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Mechanical properties of stabilized artificial organic soil

XU Riqing, GUO Yin, LIU Zengyong

《结构与土木工程前沿(英文)》 2008年 第2卷 第2期   页码 161-165 doi: 10.1007/s11709-008-0023-9

摘要: In order to study the influence of organic matter on the mechanical properties of stabilized soil and the effect of XGL2005 on stabilizing organic soil, unconfined compressive strength tests were carried out. Test results indicated that the strength of stabilized soil decreased in the form of a logarithmic function as the organic matter content increased. In contrast, the strength increased in the form of a power function as the content of the stabilization agent increased. The strength of cement stabilized organic soil was reinforced greatly by adding the stabilizer XGL2005. Based on the law obtained from the test, a strength prediction model was established by regression analysis. The model included the influence of the curing time, the content of the cement, the organic matter content and the stabilization agent on the strength of stabilized soil.

关键词: compressive strength     stabilized     stabilization     regression analysis     stabilizer XGL2005    

Biopolymer-stabilized emulsions on the basis of interactions between β -lactoglobulin and ι -carrageenan

Qiaomei RU, Younghee CHO, Qingrong HUANG,

《化学科学与工程前沿(英文)》 2009年 第3卷 第4期   页码 399-406 doi: 10.1007/s11705-009-0253-y

摘要: -Carrageenan and -lactoglobulin (-lg) stabilized oil-in-water (O/W) emulsions, which can be used for the oral administration of bioactive but environmentally sensitive ingredients, have been successfully prepared. The effects of protein/polysaccharide ratios, total biopolymer concentration, environmental stress (thermal processing and sonication), and pH on the complex formation between -carrageenan and -lactoglobulin have been investigated. We found that -lactoglobulin and-carrageenan stabilized emulsions can be formed at pH values of 6.0, 4.0, and 3.4. However, the microstructures of emulsions stabilized by -lactoglobulin and -carrageenan was identified by optical microscopy, and it indicated that the emulsion prepared at pH 6.0 flocculated more extensively, while its hydrodynamic radius was much bigger than those prepared at pH 4.0 and 3.4. Regarding rheological properties, the emulsion of pH 6.0 showed a more solid-like behavior but with a lower viscosity than those of pH 4.0 and 3.4. The optimum concentration ranges for -lg and-carrageenan to form stable emulsions at pH 4.0 and 3.4 were 0.3wt-%―0.6wt-% and 0.4wt-%―0.7wt-%, respectively.

High-precision gyro-stabilized control of a gear-driven platform with a floating gear tension device

《机械工程前沿(英文)》 2021年 第16卷 第3期   页码 487-503 doi: 10.1007/s11465-021-0635-5

摘要: This study presents an improved compound control algorithm that substantially enhances the anti-disturbance performance of a gear-drive gyro-stabilized platform with a floating gear tension device. The tension device can provide a self-adjustable preload to eliminate the gap in the meshing process. However, the weaker gear support stiffness and more complex meshing friction are also induced by the tension device, which deteriorates the control accuracy and the ability to keep the aim point of the optical sensors isolated from the platform motion. The modeling and compensation of the induced complex nonlinearities are technically challenging, especially when base motion exists. The aim of this research is to cope with the unmeasured disturbances as well as the uncertainties caused by the base lateral motion. First, the structural properties of the gear transmission and the friction-generating mechanism are analyzed, which classify the disturbances into two categories: Time-invariant and time-varying parts. Then, a proportional-integral controller is designed to eliminate the steady-state error caused by the time-invariant disturbance. A proportional multiple-integral-based state augmented Kalman filter is proposed to estimate and compensate for the time-varying disturbance that can be approximated as a polynomial function. The effectiveness of the proposed compound algorithm is demonstrated by comparative experiments on a gear-drive pointing system with a floating gear tension device, which shows a maximum 76% improvement in stabilization precision.

关键词: inertially stabilized platform     floating gear tension device     nonlinear friction     disturbance compensation     proportional multiple-integral observer    

Characteristics of the stabilized/solidified municipal solid wastes incineration fly ash and the leaching

Yan SHAO,Haobo HOU,Guangxing WANG,Sha WAN,Min ZHOU

《环境科学与工程前沿(英文)》 2016年 第10卷 第1期   页码 192-200 doi: 10.1007/s11783-014-0719-0

摘要: Fly ash is a hazardous byproduct of municipal solid wastes incineration (MSWI). An alkali activated blast furnace slag-based cementitious material was used to stabilize/solidify the fly ash at experimental level. The characteristics of the stabilized/solidified fly ash, including metal leachability, mineralogical characteristics and the distributions of metals in matrices, were tested by toxic characteristic leaching procedure (TCLP), X-ray diffraction (XRD) and scanning electron microscopy-energy dispersive spectrometer (SEM-EDS) respectively. Continuous acid extraction was utilized to extract metal ions and characterize their leaching behavior. The stabilization/solidification procedure for MSWI fly ash demonstrates a strong fixing capacity for the metals by the formation of C-S-H phase, hydrated calcium aluminosilicate and ettringite. The stabilized/solidified fly ash shows a dense and homogeneous microstructure. Cr is mainly solidified in hydrated calcium aluminosilicate, C-S-H and ettringite phase through physical encapsulation, precipitation, adsorption or substitution mechanisms, and Pb is mainly solidified in C-S-H phase and absorbed in the Si-O structure.

关键词: municipal solid waste incineration (MSWI) fly ash     blast furnace slag     leaching behavior     Cr     Pb    

Remediation of soil and groundwater contaminated with organic chemicals using stabilized nanoparticles

Zhengqing Cai, Xiao Zhao, Jun Duan, Dongye Zhao, Zhi Dang, Zhang Lin

《环境科学与工程前沿(英文)》 2020年 第14卷 第5期 doi: 10.1007/s11783-020-1263-8

摘要: Abstract ▪ Overviewed evolution and environmental applications of stabilized nanoparticles. ▪ Reviewed theories on particle stabilization for enhanced reactivity/deliverability. ▪ Examined various in situ remediation technologies based on stabilized nanoparticles. ▪ Summarized knowledge on transport of stabilized nanoparticles in porous media. ▪ Identified key knowledge gaps and future research needs on stabilized nanoparticles. Due to improved soil deliverability and high reactivity, stabilized nanoparticles have been studied for nearly two decades for in situ remediation of soil and groundwater contaminated with organic pollutants. While large amounts of bench- and field-scale experimental data have demonstrated the potential of the innovative technology, extensive research results have also unveiled various merits and constraints associated different soil characteristics, types of nanoparticles and particle stabilization techniques. Overall, this work aims to critically overview the fundamental principles on particle stabilization, and the evolution and some recent developments of stabilized nanoparticles for degradation of organic contaminants in soil and groundwater. The specific objectives are to: 1) overview fundamental mechanisms in nanoparticle stabilization; 2) summarize key applications of stabilized nanoparticles for in situ remediation of soil and groundwater contaminated by legacy and emerging organic chemicals; 3) update the latest knowledge on the transport and fate of stabilized nanoparticles; 4) examine the merits and constraints of stabilized nanoparticles in environmental remediation applications; and 5) identify the knowledge gaps and future research needs pertaining to stabilized nanoparticles for remediation of contaminated soil and groundwater. Per instructions of this invited special issue, this review is focused on contributions from our group (one of the pioneers in the subject field), which, however, is supplemented by important relevant works by others. The knowledge gained is expected to further advance the science and technology in the environmental applications of stabilized nanoparticles.

关键词: Stabilized nanoparticle     In-situ remediation     Organic contaminant     Soil remediation     Groundwater     Fate and transport    

Effect of polymer structures on electro-optical properties of polymer stabilized liquid crystal films

WANG Shoulian, HE Jie, ZENG Yu, YAN Bin, WANG Yinghan

《化学科学与工程前沿(英文)》 2008年 第2卷 第3期   页码 265-268 doi: 10.1007/s11705-008-0054-8

摘要: The polymer stabilized liquid crystal (PSLC) film is a relatively novel electro-optical material, which is generally obtained by dissolving a small amount of a bifunctional photoreactive monomer in a low molecular mass liquid crystal. In this paper, the PSLC films were prepared with photoreactive biphenyl methacrylate monomers by photopolymerization induced phase separation. The effects of liquid crystal concentration, curing time, monomer structures and alignment layer on the electro-optical properties of PSLC films were investigated. The results show that the transmittance in the OFF state () increased with the liquid crystal concentration, but the driving voltage decreased. was also influenced by the curing time. Furthermore, when polyimide was used as alignment layer, the films prepared from the bifunctional monomer shows a higher T, while those from the single functional monomer exhibited a deformed electro-optical curve due to the unsteady polymer networks.

Structural characteristics of cement-stabilized soil bases with 3D finite element method

Yunfeng PENG, Yunlong HE,

《结构与土木工程前沿(英文)》 2009年 第3卷 第4期   页码 428-434 doi: 10.1007/s11709-009-0059-5

摘要: Cement-stabilized soil bases have been widely used in expressways due to its high strength, appropriate stiffness, good water resistance, and frost resistance. So far, the structural characteristics and mechanical behaviors of cement-stabilized soil bases were not investigated so much. In this paper, the 3D elastic-plastic finite element method (FEM) was used to analyze the mechanical behaviors and structural characteristics of cement-stabilized soil bases from construction to operation. The pavement filling and the traffic loading processes were simulated, and a contact model was used to simulate the contact behavior between each layer of the pavement. Considering the construction process, the structural characteristics and mechanical behaviors of cement-stabilized soil bases were studied under asphalt-concrete pavement conditions. Furthermore, the general rules of deformations and stresses in cement-stabilized soil bases under different conditions were discussed, and some suggestions were put forward for the design and construction of cement-stabilized soil bases.

关键词: different     strength     asphalt-concrete pavement     FEM     appropriate stiffness    

Unconfined compressive strength prediction of soils stabilized using artificial neural networks and support

Alireza TABARSA, Nima LATIFI, Abdolreza OSOULI, Younes BAGHERI

《结构与土木工程前沿(英文)》 2021年 第15卷 第2期   页码 520-536 doi: 10.1007/s11709-021-0689-9

摘要: This study aims to improve the unconfined compressive strength of soils using additives as well as by predicting the strength behavior of stabilized soils using two artificial-intelligence-based models. The soils used in this study are stabilized using various combinations of cement, lime, and rice husk ash. To predict the results of unconfined compressive strength tests conducted on soils, a comprehensive laboratory dataset comprising 137 soil specimens treated with different combinations of cement, lime, and rice husk ash is used. Two artificial-intelligence-based models including artificial neural networks and support vector machines are used comparatively to predict the strength characteristics of soils treated with cement, lime, and rice husk ash under different conditions. The suggested models predicted the unconfined compressive strength of soils accurately and can be introduced as reliable predictive models in geotechnical engineering. This study demonstrates the better performance of support vector machines in predicting the strength of the investigated soils compared with artificial neural networks. The type of kernel function used in support vector machine models contributed positively to the performance of the proposed models. Moreover, based on sensitivity analysis results, it is discovered that cement and lime contents impose more prominent effects on the unconfined compressive strength values of the investigated soils compared with the other parameters.

关键词: unconfined compressive strength     artificial neural network     support vector machine     predictive models     regression    

hydrogenation of halogenated nitrobenzenes over metal–organic-framework-derived ultra-dispersed Ni stabilized

《化学科学与工程前沿(英文)》 2022年 第16卷 第12期   页码 1782-1792 doi: 10.1007/s11705-022-2220-9

摘要: Ultra-dispersed Ni nanoparticles (7.5 nm) on nitrogen-doped carbon nanoneedles (Ni@NCNs) were prepared by simple pyrolysis of Ni-based metal–organic-framework for selective hydrogenation of halogenated nitrobenzenes to corresponding anilines. Two different crystallization methods (stirring and static) were compared and the optimal pyrolysis temperature was explored. Ni@NCNs were systematically characterized by wide analytical techniques. In the hydrogenation of p-chloronitrobenzene, Ni@NCNs-600 (pyrolyzed at 600 °C) exhibited extraordinarily high performance with 77.9 h–1 catalytic productivity and > 99% p-chloroaniline selectivity at full p-chloronitrobenzene conversion under mild conditions (90 °C, 1.5 MPa H2), showing obvious superiority compared with reported Ni-based catalysts. Notably, the reaction smoothly proceeded at room temperature with full conversion and > 99% selectivity. Moreover, Ni@NCNs-600 afforded good tolerance to various nitroarenes substituted by sensitive groups (halogen, nitrile, keto, carboxylic, etc.), and could be easily recycled by magnetic separation and reused for 5 times without deactivation. The adsorption tests showed that the preferential adsorption of –NO2 on the catalyst can restrain the dehalogenation of p-chloronitrobenzene, thus achieving high p-chloroaniline selectivity. While the high activity can be attributed to high Ni dispersion, special morphology, and rich pore structure of the catalyst.

关键词: halogenated nitrobenzenes     room-temperature hydrogenation     Ni nanoparticles     nitrogen-doped carbon nanoneedles     metal–organic-framework    

Crushed rocks stabilized with organosilane and lignosulfonate in pavement unbound layers: Repeated load

Diego Maria BARBIERI, Inge HOFF, Chun-Hsing HO

《结构与土木工程前沿(英文)》 2021年 第15卷 第2期   页码 412-424 doi: 10.1007/s11709-021-0700-5

摘要: The creation of the new “Ferry-Free Coastal Highway Route E39” in southwest Norway entails the production of a remarkable quantity of crushed rocks. These resources could be beneficially employed as aggregates in the unbound courses of the highway itself or other road pavements present nearby. Two innovative stabilizing agents, organosilane and lignosulfonate, can significantly enhance the key properties, namely, resilient modulus and resistance against permanent deformation, of the aggregates that are excessively weak in their natural state. The beneficial effect offered by the additives was thoroughly evaluated by performing repeated load triaxial tests. The study adopted the most common numerical models to describe these two key mechanical properties. The increase in the resilient modulus and reduction in the accumulated vertical permanent deformation show the beneficial impact of the additives. Furthermore, a finite element model was created to simulate the repeated load triaxial test by implementing nonlinear elastic and plastic constitutive relationships.

关键词: organosilane     lignosulfonate     crushed rocks     pavement unbound layers     repeated load triaxial test     finite element analysis    

Modeling of unconfined compressive strength of soil-RAP blend stabilized with Portland cement using multivariate

Ali Reza GHANIZADEH, Morteza RAHROVAN

《结构与土木工程前沿(英文)》 2019年 第13卷 第4期   页码 787-799 doi: 10.1007/s11709-019-0516-8

摘要: The recycled layer in full-depth reclamation (FDR) method is a mixture of coarse aggregates and reclaimed asphalt pavement (RAP) which is stabilized by a stabilizer agent. For design and quality control of the final product in FDR method, the unconfined compressive strength of stabilized material should be known. This paper aims to develop a mathematical model for predicting the unconfined compressive strength (UCS) of soil-RAP blend stabilized with Portland cement based on multivariate adaptive regression spline (MARS). To this end, two different aggregate materials were mixed with different percentages of RAP and then stabilized by different percentages of Portland cement. For training and testing of MARS model, total of 64 experimental UCS data were employed. Predictors or independent variables in the developed model are percentage of RAP, percentage of cement, optimum moisture content, percent passing of #200 sieve, and curing time. The results demonstrate that MARS has a great ability for prediction of the UCS in case of soil-RAP blend stabilized with Portland cement ( is more than 0.97). Sensitivity analysis of the proposed model showed that the cement, optimum moisture content, and percent passing of #200 sieve are the most influential parameters on the UCS of FDR layer.

关键词: full-depth reclamation     soil-reclaimed asphalt pavement blend     Portland cement     unconfined compressive strength     multivariate adaptive regression spline    

Effect of earth reinforcement, soil properties and wall properties on bridge MSE walls

《结构与土木工程前沿(英文)》 2021年 第15卷 第5期   页码 1209-1221 doi: 10.1007/s11709-021-0764-2

摘要: Mechanically stabilized earth (MSE) retaining walls are popular for highway bridge structures. They have precast concrete panels attached to earth reinforcement. The panels are designed to have some lateral movement. However, in some cases, excessive movement and even complete dislocation of the panels have been observed. In this study, 3-D numerical modeling involving an existing MSE wall was undertaken to investigate various wall parameters. The effects of pore pressure, soil cohesion, earth reinforcement type and length, breakage/slippage of reinforcement and concrete strength, were examined. Results showed that the wall movement is affected by soil pore pressure and reinforcement integrity and length, and unaffected by concrete strength. Soil cohesion has a minor effect, while the movement increased by 13–20 mm for flexible geogrid reinforced walls compared with the steel grid walls. The steel grid stresses were below yielding, while the geogrid experienced significant stresses without rupture. Geogrid reinforcement may be used taking account of slippage resistance and wall movement. If steel grid is used, non-cohesive soil is recommended to minimize corrosion. Proper soil drainage is important for control of pore pressure.

关键词: mechanically stabilized earth walls     precast concrete panels     backfill soil     finite element modeling     earth reinforcement    

NIM的微波-光学频率基准研究——复现米和秒定义

李天初

《中国工程科学》 2007年 第9卷 第6期   页码 27-31

摘要:

报道中国计量科学研究院(NIM)在微波-光学频率计量研究的新进展:用NIM4激光冷却-铯原子 喷泉钟复现国际单位制(SI)时间单位秒(s),用飞秒(FS)光学频率梳间接复现长度单位米(m)并标定稳频 激光波长实际实施米定义。NIM4铯原子喷泉钟的不确定度达到5×10-15,飞秒(FS)光梳锁定到NIM4钟控制的 氢钟后,其频率不确定度为2.2×10-14。在此基础上讨论铯原子喷泉钟、稳频激光、FS光梳的作用、意义和相互 关系。最后简要介绍NIM5铯原子喷泉钟的研究进展和2006年起NIM立题研制锶原子存储

关键词: 计量     频率基准     稳频激光     铯原子喷泉钟     飞秒光梳    

Brazing of ceramic-to-ceramic and ceramic-to-metal joints in air

Kirsten BOBZIN, Thomas SCHLAEFER, Lidong ZHAO, Nils KOPP, Arne SCHLEGEL

《机械工程前沿(英文)》 2010年 第5卷 第2期   页码 125-129 doi: 10.1007/s11465-010-0007-z

摘要: Reactive air brazing (RAB) is an emerging technology for the production of ceramic-to-ceramic and ceramic-to-metal joints. In this study, RAB was investigated with respect to the potential applications for solid oxide fuel cells (SOFCs) as one example of use. It was found that alumina could be well brazed by RAB with AgCu and AgCuTi brazes. Both braze composition and brazing temperature influenced significantly the wetting behavior and their mechanism of wetting. AgCu and AgCuTi braze alloys could also be used to produce brazed joints with the SOFC materials ceramic yttria stabilized zirconia and steel X1CrTiLa22. However, CuO reacts with the steel, forming a brittle oxide layer on the steel surface, which is undesirable for SOFC applications. The first trials with Ag0.5Al showed a promising solution.

关键词: reactive air brazing (RAB)     X1CrTiLa22     Al2O3     yttria stabilized zirconia (YSZ)     solid oxide fuel cell (SOFC)    

Preparation and characterization of nanocrystalline ZrO2-7%Y2O3 powders for thermal barrier coatings by high-energy ball milling

Kirsten BOBZIN, Lidong ZHAO, Thomas SCHLAEFER, Thomas WARDA

《机械工程前沿(英文)》 2011年 第6卷 第2期   页码 176-181 doi: 10.1007/s11465-011-0220-4

摘要:

High-energy ball milling is an effective method to produce nanocrystalline oxides. In this study, a conventional ZrO2-7%Y2O3spray powder was ball-milled to produce nanocrystalline powders with high levels of crystalline disorders for deposition of thermal barrier coatings. The powder was milled both with 100Cr6 steel balls and with ZrO2-3%Y2O3 ceramic balls as grinding media. The milling time was varied in order to investigate the effect of the milling time on the crystallite size. The powders were investigated in terms of their crystallite sizes and morphologies by X-ray diffraction analysis (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results show that under given milling conditions the powder was already nanostructured after 40 min milling. The crystallite size decreased significantly with increasing milling time within first 120 min. After that, a further increase of milling time did not lead to a significant reduction of the crystallite size. Ball-milling led to lattice microstrains. Milling with the steel balls resulted in finer nano-sized crystal grains, but caused the contamination of the powder. The nano-sized crystal grains coarsened during the heat-treatment at 1250°C.

关键词: nanostrucured powders     yttria stabilized zirconia (YSZ)     high-energy ball milling     thermal barrier coatings    

标题 作者 时间 类型 操作

Mechanical properties of stabilized artificial organic soil

XU Riqing, GUO Yin, LIU Zengyong

期刊论文

Biopolymer-stabilized emulsions on the basis of interactions between β -lactoglobulin and ι -carrageenan

Qiaomei RU, Younghee CHO, Qingrong HUANG,

期刊论文

High-precision gyro-stabilized control of a gear-driven platform with a floating gear tension device

期刊论文

Characteristics of the stabilized/solidified municipal solid wastes incineration fly ash and the leaching

Yan SHAO,Haobo HOU,Guangxing WANG,Sha WAN,Min ZHOU

期刊论文

Remediation of soil and groundwater contaminated with organic chemicals using stabilized nanoparticles

Zhengqing Cai, Xiao Zhao, Jun Duan, Dongye Zhao, Zhi Dang, Zhang Lin

期刊论文

Effect of polymer structures on electro-optical properties of polymer stabilized liquid crystal films

WANG Shoulian, HE Jie, ZENG Yu, YAN Bin, WANG Yinghan

期刊论文

Structural characteristics of cement-stabilized soil bases with 3D finite element method

Yunfeng PENG, Yunlong HE,

期刊论文

Unconfined compressive strength prediction of soils stabilized using artificial neural networks and support

Alireza TABARSA, Nima LATIFI, Abdolreza OSOULI, Younes BAGHERI

期刊论文

hydrogenation of halogenated nitrobenzenes over metal–organic-framework-derived ultra-dispersed Ni stabilized

期刊论文

Crushed rocks stabilized with organosilane and lignosulfonate in pavement unbound layers: Repeated load

Diego Maria BARBIERI, Inge HOFF, Chun-Hsing HO

期刊论文

Modeling of unconfined compressive strength of soil-RAP blend stabilized with Portland cement using multivariate

Ali Reza GHANIZADEH, Morteza RAHROVAN

期刊论文

Effect of earth reinforcement, soil properties and wall properties on bridge MSE walls

期刊论文

NIM的微波-光学频率基准研究——复现米和秒定义

李天初

期刊论文

Brazing of ceramic-to-ceramic and ceramic-to-metal joints in air

Kirsten BOBZIN, Thomas SCHLAEFER, Lidong ZHAO, Nils KOPP, Arne SCHLEGEL

期刊论文

Preparation and characterization of nanocrystalline ZrO2-7%Y2O3 powders for thermal barrier coatings by high-energy ball milling

Kirsten BOBZIN, Lidong ZHAO, Thomas SCHLAEFER, Thomas WARDA

期刊论文