导体材料及辅助材料发展战略研究

“先进半导体材料及辅助材料”编写组

《中国工程科学》 2020年 第22卷 第5期   页码 10-19 doi: 10.15302/J-SSCAE-2020.05.002

摘要:

目前,以SiC、GaN为代表的第三代半导体材料快速发展,我国亟需抓住战略机遇期,实现先进半导体材料、辅助材料的自主可控,保障相关工业体系安全。本文在分析全球半导体材料及辅助材料研发与产业发展现状的基础上,寻找差距,结合我国现实情况,提出了构建半导体材料及辅助材料体系化发展、上下游协同发展和可持续发展的发展思路,制定了面向2025年和2035年的发展目标。为推动我国先进半导体材料及辅助材料产业发展,提出了建设集成电路关键材料及装备自主可控工程,SiC和GaN半导体材料、辅助材料、工艺及装备验证平台,先进半导体材料在第五代移动通信技术、能源互联网及新能源汽车领域的应用示范工程,并对如何开展三项工程进行了需求分析,设置了具体的工程目标和工程任务。最后,为推动半导体产业的创新发展,从坚持政策推动,企业和机构主导,整合国内优势资源;把握“超越摩尔”的历史机遇,布局下一代集成电路技术;构建创新链,进行创新生态建设等方面提出了对策建议。

关键词: 先进半导体材料     辅助材料     第三代半导体     2035    

Novel slack-based robust scheduling rule for a semiconductor manufacturing system with uncertain processing

Juan LIU, Fei QIAO, Yumin MA, Weichang KONG

《工程管理前沿(英文)》 2018年 第5卷 第4期   页码 507-514 doi: 10.15302/J-FEM-2018045

摘要:

The NP-hard scheduling problems of semiconductor manufacturing systems (SMSs) are further complicated by stochastic uncertainties. Reactive scheduling is a common dynamic scheduling approach where the scheduling scheme is refreshed in response to real-time uncertainties. The scheduling scheme is overly sensitive to the emergence of uncertainties because the optimization of performance (such as minimum make-span) and the system robustness cannot be achieved simultaneously by conventional reactive scheduling methods. To improve the robustness of the scheduling scheme, we propose a novel slack-based robust scheduling rule (SR) based on the analysis of robustness measurement for SMS with uncertain processing time. The decision in the SR is made in real time given the robustness. The proposed SR is verified under different scenarios, and the results are compared with the existing heuristic rules. Simulation results show that the proposed SR can effectively improve the robustness of the scheduling scheme with a slight performance loss.

关键词: semiconductor manufacturing system     uncertain processing time     dynamic scheduling     slack-based robust scheduling rule    

Developments in semiconductor thermoelectric materials

Laifeng LI, Zhen CHEN, Min ZHOU, Rongjin HUANG

《能源前沿(英文)》 2011年 第5卷 第2期   页码 125-136 doi: 10.1007/s11708-011-0150-1

摘要: A surge in interest in developing alternative renewable energy technologies has been observed in recent years. In particular, thermoelectrics has drawn attention because thermoelectric effects enable direct conversion between thermal and electrical energy, and provide power generation and refrigeration alternatives. During the past decade, the performance of thermoelectric materials has been considerably improved; however, many challenges continue to exist. Developing thermoelectric materials with superior performance means tailoring interconnected thermoelectric physical parameters-electrical conductivities, Seebeck coefficients, and thermal conductivities for a crystalline system. The objectives of this paper are to introduce the recent developments in semiconductor thermoelectric materials, and briefly summarize the applications of such materials.

关键词: thermoelectric materials     thermoelectric figure of merit     applications    

Ga(X)N/Si nanoarchitecture: An emerging semiconductor platform for sunlight-powered water splitting toward

《能源前沿(英文)》 doi: 10.1007/s11708-023-0881-9

摘要: Sunlight-powered water splitting presents a promising strategy for converting intermittent and virtually unlimited solar energy into energy-dense and storable green hydrogen. Since the pioneering discovery by Honda and Fujishima, considerable efforts have been made in this research area. Among various materials developed, Ga(X)N/Si (X = In, Ge, Mg, etc.) nanoarchitecture has emerged as a disruptive semiconductor platform to split water toward hydrogen by sunlight. This paper introduces the characteristics, properties, and growth/synthesis/fabrication methods of Ga(X)N/Si nanoarchitecture, primarily focusing on explaining the suitability as an ideal platform for sunlight-powered water splitting toward green hydrogen fuel. In addition, it exclusively summarizes the recent progress and development of Ga(X)N/Si nanoarchitecture for photocatalytic and photoelectrochemical water splitting. Moreover, it describes the challenges and prospects of artificial photosynthesis integrated device and system using Ga(X)N/Si nanoarchitectures for solar water splitting toward hydrogen.

关键词: Ga(X)N/Si nanoarchitecture     artificial photosynthesis     water splitting     solar toward hydrogen    

我国半导体硅片发展现状与展望

张果虎,肖清华,马飞

《中国工程科学》 2023年 第25卷 第1期   页码 68-78 doi: 10.15302/J-SSCAE-2023.01.002

摘要:

硅片是半导体关键的基础材料,我国半导体硅片对外依存度较高,增强硅片的自主保障能力,对提升我国半导体产业整体水平至关重要。本文重点围绕市场主流的8 in、12 in硅片,分析了全球半导体硅片的技术和产业发展现状,研判了全球半导体硅片产业未来的发展趋势,重点分析了我国半导体硅片的发展现状,指出我国半导体硅片在当前市场需求、宏观政策、配套能力、研发投入等利好因素下迎来难得的发展机遇,同时提出我国半导体硅片产业发展面临挑战,在此基础上,从进一步加强顶层设计和宏观规划、强化政策落实和政策持续性、协调支持产业链协同发展、布局研发集成电路先进制程用半导体硅片等方面提出对策建议,以期为推动我国半导体硅片向更高质量发展提供参考。

关键词: 半导体硅片;8 in;12 in;产业协同;先进制程    

受疫情影响的半导体供应链危机

Mitch Leslie

《工程(英文)》 2022年 第9卷 第2期   页码 10-12 doi: 10.1016/j.eng.2021.12.006

Structural and optical properties of nanostructured copper sulfide semiconductor synthesized in an industrial

Marcela Achimovičová, Erika Dutková, Erika Tóthová, Zdenka Bujňáková, Jaroslav Briančin, Satoshi Kitazono

《化学科学与工程前沿(英文)》 2019年 第13卷 第1期   页码 164-170 doi: 10.1007/s11705-018-1755-2

摘要:

Chalcogenide nanostructured semiconductor, copper sulfide (CuS) was prepared from copper and sulfur powders in stoichiometric ratio by a simple, fast, and convenient one-step mechanochemical synthesis after 40 min of milling in an industrial eccentric vibratory mill. The kinetics of the mechanochemical synthesis and the influence of the physical properties of two Cu powder precursor types on the kinetics were studied. The crystal structure, physical properties, and morphology of the product were characterized by X-ray diffraction (XRD), the specific surface area measurements, particle size distribution and scanning electron microscopy. The XRD analysis confirmed the hexagonal crystal structure of the product-CuS (covellite) with the average size of the crystallites 11 nm. The scanning electron microscopy analysis has revealed that the agglomerated grains have a plate-like structure composed of CuS nanoparticles. The thermal analysis was performed to investigate the thermal stability of the mechanochemically synthesized CuS. The optical properties were studied using UV-Vis and photoluminescence spectroscopy. The determined optical band gap energy 1.80 eV responds to the value of the bulk CuS, because of agglomerated nanoparticles. In addition, a mechanism of CuS mechanochemical reaction was proposed, and the verification of CuS commercial production was performed.

关键词: copper sulfide     industrial mechanochemical synthesis     thermal analysis     optical properties    

基于半导体纳米晶体的神经突触器件 Review

步明轩1,2,王越1,2,尹蕾1,2,童周禹1,2,张懿强3,杨德仁1,2,4,5,皮孝东1,2,4,5

《信息与电子工程前沿(英文)》 2022年 第23卷 第11期   页码 1579-1601 doi: 10.1631/FITEE.2100551

摘要:

近年来,人们对信息处理的需求日益增长,脑启发式神经形态器件得到了广泛的关注。突触器件作为一类重要的神经形态器件,在短短几年内迅速升温。在用于制备突触器件的各种材料中,半导体纳米晶体(NCs)因其优异的电学和光学性能而成为首选材料之一。本综述论文首先介绍了基于半导体纳米晶体的突触器件的研究背景及半导体纳米晶体的基本性质。然后,根据器件有源层所用纳米晶体种类的不同,分类介绍了基于纳米晶体的突触器件的最新研究进展。最后,讨论了基于半导体纳米晶体的突触器件目前仍面临的问题和挑战。

关键词: 半导体纳米晶体;突触器件;神经形态计算    

几种新体制半导体激光器及相关产业的现状、挑战和思考

韦欣,李明,李健,汪超,李川川

《中国工程科学》 2020年 第22卷 第3期   页码 21-28 doi: 10.15302/J-SSCAE-2020.03.004

摘要:

半导体激光器产业体量大、辐射和带动能力强,作为激光器工业的基础,被广泛应用在光通信、光信息处理、新型加工、激光显示、生物和医学传感等工业、军事和消费生活领域。为了适应逐渐扩大的应用范围,满足不同应用场景所提出的新要求,半导体激光器领域近年来通过学科交叉渗透不断地引入了各种新机制、新概念以及新结构,大大优化了其波长覆盖范围、光束质量、器件体积和功耗、调制速度以及输出功率。本文通过对比几种新型激光器的物理内涵、结构设计及制备手段,介绍了几种应用前景广泛且发展势头强劲的半导体激光器。结合我国相关产业的发展现状指出,半导体激光器产业的发展仍然应与应用紧密结合,通过市场和强大的系统开发能力闭环优化器件性能,提升核心技术,通过交叉学科融通不断引入新概念、新结构和新工艺。同时,结合国内政策导向优势,在垂直外腔面发射激光器、微纳结构激光器以及拓扑绝缘体激光器等几个发展势头强劲的新型激光技术中加大投入,进行批量生产和可控制备研发,力争在国际相关领域的竞争中抢占战术制高点。

关键词: 半导体激光器,光泵浦垂直外腔面发射激光器,纳米激光器,拓扑绝缘体激光器    

Cystine-assisted accumulation of gold nanoparticles on ZnO to construct a sensitive surface-enhanced Raman spectroscopy substrate

《化学科学与工程前沿(英文)》 2023年 第17卷 第1期   页码 15-23 doi: 10.1007/s11705-022-2177-8

摘要: Recently, various semiconductor/metal composites have been developed to fabricate surface-enhanced Raman spectroscopy substrates. However, low metal loading on semiconductors is still a challenge. In this study, cystine was introduced to increase the accumulation of gold nanoparticles on zinc oxide, owing to the biomineralization property of cystine. Morphological analysis revealed that the obtained ZnO/Au/cystine composite not only had a higher metal loading but also formed a porous structure, which is beneficial for Raman performance. Compared with ZnO/Au, the ZnO/Au/cystine substrate displayed a 40-fold enhancement in the Raman signal and a lower limit of detection (10–11 mol·L−1) in the detection of rhodamine 6G. Moreover, the substrate has favorable homogeneity and stability. Finally, ZnO/Au/cystine displayed excellent performance toward crystal violet and methylene blue in a test based on river water samples. This study provided a promising method to fabricate sensitive semiconductor/noble metal-based surface-enhanced Raman spectroscopy substrates for Raman detection.

关键词: biomineralization     cystine     semiconductor/metal composite     SERS detection     Raman detection    

Ultrasonic linear motor using the L-B mode Langevin transducer with an exponential horn

SHI Shengjun, CHEN Weishan, LIU Junkao, ZHAO Xuetao

《机械工程前沿(英文)》 2008年 第3卷 第2期   页码 212-217 doi: 10.1007/s11465-008-0026-1

摘要: An ultrasonic linear motor is proposed and fabricated by using the longitudinal and bending vibration double mode bolt-clamped Langevin type transducer to meet high power and speed requirements in the aerospace and semiconductor ind

关键词: longitudinal     vibration     bolt-clamped     semiconductor     ultrasonic    

标题 作者 时间 类型 操作

Recent advances of hydrogen production through particulate semiconductor photocatalytic overall water

期刊论文

Advantageous mechanochemical synthesis of copper(I) selenide semiconductor, characterization, and properties

期刊论文

Liquid metal printing opening the way for energy conservation in semiconductor manufacturing industry

期刊论文

中国先进半导体材料及辅助材料发展战略研究

“先进半导体材料及辅助材料”编写组

期刊论文

Novel slack-based robust scheduling rule for a semiconductor manufacturing system with uncertain processing

Juan LIU, Fei QIAO, Yumin MA, Weichang KONG

期刊论文

Developments in semiconductor thermoelectric materials

Laifeng LI, Zhen CHEN, Min ZHOU, Rongjin HUANG

期刊论文

Ga(X)N/Si nanoarchitecture: An emerging semiconductor platform for sunlight-powered water splitting toward

期刊论文

我国半导体硅片发展现状与展望

张果虎,肖清华,马飞

期刊论文

受疫情影响的半导体供应链危机

Mitch Leslie

期刊论文

Structural and optical properties of nanostructured copper sulfide semiconductor synthesized in an industrial

Marcela Achimovičová, Erika Dutková, Erika Tóthová, Zdenka Bujňáková, Jaroslav Briančin, Satoshi Kitazono

期刊论文

基于半导体纳米晶体的神经突触器件

步明轩1,2,王越1,2,尹蕾1,2,童周禹1,2,张懿强3,杨德仁1,2,4,5,皮孝东1,2,4,5

期刊论文

几种新体制半导体激光器及相关产业的现状、挑战和思考

韦欣,李明,李健,汪超,李川川

期刊论文

Cystine-assisted accumulation of gold nanoparticles on ZnO to construct a sensitive surface-enhanced Raman spectroscopy substrate

期刊论文

Ultrasonic linear motor using the L-B mode Langevin transducer with an exponential horn

SHI Shengjun, CHEN Weishan, LIU Junkao, ZHAO Xuetao

期刊论文

Han Huang:Deformation and Removal of Semiconductor and Laser Crystals at Extremely Small Scales(2019年

2021年04月23日

会议视频